Cul es la Temperatura para que la conversion sea del 95% si se alimentan 2

SO2 + 2O2

SO3

CA = CA0 - (vi/va) XACA0

CA = 2 - (1/1)(0.95)(2)

8.314

CB = CB0 -(vi/va) XACA0

CB = 3 -(0.5/1) (0.95)(2)

To

298

CC = CC0 +(vi/va) XACA0

CC = 0 +(1/1) (0.95)(2)

-300194

Hf,i
(KH/Kmol)
-296830

A
5.699

-0.5

3.639

SO3

-371060

-395720

8.06

N2

Componente
i
SO2

vi

Gf,i (KJ/Kmol)

-1

O2

Ln KeT0
H

28.60300326

-1.03E+05
-15.44459844

T (K)

Ln KeT

298
300
400
500
600
700
800
900
1000
820
840
860
880
845
850
855
856
857
856.5
856.4
856.3

28.60300326
28.33689901
18.41332696
12.45660472
8.491169141
5.6655779
3.552765919
1.915047452
0.60967248
3.192784099
2.850181982
2.523745013
2.212368912
2.767102178
2.685014305
2.603900927
2.587793685
2.571724606
2.579754383
2.581361481
2.58296896

0
3.28
-70866
-98890
0.5415
La reaccion es exotermica ya que su valor indica que libera calor
2.64318E+12
Ln Ket
28.60300326

KeT
2.64318E+12
2.02562E+12
99267318.5
256941.7591
4871.558286
288.7548044
34.9097416
6.787260857
1.83982872
24.35614306
17.2909282
12.47522919
9.13733632
15.91245567
14.65841106
13.51636166
13.30039435
13.08837728
13.19389712
13.21511805
13.23637816

HRx,T
-98890
-98897.71629
-99070.1348
-98993.10559
-98791.26938
-98518.04363
-98200.13705
-97852.38783
-97483.69889
-98132.62719
-98064.02495
-97994.4061
-97923.83948
-98046.71275
-98029.33815
-98011.90224
-98008.4078
-98004.91095
-98006.65968
-98007.00935
-98007.359

(-H/Rto)
41.46877999

1/t
0.003355705
0.003333333
0.0025
0.002
0.001666667
0.001428571
0.00125
0.001111111
0.001
0.001219512
0.001190476
0.001162791
0.001136364
0.001183432
0.001176471
0.001169591
0.001168224
0.001166861
0.001167542
0.001167679
0.001167815

Por

856.2
856.1
856.1417

2.58457682
2.586185062
2.585514379

13.25767752 -98007.70862
13.27901623 -98008.05822
13.2701132 -98007.91244

0.001167951
0.001168088
0.001168031

del 95% si se alimentan 2Kmol de SO2 y 3 Kmol de O2?, asi mismo calcule el valor de Ke y Ea

Chart Title
35

0.1
2.05

.
0 5

30
25

1.9
B-3
8.01E-04

y = 11891x

13.2701756
20

C-6
0.00E+00

D5
-1.02E+05

15
10

5.06E-04

-2.27E+04

1.06E-03

-2.03E+05

5.93E-04
2.00E-06

4.00E+03
-9.00E+04

0.0005

0.001

0.0015

0.002

Series1

0.0025
Linear (Series1)

que libera calor

Por partes
(ALn T0)

(BT0/2)

(CT02/6)

3.084976123

0.000298

Ea
-6.54866E+15
-5.05231E+15
-3.30123E+11
-1067987990
-24158598.13
-1514031.452
-41947.37805
163238.4741
222509.0331
28952.88452
79000.81735
115314.2298
142417.0484
89155.28474
98545.03862
107242.9392
108905.3623
110543.2305
109727.3357
109563.4292
109399.2791

Ke
1.82703E+14
1.40016E+14
6861612804
17758532.9
334786.2445
18010.97085
464.5411296
-1479.35775
-1821.3371
-264.950999
-753.316991
-1086.19061
-1316.91443
-848.600591
-935.28341
-1014.22483
-1029.15305
-1043.80822
-1036.51442
-1035.04757
-1033.57802

(-H/RT)
41.46878
41.1923215
30.8942411
24.7153929
20.5961607
17.6538521
15.4471205
13.7307738
12.3576964
15.0703615
14.7115434
14.3694145
14.0428369
14.6244928
14.5384664
14.4534461
14.4365613
14.4197158
14.4281336
14.4298184
14.4315035

