Calorimetry Test Name: Score: 143 Mul Section Choice (17 marks) Please circle the correct answer. There is only one correct answer for each question. >>> > D> Dd DOO WOO eee aaanananaanaanaaanaa vovuvynvVUvevvoeovDVDoN m1 B >>> >>> > eedMULTIPLE cHeice Questions | In Victoria, brown coal deposits will be able to supply the State's electrical needs for many years to come, In a coal burning power station, ‘A. all the chemical bond energy released from the coal is converted into electrical energy. B all the heat energy released from the coal is converted into electrical energy. € all the chemical bond energy released from the coal is converted into either electrical or heat energy. D all the heat energy released from the coal is converted into either electrical or chemical bond energy. ‘The next two items refer to the following information 100.0 cm? of water containing 0.2 mol of hydrochloric acid at 10.10 °C is added to 100.0 om* of water containing 0.2 mol of sodium hydroxide at 10.10 °C in a thermally insulated container. The final temperature of the mixture is found to be 11.50 °C. 2, 1f200 cm? of water containing 0.2 mol of hydrochloric acid at 10.10 °C were added to 200 cm? of water containing 0.2 mol of sodium hydroxide at 10.10 °C in # thermally insulated container, the amount of heat energy released A would be the same in the second as that released in the first mixture. B_ would be larger in the second than that released in the first mixture, C would be smaller in the second than that released in the first mixture, D_ cannot be determined from the data given. 3.| The final temperature of the second mixture will be | Af 5.05°c. B 5.75°C. Cc 10.80°C. D 11,50°C. EB 13.00°C, ‘The next two items refer to the following information. 150 cm? of water at 303 K was placed in an insulated flask, and the temperature measured at 20 second intervals for 3 minutes. The results are shown on the graph below. After 60 seconds, 0° I mol of the compound NaX was added to the water. Room temperature was 293 K throughout the experiment, 307 temp 305 flask ask 303 301 299 0 20 40 80 80 “100 120 140 160 180 time elapsed /seconds. 4, The solution process NaX(s) + aq -» Na*(aq) + X~(aq) is A. exothermic. C endergonic. B_ endothermic, D_ thermoncutral. 'S. The sign for OH in the above reaction is A. negative, as the system gradually gains heat from its surroundings. B_ positive, as the water tends to gain energy. C positive, as the solid tends to lose energy to the water. : D_ negative, as the system produces heat which it gradually loses to its surroundings.6. The combustion of butane can be represented by the thermochemical equation 2CyHio(@) + 130,(8) > 8C0,(@) + 10#,0() AH = 5770 ki mol ‘The formation of 2 mol of butane from carbon dioxide and water involves A. absorption of 5770 kJ of heat. C release of 5770 kJ of heat. B_ absorption of 11540 kJ of heat D_ release of 11540 kJ of heat. 7. A calorimeter has a calibration factor of 450 J °C-!, When 0.01 mol of a salt is dissolved in water within this calorimeter, there is a temperature rise of 3.0 °C, The energy released during the dissolution process was A 450 x 3.05, © 450 x 3.0 x 0.01 5. 450 x 3.0, 430 B ; poor oor? D x0 x 00 8. 0.020 mol of solid KOH was added to a calorimeter containing 250 cm? of water. The temperature rose from 18.64 °C to 19.58 °C as the solid dissolved. If the calibration factor of the calorimeter was 1200 JC, AH for the reaction KOH() + aq + K*(aq) + OH-(aq) has a magnitude of A 1200 5 978.98 5 gol 1200 O94 x 0070 1200 x 0.94 Cc 90020 D_ 1200 x 0.94 x 0.020 5 mo!~! J mol” B J mol" 4. 4 calorimeter has a calibration factor of 530, K~?. What temperature rise would be expected if a volume ‘of 30 cm? of methane measured at STP is burat in the calorimeter according 10 the following equation? CH,(g) + 20x(g) + CO,(g) + 2420(@) AH = —889 ki mol! (molar volume of methane at STP = 22400 em? mol™') 30__, 889 , 1000 cao x 88K A pao * 330% T Rea * 330 22400 | 530 1 30 530_,, 1000 B So _* geo * ro0o* D aor™ Fe* TK pe 22400. 