THI TH I HOC.

Phn Hu c
Cu 1: Khi cho cht A c cng thc phn t C3H5Br3 tc dng vi dung dch NaOH d thu c cht hu c X
c phn ng vi Na v phn ng trng gng. Cng thc cu to thu gn ca X l
A. 1,2,3-tribrompropan. B. 1,1,1-tribrompropan. C. 1,1,3-tribrompropan. D. 1,2,2-tribrompropan.
Cu 2: Mt hn hp gm hai cht A, B l sn phm th nitro ca benzen, cch nhau 1 nhm NO 2. Ly 0,03 mol
hn hp A, B v bin ton b nit trong thnh N 2 th thu c 0,896 lit (ktc). Xc nh tn v s mol ca A,
B.
A. 0,01 mol p-initrobenzen; 0,02 mol 1,3,5-trinitrobenzen.
B. 0,01 mol m-initrobenzen; 0,02 mol 1,3,5-trinitrobenzen.
C. 0,01 mol o-initrobenzen; 0,02 mol 1,3,5-trinitrobenzen.
D. 0,02 mol nitrobenzen; 0,01 mol m-trinitrobenzen.
Cu 3: Pht biu no sau y khng ng ?
A. Oxi ha glucoz bng AgNO3 trong dung dch NH3 thu c amoni gluconat.
B. Metyl glucozit c th chuyn c t dng mch vng sang dng mch h.
C. Kh glucoz bng H2 thu c sobitol.
D. Fructoz cn tn ti dng -, vng 5 cnh trng thi tinh th.
Cu 4: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thot ra 1,68 lt
kh (ktc). Nu cho hn hp trn tham gia phn ng cng H2 hon ton th khi lng sn phm cui cng l
A. 11,1 gam
B. 11,2 gam
C. 7,4 gam
D. 11,0 gam
Cu 5: Cao su lu ha c 2% lu hunh v khi lng, gi thit rng S thay th cho H cu metylen trong
mch cao su. S mt xch isopren c mt cu isunfua S S l
A. 46
B. 45
C. 47
D. 48
Cu 6: Cho cc polime sau:
CH2 - CH = CH - CH2 ; CH2 - CH2
n ; NH -[CH2]5 - CO n
n
Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l
A. CH2=CHCl, CH3- CH=CH- CH3, CH3- CH(NH2)- COOH.
B. CH2=CH2, CH3- CH=CH-CH3, H2N- CH2- CH2- COOH.
C. CH2=CH2, CH3- CH=C=CH2, H2N- [CH2]5- COOH.
D. CH2=CH2, CH2=CH- CH= CH2, H2N- [CH2]5- COOH.
Cu 7: Cho cht hu c A ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5M thu c 24,6g
mui v 0,1 mol ancol. Lng NaOH d c th trung ha ht bng 0,5 lt dung dch HCl 0,4M. Cng thc cu
to thu gn ca A l
A. C3H5(OCOCH3)3
B. CH3COOC2H5
C. (HCOO)3C3H5
D. (CH3COO) 2C2H4
Cu 8: Hn hp A gm glucoz v tinh bt c chia thnh hai phn. Phn th nht c khuy trong nc, lc
v cho nc lc phn ng vi dung dch AgNO 3 d/NH3 thy tch ra 2,16g Ag. Phn th hai c un nng vi
dung dch H2SO4 long, trung ha hn hp thu c bng dung dch NaOH ri cho sn phm tc dng vi dung
dch AgNO3 (d)/NH3 thy tch ra 6,48gam Ag. Gi s cc phn ng xy ra hon ton. Hn hp ban u c %
khi lng glucoz v tinh bt ln lt l
A. 64,71 v 35,29
B. 35,29 v 64,71
C. 64,29 v 35,71
D. 35,71 v 64,29
Cu 9: un 12,00 gam axit axetic vi 11,5 gam ancol etylic (c axit H 2SO4 c lm xc tc). n khi phn ng
dng li thu c 11,00 gam este. Hiu sut ca phn ng este ha l
A. 75%
B. 50%
C. 70%
D. 62,5%
Cu 10: Cho A c cng thc phn t C5H8O2 phn ng vi dung dch NaOH to ra mui A1 v cht hu c A2 ,
nung A1 vi vi ti xt thu c mt cht kh c t khi vi hiro l 8; A2 c phn ng trng gng. Cng thc
cu to ca A l
A. CH3COO-CH2-CH=CH2
B. CH3COO-CH=CH-CH3
C. C2H5COO-CH=CH2
D. CH3COO-C(CH3)=CH2
Cu 11: Anehit X mch h, cng hp vi H2 theo t l 1:2 (lng H2 ti a) to ra cht Y. Cho Y tc dng ht
vi Na thu c th tch H2 bng th tch X phn ng to ra Y ( cng t 0, p). X thuc loi hp cht no sau
y ?
A. Anehit khng no (cha mt ni i C=C), hai chc

