i ’ . SOALAN RAMALAN 2015 (501362) CHEMISTRY Kertas 2 Dua jam tiga puluh minit 1. Kertas soalan ini adalah dalam dwibahasa. 2. Soalan dalam bahasa Inggeris mendahului soalan yang sepadan dalam bahasa Melayu, 3. Calon dibenarkan menjawab keseluruhan atau sebahagian soalan sama ada dalam bahasa Inggeris atau bahasa Melayu. 4, Calon dikehendaki membaca maklumat di halaman 4, © 2015 Hak Cipta Adabi Gaya Pos Sdn. Bhd.cuemsray paren 2*SPM a rusian 4 = SOALAN RAMALAN 2015. IIH IN FOR CANDIDATES MATIO) LAE UK CALON MAKLUMAT UNT ons: Section A, Section B and This question paper consists of three secti agian B dan Bahagian C. Section C. Kertas soalan ini mengandungi tiga bahagian: Bahagian 4, Ba i ion Aint Answer all questions in Section A. Write your answers for Section the spaces provided in this question paper. Jawab ce soalan dalam Bahagian A. Tulis jawapan anda bagi Bahagian A pada ruang yang disediakan dalam kertas soalan. any one question from ion from Section B and Answer any one question fr tables, graphs and other Section C. You may use equations, diagrams, suitable methods to explain your answers. / Jawab mana-mana satu soalan daripada Bakagian B dan mana-mana satu soalan daripada Bahagian C. Anda boleh menggunakan persamaan, rajah, jadual, graf dan cara lain yang sesuai untuk menjelaskan jawapan anda, The diagrams in the questions are not drawn to scale unless stated. Rajah yang mengiringi soalan tidak dilukis mengikut skala kecuali dinyatakan. Marks allocated for each question or sub-part of a question are shown. in brackets. Markah yang diperuntukkan bagi setiap soalan atau ceraian soalan ditunjukkan dalam kurungan. Show your working. It may help you to get marks. Tunjukkan kerja mengira. Ini membantu anda mendapatkan markah. If you wish to change your answer, cross out the answer that you have done. Then write down the new answer. Jka anda hendak menukar jawapan, batatkan jawapan yang telah dibuat. Kemudian tulis jawapan yang baharu. You may use a scientific calculator. Anda dibenarkan menggunakan kalkulator saintifik, You are advised to spend 90 mi 1A minutes to answer questions i Aa I s estions in Section A, 30 minutes for Section B and 30 minutes for Section Cc et Anda dinasihati supaya mengambil masa 90 minit untuk menjawab soalan del ‘init untuk Bahagian B dan 30 minit untuk Bahagian C. " [2] dalam Bahagian A, 30‘SOALAN RAMALAN 2015 cHemistey paper 2*SPM w puinan 4 s> Section A [60 marks) Answer all questions in this section, ‘Jawab semua soclan dalam bahagian in 1. Diagram 1 shows the apparatus set-up for the neutral: Potassium hydroxide solution for preparation of salt X. Rajah 1 menunjubkan susunanrades bagi tindak bles peneutrolanantaracsi nitik den laruton klum hidroksido agi penyediaan garam X. between facid and 20.0 cm? of 0.5 mol dm? nitric acid 20.0 cm? asid nitrik 0.5 mol dm? 20.0 cm? of 0.5 mol dm? potassium hydroxide solution + phenolphtalein indicator 20.0 em? loruton kalium hidroksida (0.5 mol dm + penunjuk fenolftalein Diagram 1 (@ State the colour change of the solution in the conical flask at the end point. Nyotaken perubahan watha b29ierutan di dalam kelalang kon pada taket akhin. [1 mark] (>) @ State the name/of salt X. ‘Nyatakan nama bagi garam X. “{ mark) Ye a chemical equation for the reaction. rafskan persamacn kimia bagi tindak balas itu. [2 marks} Gi) Calculate the maximum mass of salt X formed. [Relative atomic mass : K: 39, N: 14, 0: 16] Hitung jim moksimum garam X yang terbentuk Egisim atom Relatif :K :39,N 14,0 :16) : [3 marks]\MALAN 2015 III cuemisrry paper 2*SPM a puman 4 SOALAN RA > different types of strong acid fF two (©) Table 1 shows the concentration and volume 0} 5 mol dm potassium hydroxide ‘Mand N which are used to neutralise 20.0 cm? of 0. solution. ‘Jadual | menunjukkan kepekaton dan isi padu dua jenis 0 untuk meneutalkon 20.0 em’ larutan kali hidroksida 0.5 mol J sid kuot yang berfainan M dan, yang digunakan Concentration Kepekaton ' Based on the information in Table 1, identify acid M Berdasarkan meklumat dalom Jadual 1, kenal posti asid M dan asid N. [2 marks} Copper P. Copper Q Kuprum® KuprumQ Zine sulphate ue US - a oa iter Copper({1) sulphate Kaprum(21) sulfat Copper(II) sulphate Kuprun({D) sulfat Cell I 7 Cell IT seit SelIr Diagram 2SOALAN RAMALAN 2015, CHEmisTRY PAPER 2° SPM mw piuinan 1 iil (For the reaction in Cell 1, Bogi tndak balas Sel T, (i) State the energy change. Nyatakan perubohan tenaga State one observation, Nyatakan satu pemerhatian () Identify the negative terminal of : Tentukan terminal negatf bagi: Cell (seit): Cell IT (seit) [2 marks] (©) For the reaction that occurs in Cell IT: Bagi tindak balas yang berloky di Sel TZ (What is the function of thi Avakah fungsipasu berliang? [1 mark} (ii) State one observation, Nyatokan setu ii) Write the dvergll ionic equation for the reaction. Tuliskan persamean ion keseluruhan bogi tidak bales itu . (1 mark] @ ine CleGFrode and zine sulphate solution in Cell IT are replaced by iron electrodenein vveaper 2°SPM a piLinan 1 SOALAN RAMALAN 2018 IIIB CHEMISTR +t of the Periodic Table of Elements. 3. Diagram 3 shows por! symbol of the elements. DEG L, Mand J do not represent the octid a ian dori Jadual Berka Unsur Rajah 3 menunjukkan seboho yr bagi unsur. .€,6,L,M danZ tidak menunjukken simbol sebenai Diagram 3 Using letters given in the Periodic Table of the El Biagram 3, answer the following questions: Dengan menggunakon huruf yang diberikan dalam Jadual Berkala Unsur 3 berikut: fom Rajah 3, jawab soalan-scalan (@) State the position of element E in the Periodic Table. [Nyatakan kedudukan unsur € delom jadual Berkala Unsur. {1 mark} (b) Choose element which exhibit differen? oxidation numbers in its compounds. Pilih unsur yang menunjukkan nombor pengoksMacn yang berbeza dolam sebatianny {1 mark) (© Element D combines withylement L to form a compound. [2 marks] (©) Gnd E have the same chemical properties, D dan E mempunyai sifat kimia yang sama, (Which element is more reactive? Unsur manakah yang lebih reoktif? [1 mark]SOALAN RAMALAN 2015 chemistry parer 2*SPM sw piuinan 1 ite} Gi) Explain your answer, Terangkan jawopan onde. [2 marks] (© (i) Which elements exist as diatomic molecules? aS Unsur manokohwujud sebog mlekul cto? [1 mark} (ii) Name the chemical bond in these diatomic molecule ‘Noman htan ke bog mele dato terebut ui [1 mark} 4. (@) Diagram 4.1 shows the equation for the formation of polythene. Polythene is a synthetic polymer. Rajah 4.1 menunjukkan persamacn pembentukan polietena Pelietena merupakan polimer sintetik Polythene Polietena Diagram 4.1 (i)_What is meant by polymer? itn yang dimaksudkan dengan polimer? [1 mark] ) Name the process for the formation of polythene. Namakan proses bagi pembentukon polietena, [1 mark)N RAMALAN 2015 Ill cuemisray paper 2*SPM = piunan 4 SOALA! > (iii) State one uses of polythene in our daily life. iehidupon harian ki Nyotakan satu kegunaan polietena dalam ki [1 mark] (b) Synthetic polymers are widely used today, but they are difficult to 2. . Polimer sintetik mempunyal bonyok kegunaan pada masa kin, tetapi ia sangat ‘sukar (2) Burning of polymer can caused air pollution. Explain why. Pembokaren