Bai giai chi tiét aé thi th CHUYEN HUNG VUONG -PHU THO Ian 3 - 2016 86 GIAO DUC VA DAO TAO. DE THI THU THPT QUOC GIA LAN IIL NAM 2016 TINH PHU THQ Mon: HOA HQC THPT CHUYEN HUNG VUONG Thos gian lam bai: 90 phi; (30 cdiu treic nghiém) Cho biét nguyén tir khéi ctia cdc nguyén 6: H-=l, Lis 7, C = 12, N= 14, 0 = 16, Na = 23, Mg = 24, Al = 27, S =32, Cl = 35,5. K = 39, Ca= 40, Cr= 52; Fe = 56, Cu = 64, Zn = 65, Ag = 108; Ba=137 Cau 1: X 1a ancol no, ¢6 cng thite don gidn nhat la CHyO. Céng thite phan ti ctia X 1a B. C3H0s. C.CH.O. D.CiHi20. Hwéng dan giai Bién luan X: (CHO), voi s6 nguyén tir H ludn la s6 chin (1) va so H < 2.86 C+ 2 (2) + Véi n= 1 suy ra X la CHs0 —» Loa + Voi n=2 suy ra X la CHs02— Thoa Toi dy khOng cén x¢t nifa vi cing ting n thi khéng thoa diéu kign s6 (2) = Chon A. Cau 2: Nude citng 1a nude 66 chita nhic ion nao sau day ? A. Cl vaSO” B. HCO; Ca vag D. Na‘ va K*. Hwéng din giai = Theo dinh nghia thi nude eéing la nude chtta nhiéu ion Ca" va Mg’. > Chon C. Cau 3: Dé hoa tan hoan toan a gam Al(OH); can vita dit Vj lit dung dich NaOH IM hoi V2 lit dung dich H,SO1 1M. Ti lé Vi: Vala Alek B.2:3, C.3:2. D.3:1 Huéng din giai NaOH: Vj mol—>V; = AI(OH)s Amol 8 [Vii V2 =2:4)—> Chon B. HSO4 : Vo mol—>nyy- = Moy, > 2V2 = A. Fes. Zn. D.CaCOs. Huéng din gitti (Cau 4: Chat X tac dung voi a dich HCI dic, dun néng tgo ra khi Cla, Chat X la — Chon B. Phuong trinh: MnO; + HCkaj.) > MnCl: + Ct + HO Luu ¥ : Diéu ché Cl trong phong thi nghiém bang mé hinh sau Tan Thjnh — Hoang Phan Trang 1Bai giai chi tiét dé thi th CHUYEN HUNG VUONG -PHU THQ lin 3- 2016 ~ MnO; ¢6 thé thay thé bing KMnO,, KCIO3... binh chite dung dich NaCl dé hap phy khi HCI bay hoi trong qué trinh dun ndng, binh chira dung dich HzSOs aie) €é hap thy hoi nude va khi thu duge la Clz la tinh khiet, Béng tam dung dich dich xut dac de tranh Cle ré ri ra ngoai trong qua trinh diéu che. (Céu 5: Cho 1,92 gam hén hop gdm MgO, CuO, FeO tic dung vira di véi 100 ml dung dich HSO, 0,3M. thu duoc dung dich X. C6 can X thu duce m gam chat rin khan, Gié tri cia m 1a A. 4,80. B. 4,32. C. 3,60. D. 3,84. Huéng dan giai {MgO, CuO, FeO} +HSO4 —> Ran X +H20 192 gam 0.03 mat mean BTKL. 1,80, — >| Taco: nu,o joxt + Myz,50, —_My,0 = 4,32 gam] — Chon B. 192 “oie 00318 Cau 6: Phuong phap diéu ché kim loai bang cach ding cac chat khir C, CO, Hg dé khtr ion kim loai trong hop chat 6 nhiét d6 cao doe goi la phuong phap ‘A. dign phan dung dich. C. thuy luyén. D. dign phan néng chay. Huéng din giai Lew huong phap dieu che kim loai bang cach ding cac chat khur C, CO, Hg de khir oxit kim loai dimg, sau nhom. = Chon B. Cau 7: Cén bing hod hoc sau duvoc thyc hign trong binh ki: PCIs(k) <= PCIs(W) + Cla (Kk) AH>0 Cn bang trén chuyén dich theo chiéu tir trai sang phai khi A. ting néng dd Cle. B. ting dp suat. C. ding chat xtc tae. D. ting nhiét d6- Huong din (Cau Az Tang néng 46 Cle lam can bang chuyen dich thiéu chiéu gidm Cle la chigu nghich Cau B: Tang dp suat kim edn bang chuyén dich theo chiéu giam ap suat (tire la cde chat trude phan tmg e6 hé s6 khi nho hon sau phan dmg) la chiéu nghich Cau C: Chat xitc tac khéng lam ean bing bi chuyén dich Cau D: Ta co AH>Ossuy ra phan img nay la phan img thu nhiét mudn lam edn bing chuyén dich sang chiéu ‘thudn thi phai tang nhiét 46, = Chon D. Cau 8: Cho 4,44 gam mét axit don chirc X vio 600 ml dung dich chtta NaOH 0,1M va KOH 0,1M thu duoc. dung dich ¥. C6 can dung dich ¥ thu duge 9,12 gam chat rin, Céng thite cua X 1a A. HCOOH. B. C:H;COOH. C. CH,=CHCOOH. D. CH,COOH, Huéng din BIEL, my + myo +MKOH = Man + ™MH,0 + 4M “0640 0056 912 >Mx = 74 [X:C,HjCOOH] — Chon B. (2x ="H,0 Cu 9: Thiy phan hoan toin 12 gam loai bang thién nhién trong dung dich H2SOj long, dun néng, sau 46 lay toan bét Iuong glucozo thu duoc dem phan ing trang guong, tao ra 12,96 gam Ag. Ham luong xenlulozo e6 trong bong do la: B. 72%. €. 