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ds C p dT
R dP
T
P
GAS
s2
P1 V1
P2 V2
T1
T2
s1
s2
s1
T
C p0
T
dT
Entropy change determination formulas, for an ideal gas, ANY process type
mass constant
R ln
dT
R ln
s2
Solving
s1
s1
ln
C p 0 ln
T2
R ln
T1
T2
P1
T2
T1
h2
h1
C p T2
T1
Table A.6
s2 s1
Cv
P2
R ln
P1
u1
T1
P2
Using
Table
A.7 or
A.8
du C v0 dT
dh C p0 dT
C p0 C v0 R
s2
Assume
constant
specific
heat
u2
s 0T 2
s 0T 1
R ln
P2
P1
s1
sgen
Law Q
dU
Gibbs
equations
dH
so
dU
P2
T1
constant V
V dp
Cp0 ln
s2
P1
T1
wtotal v dP
i
1
n
n 1
V1
V2
s1
Cv0
R T1 ln
ln
Pi
ln
R Ti ln
R Ti ln
Pe
P2
P1
gZ i Z e
P2
Pi
Pe
P2
1
R T2
k
T1
Pi
e
1 k
kR
1
Entropy
change
s2
s1
Entropy
change
V2i V2e
2
T2
T1
P1
ln
Boundary
Work
P2
R T1 ln
P1
Total specific work for steady state flow process where only
shaft work is involved (no boundary work). Valid for ANY
reversible process (do not have to be polytropic)
Ti
s 2 s 1 R ln
Introduction to Thermodynamics,
equations. By Nasser Abbasi
image2.vsd
August 2004
Te
Pi
Boundary
Work
T2
T1
Cv0 ln
s2
1 constant T
P
i
s1
T2
Pe e Pi
R Te Ti
Entropy
change
T2
T1
P2
Boundary
Work
Entropy
change
s1
P dV
V dP
Shaft work
(for FLOW
process
only)
s2
dH
Pe
PV
Specialized polytropic
processes work formulas
Boundary
Work
P2 2
R T2
enthlapy law H
Substitute into
0 constant P
constant
General
polytropic
relation
T dS
P dV
P Vn
P dV
Substitute into
2
T ds
n
T1
1 n
nR
formulas for
general
polytropic
process
W
st
1
R T2
ds
1
1
P2
Shaft Work
s2
P2
Boundary
Work
reversible
WORK
irreversible
Pe
Te
Ti
Pi