1

Cu 1
Xc nh thnh phn pha lng v pha hi ca hn hp benzene - toluene
nhit 950C v p sut 760 mmHg. Cho bit p sut hi ca benzene v toluene
ph thuc vo nhit theo phng trnh sau :
Pbenzene = 106,90565 - 1211,033/(220,79 + t)
Ptoluene = 106,95464 - 1344,8/(219,482 + t)
Pbenzene : p sut hi ca benzene tnh bng mmHg
Ptoluene
: p sut hi ca toluene tnh bng mmHg
t
: nhit (0C)
Hn hp tun theo nh lut Raoult.
Cu 2
Xc nh nhit im sng ca hn hp hi c thnh phn ging nh kt
qu ca cu 1 (thnh phn ca pha hi) p sut 780 mmHg. p sut hi ca
benzene v toluene ph thuc vo nhit theo phng trnh ging nh trong cu
1. Hn hp tun theo nh lut Raoult.
Cu 3
Mt thit b lm vic p sut thng tch hn hp benzene - toluene c
thnh phn benzene (cu t d bay hi) l 37,5% (theo % khi lng). Sn phm
nh c thnh phn benzene l 96% (theo % khi lng), sn phm y c thnh
phn benzene l 8% (theo % khi lng). Nhp liu vo h thng nhit si.
3.1. Thit lp phng trnh ng lm vic phn luyn v trnh by cch xc
nh s on l thuyt, cho bit t s hon lu thch hp l R = 1,5 Rmin, s liu cn
bng ca h benzene - toluene c cho trong bng sau :
ybenzene
0 0,118 0,214 0,380 0,511 0,619 0,712 0,790 0,854 0,910 0,959 1
xbenzene
0 0,05 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,80 0,90 1
Nhit 110,6 108,3 106,1 102,2 98,6 95,2 92,1 89,1 86,8 84,4 82,3 80,2
si (0C)
3.2 Tnh lng khi lng sn phm nh, sn phm y v khi lng hi
ra khi nh thp, nu khi lng nhp liu vo h thng l 1000 kg/gi?

 2
Cu 1
Xc nh nhit im sng ca hn hp hi gm c 40% (theo % khi
lng) acetone (C3H6O), 40% (theo % khi lng) ethanol (C2H6O) v 20% (theo %
khi lng) methanol (CH4O). p sut tng cng ca hn hp l 750 mmHg. Cho
bit p sut hi ca acetone, ethanol v methanol ph thuc vo nhit theo
phng trnh nh sau :
Pacetone = 107,02447 - 1161/(224 + t)
Pethanol = 108,04494 - 1554,3/(222,65 + t)
Pmethanol = 107,87863 - 1473,11/(230 + t)
Pacetone
: p sut hi ca acetone tnh bng mmHg
Pethanol
: p sut hi ca ethanol tnh bng mmHg
Pmethanol
: p sut hi ca methanol tnh bng mmHg
t
: nhit (0C)
Hn hp tun theo nh lut Raoult.
Cu 2
Mt thit b lm vic p sut thng tch hn hp benzene - toluene c
thnh phn benzene (cu t d bay hi) l 30% (theo % khi lng). Sn phm nh
c thnh phn benzene l 90% (theo % khi lng), sn phm y c thnh phn
benzene l 10% (theo % khi lng). Nhp liu vo h thng nhit si.
2.1. Tnh lng khi lng sn phm nh, sn phm y, tnh khi lng
hn hp hon lu v t s hon lu.
2.2 Thit lp phng trnh ng lm vic phn luyn v trnh by cch xc
nh s on l thuyt, s liu cn bng ca h benzene - toluene c cho trong
bng sau :
ybenzene
0 0,118 0,214 0,380 0,511 0,619 0,712 0,790 0,854 0,910 0,959 1
xbenzene
0 0,05 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,80 0,90 1
Nhit 110,6 108,3 106,1 102,2 98,6 95,2 92,1 89,1 86,8 84,4 82,3 80,2
si (0C)
Cho bit khi lng nhp liu vo h thng l 1200 kg/gi?
Khi lng hi thot ra khi nh thp l 1080 kg/gi
T s hon lu c nh ngha l R = L/D. L l khi lng hn hp hon
lu v D l khi lng sn phm nh

