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    chem 17

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    chem 17

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    8 views2 pages

    DS 2

    Uploaded by

    James M
    chem 17

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    of 2
    DS Chemical Kinetics Part 1 4) Consider the reaction of peroxydisulfate ion, SOs? with iodide ion, I, in aqueous solution: S20: aq) + 3 (oy + 280-2 aq + 10 Ata particular temperature, the rate of disappearance of S20s* varies with reactant concentrations in the following manner; Experiment | (SOF) | (LQ) [Rate (Ws) 1 0.018 0.036 2.6x 108 2 0.027, 0.036; 3.9x 108 3 0.036 0.054 7.8x108 What s the rate of disappearance of when [Sz0s?] = 0.075 M and [}] = 1.050 M? For number 2-9; Based on the of integrated rate law equations below (answers per item can be one or more of the choices): it if A.[A] = [A]o — kt B. In[A] = —kt'+ In[A]o om =kt+ ae Which would exhibit the following relations? 2.) Increasing the initial concentration also increases the half-life te 3,) Increasing the intial concentration decreases the half-life ta 4,) Doubling the rate constant decreases the halfife tuo by 2 5.) Increasing the temperature also increases the rate constant 6) The linear plot of y (converted variable) versus x (time) gives a positive slope 7.) Concentration decrease a with time 8.) Doubling the initial concentration retains the half-life te 9.) Increasing the concentration of species does not change the reaction rate DS Chemical Kinetics Analysis (Part 2) (Ozone layer depletion, discovered inthe early 1970's, has been accurately shown as en atmospheric phenomenon that is atbuted mainly to the degrading action of chlorine and bromine atoms fo ozone molecules. Human actly has dramaticaly increased the levels of Cand Brin the ‘atmosphere through release of chloratuoracarbons (CFCs) and Halons. These compounds remain inactive in the troposphere, but 2s they ‘each stratospheric levels, UV radiation allows decomposition into various radicals: CFClyg 29 CECI, y+ CI ‘The chlorine radicals act as catalysts in the decomposition of Oag into Ozy via the general reaction 209) > 30ay,. Ozone is an essential ‘atmospheric gas particle because it absorbs UV radiation in the range 200 210 ne, whichis harmful to humans end other living organisms, ‘The kines of ozone decomposion in the presence of tchiorofuorocarbon was studied in a closed UV lamp source {gas-chamber experiment at -10°C, as shown. Ozone gas is pumped into the chamber, wth a constant ‘amount of CFC throughout the experiment. The ital rte of ozone decomposition (in M s) versus varying [0 is tabulated as follows: inal rate (M5 sa (0.032625, 4,089 0.093150 [ 0.261700, (@) Determine the rate law and rate constant k forthe reaction from the data (b) Ata temperature of 50°C, the new reaction constant obtained has a magnitude of 1.115 x 104. Determine the Es for tis reaction at the siven conditions. (¢) Ano set of eximents wor pred such hatte sare amour of 0: wore paced inthe chamber, but added vith © known ‘Socata of O: gs twas fund rath presence of Oxy eles thera of decorposon - wh Or te chonber the racine wat hoored to eczeas, Doubling the anout of Ong ne caber decreases te ree sapoararca of On by ice a mich. Detine the expeced odor wth respect Ory based on hs newinfomaton (@) Two sifernt mechanisms woe propose o exp he bined rat awin er), Dtemine wich is consistent wih he expert Tels thenor-sleay aporoac'sepplcabe forthe eacton(baed onthe newt rt om tr). () ly +05) GE ClOxp (fast, equilibrium) (2) ClO, 2 Oxy + Clg + Oy (fast, equilibrium)} Mechanism A 2 Ge Ory + Cle + Ow QB) Og + Oy) —24 202 (slow) (1) Cle + Ox) eC + Ox > (fast, equilibrium) (2) ClOy +Oyg 22 ClOyg + Ong (fast, equilibrium) } Mechanism B (3) Cl0yy-—-9Cl,,+0xy (slow) (6) Draw the Lewis structure ofthe transition state based on the consistent mechanism obtained in (4) (0) Given the folowing Gibbs fee of formation and ocder of magnitude frre content) values foreach sep, draw the accurate onergy ciagram forthe correct mechanism (os0d on your answer inc). Ka <<< ke < ka

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