90%. D. 60%. Tan Thinh — Hoang Phan Trang 2Bai giai chi tiét dé thi thir CHUYEN HUNG VUONG ~PHU THO Lin 3 - 2016 Huwéng din giai Trong Béng cé chita thinh phan chinh la xenlulozo. (CoHoOs) > CoHiO5 AWN 528 Nacrnctiyo, = Oto 0,06 «006 0.12 shin hoan toan triolein trong dung dich HzSO, loang tao ra axit béo la ‘A. CittgCOOH. B. CyyHssCOOH. C. CisHyiCOOH, D. CyzHs,COOH, Hudng din giai 100% = 81%] > Chon A. 17HCOOH + Axit stearic: C7HysCOOH Ci7Hy;COOH + Axit panmitic: CsHs\COOH = Phurong trinh: (C)zHzyCOO)C3Hs +H, 222% CyHs(OH)s + CyHayCOOH. Chon A. (Cau 11: Cap chat déu thude loai polime ting hop la A. Poli (mety! metacrylac), to tim C. Polipropilen, xenloluzo D. To xenlulozo axetat, nilon-6,6. Huéng din gidi ~ Cac polime thién nhién 14: xenloluza, to tim - Cac polime tang hop la: poli (mety! metacrylac), polipropilen, nilon-6,6, poli (vinyl clorua), polibuta-1,3- dien. - Cc polime ban téng hop (nhan tao) la: to xenlulozo axetat. » Chon B. (Cau 12: Cho 10 gam hén hgp Mg, Al, Fe vao 100 ml dung dich H2SOj 1,0M thay cén lai 5,6 gam chat rin cchua tan, Tinh thé tich dung dich H2SO, 1,0M cin dung dé héa tan hét 10,0 gam hén hyp X la ‘A. 250 ml B. 225 ml C. 200 ml D. 275 ml Huong din gi 10 gam{Mg; Al; Fe} + H2SO4-——»5, 6 gam chat rin Or mal ‘Voi khoi long chat ran nhur trén ta 6 the du doan duge do la Fe du (vi 5,6 chia hét cho 56). fy = BHO. + Meds _ 9,» ‘Vay dé hoa tan hét 10 gam HSQq thi can luong thé tich Li Nhjn xét: Bai todn nay thién vé hung dy dodn hon, that chét ma ndi thi ta khéng thé nao xéc dinh 13 rang dugc luong chat rin véi nhiing dir kign ma dé bai cho duoc. + Chon C. (Cau 13: Bign phn 400 ml dung dich NaCl 0,2M (dign cuc tro, c6 mang ngin). Sau mét thai gian, 6 anot thu duge Wit khé (ake) va dung dich thu duge c6 pH = 13 (coi thé tich dung dich khng thay 46i trong qué trinh dién phan). Gia tri cia V Ta A.0,224. B. 0,896. C.0,448. D.0,112. Hung din gift Tu pH = 13 — [OH™]=0,1M > ny,on =0,1.0,4 = 0,04 mol 2NaCl + 2H20 —>2NaOH + H2 + Cla — Yomi =0,04 mol + V= 0,04» 0,02 0,02 > 896 lil + Chon B, (Cu 14: Khi hidrat hoa m6t anken X thu duge mot ancol no, don chire duy nhat. Anken X 1a : Tin Thinh — Hoang Phan Trang 3HUNG VUONG -PHU THO Ian 3 - 2016 Bai giai chi tiét a@ thi thir CHUY! A. propen B. 2-metylbut-2-en C. but-2-en D. but-1-en Huéng din gidi ~ Anken X phai 6 tinh di xting vay X la but-2-en (CHs-CE SH-CH:) — Chon C. Cau 15: Cap chat déu tic dung voi dung dich NaOH (dun néng) la A. phenol va ancol etylic. C. nati phenolat va axit axetic. D. phenylamoni clorua va anilin Huéng dan giai ~ Cc chat éu tac dong véi NaOH gdm e6 phenol, alanin, etyl axetat,axit axetic, phenylamoni clorua > Chon B, iN Cau 16: Khi gay ra higu img nha kinh la B. SO». C. Os. D.No. Huéng din giai ‘Tim hiéu vé hién tong higu dng nha kinh nhén logi voi tae nhan chinh la CO2. * Trong nhiing nam gan day, van dé nong 1én toan céu chinh la moi lo chung cua toan nhan loai va ai trong ching ta it nhigu ciing y thie duge anh hudng eva n6. * Ching ta biét rng, khi Trai Dat- ngéi nha chung cia ching ta néng lén, thi tit cd moi hoat déng, cia ching ta s€ bj anh huong, va hon hét 1a sie sng cia nhan loai chiing ta, ciing nhur cia toan thé cae sinh vat xinh dep trén trai dat nay dang dan di vao quy dao cita su hy diét. “DO LA DiEU KHONG Al MONG MUON”. * Gan day, dién ra rat nhiéu sy kién xoay quanh dén vin dé néng Ién todin cau dién hinh la: Trong I trao gid Oscar lan thir 88 nam tai tir Leo DiCaprio 4a néu én quan diém nh vé van, dé bién ddi khi hau trong hic phi Hoi nghi COP 21 dién ra tai tha d6 Paris — bigu nhan gi Phap nam 2015 1, Higu dmg nha kinh 1a gi? ~ Higu (ing nha kin 1a higu img Lim cho khéng khi ciia Trai 6 thé xuyén qua tang khi quyén chiéu xuéng mat dat; mat quyén dé CO; hap thu lam cho khéng khi nong én, ~ Su thay déi néng d6 cua cdc khi nha kinh trong vong 100 nam lai day (dioxide carbon tang 20%, methane ting 90%) da khuyéch dai higu ting nha kinh 1én rit nhiéu khién nbiét d6 tdi dat tang lén 16i 2°C. 2. Nguyén nhan gay ra higu dng nba kinh ? ~ Cac khr gay ra higu ing nha kinh bao gom: COz, kh metan (CH,). kh CFC, ozon, cac oxit cia nito, Nguyén nhan chinh van la kh‘ COz.Day a loai khi gay higu tg nha kinh manh vi nd chiém ty trong rat lon trong bau khi quyén, Nong d CO, da TANG lén 38% ké tir cude Ciich mang Céng nghigp. - Cae kh nay sinh ra la do hoat déng nai lita, con ngudi sir dung cac loai nhién ligu nhur dau mé, khi dot, than da, khi thai tir nha may, cdc khu céng nghiép, chat pha rimg, dét rimg bita bai dé lay dat tréng trot, siz ting dan s6 nhanh chéng,..... Chinh nhiing diéu nay d& lam gia tang lugng khi COz mot cach nhanh chéng., 3. Anh hudng ? At néng lén do bre xa song ngan cia Mat trai ip thu néng 1én lai bite xa s6ng dail vio khi Tan Thinh — Hoang Phan ‘Trang 4Bai giai chi tiét 4@ thi thir CHUYEN HUNG VUONG ~PHU THQ lin 3 - 2016 ~ Néu