nhien liệu diezel PDF

DIESEL FUEL
Phm Minh c
Trnh Quang Thanh
Phm Thanh Tng
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2008
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Petrolimex Corporation : S 1 Khm Thin,

ng a, H Ni, Vit Nam
PV Oil: S 194 Thi Thnh, Phng Lng H,
Qun ng a, TP. H Ni
www.themegallery.com
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990,77 (
USD/ 1
tn du )
19800
ng/l
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Ga iesel M : 20000/ lt
Ga xng M : 16000 /lt
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NHIN LIU DIESEL
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NHIN LIU DIESEL
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NHIN LIU DIESEL
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TNH CHT NHIN LIU DIESEL

Boiling point
Heat Value
Pour point
Cetan number
DIESEL
FUEL
Viscosity
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C TNH NG C
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Motor Gasoline
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Diesel engines
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Fuel injection
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Turbocharging
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Turbocharging
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Supercharging
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Supercharging
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Two Stroke Cycle
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Diesel Engines And Emissions

Nox
Hydrocacbon
CO
Particulates
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Emission Reduction Technologies

Higher Ijection Pressures.
Careful Ijection Targeting.
Charge Shaping.
More Air Motion.
Charge Cooling ( Forcus Air Induction
Engines).
Lower Oil Consumption.
Exhaust Gas Recirulation ( EGR ).
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Exhaust Aftertreatment Systems

Particulate traps, or filters, filter the exhaust
gas.
Catalytic converters HC and CO.
Exhaust Gas Recirulation ( EGR ).
Selective catalytic reduction ( SCR ).
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Diesel Fuil Additives

Engine and fuel delivery system
performance.
Fuel handing.
Fuel stability.
Contaminant control.
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Engine and fuel delivery system.

performance
Cetane Number Improves
Additives:
Alkyl nitrates.
Ether nitrates.
Peroxides.
Nitroso ( RN=O ).
0,05 0,4 % wt
Ditertiary butyl
peroxide
DTBP
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performance
Injector Cleanlines
Additives:
Ashless polymeric
detergent.
50 300 ppm
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performance
Lubricity Additives:
Mono acids: 10 50 ppm.
Amides: 50 250 ppm.
Esters: 50 250 ppm.
D 975
EN 590
Smoke Suppressants:
Organometallic.
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Fuel Handling Additives

Antifoam Additives:
Organosilicone: 10 ppm.
De-Icing Additives:
Low molecular weight alcohols or glycols.
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Low-Temperature Operability Additives:
Specialized additives for narrow boiling range
fuels.
General purpose additives.
Specialized additives for high final boiling point
fuels.
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Conductivity Additives
Drag Reducing Additives
High molecular weight polymers 15 ppm.
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Fuel Stability Additives

Antioxidants:
Phenol.
Amines.
10 80 ppm
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Stabilizers:
Strongly basic amines.
50 150 ppm
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Metal Deactivators:
1 15 ppm
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Dispersants
15 100 ppm
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Contaminant Control Additives

Biocides:
200 600 ppm.
Demulsfiers:
5 30 ppm.
Corrosion Inhibitors:
5 -15 ppm.
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Contaminant Control Additives

Biocides:
200 600 ppm.
Demulsfiers:
5 30 ppm.
Corrosion Inhibitors:
5 -15 ppm.
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Use of Additives
Lubricity additive.
Pour point reducers.
Stability additive.
A cetan number improver.
Coud point.
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Distribution System Additization

A detergent/ dispersant.
Lubricity improver.
One or more stabilizing additives.
A low temperature operability additive.
A conductivity additive.
A biocide.
A corrosion inhibitor.
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Additives in Viet Nam

A low temperature operability additive.
Water Remover.
Diesel Fuel Treatment & Injector Cleaner.
Fuel Injector & Carburetor Treatment.
Diesel Fuel Energizer.
A corrosion inhibitor.
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Diesel Fuel
Specifications and Test Methods
Diesel and Biodiesel fuel
Specification
Content
Test methods
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Diesel fuel specification
EU
Vietnam
Text in
here
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Unit
Cetane number
Density at 15oC
Polycyclic aromatic HC
Sulfur content
Kg/m3
Viet Nam
USA
46
40
820-870
EU
820-845
% (m/m)
11 max
mg/kg
500, 2500
15, 500,5000
10, 50
oC
55
38, 52, 55
>55
Carbon residue (10% Dist. residue)
% (m/m), max
0.3
0.15(1D),0.35(2D
0.3
Ash content
% (m/m), max
0.01
0.01
0.01
Water content
mg/kg, max
200
0.05 %Volume
200
Total contamination
mg/kg, max
Flash point
Copper strip corrosion (3h at 50oC)
Viscosity at 40oC
Fatty acid methyl esters
mm2/sec
(cSt)
% V/V
24
No.1
No.3
No.1
2-5
1.3, 2.4 (1D),

