TIU CHUN VIT NAM

TCVN 6122 : 1996

ISO 3961 : 1089
DU M NG VT V THC VT - XC NH CH S IT
Animal and vegetable fats and oils - Determination of iodine value
Li ni u
TCVN 6122:1996 hon ton tng ng vi ISO 3961:1989;
TCVN 6122:1996 do Ban k thut tiu chun TCVN / TC / F2
Du m ng vt v thc vt bin son, Tng cc Tiu chun - o lng - Cht lng ngh,
B Khoa hc, Cng ngh v Mi trng ban hnh.
DU M NG VT V THC VT - XC NH CH S IT
Animal and vegetable fats and oils - Determination of iodine value
1. Phm vi p dng
Tiu chun ny quy nh phng php xc nh ch s it ca du m ng vt v thc vt.
2. Tiu chun trch dn
TCVN 6128:1996 (ISO 661:1989) Du m ng vt v thc vt - Chun b mu th;
TCVN 4851-89 (ISO 3696:1987) Nc dng phn tch trong phng th nghim - Yu cu k
thut v phng php th;
ISO 5555:1991 Du m ng vt v thc vt - Ly mu.
3. nh ngha
p dng cc nh ngha sau y cho mc ch ca tiu chun ny:
Ch s it: Khi lng it do mu th hp th di cc iu kin thao tc c quy nh trong
tiu chun ny.
Ch s it c biu th bng gam it trn 100g mu th.
4. Nguyn tc
Ha tan lng mu th trong dung mi v cho thm thuc th Wijs. Sau mt thi gian xc nh
cho thm dung dch kali iodua v nc, chun it c gii phng vi dung dch natri
tiosunphat.
5. Thuc th
Tt c cc thuc th u l loi ha cht tinh khit phn tch.
5.1. Nc, theo TCVN 4851- 89 (ISO 3696:1987), hng 3.
5.2. Kali iodua, 100 g/l dung dch, khng c iot ha hoc iod t do.
5.3. Dung dch tinh bt
Trn 5 g tinh bt ha tan trong 30 ml nc, cho thm vo dung dch ny 1000 ml nc si, un
si trong 3 pht v sau lm ngui.
5.4. Natri tiosunfat, dung dch chun, c(Na2S2O3.5H2O) = 0,1 mol/l, khng qu 7 ngy trc khi
s dng.
5.5. Dung mi cacbon tetraclorua

Cnh bo - Cacbon tetraclorua l cht c. Mt dung mi t c hn ang c nghin

cu
5.6. Thuc th Wijs, cha it clorua n trong axit axetic. C th s dng thuc th Wijs loi
thng phm.
6. Thit b
S dng cc thit b thng thng trong phng th nghim v:
6.1. Tha cn bng thy tinh, ph hp vi phn mu th v cho c vo trong bnh (6.2)
6.2. Bnh nn, dung tch 500 ml, c nt thy tinh mi va kht v c sy kh.
7. Mu th
Mu th c tin hnh ly theo ISO 5555:1991.
8. Chun b mu th
Mu th c chun b theo TCVN 6128:1996 (ISO 661:1989).
9. Tin hnh th
9.1. Phn mu th
Khi lng phn mu th thay i theo ch s it d kin bng 1.
Bng 1
Ch s it d kin

Khi lng phn mu th

g

Nh hn 5

3,00

5 n 20

1,00

21 n 50

0,40

51 n 100

0,20

101 n 150

0,13

151 n 200

0,10

Cn phn mu th chnh xc n 0,1 mg cho vo tha cn bng thy tinh bit trng lng
(6.1).
9.2. Tin hnh xc nh
t phn mu th vo bnh dung tch 500ml (6.2). Cho thm 20ml dung mi (5.5) ha tan m.
Thm chnh xc 25ml thuc th Wijs (5.6), y np v lc mnh, t bnh trong bng ti. Khng
c dng ming ht thuc th Wijs qua pipet.
Tng t chun b mt mu th trng vi dung mi v thuc th nhng khng c mu th.
i vi mu c ch s it thp hn 150, bnh trong bng ti mt gi, i vi mu c ch s it
trn 150 v cc sn phm polyme ha hoc sn phm b oxy ha tn i ln th hai gi.
n cui thi im, cho thm 20ml dung dch kali ioua (5.2) v 150ml nc (5.1) vo mi bnh.
Chun bng dung dch natri tiosunfat chun (5.4) cho n khi gn mt ht mu vng ca it.
Thm mt vi git dung dch h tinh bt (5.3) v tip tc chun cho n khi lc mnh bnh th
mu xanh bin mt.
Ch thch - Cho php xc nh im kt thc phn ng bng cch o in th.
9.3. S php xc nh
Tin hnh hai php xc nh trn cng mt mu th.

10. Biu th kt qu
10.1. Phng php tnh ton
Ch s it c tnh theo cng thc

12,69 c (V1 V2 )
m
Trong
c l nng chnh xc ca dung dch natri tiosunphat chun (5.4) s dng, tnh bng mol trn
lt;
V1 l th tch dung dch natri tiosunphat chun (5.4) s dng cho mu trng, tnh bng mililit;
V2 l th tch dung dch natri tiosunphat chun (5.4) dng xc nh, tnh bng mililit;
m l khi lng mu th (9.1), tnh bng gam.
Kt qu l gi tr trung bnh cng ca hai php xc nh, vi iu kin lp li (10.2) phi c
tha mn.
10.2. lp li
S chnh lch gia cc gi tr ca hai php th c tin hnh k tip nhau (hoc cng mt lc)
cng mt ngi phn tch, s dng cng cc thit b trn cng mt mu th khng c vt
qu 0,5 n v ch s it
Ch thch - Nhng s liu ny c chp nhn. Nu cn n s c b sung khi cc kt qu
ca cc phng th nghim c sn.
11. Bo co kt qu
Bo co kt qu phi ghi r phng php s dng, kt qu thu c v phng php tnh ton.
Bo co kt qu cng phi cp n cc iu kin thao tc khng c quy nh trong tiu
chun ny, hoc lin quan nh la chn mu, thi gian phn ng (xem 9.2), cc chi tit bt k c
nh hng ti kt qu.
Bo co kt qu cng bao gm tt c cc chi tit cn thit cho vic nhn bit mu.