polimer boleh menyebabkan pencemaran udara. Terangkan mengapa. a mark) (ii) State one ways to overcome the problem in 4(¥, Nyatakan satu cara untuk mengatasi masolah di 4(2)(), [1 mark] (©) Diagram 4.2 shows the flow chart for the preparation of detergent R. Rajah 4.2 menunjukkan carta alr bagi penyes R. Process A ° Proses A " CH,(CH,),CH,OH —————» CH,(CH,),CH, —>» O-S—O-H Sulphuric acid tl ‘sid sulfurik Alkyl sulphonic ° acid Asid all sulfonik Sodium hydroxide solution Process B Larston Proses B rotrium hidroksida ° I CH,(CH,),CH, —» O-S—0-—Na.. Detergent R x Detergen® Diagram 4.2 (i). Name detergent R. Namakon detergenR,Be ee tetih SOALAN RAMALAN 2015 chemistry paper 2*SPM w pian 1 n> (ii) State the processes A and B, Nyetakan proses A dan proses 8, Process A (Proses A) Process B (Proses 8) Gil) Based on the structure of detergent R in Diagram 43, cir hydrophilic part and hydrophobic part. Berdasarkan struktur detergen R delam Rajah 4.3, bulatkan den labelkan bahagian rok den hidrofobik . el the: ° i} a CH,(CH,),CH, > O- $—0-Né II ° Diagram 4,3 U mark] (iv) Give one example of additive in detergent. ‘Nyotakan satu conteh bahan tamboh dalam detergen, U1 mark} (State one advantage of using Yetergent as a cleaning agent compare to soap. 'Nyatakan satu kelebihan menggunakan Yetergen berbonding sabun sebagai agen pembersihan (mark) Rajah 5 menunjukkon cof ian kualitavif sebatian X. 5. Diagram 5 shows a eer) for the qualitative analysis of compound X. Process I Proses I Dilute nitric cain Sid niteik coir Process IT Process IIT Lead(EI) nitrate Prose id Plumbum(XE) nitrat Sodium hydroxide Copper(II) chloride solution solution Larutan natrium hidroksida Laruten kuprum(II) klorida Y and sodium nitrate solution ¥ dan laruten natrium nitrat Zanid copper(IL) nitrate solution Z dan larutan kuprum(ZZ) nitrot Diagram 5SOALAN RAMALAN 2015. I> chemstry paver 2*SPM wpninan 4 (@) Based on process T, Berdasarkan proses, (Name the yellow powder of X. ‘Namakan serbuk kuning X (ii) Name process I. Namokan proses I Gi) Write a balanced chemical equation for the ref (iv) Why is the yellow powder X added in excess in the reaction? ‘Mengopa serbuk kuning X ditamboh secara berlebihan di dalam tindak balas? [1 mark] (b) Based on process III, Berdasarkan proses IL, @ Name the process. ‘Namakan proses itu [1 mark « [2 marks} (iii) How can you separate compound Z from the copper(II) nitrate solution. Bagaglana anda melokukan penisohanterhadap sebatan Z dar larutankupeumEX) rtrat © Bdsed on process T and ITT, state the cation and ani: anion pr i aerate! xT, ron inn enon ang eee Sota Cation (Kation) > cases roan Anion (Anion) +. [2 marks] 10‘SOALAN RAMALAN 2015 cHewistay paper 2*SPM mw prunan 11> 6 @ Diagram 6 shows the result of an experiment to investigate the movement of bromine particles in air. Rajah 6 menunjukken keputusan eksperimen bagi mengkaji pergerokan zarah-zarah bromin dalam dara, Process I Proses I — Bromine gas : (brown) Bromine gas 60s bromin (brown) @erang) 60s bromin @erang) Diagram 6 @ (id) State the type of particle present in bromine gas. ‘Nyotaken jenis zoroh yong hadir dalam gas bromin [2 marks] © Miscible in all proportions with water Larut campur delam air pedo sebarang perkadoran © Undergoes combustion Mengelami pembckeran © Amember of a homologous series Ani suatu srt homolog cacuemsray paper 2*SPM a puinan 4 SOALAN RAMALAN 2015 1115 nd? (What is the name of this compow Apakah nama sebation ii? [1 marky us series of this compodind? (ji) What is the general formula for the homelago ‘Apakah formula am bagi sri homoleg sebetian