 3
Cu I :
Mt dung dch lng gm c 256g ru methanol (CH3OH), 322g ru ethanol
(C2H5OH) v 300g acetic acid (CH3COOH) nhit 75OC.
1. Tnh p sut tng cng v phn mol ca pha hi cn bng vi pha lng ca dung
dch trn.
2. Xc nh nhit im sng ca hn hp hi c thnh phn ging nh thnh
phn pha hi cn bng vi dung dch lng k trn (kt qu cu 1) p sut tng cng l 0,9
atm.
Hn hp tun theo nh lut Raoult
p sut hi ca cc cht ph thuc vo nhit theo phng trnh nh sau :

P = 10A - B/(C + t)
Vi : P
:
p sut hi tnh bng n v mmHg
t
:
nhit 0C
A,B,C :
Hng s ty thuc tng cht tm trong bng nh sau
Hp cht
Acetic acid
Acetone
Ammonia
Benzene
Carbon di sulfide
Ethyl alcohol
Methyl alcohol
Toluene

Cng thc Nhit p dng

C2H4O2
360C 1700C
C3H6O
Mi nhit
NH3
-830C 600C
C6H6
Mi nhit
CS2
-100C 1600C
C2H5OH
Mi nhit
CH3OH
-200C 1400C
C7H8
Mi nhit

A
7,18807
7,02447
7,55466
6,90565
6,85145
8,04494
7,87863
6,95464

B
1416,7
1161
1002,711
1211,033
1122,500
1554,300
1473,110
1344,800

C
211
224
247,885
220,790
236,460
222,650
230
219,482

Cu II :
Mt thit b lm vic p sut thng tch hn hp benzene - toluene c thnh
phn benzene (cu t d bay hi) l 30% mol. Sn phm nh c thnh phn benzene l
90% mol, sn phm y c thnh phn benzene l 10% mol. Nhp liu vo h thng
nhit si.
1. Tnh lng khi lng sn phm nh, sn phm y, tnh khi lng hon lu
v t s hon lu? T s hon lu R c nh ngha l t s gia tng s mol hon lu vi
tng s mol sn phm nh (R = L/D).
Cho bit khi lng nhp liu vo h thng l 1053,6 kg/gi?
Khi lng hi thot ra khi nh thp l 857,52 kg/gi
2. Thit lp phng trnh ng lm vic phn luyn v trnh by cch xc nh s
bc thay i nng l thuyt. S dng gi tr ca t s hon lu trong kt qu ca t s
hon lu trong cu 1l gi tr ca t s hon lu thch hp. S liu cn bng ca h benzene
- toluene c cho trong bng sau :
ybenzene
xbenzene
Nhit si (0C)

0 0,118 0,214 0,380 0,511 0,619 0,712 0,790 0,854 0,910 0,959 1
0
0,05 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,80 0,90 1
110,6 108,3 106,1 102,2 98,6 95,2 92,1 89,1 86,8 84,4 82,3 80,2

 4
Mt thit b lm vic p sut thng tch hn hp benzene - toluene c
thnh phn benzene (cu t d bay hi) l 30% mol. Sn phm nh c thnh phn
benzene l 96% mol, sn phm y c thnh phn benzene l 10% mol. Nhp liu
vo h thng nhit si l 98,60C..
Thit lp phng trnh ng lm vic phn luyn v trnh by cch xc nh
s on l thuyt.
p sut hi ca cc cht ph thuc vo nhit theo phng trnh nh sau :
P = 10A - B/(C + t)
Vi : P
:
p sut hi tnh bng n v mmHg
t
:
nhit 0C
A,B,C :
Hng s ty thuc tng cht tm trong bng nh sau
Hp cht
Acetic acid
Benzene
Carbon di sulfide
Ethyl alcohol
Methyl alcohol
Toluene

Cng thc Nhit p dng

C2H4O2
360C 1700C
C6H6
Mi nhit
CS2
-100C 1600C
C2H5OH
Mi nhit
CH3OH
-200C 1400C
C7H8
Mi nhit

