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Hem Actsheet: Chemical Equilibria: K
Hem Actsheet: Chemical Equilibria: K
September 2001
Number 21
Chemical Equilibria: Kc
To succeed in this topic you need to: understand the concepts of dynamic equilibrium and Le Chataliers
Principle (Factsheet 09)
Kc =
Example 2:
[C]eq [D]eq
Kc =
Rules
1. Products over reactants (right-hand side on top)
2. Numbers in front become powers
3. + becomes
Another example:
If you have a power in the bottom of a fraction, you can bring it to the
top by changing the sign
e.g. 1/mol2 = mol-2 1/dm-3 = dm3
Every Kc has its own unit and this must be worked out every time (see box
on working with powers). For the example above:
(mol dm )
(mol dm-3) mol dm-3)3
-3 2
[A]eqw [B]eqx
-3 2
CaO(s) + CO2(g)
Kc =
CaCO3(s)
yC+zD
y
units = mol-1dm3
Kc = [CO2]eq
Writing Kc expressions
Look at the example below:
wA+xB
[SO3]eq2
[SO2]2eq [O2]eq
2SO3(g)
What is Kc ?
Kc =
2SO2(g) + O2(g)
(mol dm )
(mol dm-3)4
1
= (mol dm-3)-2 = mol-2dm6
(mol dm-3)2
2. Simplify the whole of the top of the fraction, and the whole of the
bottom of the fraction eg moldm-3moldm-3= mol1+1dm-3 +-3= mol2dm-6
3. Divide the top of the fraction by the bottom, (i.e subtract powers)
e.g. (mol dm-3)/(mol2dm-6) = mol12dm-3 -6 = mol-1dm3
Chem Factsheet
Chemical Equilibria : Kc
Method 2
You need to work out the amounts at equilibrium first, then find Kc. This
is the most common type of question! The method is outlined below:
[products]
[reactants]
N2 (g) + 3H2(g)
2NH3(g)
C(g)
!H = -92kJmol
-1
1. A
equation
2. 0.50
0.40
starting amounts
3. 0.20
equilibrium amounts
Kc calculations
There are two general types of calculations using the Kc expression:
1. finding the value of Kc given the amounts of species present,
2. finding the concentrations of species given the Kc value.
0.030
6. Kc = 0.020 0.010
Example 1.
This question refers to the following system in equilibrium:
Answer 1.
2.
3.
[C]eq2
[A]2eq[B]eq
S
0.5
+ T
?
Kc
2R
2
?
start
eqm
6.2 10 3
2
2
3 10 3 2 10 3
2 2
2R
eqm
NB. [ ] = mol dm-3, hence the need to use the 2dm3 from the question
to obtain per 1dm3.
S
0.5
T
0.5
5. Kc = [S]eq [T]eq
[R]eq2
Question (3) and (4) at the end of this Factsheet provides further practice
on finding Kc .
Chemical Equilibria : Kc
Chem Factsheet
Exam Hint:- You will never have to solve a quadratic equation using
the quadratic equation formula. If you ever find yourself with such an
equation, you have made a mistake!
This type of calculation involves being given the value of Kc and some data
about the concentrations of the species in the equilibrium reaction.
Method 1
You are provided with the K c value and some of the equilibrium
concentrations
Practice Questions
1. For each of the following equilibrium reactions write the Kc expression
and calculate the units:
Example
This question refers to the following equilibrium system:
(a)
(b)
(c)
(d)
(e)
(f)
(g)
N2O4(g) 2NO2(g)
o
At 250 C, the Kc value is 13.7 mol dm-3, and in the equilibrium mixture
there is 0.4 mol dm-3 of N2O4. Calculate the concentration of NO2 in the
equilibrium mixture.
1. Write the Kc expression
[NO2]eq2
Kc =
[N2O 4]eq
2. Substitute the values from the question into the equation
13.7 =
[NO 2]eq2
0.4
X(g)
Method 2
You are provided with the Kc value and the starting amount of a species.