ini? (iii) Draw and name two isomers of this compoupé Lukis dan nemckan dua isomer bagi sebatian ini [4 marks} (iv) One mole of this-compound undergoes complete combustion to form carbon dioksida dan ain Tuliskan persamaan kimia bagi tindak bolas itu, {1 mark) 12SOALAN RAMALAN 2015, clemistRY PAPER 2*SPM w puna 1 {13> Section B [20 marks} ‘Answer any one question from this section. Towab mona-mana satu Soalan daripado bahagion i (@) State three types of reactions in preparation of soluble salt. ‘Nyatakan tiga rindak bolas penyediaan garam larut [3 marks} (b) You are given the following materials : Ande dibekalken dengan bahan berikut : Potassium carbonate solution Leruten kolium karbonat Dilute sulphuric acid Asid sulfurik cair Zinc nitrate solution Laruten zink nitrat Describe an experiment to prepare a sample of pure zinc sulphate salt by using all the above chemicals. explanation, write the chemical equation of reaction involved. Huraikan satu ekspe yediekan garam zink sulfat tulen dengan menggunakan bahan kimia di tas, Dalam penerangan aida Zulisken persamaan kimia yang terlibat. [12 marks} (©) Explain how to conduct a chemical test to detect the presence of anions in the gate salt crystals. dan suatu ujian kimia yong perlu dijalankan bagi mengesan kehadiran anion dalam heblur garom nitrat [5 marks]NRAMALAN 2015. IKE cemsrey paren 2*SPM a puiian 4 SCALA ing rate of 8. (a) Two experiments are carried out to investigate iaesael affecting yf reaction between metal magnesium and sulphuric Ocies Table 8 shows the reactants and the time taken to co gas released. Dua eksperimen dijalenkan bogi mengk Iegam magnesium dan asid sulfurik. img Pidro ‘Jaduel8 menunjukkan bahan tindak bales dan masa yong diambil bag! mengu! pul gen yang dibebaskon. lect 30 cm? of hydrogen .dak balas di antara ai foktor yong mempengaruhi Kedar tin Time taken / s Experiment Reactants ‘Masa yang diambil / s Eksperimen Bahan tindak balas I Excess magnesium powder 50 cm? of 1.0 mol dm? of hydrochloric acid Serbuk mognesium berlebihen 50 cm doripade 1.0 mol dm os hidroklorik 10 Ir Excess magnesium powder 100 cm? of 5.0 mol dm’ of hydrochloric acid Serbuk magnesium berlebihan 100 em? daripada 0.5 mel dm? asid hidroklorik Table 20 () Write chemical equation and ionic equation for the reaction. Tulskon persamaan kimia dan persamaahienik bog tindok bala itu [3 marks] Hitung kadgh 1 agh rate of reaction for Experiment I and Experiment IT. [purata bagi Eksperimen I den Eksperimen I. [2 marks] (ii) Explain the differences in the rate of reaction between Experiment I and Experiment II based on collision theory. Terangkan perbezaan kadar tindak bolas di antara Eksperimen I dan Eksperimen 11 berdasarkan ‘teori perlonggaren zarah [5 marks} jing factor of temperature, desc i i ir bra feet P jescribe an experiment how this factor affecting ngan menggunakan faktor suhu, huraikan suatu eksperimen b rimen bagaimana faktor terset kodar tindak bolas agcimana faktor tersebut mempengaruhi [10 marks] 14‘SOALAN RAMALAN 2015 cHemisTRy PAPER 2*SPM w piuinan 41> Section C [20 marks} Answer any one questions from this section. Towa’ mano-mana satu seclan daripada bahagian ini 9. (@) Diagram 9.1 shows a structural formula of butane. e / Rajah 9.1 menunjukkan formula struktur bagi butena. Diagram 9.1 Draw another two structural forslala of buydne and write their respective names according to the IUPAC nomenclature /, Lukis dua formula struktur lei bogi burdga dag tulskan nama masing-mesing berdasarkan penamaan TUPAC, [4 marks] (b) Diagram 9.2 shows the structural formula of an ester, Ratah 