A
7,18807
6,90565
6,85145
8,04494
7,87863
6,95464

B
1416,7
1211,033
1122,500
1554,300
1473,110
1344,800

C
211
220,790
236,460
222,650
230
219,482

5
Cu 1 : Mt hn hp hi gm c 112g nitrogen (N 2), 24g hydrogen (H2) v 176g
carbon dioxide (CO2) c cha trong bnh cha kn nhit 00C.
Tnh th tch ca bnh sao cho p sut tng cng trong bnh l 2 atm ?
Gi th tch bnh cha khng thay i (nh kt qu cu 1) nu nhit
ca bnh c tng ln n 1270C nitrogen s tc dng vi hydrogen theo phn ng
nh sau : N2 + 3H2
2NH3. T l phn ng l 50% (ch 50% s gmole
nitrogen c trong hn hp phn ng vi hydrogen tng ng), CO 2 khng tham gia
phn ng. Tnh phn t lng trung bnh v p sut ca hn hp sau khi phn ng
xy ra? Hn hp tun theo nh lut kh l tng, cho bit hng s R = 0,08206
[(lit.atm)/(gmole.0K)]
Cu 2 : Mt dung dch lng gm c 1280 kg/gi methanol (CH 3OH) v 2760
kg/gi ethanol (C2H5OH) c cho vo thit b chng ct nhit si (trng thi
lng bo ha), sau qu trnh chng ct sn phm nh thu c c thnh phn 90%
mol methanol trong khi sn phm y c thnh phn methanol l 10% mol.
2.1 Tnh khi lng sn phm nh, sn phm y v tnh t s hon lu (t
s hon lu l t s gia s kgmol hon lu so vi s kgmol sn phm nh). Cho
bit lng hi i vo thit b ngng t l 131,25 kgmol/gi.
2.2 Thit lp phng trnh ng lm vic phn luyn v trnh by cch xc nh s
on l thuyt, t s hon lu thch hp c s dng l kt qu t s hon lu trong
cu 2.1.

 6
Cu I :

Mt dung dch amoniac (A) nc (B) nhit 2780K to thnh mt lp

c chiu dy 4mm c tip xc vi b mt mt dung mi hu c, dung mi hu
c ny ch ha tan amoniac m khng ha tan nc. b tip xc vi dung mi
hu c nng ca amoniac l 2% (tnh theo % khi lng) khi lng ring
ca dung dch amoniac nc v tr ny l 991,7kg/m3, b mt cn li nng
ca ammoniac l 10% (tnh theo % khi lng) khi lng ring ca dung dch
amoniac nc v tr ny l 961,7kg/m3. Tnh thng lng khuch tn N A theo
n v kgmol/m2.giy. Cho bit h s khuch tn ca ammoniac vo trong nc l
1,24 x 10-9 m2/giy.
CuII :
Mt hn hp kh A (cht khuch tn) v B (cht khng khuch tn) c
cho tip xc vi mt dung mi lng. Qu trnh khuch tn t pha kh vo pha lng
xy ra i vi A nhit 2980K v p sut 1 atm. Nng cht A trong pha kh l
yAG = 35% mol, b mt phn chia pha nng cht khuch tn A l yAi = 19,7%
mol. Trong pha lng nng cht khuch tn A b mt phn chia pha l xAi =
25,7% mol v nng cht khuch tn A trong pha lng l xAL = 5% mol. S liu
cn bng ca cht khuch tn A trong pha lng v pha kh nh sau :
xA
yA