khOng 06 higu ting nha kinh, thi nhiét dO trén Tri Dit s@ chi 1a - 15°C — mot nhigt 46 ma Khong phai bat ki sinh vét ndo trén hanh tinh nay cing c6 thé thich nghi duoc, nhung nb cé higu img nha kinh, ma nhigt dé trén Trai Dat duoc nang lén, tao diéu kign thich hgp cho céc sinh vat phat trién ~ Anh hudng Ién nhat cia higu tng nha kinh ti Trai Dat la gay bién déi khi hdu, hién tuong am 1én toin edu. - Lam thay déi hoat déng cua chu trinh hoan luu khi quyén, chu trinh nude, cdc hé sinh thai, nguy co tuyét chiing cia eae loai déng vat - Nhiét d6 Trai Dat ting 1én lam bang tan 6 hai cuc. Muc nude bién dang cao lam ngap mét sé déng bing thap. ~ Suy gidm chat luong ngudn nude, Nan chay rimg lim gidm dién tich ring tu nhién va gay 6 nhiém khéng khi, gia tng céc con bao, cée hign tuong thoi tiét cue doan, - Cac thién tai gay mat mia lién tuc, anh huéng lon dén nén néng nghiép, gay thiéu hyt luong thye thuc pham. - Site khée con ngudi cing bi anh hudng khong hé nhd. Nhiéu loai bénh tét moi déi véi con ngudi xudt hign, cdc loai dich bénh lan tran, sire khoé cua con ngudi bi suy gidm 4. Bign phap lam giim higu dmg nha kinh ? - Trong béi canh bien dang ddi khi hau lo ngai,chiing ta can co nhimng bién phap cu thé. Ké tir thang 11/2007 dco khong 175 mud ki két tham gia ban théo va ki két higp ude nghi dinh thu Kyoto, Céc qude gia nay phai chap nhan vige cit gidm lugng khi CO2. ‘Trén thé gidi: ca bién phap kh6ng it phire tap va cong nghé khoa hoe nh + Chén khi'COp duci day bién: co thé giém 5 trigu tin CO2 hoa léng méi nam va uu tri trong thoi gian 1 van nim. + Ding HCFC thay cho CFC: HCFC ¢6 tac hai chi bing 1/10, 1/50 so vai CFC nhung khong gay hai cho ting ozon. + VA mét sé bign phap céng nghé khée dang trién khai nhur - Trdng nhiéu cay xanh, Ngan chan cac nan pha ring, dét ring. - Han ché long khi thai CO2 tir eée phuong tién giao théng bing cach di b6, di xe dap. - Xtrli khi thai nha may xi nghigp, sinh hoat. ~ Sir dung nguén nang long sach nhu: anh sing mat trdi, gid nude. - Tuy€n truyén, chung tay bio vé mai trudmg xanh, sach, dep. * Méi ngudi chung ta co thé thay ddi cudc sng ciia minh bang nhimg vige lam nhé nhat. Néu tat ca moi ngudi trén trai dat déu lam duge diéu dé thi trai dat nay s& due ciru. Chi voi hanh déng nho, don gian, ban da gop phan bao vé trai dat nay. tao carbon, Cau 17: Nung nding hén hop g6m 0,36 gam Al va 0,76 gam Cr2Os dén khi phan img xay ra hoan toan, thu duge hén hgp X. Hoa tan hoan toan X cén t6i thiéu V ml dung dich HCI 1M. Gia tri cia V 1a A. 80 B.90 c.70 Hung din git Huéng tw duy 1: Tan Thinh — Hoang Phan ‘Trang 5Bai giai chi tiét a@ thi thir CHUYEN HUNG VUONG -PHU THQ Lin 3- 2016 1 Alay ggp mol + HCL 2Al+CrO3—>2Cr + Al,Os 1 X }Cr:0,01mol +2HCl = —>Vyci = 75 01005 > 0,01 0,005 | 41,05 :0,005 mol +6HCI Hung tw duy 2: Khi cho X téc dung véi HCI thi dung dich thu duoc sau phan ting 06 ant; BENEAL SF mm Cr2*: PINES 50,01 mol; Cr: —8°" 0,06 mot —| Vier a 0,06 tit] —> Chon D. Cau 18: Dung dich mudi nio sau day khi cho vao dung dich HCI, dun néng sé cé phan ting xay ra? A. FeSO,, B. Fe(NO})s. C. FeBre, D.Fe(NOd):, Huéng din g = Chon D. Phuong tinh: H’ + Fe" +NOs > Fe + NOt + HO (Céu 19: Cho cac chat: HOCH:CHZ0H, HOCH,CH,CH,OH, CHsCOOH, CgH,205 (fniictoz6). Sé chat phan img duoc véi Cu(OH)z tao dung dich mau xanh lam li ‘<3, BL. C2. D4. Huwéng dan giai - Cc chat e6 chira it nhat 2 nhom —OH lién ké nhau va cae chat c6 chira nhom chire axit eacboxylic COOH déu c6 kha ning tao thanh dung dich mau xanh lam khi tham gia phan ting véi Cu(OH) 6 nhiét dé thuéng, ~ Cc chat théa man: HOCH,CH,OH, CHsCOOH, CeH;20s (fructozo). —> Chom A. (Cau 20: Tien hanh phan ting tong hop amoniac tir mét han hop gom 4 lit No va 16 lit Hz. Sau phan img thu duge 18 lit hén hop khi (cdc thé tich do 6 cing dieu kign). The tich Nz da tham gia phan ting i B.3,0 lit. C.2.0 It. D.1,5 hit Huéng din giai Np +3H, <=" 22NHy 4 16 £ 3x 2x 4-x 15-3 2x my, +ny, +nyy, =18 > [c= 1] — Chen A. iste Gx 2x (Cau 21: Dung dich chita hai chat tan (c6 ti 1é mol 1:1) nao sau day khéng lam déi mau quy tim A. Axit oxalic va Anilin. B. Alanin va Metylamin, D. Axit Axetic va Glyxin. Hwéng dan giai ~ Cae axit cacboxylic: lam quy héa 45 - Cae amino axit e6 s6 nhom ~COOH > nhoim -NH2 : Lam quy héa héng. - Cc amin (triranilin), amino axit co sé nhom ~COOH < nhom -NHp : lam quy tim hoa xanh. - Cac amino