9.2 meant forma trot bap sat ester Diagram 9.2 @dsed on Diagram 9.2 + Berdosarkan Rajah 9.2: (Identify the two organic chemicals needed to produce the ester above. Kenal pasti dua bahan kimia yong ciperlukan untuk menghasilkan ester di tos [2 marks}" 45 ‘chemistay paper 2*SPM w prnan 4 10, © @ () SOALAN RAMALAN 2045 IIHS (ii) State two chemical properties for each organic chemicals that you stated in 1b). i ‘anda nyatakan dalam 9(b}(i). \Nyatakan dua sifat kimia bagi setiap bahan kimia organik yang nyas 1d marks] You are given an apparatus and chemicals as follow : ‘Anda diberikanalat redas dan bohan-bhan Kimia seperti berikut : Apparatus : Test tube, dropper Rodos Tabung ui penitis Chemicals: Bromine in trichloroethane, acidified potassium manganate(VIT) solution Bahan kimia : Bromin dalam trikloroetana, larutan kalium manga Berasid Describe two chemical tests using the appara; differentiate between hexane and hexene. In your description must included the procedure and observation. Huraikandua yian kimia menggurakan lat radas den Bohan kimia yang diberikan di atas untuk membezokon cantare heksana dan heksene. Dalam huraian, anda mest disertakan prosedur dan pemerhatian, [10 marks] What is meant by the heat of comkustfon of alcohol? ‘Apakch meksud haba pembakaran alkohol? [3 marks] Table 10 shows the molecular formula and the heat of combustion for alcohol X and alcohol Y. otekul don haba pembakeran bagi alkohol X dan alkohol ¥. Molecular formula Formula moleku! Heat of Combustion / kT mol Haba Pembakaran / kT mol* Table 10 Based on the information in Table 10, compare the heat 5 Nel asd asad? of combustion between Explain why there is a difference in the values of the he 5 RIK e 'eat of combustion between Berdasarken moKumat dalam Jadva 10, bandngkan haba pembokaronentaraalhohelX don elkohl’ Teranghan mengapa nil haba pembokoronbegi alkohol X dan alkohol Vberbesa, Gee a 15 marks]‘SOALAN RAMALAN 2015 chemistry paper 2*SPM w puinan 4 te (©) Describe an experiment to determine the heat of combustion of ethanol. Your ‘answer should include: Hureikan satu eksperimen bogi menentukan haba pembakaran bagi etancl. Jawapan anda mestilah ‘mengandungi: (Apparatus set up S ‘Susunan radas (i) Procedure of the'experiment Prosedur eksperimen Data obtained from the experiment Dota yang dipereleh dari eksperimen- (iv) Calculation of heat of combustion butanol Penghitungan haba pembokeran bog [12 marks} ) OF QUESTION PAPER KERTAS SOALAN TAMAT SHHSESRETS F9/113/wa/2a/0315SOALAN RAMALAN 2015 Chemistry paper 2* SPM | JAWAPAN PILIHAN PERTAMA Section A ‘Answer Question 1 (@) Pink to colourless Merah jambu kepeda tanpa worna (b) (Potassium nitrate Kalium niteat HINO, + KOH > KNO, + H,0 Number of mol (Blengan mol) 20x05 1000 0.01 mol 1 mol HNO, > 1 mol KNO, 0.01 mol HNO, > 0.01 mol KNO, (O} ii) Mass (Jism) KNO, 0.01 x [39+14+48] 1.019 (©) M2: Sulphuric acid (Asia sufuri) Ni: Hydrochloric acid (AsidhideoKlork) Answer Question 2 (@) (i) Electrical energy to chemical energy Tenaga elektrikkepade tenage kimia (i) Copper electrod P become forum P semakin nipis (b) Cel : Copper Q (Kuprum Q) Cell AY(sertt) + Zinc (Zink) © @ To prevent two solutions mixing and allow the flow of ions. Untuk menghalang dua laruten bercampur dan membenarkon pergerekan io. (ii) Zinc electrode Legge Etektrodzink semakin ip? (iii) Zn > Zne+2e" Gut + 2e > Gu @e greater than iron and copper in electrochemical series. JTorak antora zink dam kuprum lebih besor dri jarok antera ferum dan kyprum dalam Siri elektrokimia. i ew iswer Question 3 (a) Group 1, Period 4 (Kunpulan, Kala 4) (b) & © @ BL (ii) High melting and boiling point Tokatlebur don tokat didi yang tinggi @ @ ce (ii) © When going down Group 1, the atomic size of atom increase. Apabile menuruni Kumpulan 1, saiz atom semakin bertombah © Theforceattraction between * nucleus and valence electron become weaker. ayo tarikan antora nukleus don elektron valens semakinlemah. © Thus, the single valence electron can be released more easily. {adi elektron tunggl valent dapat aibebeskan dengon mudeh 49© 0 Gi) cuemistry paper 2* SPM M Covalent bond (tkatan kolaven) Answer Question 4 @ 0 o) @ © @ ii) Large long-chain molecules formed by joining together many identical repeating sub-units called monomer. Rantai panjang melekul yang besar yang terbentuk melalutiketon antara sotu sama lain bagi unit-unit kecil yang dipanggil mmonemer Polymerisation (Penpolimeran) Shopping bags Beg membeli-belah Burning synthetic polymers will produce poisonous gas” Pembakbran polimer sintetik akon ‘menghosikan gos berecun © Recycle ¢kitar semule) © Reuse (éune semula) Sodium alkyl sulphate Netrium oll sulfar Process A (Proses A): Sulphonation (Pengsuif he Proses B (roses Neutralisatio CH,(CH,), CH, - O— S— O—Na* is Hydrophlic part Bahagianhidrofi Enzimbologital Detergent are effective cleanersin both hardwater and softwater, Detergenefektif membacuhdolom keduo-dua air keros dan air lembut, SOALAN RAMALAN 2018 |I1IE Answer Question 5 @o @ Gi) Gil) (wv) &) @ Lead(IT) oxide (Plumbum(Z1) oksida) Neutralisation (Peneutralon) PbO + 2HNO, > Pb(NO,), + HO To make sure all nitric acid react completely Untuk memostikan seihua ad nitrik bertindak balas dengan lengkap Double decomposition (© Cation (Kation) : Pb? Anion (Anion) : OH” ‘Answef Question 6 ) Ci) Gi) Gi) &) @) Gi) Gi) [=] Dif fussion (Resopan) Molecule. (Meleku) © Bromine gas is made up of tiny and discrete particles. Gas bromin terdiri daripada zarah- -zarah yang halus dan diskrit © The particles move randomly into the space in between the. air particles. Zarah-2arah bromin bergeraksecara rowak ke ruang di antara zarch-zarah udra Propanol CnH.,,,;OH HHH Eel H-c-c—C-H Ll | OH HH Propan - 1 - 01SOALAN RAMALAN 2015, ——e——I=ce chemistry paver 2* SPM HHH 6. Ii H-¢~¢-c-H li H OH H 7 Propan - 2-01 , 9 (iv) CH,OH + Fr 260, + 40 8. a Section B ‘Answer Question 7 @ () © — Reaction between acid and metal Tindak balas entara asid dan logam © Reaction between acid and metal oxide Tindak bolas entarc asid dan oksida loga © Reaction between acid and metal carbonat Tindak balas antara asid den logom karbonat 1. Add zink nitrate-solution to potassium carbonéte solution into beaker. Lp) Tambo lorutanfeink alum karbonat aPdelom thar. 2. Stir the mixture. kacou campuran. 3. Filter the solid zinc carbonate formed. ,jel zink karbonat yang acig in a beaker until some zinc gfbonate no longer dissolve. Jomboh zink korbonat kepada asidsulfurik di dolom bikar sehingga zink karconat tidak fagilarut 5, Filter the mixture. Turas campuran. =] CHeMistay paper 2* SPM 10. Transfer the filtrate to a evaporating dish. Pindakkan hasilturasan ke dolam mangkuk penyejatan. Heat the filtrate until saturated / 1/3 from its origindl Volume. deri isi padu osel Allow the saturated solution to cool at room temperature. Biarkan arutan tepumenja sejukpada suhu n two sheets of filter paper. Keringkan hablur dengan menekannya di ‘antara dua keping kertos tures. KCO, + Zn(NO,), > KNO, + ZnCO, ZnCO, + H,SO, > ZnSO, +H,0 + CO, ‘Add 2 em? of salt solution into test tube. ‘Masukkan 2 em? larutan geram ke dalam tabung wi Add 2cm? of dilute sulphuric acid into test tube. Follow by 2cm? of