1.9, 4.1 (2D)
2-4.5
5 max
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Biodiesel specification
Property
Unit
Ca, Mg
ppm
Viet nam
USA
oC
Flash point
MeOH content
>=130
% mass
Water
USA
EU
<5
<5
93
>= 120
< 0.2
< 0.2
%vol
< 0.05
< 0.05
< 0.05
Viscosity
cSt
1.9 -6
1.9 -6
1.9 -6
Sulfur
ppm
15, 500
=< 10
Class 3
Class 1
47
47
51
Report
Report
< 0.05
< 0.05
< 0.5
< 0.5
Copper strip corrosion
Class
1
Vietnam
EU
Cetane
Cloud point
Carbon Residue 100% sample

Acid number
oC
% mass
mgKOH/g
Text in
here
< 0.3
< 0.5
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Biodiesel specification
Property
Unit
Viet nam
USA
EU
Free glycerin
% mass
< 0.02
< 0.02
< 0.02
Total Glycerin
% mass
0.24
0.24
0.25
Phosphorus content
ppm
< 10
< 10
< 10
Sodium/potassium
ppm
<5
<5
<5
Oxidation stability
hours
>6
>3
>6
% mass
> 96.5
Ester content
> 96.5
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Test Methods
Viet Nam
USA
EU
Cetane number
ASTM D613
D613, D976
EN ISO-5165
Density at 15oC
D1298, D4052
EN ISO-3675
Polycyclic aromatic HC
EN ISO 12916
Sulfur content
D5453, D2622
D5453, D2622,
D129
EN ISO-20846
Flash point
D3828, D93
D93
EV ISO 2719
Carbon residue (10% Dist. residue)
D189, D4530
D524
EN ISO-10370
Ash content
D482
D482
EN ISO-6245
Water content
D203
D2709, D1796
EN ISO-12937
Total contamination
Copper strip corrosion (3h, 50oC)
EN ISO-12662
D130
D130
Oxidation stability
Viscosity at 40oC
Fatty acid methyl esters
EN ISO-2160
EN ISO-12205
D445
D445
EN ISO-3104
EN ISO-14078
www.themegallery.com LOGO
Test Methods
Sulfur
Cetane index,
Cetane number
Test
Copper strip
corrosion
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Cetane number
1) ASTM D613: CN = 0 100
2) Other methods: Ignition Quality Tester (IQT)
ASTM D6890: ID (ignition delay) = 3.1 6.5 ms (6433 DCN)
ASTM D7170: ID = 2.78 4.89 ms (59.6 35 DCN)
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ASTM D613
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ASTM D6890
IQT
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Calculated cetane index

ASTM D976: hight- sulfur content
ASTM D4737 Calculated cetane index by four
variable equation.
o Procedure A: Grade 1-D S500, 1-D S5000, 2-D
S5000 and 4-D S5000.
o Procedure B: Grade 2-D S500
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Sulfur
ASTM D5453:
ASTM D2622:
ASTM D129:
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ASTM D5453
All grade (referee method for all S15 grades)
Diesel Sample
High temperature
combustion tube
H2O
SO2
UV
O2
Sulfur concentration
Fluorescence emitted
SO2*
SO2
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ASTM D129
Referee for 1-D, 2-D S5000, 4-D
Diesel sample
SO2
BaSO4
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Copper strip corrosion

ASTM D130
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Appendix
ASTM D976
CCI 420.34 0.016G 2 0.192G logM

65.01(logM) 2 0.0001809 M 2
G: oAPI
M: t50 , oF
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D4737 Procedure A
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D4737 Procedure B
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ASTM D2622
Referee for all S500 grades
X-ray
Diesel sample
Sulfur x-ray luorescence
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DIESEL FUEL

Petrolimex Corporation : S 1 Khm Thin,

NHIN LIU DIESEL

NHIN LIU DIESEL

NHIN LIU DIESEL

TNH CHT NHIN LIU DIESEL

Two Stroke Cycle

Diesel Engines And Emissions

Emission Reduction Technologies

Exhaust Aftertreatment Systems

Diesel Fuil Additives

Engine and fuel delivery system.

Engine and fuel delivery system.

Engine and fuel delivery system.

Fuel Handling Additives

Fuel Handling Additives

Fuel Handling Additives

Fuel Stability Additives

Fuel Stability Additives

Fuel Stability Additives

Fuel Stability Additives

Contaminant Control Additives

Contaminant Control Additives

Distribution System Additization

Additives in Viet Nam

A cetan number improver.

Diesel fuel specification

Carbon residue (10% Dist. residue)

Copper strip corrosion (3h at 50oC)

Fatty acid methyl esters

1.3, 2.4 (1D),

Copper strip corrosion

Carbon Residue 100% sample

Carbon residue (10% Dist. residue)

Calculated cetane index

Copper strip corrosion

CCI 420.34 0.016G 2 0.192G logM

Sulfur x-ray luorescence

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