(D/2To2)
-0.50645241 44.0476017

(ALn T)
3.08497612
3.08859821
3.24437805
3.36521029
3.46393741
3.54741
3.61971725
3.68349676
3.74054948
3.6330883
3.64613712
3.65887889
3.67132771
3.64935078
3.65254548
3.65572145
3.65635441
3.65698663
3.65667061
3.65660739
3.65654415

(BT/2)
2.98E-04
3.00E-04
4.00E-04
5.00E-04
6.00E-04
7.00E-04
8.00E-04
9.00E-04
1.00E-03
8.20E-04
8.40E-04
8.60E-04
8.80E-04
8.45E-04
8.50E-04
8.55E-04
8.56E-04
8.57E-04
8.57E-04
8.56E-04
8.56E-04

Total
-15.44459844
Por partes
2
(CT /6)
(D/2T )
2

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

-0.50645241
-0.49972222
-0.28109375
-0.1799
-0.12493056
-0.09178571
-0.07027344
-0.05552469
-0.044975
-0.06688727
-0.06374008
-0.0608099
-0.05807722
-0.06298799
-0.06224913
-0.0615232
-0.06137954
-0.06123638
-0.0613079
-0.06132222
-0.06133654

109234.8849 -1032.10575
14.433189
109070.2461 -1030.63076 14.4348749
109138.9303 -1031.24616 14.4341719

3.65648091
3.65641766
3.65644404

8.56E-04
8.56E-04
8.56E-04

0 -0.06135087
0 -0.0613652
0 -0.06135923

el valor de Ke y Ea

y = 11891x - 11.308
R = 1

0.0025

0.003

0.0035

0.004

Linear (Series1)

s
44.0476017
43.78149745
33.8579254
27.90120316
23.93576758
21.11017634
18.99736436
17.35964589
16.05427092
18.63738254
18.29478042
17.96834345
17.65696735
18.21170062
18.12961275
18.04849937
18.03239213
18.01632305
18.02435282
18.02595992
18.0275674

Total
28.60300326
28.33689901
18.41332696
12.45660472
8.491169141
5.6655779
3.552765919
1.915047452
0.60967248
3.192784099
2.850181982
2.523745013
2.212368912
2.767102178
2.685014305
2.603900927
2.587793685
2.571724606
2.579754383
2.581361481
2.58296896

18.02917526
2.58457682
18.0307835 2.586185062
18.03011282 2.585514379

Caso I

Conversion

N2

1
2

SO2 + O2

SO3

-1
-0.5

1
0.63

0.1
0.18

Presion
yi
Temperatura i
0.028169014
R
0.050704225

1
0
-0.5

0
2.37

0.9
2.37
3.55

0.253521127
0.667605634
1

vi

Componente i
SO2
O2
SO3

0.9

ni0

ni

100
#NAME?
8.314

Caso II

Pci
78.8
50.5
82

Componente i
SO2
O2
SO3

T
#NAME?
T
#NAME?

T
#NAME?

T
#NAME?

=1

Componente
i
SO2

Tci
430.8
154.6
491

wi
0.251
0.021
0.41

#NAME?

Ke

#NAME?

Pri
1.269035533
1.98019802
1.219512195

Tri
#NAME?
#NAME?
#NAME?

Bi
#NAME?
#NAME?
#NAME?

#NAME?

Pci
78.8

Tci
430.8

wi
0.251

Pri
1.269035533

Tri
#NAME?

O2
SO3
Componente
i
SO2

50.5
82

154.6
491

0.021
0.41

1.98019802
1.219512195

#NAME?
#NAME?

Pci
78.8

Tci
430.8

wi
0.251

Pri
1.269035533

Tri
#NAME?

O2
SO3
Componente
i
SO2

50.5

154.6

0.021

1.98019802

#NAME?

82

491

0.41

1.219512195

#NAME?

Pci
78.8

Tci
430.8

wi
0.251

Pri
1.269035533

Tri
#NAME?

O2
SO3
Componente
i
SO2

50.5

154.6

0.021

1.98019802

#NAME?

82

491

0.41

1.219512195

#NAME?

Pci
78.8

Tci
430.8

wi
0.251

Pri
1.269035533

Tri
#NAME?