889, 1000 , 30% 330% T 10, HCI and O, react according to the following equation, forming HO and Ch. 4HC\g) + 02g) 2H:0(@) + 2Ch(g) AM = ~113 KI mol"! If H,0 gas and Cl, ges were mixed in a thermally insulated vessel, the reaction that occurs would be A. endothermic and the temperature of the gas mixture would fall. B_ endothermic and the temperature of the gas mixture would rise C exothermic and the temperature of the gas mixture would fall. D_ exothermic and the temperature of the gas mixture would rise. I. How much heat is released on burning 1 mol (28 g) of CO? 2CO(g) + Orle) >2COx(g); AH = ~S64 KI mol! A 5642 kd C564 KI B 564 x 28 KI D S64x 2K '2. How much heat is evolved when 13 g of acetylene (C,H;) is burnt in air according to the equation 2CaHa(e) + 502(8)-+ 4CO2(@) +2400) AH = ~2610 kJ mol" (4,C=12, H=1) A 652-5 KI © 2610 ky G 1305 kt D 5220 kdiS | Methanol burns in air according to the equation 2CHOH(g) + 30x(g) > 2CO,(g) + 4H,0(e) If 67.6 KS of heat was evolved when 0.10 mol of methanol was burnt, AH for the equation would be A ~6.76 kJ mol! C676 kJ mol! B -13,52 k mol"! D ~1352 kJ mot"! (4+. The combustion of the fue! gas butane (C4H,o) proceeds according to the equation 2CsHio(g) +1302(g)-8COx(g)+ 10H20() AH = ~5760 kJ mol“! ‘The mass of butane (M, = 58) which must be burned in order to produce 1-0 KI of heat according to the equation given is a C 5760 x 2 x 58 A Tax Be. 8 10, 58 B axe D ayy % 2% 588 £ Ox 10x sg 2 15 When solid sodium nitrate is dissolved in pure water, the reaction may be represented by the equation: NaNOs(s) + aq Na” (aq) + NO5 (aq) AH = +21 KS mol"! 0-01 mol of solid NaNOs is dissolved in 100 cm? of pure water. | The quantity of heat that would need to be absorbed from the surroundings, in order to return the solution to the original temperature, is Ao 21x 1077 Ks, © 21x 10K. E 21x 10K. B 2-1 x 107K, D 21x 10'K. 1G, 300 cm? of 2 M HC! is mixed with 200 em? of 2 M KOH in a thermally insulated container. They react according to the equation H*(aq) + OHM(aq) > H,O() AH = —56 kJ mol"! The temperature of the solutions was 20 °C at the instant they were mixed. If 2.1 kJ is required to raise the temperature of 500 cm? of water every 1 °C, the final temperature of the water would be about A 10°C. B 15°C. c 20°C. D 30°C E 35°C. 17, The next two items refer to the following information “Thermochemical data for the combustion of a number of fuels are given below. methanol: 2CH,OH(1) + 30,(g) > 2COx(g) + 4H,0(g) AH = —1454 KI mol". earbon monoxide: -2CO(g) + Ox(8) —F 2COx(e) Ad = ~S64 KF mot hydrazine NiHu(1) + Ox(g) > Ny(g) + 24,068) AH = ~622 1) mol methane: CHy(g) + 20x(g) > COx(g) + 2H0(8) AH = ~$90 5 mot Which of the fuels releases the maximum amount of energy per kilogram of fuel when burnt? (Ag H = 1,C = 12,N = 14,0 = 16) ‘A CHOH B CO C Nate D CH,Section B: Extended Answer (26 marks) 1. On the axis below draw heat change diagrams for exothermic and endothermic processes. Label the diagrams clearly to indicate the change in enthalpy and the activation energy of the reaction. exothermic endothermic marks) 2. State one significant advantage and one disadvantage in the use of the following energy sources by society: reer preteen petroleum hydroelectricity nuclear power solar energy (4 marks)3 Calculate the amount of energy required to hear 200mL of water from 18°C to 98°C, given that the specific heat capacity of water is 4.18 J?C'g" and water has a density of 1.0g/mL. (2 marks) Calculate the energy released when 24g of carbon undergoes complete combustion with oxygen to produce carbon dioxide according to the equation: C{s) + Ox(g) > COAg); AH = -393.4 kI/mol (2 marks) The complete combustion of 100g of butanol produces 3620kI of energy. Use this to determine the enthalpy of reaction for the equation shown below: 2CsH»OH(1) + 1202(g) > 8CO2(g) + 104,0(g) (3 marks)A student wishes to determine the heat of reaction for a strong acid reacting to completion with a strong base. ‘The ionic equation for this reaction is: H,0°(aq) + OH (aq) —> 2H:0(1) She first electrically calibrates the calorimeter by filling it with 100.0mL of ifference of de-ionised water and passing a current of 2.872A at a potential 3.69V for 125 seconds. The temperature of the water rose from 15.41°C to 19.28°C. She then carefully added SOmL of 0.110M NaOH and 50.0mL of 0.101M HCI to the calorimeter and measured the increase in temperature as 082°C. a) Calculate the calorimeter factor for the calorimeter. b) Calculate the heat of neutralisation for the reaction, ¢) List the main experimental sources of error. 