axit co sé nhom -COOH = nhom —NE; : khéng lam déi mau quy tim. Cau A: Axit oxalic (HOOC-COOH): héa do ; Anilin (CgHsNHz): khéng lam déi mau ‘Tin Thinh — Hoang Phan ‘Trang 6Bai giai chi tiét 4@ thi thir CHUYEN HUNG VUONG ~PHU THQ lin 3 - 2016 (Cau B: Alanin (H,N-CH(CHs)-COOH). khong lim d6i mau ; Metylamin (CHjNHE): hda xanh, C4u C: Axit Glutamic (HOOC-(CH2)2-CH(NH:)-COOH): hoa héng, Lysin (HeN-(CHz) -CH(-COOH)-NH2): hoa xanh. Cau D: Axit Axetic (CHs-COOH): héa dé ; Glyxin (HeN-CHy-COOH): khéng lim 46i mau = Téi diy can phai lau ¥ cu hoi clia dé bai Ia hoa tan 2 chat theo ti I€ mol 1:1 do do xiy ra 2 trudng hop TH): Ca 2 chat déu khong lim déi mau quy tim, Vi cae dap fn 6 trén thi khéng c6 cau nao théa THz: Trong 46 co 1 chat kam quy tim hoa do (héng) va 1 chat kam quy hoa xanh, Tir cae phan tich dap an 6 trén ¢6 thé nhdn thdy cau C théa man. —> Chon C. Cau 22: Hén hop X gm 2 ancol no, don chite, mach hé vi mét hidrocacbon, Dot chiy hoan toan mot luong X cn vita da 0,07 mol Oz, thu duoc 0,04 mol CO2, Céng thitc cia hidrocacbon trong X la A. CoH. B. CoH. CCH. D. CrHs. Huéng din gi Nhin vio dap an thi ta thay hidrocacbon cn tim thude mét trong 2 diy dong ding cia anken va ankan. Ta xét hidrocacbon thude day déng ding cia ankan. [CuHemOH 0,007, [CO2 :0,04 — e007, [CuMamea |[H,0 X<ét hén hop chi chia ankan: Peg Haas = 2(l0, —L,51¢0,) = Pe, 0.02 Vay hidrocacbon can tim la CHy (logi CaHe vi néu la CH thi s6 mol COp sinh ra sé 1én hon 0,04). = Chon C. Céu 23: Thay phan khéng hoan toin hexape bao nhiéu dipeptit ? A.2. B.5. &3. D4. Hudng din gidi X c6 cau tric: Gly-Ala-Val-Gly-Gly-Ala cé thé thu duoc Tir peptitX thiyy phan thu due ede dipeptit sau: Gly-Ala ; Ala-Val ; Val-Gly ; Gly-Gly. Co tat ca la 4 — Chon D. (Cau 24: X va Y la 2 nguyén 16 canh nhau trong cing chu ky ciia bang tuan hoan cac nguyén té hoa hoc. X & nh6m VIA, co tinh phi kim manh hon Y. Hoa tri cia Y trong hop chat voi hidro la Al B.4. C3. D.2. Hudng din giai X 6 nhom VIA vay suy ra ¥.6 nhém VA hoie VIIA, vi X cé tinh phi kim manh hon ¥ vay suy ra ¥ thude nhém VA (trong, chu ki tir tri sang phai thi tinh phi kim ting dan) » Vay hoa tri cua ¥ trong hop chat véi hidro la 3 Chon C. Cau 25: Cho cac chat: ZiSO}, Al,0;, MOK, NagGO}, NaHCO}. sé ci tao két tia la AS. BA C.2. D.3. Huéng din giai phan img véi dung dich Ba(OH)2 ¥ Ba(OH), + ZnSO, — BaSO, 1 + Zn(OH)2 J. Néu ding Iugng dur Ba(OH), thi s8 tiép tuc xay ra phan img: Ba(OH)z + Zn(QH)2—> BaZnOz + HO hay Ba(OH)2 + Zn(OH)2 > Ba[Zn(OH)] —* Cudi ciing ta van thu duge ket tia 1a BaSOx, ¥ Ba(OH)2 + AlOs — Ba(Al0z)2 + H20 : phan ting nay khong tao két tia. + Ba(OH)2 + MgCl, > Mg(OH)2 | + BaClz ¥ Ba(OH)2 + NaxCOs —+ BaCOz 1 + NaOH Tan Thinh — Hoang Phan ‘Trang 7Bai giai chi tiét 4é thi thir CHUYEN HUNG VUONG -PHU THO Lin 3 — 2016 ¥ Ba(OH)2 + NaHCO; —> BaCOs, + Na,CO; + HO. Vay co 4 chat tao két tia voi Ba(OH)2 + Chon B, Cau 26: Cho 0,15 mol CO di qua dng sit chita 11,6 gam FeCOs, nung néng thu dugc 6 gam hén hop ran g6m Fe, FeO vao hén hop khi X. Ti khéi cua X so véi hidro la A. 18,0 B. 20,4 C172 D.19.6 Huéng din gidi 6 gam Fe, FeO FeCO,+ CO —>| 1@ —BTKL_s meeco, + Meo = Mey + Myyo + Meg +Meo, Tie 0us28 % sryre —>[Dxmn, =19.6] Chon D. ae reco, +co = "eo + Heo, ros (Céu 27: Hoa tan ba mudi nao sau diy vao nude duge dung dich X gém 0,35 mol Na”, 0,125 mol Mg”, 0,25 mol CI’ va 0,175 mol SO,"? ‘A. MgCl, NazSO4, NaCl. MgSOy, NaoSO4, MgCle C. MgSO,, MgCk, NaCl Hung din git ~ Dé xr li nhanh dang bai nay ta dua vao cac dap an dé xac dinh MgCl, > Mg’* + 2CI- Cau A: — Luong CI da phan tng hét do do khdng tn tai NaCl — Loai. 0,125 0,25 24 SOR cau B; M8501 > MB™ + SO wong Mg? da phan img hét do d6 khéng tén tai MgCl — Losi 0,125 0,125 Cau C: Tuong ty cau B. Cau D: Toi day cé thé chon ngay céu D. Kiém tra lai cho chinh xac: MgSO4 -> Mg** + SOf_ NazSOs => 2Na*+ SOP, NaCl-> Na*+ Cr 0,125 0,125" 0,1 0,05 * 0,25 0,25 — Chon D. Thea, (Cau 28: Cho cac chat: F@) Cu, FEO, CHO, FES, CuS. Sé chat tac dung duoc véi dung dich HCI La: 5 C.3 6 Hwéng dan giai + Déi voi cic kim loai khi tic dung voi HCI thi cdc kim loai d6 phai ding truéc cp H’/He trong day dién hoa. + bi véi cée oxit kim loai thi hdu hét déu tac dung trong dung dich HCl + Déi véi mudi sunfua Lam 3 nhém -Nh6m 1: mudi sunfua tan trong nuée nhur NaS, K2S, BaS, AlSs, Cr2Ss..., - Nh6m 2 : mudi sunfua khéng tan trong nude