O2
SO3

50.5
82

154.6
491

0.021
0.41

1.98019802
1.219512195

#NAME?
#NAME?

Caso III
T
R
Especie i
SO2

O2

SO3

T
#NAME?

#NAME?
83.14
Especie j

yi

yj

Tci

Pci

wi

SO2
O2
SO3
SO2
O2
SO3
SO2
O2
SO3

0.02816901

0.02816901
0.05070423
0.25352113
0.02816901
0.05070423
0.25352113
0.02816901
0.05070423
0.25352113

430.8

78.8

0.251

154.6

50.5

0.021

491

82

0.41

Especie i

Especie j

yi

yj

Tci

Pci

SO2

SO2
O2
SO3
SO2
O2
SO3
SO2
O2
SO3

0.02816901

0.028169014
0.050704225
0.253521127
0.028169014
0.050704225
0.253521127
0.028169014
0.050704225
0.253521127

430.8

78.8

154.6

50.5

491

82

Especie i

Especie j

yi

yj

Tci

Pci

SO2

SO2
O2
SO3
SO2
O2
SO3
SO2
O2
SO3

0.02816901

0.028169014
0.050704225
0.253521127
0.028169014
0.050704225
0.253521127
0.028169014
0.050704225
0.253521127

430.8

78.8

154.6

50.5

491

82

O2

SO3

T
#NAME?

O2

SO3

0.05070423

0.25352113

0.05070423

0.25352113

0.05070423

0.25352113

ky=
=1

kp=

=1

=
=1

Kp

0.1

Ky

39.9687378
3.99687378
#NAME?

Ke
T

Bi'
#NAME?
#NAME?
#NAME?

Ln
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?

Bi
#NAME?

Bi'
#NAME?

Ln
#NAME?

#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

Bi
#NAME?

Bi'
#NAME?

Ln
#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

Ke

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

Ke

#NAME?

#NAME?

#NAME?

#NAME?

Bi
#NAME?

Bi'
#NAME?

Ln
#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

Ke

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

Bi
#NAME?

Bi'
#NAME?

Ln
#NAME?

#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

#NAME?
#NAME?

Ke

Vci

Zci

Tcj

Pcj

wj

vcj

Zcj

122

0.269

73.4

0.288

127

0.255

430.8
154.6
491
430.8
154.6
491
430.8
154.6
491

78.8
50.5
82
78.8
50.5
82
78.8
50.5
82

0.251
0.021
0.41
0.251
0.021
0.41
0.251
0.021
0.41

122
73.4
127
122
73.4
127
122
73.4
127

0.269
0.288
0.255
0.269
0.288
0.255
0.269
0.288
0.255

wi

Vci

Zci

Tcj

Pcj

wj

vcj

0.251

122

0.269

0.021

73.4

0.288

0.41

127

0.255

430.8
154.6
491
430.8
154.6
491
430.8
154.6
491

78.8
50.5
82
78.8
50.5
82
78.8
50.5
82

0.251
0.021
0.41
0.251
0.021
0.41
0.251
0.021
0.41

122
73.4
127
122
73.4
127
122
73.4
127

wi

Vci

Zci

Tcj

Pcj

wj

vcj

0.251

122

0.269

0.021

73.4

0.288

0.41

127

0.255

430.8
154.6
491
430.8
154.6
491
430.8
154.6
491

78.8
50.5
82
78.8
50.5
82
78.8
50.5
82

0.251
0.021
0.41
0.251
0.021
0.41
0.251
0.021
0.41

122
73.4
127
122
73.4
127
122
73.4
127

Tcij

wij

Zcij

Vcij

Pcij

Trij

Prij

430.8
258.073013
459.916079
258.073013
154.6
275.515154
459.916079
275.515154
491

0.251
0.136
0.3305
0.136
0.021
0.2155
0.3305
0.2155
0.41

0.269
0.2785
0.262
0.2785
0.288
0.2715
0.262
0.2715
0.255

122
95.6519838
124.483265
95.6519838
73.4
97.7646253
124.483265
97.7646253
127

78.9729142
62.4717727
80.4783262
62.4717727
50.4331318
63.6126671
80.4783262
63.6126671
81.964911

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

1.26625693
1.60072294
1.24257057
1.60072294
1.98282352
1.57201395
1.24257057
1.57201395
1.22003427