4) Would you expect the heat evolved to have been larger, smaller or the same if SOmL of 0.101M acetic acid had been reacted with SOmL of 0.110M ammonia? Give an explanation for your answer. (2434241 = 8 marks)A research group at the Australian National University has succeeded in stabilising the material calcium chloride hexahydrate (CaClz.6H;0) so that it can repeatedly cycle through the process of fusion and solidification described by the equation below: CaCh,.6H20(8) 9 CaCl, 2H20() + 442010); AH = 437.2ki/mol This can be used as the basis of a solar energy storage system. As the solid calcium chloride hexahydrate absorbs heat from the sun its temperature increases. At 29°C it melts and absorbs the energy required for the chemical change described by the equation. At night, as the liquid solidifies, heat is given back to the surroundings. What mass of calcium chloride hexahydrate would be required to store 1.0MJ of energy? (1.0MJ = 1.0 x 10° J) (3 marks)Seeker 4 cAcaA Dawe FARA 09 8 00 1. nthe axis below draw heat change diagrams for exothermic and endothermic processes. Label the diagrams clay to indicate the change in enthalpy and the activa endothermic heat on] co | Taka ot lsu aes hme eee (4 marks) 2 State one significant advantage and one disadvantage in the use of the following energy sources by society: reer nea = reneaete ae pellnt a po Tyaocleaiciy | kqecctop ont not ped tc petty wer ielear power waste oliponed dithaet ae ons polluting | Ryh eb wp eet fenewoble (Garis) we apenthe Met eapecthy ae bergen FH aes ete oe Seca maths) 4. Caleuate the nergy teleased when 24g of carbon undergoes complete combustion with oxygen to produce eazbon dioxide according tothe equation: (9) + Ox(g)—r COsfe); AH =-293.4 kifmol nearR~ a lmel BT anol > PEGE S sane seca egteeeta et nto? beS Canty, bs marks) 5. The complete combustion of 100g of butanol produces 36201I of energy. Use this to determine the enthalpy of reactiox 2Q/HAOH() + 120:(@) > 8COxG) + 1OFOXe) nL bale o> 2 SP oe on sekok Hes ate eee 7 2 3420 42 ie fet 253574 Pasties eetees mang on Crete 2 Met) wennt = eget | Lek 2 S357 OES DiS: 3h? I (25°)2g acid reacting to for this reactions 24200) trates the calorimeter by filling it with 100.0mL of sing 9 curent of 28724 at a potemial difference of 3.69V for 125 seconds. The tm of the water rose ftom 15.61°C to 19.28°C. She then carefully added SOmL of 0.110M NaOH and S0.0mL of €.101M HCI fo the calorimeter and measured the increase in temperature a8 oa2te. Leder 8) Calculate the calorimeter eset for the calorimeter eovee 2 BGA WATERS nies Gee MeL xe = 342 T/% (22e) 1) Calculate the heat of ana enked = OTA Ce Wood rhb m Daten ty FOsde 42-5 2wo7s oes Hague teaction. ste) 20 poooss ~l ereesee nel 240-2 F 7 ele awe 2 seems 6) List the min experimental sources of ero. loss ok Mat Be Snr binge ohn tr kreting 07 tobay ammonia? Give an explanation for youranswer. 44, 60 C#0# SAR bey Cro” feck AO TS neh ot thong an me mate. tan datot ge a en rhe Jess Kent erated (2134201 = 8 marks) ANE 6 wo * TL 09 7. A research group at the Australian National University has succeeded stabilising the material ealeium chloride hexahydrate (CaCh.6H:0) so can repeatedly cycle through the process of fusion and by the equation below: CaCl, 6H (8) <2 Cac 2H ‘Tis can be used as the basi ication described aH =+37.240/mol fa system, AS the solid calcium chloride hexahydrate absorbs temperature ‘What mass of calcium chloride hoxahyérate would be requited to store LOM of en? (1LOMI= 1.0 x 10°) palate, tye) en TT Cane eidete rs ee) steer ~~ oos7t my 22d, Dies emel Pome mene BTL ET mel eee eee pare = TVs (24g men L Lu Be Mikey (unbeits Fn Bt Ge) topes 2S: 4a? 9 3 24 we aa Me yar ~ seve