nhung tan trong axit lofing nhu MnS, FeS, CoS, NiS, ZnS, - Nhém 3 : Sunfua khdng tan trong nude va cing khéng tan trong dung dich axit loang nhu CuS, AgS, CaS, HgS, SnS, SnSp, PbS, AsySs; AsiSs. Cée chat théa man g6m c6: Fe, FeO, CuO, FeS. >» Chon A. Cau 29: $6 dang phan cau tao cé chua vong benzen img véi céng thire phan tir C7HgN 1a Tan Thjnh — Hoang Phan Trang 8Bai giai chi tiét a@ thi thir CHUYEN HUNG VUONG -PHU THO Lin 3- 2016 AB B.6 C4 i Huéng dan giai CHANH, CHs CH) cH, NH—CHs NH. NH, — Chon D. Nis C4u 30; Xa phong héa mot este X mach ha ( c6 ti Khdi so véi CHy bing 5,375), thu duoe mot andehit va ‘mot mudi ciia axit hau co. Céng th Xa ‘A. CH»=CHCOOCHs 'B. CH,COOCH=CH C. HCOOCH=CH D. CHsCOOC2Hs Hudng dan gidi ~ Vi khi tham gia phan Ging thiy phan ta thu duge andehit ta loai A va D Ma Mx = 86 > IX: CH;COOCH=CH_ Chon B. Cau 31: Hin hop A g6m 2 este don chire X, ¥. Cho 0,05 mol A tic dung vira di véi dung dich NaOH thu duoc hén hop sin pham hitu co B. Bét chay hét toin bé B thu duc NazCOs va 0,12 mol CO,; 0,13 mol H,O. Khi fam bay hoi B thu duge m (g) chat rin. Gia tri cia m la B.5,84 C.5,62 D.34 Hudng dan giai Ix (NazCOs Ay +NaQH—>B— 2 5/0, :0,12 mol 0.05 mol (H20:0,13 mol X@ THi: X, Y déu mach ho, don chite co dang edng thie chung: RCOOR’ EINES ymya,coy =" GH == 0.025 mol. {BINEC .6.05.C, Chon D. Xe THe Trong A 06 chat thuse loi este cia phenol. Goi, eon camel :RyCOOR; :b mol 4 gam 05.79 = 3,95 gam ENT neo, = = 2 mo _BINTC 9 95 Ca =n, +¥4s60, =O2+4= 0,50 Cy < PAL =2,9 Suy ra Y co céng thie cau tao: HCOOCH3 BINT.O , 2, +nyaon +2No, = 3nNa,co, +2Nco, +N4,0 > No, = (0,185—0,75b) mol 2G) zac TS@art) 2012 O11 Tan Thjnh — Hoang Phan Trang 9Bai giai chi tiét a@ thi thir CHUYEN HUNG VUONG -PHU THQ Lin 3- 2016 a mB +Moz =MNaxCO FMC: +MHLO _, wy 4 37h +32. (0,185—0,75b) = 53.(2a+b) +7,62 m=Mp ~—McH,OH Thay cac gid tri cia m tir dap ap két hop véi pt: a +b = 0,05 dé giai. Nhan thay ring chi co cau A cho ra sé dep cén lai la sé x4u. Vay tir d6 chon A. Nh xét: Bai nay tac gi mudn hudng toi THz hon la TH: vige khdng tinh t6i TH, 48 lim cho bai todn ¢6 ti 2 dap s6. Do dé dé di ding hudng cua bai toan thi nén cho sé ligu cla NaOH ho&e cia NayCOs va bé di 6 liéu ctia H2O lic dé bai todn sé tro nén chinh xac hon. (Cau 32: Hoa tan het 16,32 gam hén hgp Fe va Cu trong 134,4 gam dung dich HNO; 45%, thu dugc dung dich X (khOng chia mui Cho X phan ting véi 400 ml dung dich hén hop gm NaOH 1M va KOH 0,5M, thu duge két tiia Y va dung dich Z. Nung ¥ trong khéng khi dén khéi long khdng déi, thu duoc 21,6 gam Fe,03 va CuO. C6 can Z, thu duge hon hop chat rin khan T. Nung T dén khéi luong khong doi, thu duge 43,44 gam hén hop chat rin, Nong d6 phan tram cia Fe(NOs)s trong X ¢6 gia tri gan gia tri nao sau day? ‘A.20 B.6 c.10 Da Hwéng dan giai Fe(OH), Fe(OH), {Fe,0s,Cu0} Fe pet Cull, a Fe ie {Fe _wnoyoss .y Joye , [KOH:0.4 i (Nat.K* Nea saegeeccaae NaOH:0,2 {Nak |e [Na“K NOs ~,OH- iF 1632 gam NO; OH NO; OH 43.44 (g) Me +Mcy =16,32 Sox Gly nye =0,12 mol + —BINEE.CH smg..0, +Mowo 2216 Ney = 0.15 mol 80x, bar’ BION 4 = gg Hy, cau ad 02 lon = 0 EM sms. tm Mog +My, = 43.44 {ra oe 04a, 02:39 BrDriX) - EIDE ano + Sg. +2heyes = Myo, 015 gs6 nye. =0,1 mol 2] TIDE eng 12 — a ce Mp gs» = 0,02 mol BINT:N - Se a 0) ~ "No, m™) =e Maui = Mp2 +My. +Mo,2, +My, =51,04 gam 7 Fe _ 7 a] > mgg 9 = 120,16 (Q) ™My,0 = My,o1dsHNO,) + ™1,0(nphan) = 69.12 gam —+ [26Fe(NO,)3 = 4,023%] —> Chon D. ‘Tin Thinh — Hoang Phan ‘Trang 10Bai giai chi tiét dé thi th CHUYEN HUNG VUONG ~PHU THQ lin 3 - 2016 Cau 33: Hoa tan hoan toin 19,2 gam hin hop X gm Fe, FeO, FesO, va Fe,O; trong 50 ml dung dich H,SO, 18M (dic, du, dun nong), thu duge V lit kh SO2 (Akt, sin phim khtt duy nhat) va dung dich ¥. Cho 450 ml dung dich NaOH 2M vao dung dich ¥ thu duge 21,4 gam két ta. Gid tr ctia V1a B.5,60 C.448 D.3,36 [Fe ix {E+ HeS044 3° x20: 09 mo HE Yo ESD ttec au — yy [S04 __sneonco9mel_, | Fe(QH)s 0,2 mol ‘ 9m 1H, 192 gam aa H,0 [_BUNT:Fe BINEFS snpe = mpe(orp, =0,2mol : NEe = NFe(OH). imal — BE 3npe = 2no +2ngo, nso, <0 (em 5 mgs +mo 9,2 no = 0,5 mol 302 205 Vigc ta khang dinh s6 mol Fe ban dau trong X la 0,2 1a sai nhur da chiing minh 6 trén. Goi mol Fe; O va SO, ban dau lan luot la a mol (a > 0,2) ; b mol va.