0
0

0,05
0,022

0,10
0,052

0,15
0,087

0,20
0,131

0,25
1,187

0,30
0,265

0,35
0,385

Tnh h s truyn khi tng qut theo pha kh Ky v h s truyn khi tng qut
theo pha lng Kx. Cho bit h s truyn khi cc b theo pha kh ky = 1,465 x 10-3
kgmolA/m2.giy v h s truyn khi cc b theo pha lng kx = 1,967 x 10-3
kgmolA/m2.giy.
Cu III :
Mt thit b lm vic p sut thng tch hn hp benzene - toluene c
thnh phn benzene (cu t d bay hi) l 30% mol. Sn phm nh c thnh phn
benzene l 90% mol, sn phm y c thnh phn benzene l 10% mol.
1. Tnh s kgmol/gi nguyn liu vo h thng, cho bit t s hon lu R =
2,6. T s han lu c nh ngha l t s gia tng s mol hon lu vi tng s
mol sn phm nh (R = L/D). Khi lng hi thot ra khi nh thp l 10,8
kgmol/gi
2. Nu nguyn liu vo h thng l 6 kgmol/gi trng thi lng bo ha (
nhit si), gi nguyn lng hi ra khi nh thp G = 10,8 kgmol/gi, tnh t s
han lu R? Thit lp phng trnh ng lm vic phn luyn v trnh by cch
xc nh s bc thay i nng trong trng hp ny

 7
Cu I : Mt dung dch amoniac (A) nc (B) nhit 2780K to thnh mt lp
c chiu dy 4mm c tip xc vi b mt mt dung mi hu c, dung mi hu
c ny ch ha tan amoniac m khng ha tan nc. b tip xc vi dung mi
hu c nng ca amoniac l 2% (tnh theo % khi lng) khi lng ring
ca dung dch amoniac nc v tr ny l 991,7kg/m3, b mt cn li nng
ca ammoniac l 10% (tnh theo % khi lng) khi lng ring ca dung dch
amoniac nc v tr ny l 961,7kg/m3. Tnh thng lng khuch tn N A theo
n v kgmol/m2.giy. Cho bit h s khuch tn ca ammoniac vo trong nc l
1,24 x 10-9 m2/giy
Cu II : Mt thit b lm vic p sut thng tch hn hp benzene - toluene

c thnh phn benzene (cu t d bay hi) l 30% mol. Sn phm nh c thnh
phn benzene l 96% mol, sn phm y c thnh phn benzene l 10% mol. Nhp
liu vo h thng nhit si l 98,60C..
Thit lp phng trnh ng lm vic phn luyn v trnh by cch xc nh
s on l thuyt. p sut hi ca cc cht benzene v toluene ph thuc vo nhit
theo phng trnh nh sau :
P = 10A - B/(C + t)
Vi : P
:
t
:
A,B,C :
Hp cht
Benzene
Toluene

p sut hi tnh bng n v mmHg

nhit 0C
Hng s ty thuc tng cht tm trong bng nh sau

Cng thc Nhit p dng

A
B
C
C6H6
Mi nhit
6,90565 1211,033 220,790
C7H8
Mi nhit
6,95464 1344,800 219,482

Cho bit t s hon lu thch hp R = 1,75Rmin

Cu I:
Mt lng nitrogen c th tch l 8,206 lit, nhit 27 0C v p sut
10,8 atm c nn vo mt bnh cha c th tch l 20,515 lit c cha y
oxygen nhit l 870C v p sut l 9,216 atm. Sau khi nn ht lng
nitrogen vo trn chung vi oxygen, hn hp nitrogen v oxygen c lm
lnh n nhit 330C. Tnh p sut ca hn hp sau khi lm lnh. Gi s
hn hp tun theo nh lut kh l tng [hng s kh l tng R = 0,08206
(lit.atm/gmole 0K)]
Cu II :

Mt dung dch amoniac (A)nc (B) nhit 2780K to thnh mt lp c

chiu dy 4mm c tip xc vi b mt mt dung mi hu c, dung mi
hu c ny ch ha tan amoniac m khng ha tan nc. b tip xc vi
dung mi hu c nng ca amoniac l 2% (tnh theo % khi lng) khi
lng ring ca dung dch amoniacnc v tr ny l 991,7 kg/m3, b
mt cn li nng ca ammoniac l 10% (tnh theo % khi lng) khi
lng ring ca dung dch amoniacnc v tr ny l 961,7 kg/m3. Tnh
thng lng khuch tn NA theo n v kgmol/m2.giy. Cho bit h s
khuch tn ca ammoniac vo trong nc l 1,24 x 10-9 m2/giy.