CHAPTER 3 SOAL NO 1

Diketahui : P1 = 10 atm = 7600,021 mmHg

P2 = 1 atm = 760,0021 mmHg
V1 = 60 ft3
Cp = 7 btu/lbm0F = 7 btu/lbm0F x 10F/255,9278 K = 0,02735 K
Cv = 5 btu/lbm0F = 7 btu/lbm0F x 10F/255,9278 K = 0,01954 K
Ditanya :

W, Q, U, H, dengan :
a. Volume konstan
b. Temperature konstan
c. Adiabatic

Jawab :

P2 x V 2 = P 1 x V 1

P2 xV 1
P2

V2 =

10 atm x 60 ft 3
1 atm

= 600 ft3
R = 998,970 ft3.mmHg/K.lb.mol
Gas ideal :

Pv = nRT

P1 x V1 = nRT1
T1 = P1 x V1/R x n
= 7600,021 mmHg x 60 ft3/998,970 ft3.mmHg/
K.lbmol x 1 lbmol
= 456,47 K
a. Volume konstan
W = 0 V = Cv x T
T2 = T1 x P2/P1
= 456,47 K x 10 atm/1 atm
= 4564,70 K
U = Cv x T
= 0,01954 btu/lbm.K (4564,70 456,47)
= 80,2748 btu
H = Cp x T
= 0,02735 btu/lbm.K (4564,70 456,47) K
= 112,360 btu

b. Temperature konstan
U = H = 0
Q=W
W = R x T1 x ln P2/P1
= 998,970 ft3.mmHg/K.lbmol x 436,47 K x ln (760,0021/7600,021)
mmHg/mmHg
= 45.599,98 ft3.mmHg/lbmol
= 163,17 btu/lbmol = 163,17 btu
c. Adiabatic
Q=0
U = W = Cv x T
= Cp/Cv = 7/3 = 114
T2 = T1 (P2/P1) = - 1/
= 456,47 K (1/10)1,4 - 1/1,4
= 236,43 K
U = W = Cv x T
= 0,01954 btu/lbm.K (236,43 456,47)
= -4,30 btu
H = Cp x T
= 0,02735 btu/lbm.K (236,43 456,47) K
= -6,02 btu

CHAPTER 4 SOAL NO 17
Calculate the standard heat of reaction at 25C for the following chemical
reaction :
CH4 (g) + H2O (g)
a) Using heat of formation data
b) Using heat of combustion data

CO

(g)

+ 3H2 (g)

Answer :
a) Using heat
CH4 (g) :
H2O (g) :
CO (g) :
H2 (g)
:

of formation data
C (s) + 2H2 (g)
CH4 (g) Hf 298
H2 (g) + O2 (g)
H2O (g) Hf 298
C (s) + O2 (g)
CO (g) Hf 298
Because hydrogen is an element

= -74.520 J
= -241.818 J
= -110.525 J
Hf 298 = 0. J

The heat of reation :

CH4 (g)

H 2O

H2 (g) + O2

(g)

(s)

+ 2H2

H 298 = 74.520

(g)

(g)

H 298 = 241.818 J

(s)

CH4

(g)

+ O2

(g)

+ H 2O

(g)

CO
CO

H 298 = -110.525 J

(g)

(g)

+ 3H2 (g)

H 298 = 205.813 J

The meaning of this result is that enthalpy of 1 mol of CH 4 plus 1 mol

H2O is greater than the enthalpy of 1 mol CO plus 3 mol of H 2 by
205.813 J when each product and reactant is taken as the pure gas at
25C in its ideal-gas state at 1 bar.
b) Using heat of combustion data
CH4 (g) + 3/2 O2 (g)
CO
= -519.641
3H2 (g) + 3/2 O2 (g)
The heat of reaction :
CH4 (g) + 3/2 O2 (g)
= -519.641
3 H2O (g)

(g)

+ 2 H 2O

(g)

298

J
3 H 2O

(g)

CO

+ 2 H 2O

(g)

298

J
3H 2 (g) + 3/2 O2

(g)

298

(g)

H 298 = -725.454

= 725.454
J
CH4 (g) + H2O (g)
CO (g) + 3H2 (g)
H 298 = 205.813 J
The heat reaction that using combustion data have a same value with
the heat raection using formation data = 205.813 J.