PINNACLE TWO YEAR

FIITJEE

Chennai Centre

Time: 1.5 Hours

Maximum Marks: 60

Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
You are not allowed to leave the examination hall before end of the test.
General
1.

This booklet is your Question Paper.

2.

All questions are single answer type.

3. This Question Paper contains 12 subjective questions.

4.

Each question carries +5 marks.

Any Student who indulges in Malpractice will be terminated immediately

Name of the candidate:_________________________________________________

Batch

:___________________ Date of Examination:__________

Enrollment Number : ___________________________________________________

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 2 -

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USEFUL DATA
PHYSICS

CHEMISTRY

Acceleration due to gravity

: g = 10 m/s2

Planck constant
Charge of electron

10 J s
19
: e = 1.6 10
C

Mass of electron

: me = 9.1 10

: h = 6.6

Permittivity of free space

12 2
2
C /N m
0 = 8.85 10

Density of water

K 1 mol 1

31

Gas Constant
K

kg
K

1
1

mol
mol

water

3
3
= 10 kg / m

: Pa = 10 N / m
: R = 8.314 J

Na

Plancks constant h

Atomic masses:

8.314 J K mol
0.0821 Lit atm

1.987

2 Cal

6.023

10 23

6.625 10

34

J .s

27

1 Faraday
1 calorie

=
=
=

6.625 10
erg .s
96500 coulomb
4.2 joule

1 amu

1.66 10

1 eV

Atomic No:

R =
=

Avogadros Number
:

Atmospheric pressure
Gas constant

34

1.6 10

27

19

kg

H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, F = 9, Ne = 10, Na = 11,
Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18, K = 19, Ca = 20,
Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29, Zn = 30, As = 33, Br = 35,
Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56, Pb = 82, U = 92.
H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23,
Mg = 24, Si = 28, Al = 27, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52,
Mn = 55, Fe = 56, Co= 59, Ni = 58.7, Cu = 63.5, Zn = 65.4, As = 75, Br = 80,
Ag = 108, Sn = 118.7, I = 127, Xe = 131, Ba = 137, Pb = 207, U = 238.

1. A ball of mass m hits a wedge vertically with speed v0, which is

placed, on a smooth horizontal surface. Find the maximum
compression in the spring, if the collision is perfectly elastic and no
friction any where.

m
v0
M
0

45

2. A pulley fixed to the ceiling of a lift carries a thread whose ends are attached
to the masses of 4kg and 2kg. The lift starts going down with on acceleration
of a0 = 4 m/s2 relative to ground. Calculate
(a) The acceleration of the load 4kg relative to the ground and relative to
lift.
(b) The force exerted by the pulley on the ceiling of the lift
(Thread and pulley are massless, g=10 m/s2)
3. A small disc of mass m slides down a smooth hill of height h
without initial velocity and gets onto a planck of mass M lying
on the horizontal plane at the base of the hill, as shown in the
figure. Due to friction between the disc and the plank, the disc
slows down and ultimately, both move together.
(a) Find the common velocity of the disc and the planck.
(b) Find the work done by the friction
(c) Find the distance moved by the disc with respect to the
planck before they start moving together.

a0
4 kg

2 kg

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 3 -

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4. The average person can see the red colour imparted by the complex [Fe(SCN)]2+ to an aqueous
solution if the concentration of the complex is 6 106M or greater. What minimum concentration of
KSCN would be required to make it possible to detect 1 ppm(by mass) of Fe3+ in a natural water
sample. The instability constant for [Fe(SCN)]2+
Fe3+ + SCN is 7.142 103. The density of
natural water can be assumed to be 1g/cc.
5. The type of hybridization and shape of following molecules/ion are
a) ClF2 __________ and __________
b) N ( CH3 )3 __________ and __________
c) PF2Br3 __________ and __________
d) TeCl4 __________ and __________
e) XeOF4 __________ and __________
6.