Zcj

Tcij

wij

Zcij

Vcij

Pcij

Trij

0.269
0.288
0.255
0.269
0.288
0.255
0.269
0.288
0.255

430.8
258.073013
459.916079
258.073013
154.6
275.515154
459.916079
275.515154
491

0.251
0.136
0.3305
0.136
0.021
0.2155
0.3305
0.2155
0.41

0.269
0.2785
0.262
0.2785
0.288
0.2715
0.262
0.2715
0.255

122
95.6519838
124.483265
95.6519838
73.4
97.7646253
124.483265
97.7646253
127

78.9729142
62.4717727
80.4783262
62.4717727
50.4331318
63.6126671
80.4783262
63.6126671
81.964911

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

Zcj

Tcij

wij

Zcij

Vcij

Pcij

Trij

0.269
0.288
0.255
0.269
0.288
0.255
0.269
0.288
0.255

430.8
258.073013
459.916079
258.073013
154.6
275.515154
459.916079
275.515154
491

0.251
0.136
0.3305
0.136
0.021
0.2155
0.3305
0.2155
0.41

0.269
0.2785
0.262
0.2785
0.288
0.2715
0.262
0.2715
0.255

122
95.6519838
124.483265
95.6519838
73.4
97.7646253
124.483265
97.7646253
127

78.9729142
62.4717727
80.4783262
62.4717727
50.4331318
63.6126671
80.4783262
63.6126671
81.964911

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

Bij

B'ij

Bij

Combinaciones

ij

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

i.i
i.j
i.k
j,i
j,j
j,k
k,i
k,j
k,k

0
#NAME?
#NAME?
#NAME?
0
#NAME?
#NAME?
#NAME?
0

0
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

Prij

Bij

B'ij

Bij

Combinaciones

ij

1.266256932
1.600722944
1.242570574
1.600722944
1.982823523
1.572013948
1.242570574
1.572013948
1.220034265

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

i.i
i.j
i.k
j,i
j,j
j,k
k,i
k,j
k,k

0
#NAME?
#NAME?
#NAME?
0
#NAME?
#NAME?
#NAME?
0

Prij

Bij

B'ij

Bij

Combinaciones

ij

1.266256932
1.600722944
1.242570574
1.600722944
1.982823523
1.572013948
1.242570574
1.572013948
1.220034265

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

i.i
i.j
i.k
j,i
j,j
j,k
k,i
k,j
k,k

0
#NAME?
#NAME?
#NAME?
0
#NAME?
#NAME?
#NAME?
0

Ln

Exp

KeT

#NAME?
#NAME?
#NAME?
#NAME?
0
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
0
#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

Ln

Exp

KeT

0
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
0
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
0
#NAME?

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#NAME?

#NAME?

#NAME?

#NAME?

#NAME?

Ln

Exp

KeT

0
#NAME?
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#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
0
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?

#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
#NAME?
0
#NAME?

#NAME?

#NAME?

#NAME?

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T
#NAME?

T
#NAME?

Si se alimentan 2Kmol de CH4 y 3kmol de H2O, escribe las expresiones para yi en funcion del CH4 y calcula las f
a)

CH4 + H2O

CO + 3H2

Componente i
CH4

Gf,i
(KJ/Kmol)
-50460

Hf,i (KH/Kmol)

ui

-74520

H2O

-228572

CO
H2

-1

A
1.702

B
9.08E-03

-241818

-1

3.47

1.45E-03

-137169

-110525

3.376

5.57E-04

3.249

4.22E-04

141863
Ln ker
Ker
H

205813
-57.23007379
1.39732E-25
189433.3172

7.951

(ALn T0)

-57.23007379

(-H/Rto)
-76.4207913

J
(BT0/2)

45.30159149

-1.2981451

T (K)

Ln KeT

KeT

HRx,T

Ln Ket

298.15
300
400
500
600
700
800
900
1000
1100
1101
1102
1101.1
1101.2
1101.3
1101.4
1101.5
1101.6
1101.7
1101.8
1101.9
1101.51
1101.52

-57.2300738
-56.7179559
-35.876943
-23.1241517
-14.4812144
-8.22268355
-3.47587047
0.24950905
3.25087051
5.71953083
5.74200164
5.76443248
5.74424652
5.746491
5.74873508
5.75097876
5.75322205
5.75546493
5.75770742
5.7599495
5.76219119
5.75344635
5.75367065