iron(II) sulphate solution. Tambah 2 en? osid sulfurik coir ke dalom tabung ji diikuti dengon 2 em? laruton Ferum( C1) sulfa. Adda few drops of dilute sulphuric acid, Tambch beberapa titi asi sulfurik car Carefully to the side of test tube. Dengan berhati-hati pada tepi tabung uj Brown ring forms shows present of No, Cincin perang terbentuk menunjukkan kehadiran NO, -SOALAN RAMALAN 2015 [IIIS Answer Question 8 @ () Mg+2HCl > MgCl, + H, Mg+ 2H" > Mg® + H, Gil) Experiment I ksperimen 1) Ore 10 Experiment II (Eksperimen It) 30 — =15em'st 20 (iii) 1. Concentration of hydrocloric acid in Expe; igher than Experiment Ir Kepekatonasidhidroklorik delam Eksperimen lebih tinggi dar*Eksperimen ZZ. 2, The number of H per unit volume increase. Bilangan ion "per isi podu meningkat. 3. Frequency collision between magnesium and H’ increase. Frekuens! perlanggaran ontara magnesium dan H" meningkat. 4, Frequency ef fective collision Between particles increase. Frekuensiperlanggaran berkeson 5. Rate of reaction increases. Kedar tindok boles meningkot. (b) Factor (Faktor) : Temperature (Suny) ¢ Name of reactant : Sodium thiosulphate solution, sulphuric acid. Nama bohan : Larutan natrium ses, asid sulfurik, Procedure (Suku) : €) 1, 100 cm? of OA mol fodium thicsulphate solution is poured into a conical flask. 100 en, 0.1 mol OALerutgh netrium tasulfar dimasukkan ke dalam kelolang kon, 2, The intial temperature of sodium thiosulphate solution is recorded. ‘Suhu ewallarutannatrium tosulfet dicatatkon 3. The conical flask is placed on the top of a piece of white paper marked with °x'. Kelolang kon diletokken di ctos sekeping kertas putih bertonda si 4, 5.cm? of 0.1 mol dm sulphuric acid is measured and quickly poured into conical flask. ie coni¢dl flask is shaked throughout the experiment, i. ol dm asi slfurikalukur dan cimasukkan dengan cepat ke dolam kellong kon. Kelalang kon A stop watch is started immediately. gh randlk dimulakan dengan segera, 6. The time taken for the mark X to dissapear from sight is recorded, ‘Maso yong diambil bagi tando X bilang dari penglihoton dicatotkan. +7, The experiment is repeated using sodium thiosulphate solution at temperature of 35°C, 40°C and 50°C, Eksperimen diulang dengan menggunakan larutan natrium tiosulfat pada suhu 35°C, 40°C, 45°C dan 50°C 52ore chemistry paver 2*SPM Results (Keputusan) Temperature (°C) ‘Suhu(*C) 30 | 35 | 40 | 45 LL 50 | 55 Time (8) Masa (s) 1 | | — an ‘time (masa) Plot the graph of temperature against time. Temperature (°C) Time (8) © Conclusion: The higher temperature, the higher rate of reaction. Answer Question 9 @ HoH “ 11 | H-6,—¢, H-C¢-H | H H bi | | > H-c=C-C-H but -2-ene | H 2 -methylpropene () (© Propancic acid (Asi propane) © Ethanol (Etanc!) .) Chemical properties of propancic acid ‘Sifat kimia asi ‘propanoik @. React with metal to produce salt and hydrogen gas. portindek bolas dengan logom bagi menghaskan garam don gas hirogen React ivith alkali to produce salt and water. gertindok bolos dengan alkali bogi menghasilkan garam dana. [3] 3chemssrav paren 2*SPM SOALANRAMALAN 2015 IE Chemical properties of ethanol Sifat Kinia etonot © Undergo combustion to produce carbon dioxide and water. Mengelami tindok balas pembakaran menghasilkan karbon dioksida dan ai. © Undergo oxidation to produce ethanoic acid, ‘Mengelamitindok bales pengoksidaon menghasilkan asidetenoik (©) Reaction with bromine water Tindok balas dengan air bromin Procedure (Presedur) 1. Pour 2 cm? of hexane into a test tube, ‘Masukkan 2 cm? heksana ke dalam tabung wi. 2, Add 3 or 4 drops of bromine water and shake. Tambah 3 atau 4 titis air bromin dan goncang. 