B. Anehit khng no (cha mt ni i C=C), n chc

C. Anehit no, n chc
D. Anehit no, hai chc
Cu 12: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1
mol X, tng khi lng ca CO2 v H2O thu c l
A. 16,80 gam.
B. 18,60 gam.
C. 20,40 gam.
D. 18,96 gam.
Cu 13: Cho cc cht sau: CH 2=CH-CH3; Cl-CH=CH-CH3 ; (CH3)2CH-CH=CH-CH3 ; (CH3)2C=CH-Cl; CH3CH=CH-COOH ; C6H5-CH=C(CH3)2. S cht c ng phn hnh hc l
A. 2.
B. 3.
C. 5.
D. 4.
Cu 14: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va
vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng
thc cu to thu gn ca X l
A. Metylamoni axetat.
B. Etylamoni fomat.
C. Amoni propionat.
D. imetylamoni fomat.
Cu 15: Thc hin phn ng hiro ha ankan X thu c mt hn hp Y gm ankan, anken v H 2. T khi
hi ca X i vi Y l 1,6. Hiu sut ca phn ng hiro ha l
A. 66,67%.
B. 60%.
C. 75%.
D. 80%.
Cu 16: Cho cc cht sau: etilen, axetilen, buta-1,3-ien, benzen, stiren, naphtalen tc dng vi nc brom. S
cht lm mt mu dung dch nc brom l
A. 5.
B. 3.
C. 6.
D. 4.
Cu 17: Khi lng axit axetic cha trong gim n thu c khi ln men 10 lt ru 8 0 thnh gim n l bao
nhiu gam ? Bit khi lng ring ca ru etylic l 0,8g/ml v gi s phn ng ln men gim t hiu sut 80%.
A. 834,78 gam
B. 843,78 gam
C. 667,83 gam
D. 677,83 gam
Cu 18: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt mu hon ton
dung dch cha 3,2g brom. trung han ton 3,15 gam hn hp X cn 90ml dd NaOH 0,5M. Thnh phn phn
trm khi lng ca axit axetic trong hn hp X l
A. 35,24%.
B. 45,71%.
C. 19,05%.
D. 23,49%.
Cu 19: Cho cc cht sau: (1) Anilin ; (2) etylamin ; (3) iphenylamin ; (4) ietylamin ; (5) natrihidroxit ; (6)
Amonic . Dy no sau y c th t sp xp theo chiu gim dn tnh baz ca cc cht ?
A. (5) > (4) > (2) > (6) > (1) > (3)
B. (6) > (4) > (3) > (5) > (1) > (2)
C. (5) > (4) > (2) > (1) > (3) > (6)
D. (1) > (3) > (5) > (4) > (2) > (6)
Cu 20: Cho 13,6 gam hn hp hai ancol no n chc, k tip nhau trong dy ng ng tc dng vi 6,9 gam
Na n phn ng hon ton, thu c 20,3 gam cht rn. Hai ancol l
A. C3H7OH v C4H9OH. B. CH3OH v C2H5OH. C. C2H5OH v C3H7OH. D. C3H5OH v C4H7OH.
Cu 21: Cho 13,6g mt cht hu c X (cha C, H, O) tc dng va vi 300 ml dd AgNO 3 2M trong NH3 thu
c 43,2g Ag. X c cng thc cu to l
A. HC C CHO
B. HC C CH2-CHO C. CH3-CH2-CHO
D. CH2= C = CH -CHO
Cu 22: Cho Na d vo V (ml) cn etylic 46 0 (khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml ; ca
nc l 1 g/ml) thu c 42,56 lt H2 (ktc). Gi tr ca V l
A. 100 ml
B. 237,5 ml
C. 475 ml
D. 200 ml
Cu 23: Cho 1,52 gam hn hp hai amin no n chc (c trn vi s mol bng nhau) tc dng va vi
200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc.
A. Tn gi hai amin l metylamin v etylamin.
B. Cng thc thc ca hai amin l CH5N v C2H7N.
C. Nng mol ca dung dch HCl bng 0,2M. D. S mol ca mi cht l 0,02mol.
Cu 24: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi
ca X so vi H2 bng 11,4. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp
kh Y; t khi ca Y so vi H2 bng 14,25. Cng thc cu to ca anken l
B. CH3-CH=CH-CH3.
A. CH2=CH2.
D. CH2=CH-CH2-CH3.
C. C(CH3)2=C(CH3)2.
Cu 25: Cn bng phng trnh phn ng:

CH2 -CH=CH2
+ KMnO4 + H2SO4

COOH
+CO2 + MnSO4 + K2SO4 + H2O

Tng h s ca cc cht tham gia trong phng trnh phn ng trn (l cc s nguyn nh nht) l
A. 46.
B. 45.
C. 48.
D. 47.
Cu 26: Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng
hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5.
Gi tr ca m l
A. 0,92.
B. 0,64.
C. 0,46.
D. 0,32.
Cu 27: un nng 18 gam CH3COOH vi 9,2 gam C2H5OH c mt H2SO4 c. Kt thc th nghim thu c
10,56 gam este. Hiu sut phn ng este ho bng
A. 40%.
B. 60%.
C. 30%.
D. 80%.
Cu 28: oxi ho ht 10,6g o-xylen (1,2-imetylbenzen) cn bao nhiu lit dung dch KMnO 4 0,5M trong mi
trng H2SO4 long. Gi s dng d 20% so vi lng phn ng.
A. 0,48lit.
B. 0,24lit.
C. 0,12lit.
D. 0,576lit.
Cu 29: Dn 2,8 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng
xy ra hon ton, c 16 gam brom phn ng v cn li 1,68 lt kh. Nu t chy hon ton 2,8 lt X th sinh ra
5,04 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6.
Cu 30: Dy gm cc cht u phn ng vi phenol l:
A. dung dch NaCl, dung dch NaOH, kim loi Na.
B. nc brom, axit axetic, dung dch NaOH.
C. nc brom, anehit axetic, dung dch NaOH.
D. nc brom, anhirit axetic, dung dch NaOH.
Cu 31: Hp cht
CH2 CH C CH2 CH3
O
c tn gi
A. Etylvinyl xeton.
B. Penten-3-ol.
C. imetyl xeton.
D. Vinyletyl xeton.
Cu 32: Dy gm cc cht u tc dng vi AgNO3 trong dung dch NH3, l
A. anehit axetic, but-1-in, etilen.
B. anehit axetic, axetilen, but-2-in.
C. anehit fomic, axetilen, etilen.
D. axit fomic, vinylaxetilen, propin.
Cu 33: Cho cc cht: xiclopropan, xiclobutan, 2-metylpropen, but-1-in, stiren, naphtalen. S cht phn ng
vi dung dch brm l
A. 5.
B. 3.
C. 4.
D. 6.
Cu 34: Khi cho isopren phn ng vi HBr theo t l mol 1:1 th s cht hu c thu c nhiu nht (l ng
phn cu to) l
A. 6.
B. 5.
C. 8.
D. 4.
Cu 35: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c
khi lng 8,2 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,2 mol C2H4 v 0,1 mol C2H2.
B. 0,1 mol C2H4 v 0,2 mol C2H2.
C. 0,2 mol C3H6 v 0,1 mol C3H4.
D. 0,1 mol C3H6 v 0,2 mol C3H4.
Cu 36: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia
X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch AgNO 3/NH3 d thu c 21,6 gam
bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l
A. HCOOH, C3H7COOH.
B. CH3COOH, C2H5COOH.
C. CH3COOH, C3H7COOH.
D. HCOOH, C2H5COOH.
Cu 37: Hn hp X gm 2 cht hu c k tip nhau trong cng dy ng ng, phn t ca chng ch c mt
loi nhm chc. Chia X thnh 2 phn bng nhau.
- Phn 1 : em t chy hon ton ri cho ton b sn phm chy (ch c CO 2 v hi H2O) ln lt qua bnh
(1) ng dung dch H2SO4 c, bnh (2) ng dung dch Ca(OH)2 d, thy khi lng bnh (1) tng 2,16 gam,
bnh (2) c 7,0 gam kt ta.
- Phn 2 : cho tc dng ht vi Na d th th tch kh H2 (ktc) thu c l bao nhiu ?