1.39732E-25
2.33187E-25
2.62326E-16
9.06376E-11
5.13912E-07
0.000268494
0.030934894
1.283395174
25.81280048
304.7619038
311.687672
318.758091
312.3881597
313.0900966
313.7934854
314.4983289
315.2046298
315.9123907
316.6216146
317.3323041
318.044462
315.2753401
315.3460651

(CT02/6)

-0.008708

(D/2To2)

0.03206089 0.05455972

1/t
205813 0.00335402
205899.882 0.00333333
210265.502
0.0025
214024.189
0.002
217225.368 0.00166667
219910.78 0.00142857
222119.29
0.00125
223888.481 0.00111111
225255.295
0.001
226256.327 0.00090909
226264.613 0.00090827
226272.866 0.00090744
226265.44 0.00090818
226266.266
0.0009081
226267.092 0.00090802
226267.918 0.00090794
226268.744 0.00090785
226269.569 0.00090777
226270.394 0.00090769
226271.218 0.00090761
226272.043 0.00090752
226268.826 0.00090784
226268.909 0.00090784

Ea
9.5225E-18
1.599E-17
2.3984E-08
0.01035861
70.4794914
42959.0802
5656680.48
264013382
5900083432
7.6626E+10
7.8439E+10
8.0291E+10
7.8622E+10
7.8806E+10
7.899E+10
7.9175E+10
7.936E+10
7.9545E+10
7.9731E+10
7.9917E+10
8.0104E+10
7.9378E+10
7.9397E+10

1101.53
1101.54
1101.55
1101.56
1101.57
1101.58
1101.59

5.75389495
5.75411925
5.75434354
5.75456782
5.75479211
5.75501639
5.75524066

315.4168046
315.4875588
315.5583276
315.629111
315.699909
315.7707216
315.8415489

226268.991
226269.074
226269.156
226269.239
226269.321
226269.404
226269.486

0.00090783
0.00090782
0.00090781
0.0009078
0.0009078
0.00090779
0.00090778

7.9415E+10
7.9434E+10
7.9452E+10
7.9471E+10
7.9489E+10
7.9508E+10
7.9527E+10

a yi en funcion del CH4 y calcula las fracciones molares.

R
8.314
To
298.15

C
-2.16E-06

D
0

2CH4 + 3H2O
Xa

1.21E+04

Componente
i
CH4

-3.10E+03

0
0.000002164

CO + CO
0.7756

vi

ni0
-2

H2O

-3

8.30E+03

CO2

9700

H2

7
1
4

0
0

CO

Ke=Ky
315.8157223
Por lo tanto la temperatura corresponde al valor

Total
-32.3307243 -24.89934944
(-H/RT)
-76.4207913
-75.9495298
-56.9621474
-45.5697179
-37.9747649
-32.5497985
-28.4810737
-25.3165099
-22.7848589
-20.7135081
-20.6946948
-20.6759156
-20.6928153
-20.6909362
-20.6890574
-20.687179
-20.6853009
-20.6834231
-20.6815457
-20.6796687
-20.6777919
-20.6851131
-20.6849253

(ALn T)
45.30159149
45.35077446
47.63813461
49.41234899
50.86198769
52.08763974
53.14934785
54.08584076
54.92356222
55.68137346
55.68859836
55.6958167
55.68932049
55.69004255
55.69076455
55.69148648
55.69220835
55.69293015
55.69365189
55.69437356
55.69509516
55.69228053
55.69235272

(BT/2)
-1.30E+00
-1.31E+00
-1.74E+00
-2.18E+00
-2.61E+00
-3.05E+00
-3.48E+00
-3.92E+00
-4.35E+00
-4.79E+00
-4.79E+00
-4.80E+00
-4.79E+00
-4.79E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00

Por partes
2
2
(CT /6)
(D/2T )
0.03206089
0.03246
0.05770667
0.09016667
0.12984
0.17672667
0.23082667
0.29214
0.36066667
0.43640667
0.43720049
0.43799504
0.43727992
0.43735935
0.43743878
0.43751823
0.43759768
0.43767714
0.4377566
0.43783608
0.43791556
0.43760562
0.43761357