3. Calculate the value of Kc for each of the following and its units
(a) For the reaction: 2HI (g) H2(g) + I2(g)
At equilibrium there are 1.8 10-2 mol dm-3 of hydrogen iodide and the
hydrogen and iodine are both at a concentration of 3.2 10-3 mol dm-3.
Example
For the following equilibrium system, Kc = 0.1
X(g) Y(g)
W(g)
N2(g) + 3H2(g)
There are 0.020 mol NH3, 0.015 mol N2 and 0.050 mol H2
in a total volume of 750cm3.
4. For each of the following calculate the Kc value and give its units:
(a) This question is about the reaction: N2O4 (g) 2NO2(g)
0.4 moles of N2O4 is allowed to decompose. At equilibrium there
is found to be 0.1 mole of N2O4 in the 0.5 dm3 gaseous mixture.
2. Convert to concentrations
(c) When 1 10-2 mol ethanoic acid reacts with 2 10-2 mol ethanol
according to the equation,
CH3COOH(l) + C2H5OH(l)
CH3COOC2H5(l) + H2O(l)
(d) When 0.4 mol M is mixed with 0.4 mol N they react together
according to the following equation : 2M(g) + N(g) 4P(g)
In a total volume of 2 dm3 there is found to be 0.3 mol.
x
Then multiply up:
Expand brackets:
Rearrange to find x:
X(g) + Y(g)
the amounts of W, X & Y are 0.25 moles, 0.01 moles of 0.17 moles
respectively. The total volume is 1.2 dm3.
0.1 =
H = -15 kJ mol-1
2Y(g)
-3
(10 x)
0.1(10 x)
=x
1 0.1x
=x
1
= 1.1x
x = 1/1.1 = 0.91 moles
(e) This question is about the equilibrium : C(s) + O2(g) CO2 (g)
1 10-2 mol oxygen reacts with carbon and the system reaches the
equilibrium position. In the total volume of 200 cm3 there are 7.5 10-3
moles of carbon dioxide.
Chem Factsheet
Chemical Equilibria : Kc
5. (a) Kc is 15.6 mol-1 dm3 at 370oC for the system
(b) 6.67 mol- dm3 ([SO2]eq = 0.1, [O2]eq = 0.15, [SO3]eq = 0.1)
(c) 0.33 no units (Kc = (0.5 10-2)2 / (0.5 10-2 1.5 10-2)
(d) 0.025 mol dm-3 ([M]eq = 0.15, [N]eq = 0.175, [P]eq = 0.1)
A(g) 2B(g)
Kc = 0.02 mol dm-3 at 170o C.
At equilibriu,m the concentration of B is 0.12 mol dm-3.
What is the equilibrium conentration of A?
5. (a) 15.6 =
0.6
x2
15.6x2 = 0.6
x2 = 0.6/15.6 = 0.03846
x = 0.03846 = 0.196 moles
(b) 0.02 =
If there were 2 moles of R at the start, how many moles of R would
there be at equilibrium?
0.122
A
0.02A = 0.122
A = 0.122/0.02 = 0.72 moles
x
2x
0.88 (2 x) = x
1.76 - 0.88x = x
1.76 = 1.88x
x = 1.76/1.88 = 0.936 moles
Kc = 1 at 120oC
Six moles of F and six moles of G were used at the start. How
many moles of J will there be at equilibrium?
Answers
1. (a) Kc =
[N2]eq [H2]eq
[NH3]eq2
3
2
-6
mol dm
x2
1 = (6 x)(6 x)
(b) Kc =
[SO3]eq
mol-1dm3
[SO2]eq2 [O2]e
(6 x)(6 x) = x2
36 12x + x2 = x2
36 = 12x
x = 3 moles
(c) Kc =
[CO2]eq
[O2]eq
(d) Kc =
[NO2]eq2
mol dm-3
[N2O4]eq
(e) Kc =
(f) Kc =
(g) Kc =
(C(s)!!) No units
[H2]eq [I2]eq
[HI]eq2
No units
[CH3COOC2H5]eq [H2O]eq
[C2H5OH]eq [CH3COOH]eq
No units