Cu 1 Nu cht in ly phn ly thnh 2 ion c tr s in tch bng nhau th s

ti s c biu din bng t s gia tc tuyt i ca ion v tng i s tc

tuyt i ca 2 ion. Mt khc nu nhn tc tuyt i ca cc ion vi s
Faraday ta nhn c dn 100 in ng lng ca cc ion:
+ = F.V+

= F.V- (2)

S ti ca ion c xc nh bng phn in lng c ti bi ion so vi

in lng tng cng c ti bi cc loi ion c trong dung dch v k hiu l
t.

D thy: t+ + t- = 1.
Do tc chuyn ca cation v anion khc nhau, s ti ca chng khc
nhau, nn nng dung dch gn cc in cc cng khc nhau. V vy c th
xc nh s ti ca ion bng thc nghim nh vo vic xc nh lng in
chuyn qua dung dch v s thay i nng cht in ly gn cc in cc
Cu 2: Nguyn tc hot ng ca Cu long kh :
Culng k kh hot ng theo nguyn tc in phn dung dch H2SO4. cc
m c phn ng kh ion H+ : 2H3O+ + 2e = H2 + 2H2O
cc dng c phn ng: 4OH- - 4e = O2 + 2H2O
Kh H2 v O2 gii phng ra s y dung dch in phn dn sang bu cha.
Dung dch in phn y l H2SO4 c nng c tnh sao cho in tr ca
bnh khng qu ln (trong bi ny ta dng H2SO4 1M)