¢ mol (neon = 3nFe(OH), +My, —> Nyy, =03mol — 302 {PE vangoy =3ng.s + ypr4q > Mgoy- = 15a+0,15 {®2* 2nso, =3mre—2no > 2e=3a—2b +1 BINTS 5 nis.s0, =Mgoz- so, > 1,5a +015 + e= 72 Ii [Mx = mp. +m > 56a +16b=19,2 = Chon A, Cau 34: Cho m gam Mg vao dung dich chita 0,02 mol Fe(NO;)3 va 0,05 mol Cu(NOs)2, sau mot thoi gian thu duoc 2,14 gam két ta vi dung dich X chita 3 mudi, Tach lay két ta va them tiep 8 gam NaOH vio dung dich X, sau khi cic phan cing hodn toan thu duoc 6,48 gam ket tia. Gia tri gm mhat cua m la B.ALat €.2,40 D.4,32 Huéng din giai fant J NOW:02 | A(QH), a 008 Neem (Noy :016 ae Cu(NOs)p :0,05 ti ze MacoH), ~ Ma + Morr oi? o16ir +} FEE sto = yo, —>[myjy =1.58(@)] > Chon A. ous. BTKL: kimloal = Mp. Mga +My = My +My 0.0256 O0564 2a Tan Thinh — Hoang Phan Trang 11Bai giai chi tiét 4@ thi thir CHUYEN HUNG VUONG ~PHU THQ lin 3 - 2016 Cau 35: Cho 20 gam hin hop X gdm Fe, FeCOs, Fe203 vao dng sit nung nong va din tr tir 0,2 mol hin hop kh gém CO va He (ti khéi so voi Ho bang 4,25 ) qua dng sit sau mot thoi gian thu duoc hén hop rin Xi va khr Y;. Cho kh’¥, hap thu vao dung dich Ca(OH), du thu duge 7 gam ket ttia va 0,06 mol khi Ye (ti khdi so voi Hz bang 7,5). Hoa tan X; bing dung dich HNOs (dic, nong, dur), thu duroe dung dich Z, va 0,62 mol hop hai khi trong 46 ¢6 mét khi mau néu d6 li sin phim khi duy nhat eta N°°. Néu cho X téc dung véi dung dich H,SO, (dc, néng, du) thi thu duge 0,225 mol hn hop 2 khi, Phan trim khdi long ciia FeoOs trong X la A. 32% B. 48% C. 16% ‘D. 40% Huéng din giai / [coe ‘CaCOs :0,07 mol(=nco,) Yad Hedy 5) Hi gg 0,03 mol / con CO :0,03 mol CO:0,05 mol Soe ‘ Fe:a mol \ O15mol 7 B20: 9015 -0,03=0.12 mol X4FeCOs:bmol+{ | ————~ Fe: BINT ya sh+2e Fe2O3: ¢ mol \ X40: —BINEO 53h #'3¢ 0,242 HNO ib ae ite C:BENEE 50,05 : BINTC H,S04 acd —>] 02> S02 :0,225=b [B2omee +mreco, =m, =20 (56a 116b--160¢—20 —{ x BEY, 3nge +mpeco, =2Ns0, > {3a +b =2.(0,225-b) [xi EES 43nge-+4me =2ng + x0, 3.€a-+b+20) + 4.(b-0,05) =2.8b+ 3-0, 24) +0,67 -b ‘a =0,09 —>{b= 0,06 —4}%mge,0, c= 0,05 0,05.160 20 100% = 40%] — Chon D. Cu 36: Cho cic chit saul (5) mudi a-amoni axetic clorua. $6 chat tac dung véi NaOH va HCI la? - Tat ca eac chat trén deu tic dung duge voi NaOH, HCI trir chat so (5) chi tac dung duge voi NaOH. = Chon D. C4u 37: Mét hdn hop khi X gdm hidro, propen, propin. Dan hén hyp khi trén qua Ni nung néng, sat Khi phan éing xdy ra hoan toan thu duoc hon hop khi ¥. Chia ¥ thanh 2 phan bing nhau, Dét chay hodn toan phan (1) edn ding vira dit V lit Op (dkte). Hap thu toan bé sin phim vao nuée véi trong du, dung dich thu duoc cé khéi lung gidm 16,2 gam. Dan phan (2) qua dung dich Brz du thay co 16 gam Br phan img. Gid tricia Va A. 12,32 B.11,20 C. 15,68 D. 13,44 Hung din giiti Phan Ging xay ra hodn toan va dung dich Y + Brz —» Hz hét. Trong Y luc nay chi chira toan H.C Tan Thinh — Hoang Phan ‘Trang 12Bai giai chi tiét dé thi th CHUYEN HUNG VUONG ~PHU THQ lin 3 - 2016 Hung tw duy 1; Dat cOng thite chung Y la: C3Hx voi k 28x a (d6 bat bao hoa). Coy |e 108) fae C0002 A, ry, =16,2.gam X4 CoH SY (CoH, :a mol} | H,0:0,5ax mol i Hz P(t) 219 kny =ng, = 0,1 {mMco, +MH,0 ~Mcaco, =—Mgiam _, [4430+18. 0,5ax-100.3a=—16,2 {a=0,15 mol kny =m, = 0,1 [a.@-x)=012 \ax =1 mol —BINEO 2nco, +nH,0 = 2no, >No, =0,7 mol — V = 15,68 lit “iia 05 Huong tw duy 2: Dat so mol CO, va H20 lan lugt la a mol va b mol * —Mcaco, =—Mgiam | = {meco, +mu,0-Mecaco, =—Mym —(44a+18b-100a=-16.2/4 6.45 mol of kny =np., =01 > a > = b=0,5 mol a—b=0,1- {nco, mio = (k-1).ny 3 SINE, 2nco, +nu,0 =2no, ~> no, =0,7 mol — |V = 15,68 lil > Chon C. “2ias 05 Cu 38: Cho cae poline sau: ETAT, on ARAN, OSGI 5 polisopren poli (etylen terephtalat), S6 polime diéu ché bang phuong phap tring hop la A2 B.3 ~ Cae chat c6 chita lién két béi trong phan ti hoge vong kém bén thi c6 thé tham gia phan img tring hop do 1a cac chat: thay tinh hitu co, to nitron, to capron, cao su buna — § (déng tring hop), poliisopren. Luu Y: to nilon 6 va to capron déu ¢6 cimg céng thu don gian nhat, nhung néu nhu dieu ché tir phan ing trig ngung axit e — aminocaproic (HyN(CH2)s;COOH) thi n6 duge goi 1a to nilon 6, con néu nhur duoc ° aig 7 Cau 39: Cho cic chit va dung dich: SO2, HS, Bre, HNOs, CuSO, phan img timg di mét véi nhau. 6 diéu kign thich hgp, s6 cap chat phan img voi nhau tao thanh HSOy la digu ché tir phan img trig hgp caprolactam ( thi thu duge to capron = Chon D. B.6 C3 DA Huéng din {H,S—>S+H20 | Bry + HO—>HBr + HeSO, Br, + #20—>HBr + H,SOq ¥ SO +4 ¥ HpS+{ HNOs oang —>H2SO, +NO+H0 4+HNO3 joang —> H2S04 +NO+H20. {cuso >< HNO3 tae —>HBrO3 + NO2 + H20 CuSO; >< Co tt ca 5 phan dng tao thanh sén phim c6 HeSOy —> Chon A. CuSO, —>CuS, +HzS0, vBn+ ¥ HNOs + CuSO, >< Tan Thinh — Hoang Phan Trang 13Bai giai chi tiét aé thi th CHUYEN HUNG VUONG -PHU THO Ian 3 - 2016 Cau 40: Hay cho biét phuong trinh héa hoe cia phan tng nao sau dy khéng ding? ‘A. 2K2C104 + HeSO4 tng —> KeCteO7 + KeSOs + HzO B. 2KCr0> + 3H,02 + 2KOH > 2K,Cr0j + 4H20 D.K,Cr0; + 2KOH > 2K2CrOy + HO Huéng din gi — Chon C, Phuong trinh dang” 2K2CrO4 + 16HCI gse > AKCI + 2CrCly + 3Clz + 8H20 Cau 41: Cho 300 ml dung dich Ba(OH), 0,1M vo 250 ml dung dich Al,(SO,)s xM thu duge 8,55 gam két ta, Thém tiép 400 ml dung dich Ba(OH); 0,1 M vao hén hop phan ting thi lugng két tia thu duge 1a 18,8475 gam. Gié tri cla x la A, 0,06 D.0,10 BaSO,: NEP 0,03 mol + Cho Ba(OH), :0,03 mol + Alz(SO4)3 :0,25x ——» Mk anaes Al(OH) :0.02 mol BaSO, : 2250 _50,75x mol + Cho Ba(OH) :0,07 mol + Al (SO4)3:0,25x —>. . AN(Ons 88475: of T5X233 oy (néu mol BaSO, tinh theo mol Ba’* thi sé mol cua Al(OH)s sé bi xu). Voi diéu kién npaso, = 0,75x <0,07 +3 < Fo <4 —4n gp. — Noy =NAioH)s ‘AI 1884790194239 + [k=0,00M)— Chon B. —4.0,5x 0,14 = (Cau 42: Cho cac cap chat sau: 86 cap chat xay ra phan tng la AT B10 £9 D.8 Huéng din giai ()Hg +S Hgs (2) HaS + SO. S+H20 (3) NO +03 > NOz + Oz (4) HS + CuCl — CuS +HCL (5) 3NH3 + AICI; + 3H,0 > AI(OH)s+NH,Cl (6) SOz + NazCOs + H,0 — NaHSO3 + NaHCO} (J) K.CrO; + 2KOH — 2K,CrO, + HO (8) NaH2PO, + NagPO4 — NagHPOy (9) AgNOs + FeCl -> AgCl| + Fe(NO:)s (@) Ht + Fe + NOs > Fe®* +NO} +H.0 — Chon B. Cau 43: Hap thu hoan toan 8,96 lit CO, (dktc) vao V ml dung dich chita NaOH 2,75M va KpCO3 1M thu durge dung dich chira 64,5 gam hn hop 4 musi, Gia tri cia V la ‘A200 B. 140 Cc. 160 D. 180 Huéng din gi Tan Thjnh — Hoang Phan Trang 14Bai giai chi tiét dé thi thi CHUYEN HUNG VUONG ~PHU THO Lin 3 - 2016 k*;BINEK 2V mol 4 ,_BINT.Na (60310 Aum ee roe bd game) tees eereeaEE oor eA: K,C03:V mol cot sx mol HCO§ :y mol {__BIDT {PEPE ny: +Mygs = 2ggF- + NyCo; 2V+2,75V=2x+y {BIXEE sno, +1K,C0s =Meo +Myco; 7404+ V=x+y Weo2t [mics FMygs + MeoF +Myco; = 645 39.2V + 23.2, 75V + 60x + 6ly = 64,5 = Chon A. Cau 44: Hon hop T gm axit cacboxylic X hai chire ( c6 phan tm khéi long cla Oxi nho hon 70% ), ¥ va Z la hai ancol dong ding ké tiép (My < Mz). Dot chay hoan toan 0,2 mol hén hgp T ean vira dit 8,96 lit Khr Op (dkte), thu duoe 7,84 lit ‘Op (dkte) va 8,1 gam H20. Phan tram khéi lurong cia ¥ trong hén hop tren la A. 29,6% B. 29,9% LC. 15,9% D. 12,6% Huéng din giai R(COOH), (| _osoa ee ROH J H,0:0,45 02 R(COOH), (X) zn _ Boo, 4 0 = 88% <1,75 57 J CHLOH(Y) ae C, H,OH (2) {ang + mgpeot =0,2 am [Pant = By +My = | BESEO any +Mppaa +2N0, = 2M, *1,0 | ny = 0,05 04 035° 045 m:3 BINT 40,05.m+ny+2 mz =Mco, >4my 20,1 (Voi m la s6 nguyén tt C 66 trong X) (45-ry) 035 (nz :0,05 EL my + mo, =Mco, +My,9 > Mp =10,7 (g) —> [%my = 29,9] + Chon B 043 03544 045.18 (Cau 45: Hin hop X gém hai andehit don chitc, mach hé, déu khéng cé déng phan cing chite. Chia m gam hén hop X thanh 2 phan bang nhau. Cho phan (1) tac dung voi luong du dung dich AgNOs trong NHs, thu duoc 86,4 gam két tiia. Cho phan (2) tac dung vira dui voi | gam He (xu tac Ni, t° ) thu duge hén hop ancol Y. Ngung tu Y, r6i cho toan b6 san pham vao binh chtra Na du thay khoi lugng binh tang (0,5m + 0,7) gam, Phan tram khdi luong cia andéhit 06 phan tir khdi Ién hon trong X gan nhat voi gid tri A. 60%. B80% C.30% D. 40%. Huéng din gidi Tan Thinh — Hoang Phan ‘Trang 15Bai giai chi dt a8 thi thir CHUYEN HUNG VUONG -PHU THQ lin 3- 2016 ; ‘AgNOWINHS Goi x8 ™ aay emtyy «(PO eee Oem \B:b mol *\p(q Haast yy N00 yg = 0.54047 an re {ny =nx =2nn, Ta 22, my =0,5m+1—>4 > 0,5m+0,7=0,5m+1—ny nx =0,3 mol Myung = My ~My, a+b 1,3 0.1 Vi 2nx Trong X cé chira A: HCHO va B: RHO ap Tir 2 4ny, = mucHo +kme-cro —>k =2: B e6 | lién két x trong géc H.C 0s 03 02 Dé bai cho khuat an khdi lugng cia X do vay ta can phai bién luan CTPT B nhu sau: P ae 0.2.56 + Gia str B 6 géc -R nhé nit la: ~CoH: mp ==" ___100% = 78,9% ia iB c6 gbe-R nho nit la: Cally —99mB = 95 FF 9 ra5 + Néu cang ting 6c -R thi mp cang l6n khi db: 78,9% <%mp, < 100%, ‘Ti cdc dap an ta thay chi c6 B thoa diéu kign trén. — Chon B. (Cu 46: Dot chay 3,4 mol hén hop X gdm axit axe axit fomic va hai