(1 Mark)
(1 Mark)
(1 Mark)
(1 Mark)
(1 Mark)

a) How many number of angular and spherical nodes are present in the following orbitals
4d ______________
(1 mark)
2s______________
(1 mark)
3p______________
(1 mark)
b) Predict total spin for each configuration
i) 1s2 2s2 2p6 ______________
ii) 1s22s22p5 ______________
iii) 1s2 ______________
iv) 1s22s22p3 ______________

(1/2 mark)
(1/2 mark)
(1/2 mark)
(1/2 mark)

7. Let ABC be a triangle with AB = AC. If D is the mid point of BC, E foot of perpendicular drawn from
D to AC and F is mid point of DE. Prove that AF is perpendicular to BE.
8. Ai, Hi, Gi (i = 1, 2, 3, ......, n) are respectively n arithmetic means, n harmonic means and n geometric
means inserted between two positive numbers a and b. Prove that
1

2
A1 + A 2 + ..... + A n (G1.G2 ......Gn ) n

.
n
H1.H2 ......Hn

9. Consider two lines L1: a1x + b1y + c1 = 0 and L2: a2x + b2y + c2 = 0, where c1, c2 0. Intersecting at a
point P. A line L3 is drawn through the origin meeting the line L1 and L2 in A and B respectively such
that PA = PB. Similarly one more line L4 is drawn through the origin meeting the lines L1 and L2 in
A1 and B1 respectively such that PA1 = PB1. Obtain the combined equations of lines L3 and L4.
10. Explain prophase I of meiosis.
11. Brief note on the digestion of food in the stomach.
12. Explain the process of urine formation with the help of the diagram.

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 4 -

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Space for Rough Work

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 5 -

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KVPY MOCK TEST PAPER 2 (SUB) CLASS XI

SOLUTIONS
1.Sol.

The ball rebounds horizontally. Let say with speed v

and the wedge with V.
Momentum conservation mv = MV

45
0

MV
v=
m

45

45

Restitution
1=

V cos 45 + v cos 45 v + V
=
v 0 cos 45
v0

v + V = v0

MV
+ V = v0
m
(m + M)V
= v0
m
1
1
MV 2 = kx 2
2
2
2.sol.

mv 0
m+M
M
M mv 0
v =
k
k m+M

V=

x=

Free body diagrams :

f1

f2

P
f1

f1

f2

MAg

f2
MCg

Cylinder B

Cylinder A

Cylinder C

MBg

For the cylinder B

MBg (f1 + f2) = MB aB
f1 + f2 = 25 2.5aB

. . . (i)

Taking torque about point P for cylinder A

P = IP A = f1 2r1 + MAg r
1
[ 2 (0.2)2 + 2 (0.2)2 ] A = f1 0.4 + 2 10 0.2
2
0.1 2 A = 0.4 f1 + 4

. . . (ii)

Taking torque about point Q for cylinder C

Q = IQ C = f2 2r2 + Mc.g r2
1
[ 1 (0.1)2 + 1 (0.1)2 ] c = f2 2 0.1 + 1 10 0.1 ]
2
0.015 c = 0.2 f2 + 1

. . . (iii)

Also, aB = A 0.4
1
A =
aB = 2.5aB
0.4
and aB = C 0.2
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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 6 -

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C= 5 aB
Putting values of A C in (ii) and (iii) ,
0.12 2.5 aB = 0.4 f1 + 4 0.3 aB = 0.4 f1 + 4

. . . (iv)

0.015 5aB = 0.2 f2 + 1

. . . (v)

0.15 aB = 0.4f2 + 2

from (iv) and (v)

(0.3 + 0.15)aB = 0.4(f1 + f2) + 6
0.45 aB = 0.4 (25 2.5 aB) + 6
16
= 11.03 m/s2
aB =
1.45
3.sol.