3. Record the observation and repeat with hexene, Catatkan pemerkatian dan ulang dengan heksena. Observation (Pemerhatian) ¢ Hexane : brown colour remain unchanged\ 7 Heksana : warna perang tidak berubah Hexene : brown colour decolourised. Heksena : warna perang dinyahwarnakan Reaction with acidified potassium manganate(VIZ) solution. ‘Mesokkan 2 em? heksana ke dalam tabung uj. ‘Add 3 or 4 drops of acidified potassium manganate(VII) solution and shake, Tambah 3 etou 4 tts lorutan kalium mangonet(VE) beresid den goncang, Hexahé : purple colour remain unchanged. ‘Heksona : worra ungu tidak berubah Hexene : purple colour decolourised, Heksena : warna ungu dinyahwarnakan.cHemistay paper 2* SPM SOALAN RAMALAN 2015, i> Answer Question 10 (@ Heat released when 1 mol of an alcohol is completely burnt in excess oxygen to produce carbon dioxide and water, Haba yang dibebeskan epabila1 mel alkohol terbokar dengan lengkap dalam oksigen berlebihan bagi menghasilkon karbon diokside dan ai. (b) , © Heat combustion of alcohol ¥ is higher than alcohol X. Haba pembakaron alkohol Y lebih tingl der elkoholX, The number of carbon atom per molecule alcohol ¥ higher. Bilangan atom kerbon permolekul alkohol lebih tinggi Alcohol Y procedure more carbon dioxide and water molecule than alcohol X // release more heat energy. ‘Alkohol Y menghasilkan lebih karbon dioksida dan molekul air ber} oo IkohbIX // membebeskan lebih tenaga haba, (©) Methanol / ethanol / propanol . Metanel /etanel / propanol. Apparatus (Radas) ; : Copper can, tripod stand, thermometer, measuring cylinder, spirit lamp, weighing balance, wooden block, windshield. Tin kuprm, tng kok tiga, temmometr. sling pep elit, pninbon, bok koy,penghodong angi Thermometer Termometer —— Windshield Penghadang angin L- Spirit lamp Pelta Wooden block Blok kay : 1, (100 - 250 cm’) of water is measured and poured into a copper can and the copper ' is d on a tripod stand. dpa lukur don dmasukkan Ke dalam tn pram don tn huprum cpindehkan ke ats urgky 6 Rel ir diukur dan direkodkan / 3 A can fam with ethanol is weighed and its mass is recorded. ; mengendungi eranol ditimbang dan jisin direkodkon He Te ramp rer placed under the copper can and wick of the lamp is light up 4, The lar immediately. pelitadiletakkan di bawoh tin initial temperature of water is measured and recorded. kuprum dan sumbu dinyalaken dengan segera. 55ee ATTN AO | me cuewsrav aren 2*SPM “ SOALAN RAMALAN 2015 I> cuemsray aren 2*SPM __”_-SOALAN RAMALAN 2048 5. The water in the copper can ts stirred continuously until. temperature of the water increases by about 30°C. : Air di dolam tin kuprum dikacau sehingga suhu ir meningkat sebanyak 30°C. 7 6. The flame is put off and the highest temperature reached by the water is recorded. ‘Nyalaan dipadamkan dan suhu tertinggi yang dicapai oleh air dicatatkan. 7. The lamp and its content is weighed and mass is recorded. Pelita don kandungannya diukur dan jisim dicatotkan Data : The highest temperature of water = t Suhu tertinggi air The initial temperature of water = Suku onal air Increase in temperature = t, - Peningkaton subu ‘Mass of lamp after burning = M, LTisim pelta selepos pembokaran ‘Mass of lamp before burning = M, LTisim pelta sebelum pembakaran ‘Mass of lamp ethanol burnt = M, - M, = ‘Tisim pelita selepas etanoldibakar Calculation (Hitungan) t Number of mole of ethanol (langan mol eta), CH,OH, n= 46 = The heat energy e Tenaga haba diseray/oldeain Heat of combustion of ethanol (Haba pembakaran etanol) : ME Smart = P REPSRELESE F9/L13/wa/2a/0315