hidrocacbon mach hé, ke tiép nhau trong day déng ding cin diing vira dii 92,96 lit khi oxi (dktc), sau phan tmg thu duge 81 gam nude. Néu cho 3.4 mol hén hop X tac dung vira dit véi dung dich brom trong CCl dur thi thay eo x mol brom phan ting Gia tri cua xla A.0,70 B. 0,65 C.0,75 D.0,80 Huéng din giai sit hai hidrocacbon mach hé thude diy déng ding anken thi ta cd (CH,COOH ee 0, : 4,15 mol—> x{HcooH }+(-? H,0: 4,5 mol a Bi (CCL) x mat 3A mol 51H, No, Ns 15 fis RN g TGA ‘mol Tage +No,y,, = 34 Calan Vay trudng hop ta gid sit 1a dng = Chon D. Cau 47: Hop chat hitu co X 6 cong thire phan tir CsHyOs. X tic dung véi NaOH trong dung dich theo ti 1é mol 1:2, tgo ra mui cla axit no ¥ va ancol Z. Dan Z qua CuO nung ndng thu duge andehit T co phan ting trang bac, tao ra Ag theo ti Ié mol 1:4. Biét ¥ khéng c6 déng phan nao khac. Phat biéu nao sau day la ding? ‘A. Ancol Z khéng no c6 1 lign két C=C B. Axit ¥ cé tham gia phan img trang bac. Ancol Z. ie hoa tan Cu(OH)2 dé tao ca dich mau xanh. Hwéng din giai ~ X tic dung vai NaOH theo ti1é mol 1:2 suy ra X chira 2 chiic este. = T phan img tring bac, tgo ra Ag theo ti 1é mol 14 suy ra T c6 thé li HCHO hoe R(CHO):. Trong X eo A =3: X la este vong durgc tao tir axit no Y: HOOC-CH2-COOH va ancol Z: HO-CHe-CH2-OH ‘£00-CHe l Tan Thinh — Hoang Phan ‘Trang 16Bai giai chi tiét a@ thi thir CHUYEN HUNG VUONG -PHU THQ Lin 3- 2016 HG, CO0-CHy (Cai A: Sai. Vi ancol Z 1a ancol no 2 chite, mach he, (Cau B: Sai. Vi trong day céc axit cacboxylic thi chi co HCOOH tham gia phan tmg trang bac. Cau C: Sai. Vi etilenglycol co thé hoa tan Cu(OH), tao dung dich mau xanh lam Cau D: Daing. Andehit T la (CHO)z né Ia chat dau tién ciia day andehit no 2 chire, mach hd. = Chon D. Cau 48: Cho m gam hin hop X gdm Ba, BaO, Al vio nude dur phan ting két thie thu duge 3,024 Lit Khir (aktc), dung dich A va 0,54 gam chat rin khéng tan. Cho 110 ml dung dich HCI IM vao dung dich A duoc 5,46 gam két tia, Gid tri ctia m [a A.8,74 B.7,21 C82 D. 8,58 Hudng dan gi AP OO) Ba Al:0,02mol AL —*#i0_,( | Hp :0,135 mol Bal), Ba(AIO,), UE AI(OH),:0,07 Ngo. ~My ag 01), =F ogo, = 0.08 7 BINT: Pa > Bpa(Ald,); = B20 +B oo npg :0,015, +4) —PEe 2m, = 2p, +3nq. > npao 20,025 ——>|my =8,58 (@)| > Chon D ass yy, 10.08 BINTAL A, = Malo, 008 Lar § : sau khi tinh toan nhé cng thém luong nhém du thi méi thu duge két qua la 8,58 (g) Cau 49: Dét chay hodn toin m gam hdn hop X gm andehit malonic, andebit acrylic va mot este don ehite Y can 0,72 mol O», thu duoc 0,66 mol CO; va 0,44 mol HO. Néu cho m gam hén hop X trén tac dung vira a voi dung dich chita 0,06 mol NaOH thi thu duge dung dich Z. Cho Z tac dung v6i lugng dur dung dich AgNOs trong NH, khéi luong Ag t6i da thu duoc la ‘A. 34,56 gam C. 47,52 gam D. 43,20 gam Huwéng din giai OHC-CHy-CHO:xmol / 0, —> CO, + H20 X{CH) =CH-CHO:y mol eae 0.961 0,44 met RCOOR':z mol \ NaOH : 0,06 mol -> dd Z—*48%92/N_, my gam Ag nyson =2=0,06 mol : Taal —. > 2xty=0, BING say sy42242n0, =2nco, +40 86 C>— Reo. _ 0.66 2x+ytz 0,2+0,06 ‘Dé lugng két tiia thu duge téi da thi este 46 phai c6 dang HCOOCH;=CH-R”. = 2,54. ‘Tin Thinh — Hoang Phan ‘Trang 17Bai giai chi tiét a@ thi thir CHUYEN HUNG VUONG -PHU THQ Lin 3- 2016 CH (CHO), :x mol RCOONA:0,06 mols agnoy nity R"-CH2CHO: 0,06 mol C3H,0:y mol Ti (1) taco Mag =4x-+2y +22+22=0,4+0,12+0,12=0,64 mol — mag = 69,12 gam|— Chon B. Ag . ‘Cau 50: Hon hop A gém peptit Ala ~ X ~ X (X la amino axit no, mach hé, chira mot nhom —NHb va 1 hom ~COOH trong phan tt) va axit cacboxylic ¥ no, don chife, mach ho tae dung vira di véi 450 ml dung dich NaOH IM thu duoc m gam mudi Z. Dot chay hoan toan Z cin 25,2 lit O2 (dktc) thu duge hin hop khi gom CO», HzO, Np va chat rn NayCOs. Biét tong khéi luong cua CO; va H,O 1a 50,75 gam. Khéi luong cia ‘mudi c6 phan ti khOi nhé nhdt trong Z 1: A. 26,10 gam. B. 14,55 gam C.12,30 gam D. 29,10 gam Huéng dan [{CO,,H,0} 50,75 gam BINENS _, Na,COs : 0,225 Ala-X-X_ naon:045 NH, ~R-COONa A Moths 7 {reoon RCOONa Meo, +My1,0 = 50,75 20,775 +4_BINEO joo: 2n_coona +211, =3Ny,, «raceme fe 0,925 os 125 odes + Dat X va Y c6 CTTQ lan luot CuHen-102N, CaHanOz aoe INH,RCOONa Bu, Ro, n, = x 2 9,3 > A | Bale-X-X 5 05 =01 — Dyn, RCOONa Nrcoon | 0,15 eS nay xx -G+n+n)+NReooH = Meo, +MNa,co, >= m=2 01 018 ors oss X:NH, CH,COOH =12,3@)] — Chon C. —* cH,CooH —~ [Mc#:coo%s ®) on ‘Tin Thinh — Hoang Phan ‘Trang 18