(a) Velocity of the disc at the foot of the

hill is v0 =

2gh . When it slides on the

f

plank, friction opposes its motion and

favours the motion of the plank as shown
in the figure.

ms

Let their common velocity be V, then

for m,
V = v0 - gt
for M,

V=

mgt
M

Eliminating t from the above two equations,

V=

mv 0
m+ M

(b) Using Work - Energy theorem

Wf = Kf - Ki

1
1
(m + M)V2 - mv02
2
2
2
1 mMv 0
mMgh
==m+ M
2 m+ M

Wf =

(c) Acceleration of the disc w.r.t the plank is

arel = g +

m
m + M
g = g

M
M

u 2rel
Mv 20
Mh
=
=
xrel =
2 a rel 2g( m + M) ( m + M)
4.sol

Initial concentration of Fe3+ =

10 3 g 10 3
=
moles / litre
1L
56

Let initial concentration of SCN be a M

Fe3+

[Fe(SCN)]2+
Initial
0
1.78 105
At eqm. x
(1.78 105 x)
6
x = 6 10 M

(1 Mark)

SCN
aM

(a x)
(2 Mark)

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 7 -

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(a 6 106 )(1.78 105 6 106 )

= 7.14210-3
6 106

a = 3.637 103M
5.sol

a)

(1 Mark)

ClF2 :- Hybridization = sp3 d

shape = Linear

Cl

N ( CH3 )3 :- Hybridization = sp3

b)

shape =Pyramidal

N
CH3

c)

CH
CH3 3
F
Br

PF2Br3 :-Hybridization = sp3 d

shape =Trigonal bi pyramidal

Br

Br

d)

Cl
Cl

TeCl4 : Hybridization = sp3 d

shape =see saw shape

Te
Cl
Cl
(e)

XeOF4 :Hybridization sp3d2

Structure octahedral
Shape:- square pyramidal

F
F

6.sol

a)

Xe

Angular nodes
(l)
2
0
1

4d
2s
3p
b) (i) 0

(ii)

1
2

(iii) 0

(iv)

F
special nodes
(n-l-1)
1
1
1

3
2

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 8 7.

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ab 2
a 2b

,
a2 + b2 a2 + b2

ab
a 2b

Coordinates of point F is
,
2(a2 + b2 ) 2(a 2 + b 2 )

2
ab
b
a2b + 2b3
a2 + 2b2
2(a 2 + b2 )
=

Slope of AF =
ab
ab 2
ab 2
2
2
2(a + b )

Coordinates of point E is

A(0, b)
E
F
B(a, 0) D

C(a, 0)

a 2b
2
2
ab
= 2
Slope of BE = a 2+ b
ab
a + 2b 2
+
a
a2 + b2
As Product of slopes of AF and BE = 1
AF and BE are perpendicular.
8.

We have

A1 + A 2 + ...... + A n a + b
=
n
2
1

(G1G2......Gn )n

= ab

1
1
1
1 1
+
+ ....... +
+
a+b
H1 H2
Hn
and
= a b =
2
2ab
n
2
A + A 2 + ...... + A n a + b
1 1
1
1
[
]
=
ab = +
+ .... +
G
G
.......
G
n
Hence 1
1 2
n
n
2ab
n H1 H2
Hn

1
2 n

= (G1G2 .......Gn )

1
1
1
1
+ .... +
+

1
n
H
H
H

1
1
1
2
2
n
1
(G1G2 .......Gn ) n .
....
n
Hn
H1 H2

2
A + A 2 + ...... + A n [G1G2 .......Gn ] n
1

.
n
H1H2 .........Hn

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KVPY MOCK TEST-PAPER-2(SUB)-CLASS-XI . P - 9 9.

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Draw lines L5 and L6 through P parallel to L3 and L4 respectively.

( AP = BP)
A1PM = PAB = PBA
= B1PM i.e. L5
PM is the bisector of L1 and L2
M
B

B1

L4
O

A1
N
P

L6

A
L2: a2x+ b2y+ c2 =0

Again APN = PA1B1 = PB1A1 = BPN

L5

( A1P = B1P)

PN i.e. L6 is the bisector of L1 and L2

Now joint equation of L5 and L6 is
Joint equation of L3 and L4 is
pass through origin ]

a1x + b1y + c1
a12 + b12

a1x + b1y
a12 + b12

L1: a1x+ b1y+ c1 =0

L3

a2 x + b2 y + c 2

a2 x + b2 y
a22 + b 22

a 22 + b 22
[ L3 and L4 are parallel to L5 and L6 respectively and

(a1x + b1y)2 a 22 + b22 = (a2x + b2y)2 a12 + b12 .

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