A. 0,224 lt.
B. 2,24 lt.
C. 0,56 lt.
D. 1,12 lt.
Cu 38: un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau trong dy ng ng vi
H2SO4 c 1400C. Sau khi phn ng kt thc, thu c 12,3 gam hn hp 3 ete v 2,7 gam nc. Cng thc
phn t ca hai ru trn l
A. C3H5OH v C4H7OH.
B. C3H7OH v C4H9OH.
C. C2H5OH v C3H7OH.
D. CH3OH v C2H5OH.
Cu 39: Cho hn hp HCHO v H 2 d i qua ng ng bt Ni un nng thu c hn hp X. Dn ton b sn
phm thu c vo bnh nc lnh thy khi lng bnh tng 11,80 gam. Ly ton b dung dch trong bnh cho
tc dng vi dung dch AgNO3/NH3 d thu c 21,60 gam Ag. Khi lng ancol c trong X l gi tr no di
y ?
A. 1,03 gam.
B. 10,30 gam.
C. 9,30 gam.
D. 8,30 gam.
Cu 40: Mt hn hp gm hai anehit X v Y k tip nhau trong dy ng ng ca anehit no n chc, mch
h. Cho 1,02 gam hn hp trn phn ng vi dung dch AgNO 3/NH3 d thu c 4,32 gam Ag kim loi (hiu
sut phn ng 100%). Cng thc cu to ca X v Y ln lt l
A. HCHO, C2H5CHO.
B. CH3CHO, C2H5CHO.
C. C3H7CHO, C4H9CHO.
D. CH3CHO, HCHO.
Cu 41: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t
ca X. Cc cht X, Y, Z thuc dy ng ng
A. ankan.
B. anken.
C. ankin.
D. ankaien.
Cu 42: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 0 l
(bit hiu sut ca qu trnh l 86,4% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml)
A. 3,75 kg.
B. 4,5 kg.
C. 6,0 kg.
D. 5,0 kg.
Cu 43: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C 7H8O2, tc dng c vi Na v
vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H 2 thu c bng s mol X tham gia phn ng. S
cht X l
A. 7.
B. 8.
C. 9.
D. 10.
Cu 44: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong
khng kh, oxi chim 20% th tch), thu c 10,08 lt kh CO2 ( ktc) v 12,6 gam nc. Th tch khng kh
(ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l
A. 100,4 lt.
B. 107,52 lt.
C. 89,6 lt.
D. 71,68 lt.
Cu 45: Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu
c hn hp kh Y c t khi so vi metan l 1,45. Nu cho ton b Y sc t t vo dung dch brom (d)
th c m gam brom tham gia phn ng. Gi tr ca m l
A. 48,0.
B. 24,0.
C. 16,0.
D. 32,0.
Cu 46: Cho 3 cht : CH3CH2CH2Cl (1); CH2=CHCH2Cl (2) v Phenyl clorua (3). un tng cht vi dung dch
NaOH d, sau gn ly lp nc v axit ho bng dung dch HNO 3, sau nh vo dung dch AgNO 3 th
cc cht c xut hin kt ta trng l
A. (1), (3).
B. (2), (3).
C. (1), (2), (3).
D. (1), (2).
Cu 47: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l
75,5. Tn ca ankan l
A. isopentan.
B. 2,2-imetylbutan.
C. 2,2,3,3-tetrametylbutan.
D. neopentan.
Cu 48: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng
tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t hn c trong X l
A. 3,0 gam.
B. 4,6 gam.
C. 7,4 gam.
D. 6,0 gam.
Cu 49: Cho cc cht sau : 1,1 imetylxiclopropan, 1,2 imetylxiclopropan, But-1-en, But-2-en, 2-metylbut2-en, buta-1,3-ien, stiren, axit oleic, axit panmitic, 1,2-icloeten. S cht c ng phn hnh hc l
A. 6
B. 3
C. 4
D. 5
Cu 50: Cho cc cht sau : C2H5OH, CH3COOH, HCOOH, C6H5OH
Chiu tng dn linh ng ca nguyn t H trong nhm -OH ca 4 cht l
A. C6H5OH, C2H5OH, CH3COOH, HCOOH.
B. C2H5OH, C6H5OH, CH3COOH, HCOOH.
C. C6H5OH, C2H5OH, HCOOH, CH3COOH.
D. C2H5OH, C6H5OH, HCOOH, CH3COOH.