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/مشخصهیابی فیزیکی و شیمیایی رسوب چربی و روغن موجود در خطوط فاضلاب شهر مشهد و راههای جلوگیری از آنPhysical and Chemical Characterization of the fat and oil deposits in Mashhad city sewer lines and proposing solutions to this problem
/مشخصهیابی فیزیکی و شیمیایی رسوب چربی و روغن موجود در خطوط فاضلاب شهر مشهد و راههای جلوگیری از آنPhysical and Chemical Characterization of the fat and oil deposits in Mashhad city sewer lines and proposing solutions to this problem
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1. Arthur, S., and Blanc, J. (2013). Management and recovery of FOG (fats, oils and greases). CREW Project
CD2013/6. Available online at: <crew.ac.uk/publications>.(Aug. 2015)
2.
3.
Scottish
Water.
(2012).
Your
guide
to
disposing
<<http://www.scottishwater.co.uk/assets/domestic/files/you%20>> (June 2015)
CRD.
(2013).
Capital
regional
district
fats,
oils
and
grease
cooking
disposal
fats.
campaign.
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19. Kabouris, J.C., Tezel, U., Pavlostathis, S.G., Englemann, M., Dulaney, J.A., Todd, A.C., and Gillette, R.A.
(2009). Mesophilic and thermophilic anaerobic digestion of municipal sludge and fat, oil, and grease. Water
Environ. Res., 81 (5), 476-485.
20. Kabouris, J.C., Tezel, U., Pavlostathis, S.G., Englemann, M., Dulaney, J., Gillette, R.A., and Todd, A.C.
(2009). Methane recovery from the anaerobic codigestion of municipal sludge and FOG. Bioresour.
Technol., 100 (15), 3701-3705.
21. Suto, P., Gray, D.M.D., Larsen, E., and Hake, J. (2006). Innovative anaerobic digestion investigation of
fats, oils, and grease. Proceedings of the Water Environment Federation, 2, 858-879.
22. Canakci, M. (2007). The potential of restaurant waste lipids as biodiesel feedstocks. Bioresour. Technol.,
98 (1), 183-190.
23. Gunstone, F. (2009). The chemistry of oils and fats. Sources, composition, properties and uses, John wiley
and Sons, USA.
24. Frnd, H. C., and Schoenen, D. (2009). Quantification of adipocere degradation with and without access to
oxygen and to the living soil. Forensic Science International, 188(1), 18-22.
26. Shin, H., Han, S., and Hwang, H. (2014). Analysis of the characteristics of fat, oil, and grease (FOG)
deposits in sewerage systems in the case of Korea. Desalination and Water Treatment, 54 (4-5), 1318-1326.
27. He, X., Iasmin, M., Dean, L.O., Lappi, S.E., Ducoste, J.J., and Reyes, de F.L. los. (2011). Evidence for fat,
oil, and grease (FOG) deposit formation mechanisms in sewer lines. Environ. Sci. Technol., 45, 4385-4391.
25. Gutirrez-Padilla, M. G. D., Bielefeldt, A., Ovtchinnikov, S., Hernandez, M., and Silverstein, J. (2010).
Biogenic sulfuric acid attack on different types of commercially produced concrete sewer pipes. Cement
and Concrete Research, 40(2), 293-301.
28. Bockisch, M. (1998). Fats and oils handbook, AOCS Press, Champaign, Illinois, USA.
29. Bettelheim, F., Brown, W., Campbell, M., Farrell, S., and Torres, O. (2012). Introduction to organic and
biochemistry, Cengage Learning, N.Y.
30. Marchetti, J. M., Miguel, V. U., and Errazu, A. F. (2007). Heterogeneous esterification of oil with high
amount of free fatty acids. Fuel, 86(5), 906-910.
31. National Restaurant Association. (2006). Fats, oils and grease control. program tool kit.
<http://www.ci.rockford.il.us/media/Restaurant%20Grease%20Brochure.pdf>. (Dec. 2015)
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Abstract
Formation of oil, fat, and grease deposits in sewer pipelines is a major concern as they result in
sewage overflow and pose health problems. Analysis of two sample deposits collected from the sewer
lines of Imam Reza Street in the city of Mashhad suggested that the chemical reactions promoted by
edible oils in the sewer lines lead to the formation of insoluble soap and deposits. Being sticky, the
deposits accumulate over time to eventually block the lines. The analysis also showed that the
moisture content of the samples ranged between 50T62%, indicating that water does not play a main
role in their formation. The samples were also found to contain 61.78% and 84.35% saturated fatty
acids, with palmitic acid being the dominant one. Calcium was the main metal in the samples, which is
due to both water hardness and corrosion of the sewer lines. Based on the results obtained, the origin
of these deposits, and the relevant protocols for the management of oil and fat wastes, solutions were
proposed to prevent deposit formation and sewer line clogging that suit the special cultural and
environmental conditions of the city. These proposals are under consideration for implementation in
the region.
Keywords: Physical and Chemical Characterization, Fat, Oil and Grease Deposits, Sewer Lines
Blockage Prevention, FOG Managements.
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