0.05455972
0.05388889
0.0303125
0.0194
0.01347222
0.00989796
0.00757813
0.00598765
0.00485
0.00400826
0.00400099
0.00399373
0.00400026
0.00399953
0.00399881
0.00399808
0.00399736
0.00399663
0.0039959
0.00399518
0.00399445
0.00399728
0.00399721

-3.23E+01
-3.18E+01
-1.10E+01
1.78E+00
1.04E+01
1.67E+01
2.14E+01
2.51E+01
2.82E+01
3.06E+01
3.06E+01
3.07E+01
3.06E+01
3.06E+01
3.06E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01

-20.6847375
-20.6845498
-20.684362
-20.6841742
-20.6839864
-20.6837987
-20.6836109

55.6924249
55.69249708
55.69256926
55.69264144
55.69271362
55.6927858
55.69285797

-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00
-4.80E+00

0.43762151
0.43762946
0.43763741
0.43764535
0.4376533
0.43766124
0.43766919

0.00399714
0.00399706
0.00399699
0.00399692
0.00399685
0.00399677
0.0039967

3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01
3.07E+01

CO + CO2 + 7H2
CH4 + 2H2O
ni

yi

CO2 + 4H2

Gf,i
(KJ/Kmol)
-50460

Hf,i
(KH/Kmol)
-74520

-1

A
1.702

ui

0.4488

Componente i
CH4
0.055390995

0.6732

0.083086493

H2O

-228572

-241818

-2

3.47

0.7756

0.095724724

CO2

-394359

-393509

5.457

5.4292
0.7756
8.1024

0.670073065
0.095724724
1

H2

0
164647
-45.6850603
1.4429E-20
140610.412

3.249
9.811

corresponde al valor

0
113245
Ln ker
Ker
H

1101.57
J
Ln Ket

(ALn T0)
(-H/Rto)
-45.68506028 -56.72475729 55.8991214
Total
-57.23007379
-56.71795589
-35.87694301
-23.12415166
-14.48121443
-8.222683554
-3.475870475
0.249509046
3.250870512
5.719530829
5.742001635
5.76443248
5.744246516
5.746490998
5.74873508
5.750978763
5.753222046
5.755464931
5.757707416
5.759949503
5.762191191
5.753446353
5.753670655

T (K)
298.15
300
400
500
600
700
800
900
1000
1100
1101
1102
1101.1
1101.2
1101.3
1101.4
1101.5
1101.6
1101.7
1101.8
1101.9
1101.51
1101.52

(BT0/2)

(CT02/6)

-1.3786456 0.032060894

Ln KeT

KeT

HRx,T

-45.68506028
-45.27534531
-28.53697089
-18.20136882
-11.13263767
-5.96967932
-2.02229780
1.09863652
3.63013456
5.72532058
5.74445007
5.76354663
5.74636121
5.74827202
5.75018249
5.75209264
5.75400246
5.75591195
5.75782111
5.75972995
5.76163845
5.75419342
5.75438439

1.4429E-20
2.1735E-20
4.0416E-13
1.2452E-08
1.4627E-05
0.00255506
0.132351
3.00007269
37.7178914
306.531518
312.451755
318.475843
313.049463
313.648212
314.248003
314.848837
315.450716
316.053642
316.657616
317.26264
317.868715
315.510962
315.571217

164647
164739.99
169688.422
174307.608
178485.681
182195.26
185440.644
188240.217
190619.399
192607.454
192625.464
192643.439
192627.263
192629.062
192630.86
192632.658
192634.456
192636.253
192638.05
192639.847
192641.643
192634.636
192634.816

1/t
0.003354016
0.003333333
0.0025
0.002
0.001666667
0.001428571
0.00125
0.001111111
0.001
0.000909091
0.000908265
0.000907441
0.000908183
0.0009081
0.000908018
0.000907935
0.000907853
0.000907771
0.000907688
0.000907606
0.000907523
0.000907845
0.000907836

5.753894953
5.754119248
5.754343538
5.754567825
5.754792107
5.755016386
5.75524066

1101.53
1101.54
1101.55
1101.56
1101.57
1101.58
1101.59

5.75457534
5.75476630
5.75495725
5.75514819
5.75533914
5.75553008
5.75572102

315.631484
315.691761
315.752048
315.812346
315.872654
315.932973
315.993302

192634.995
192635.175
192635.355
192635.535
192635.714
192635.894
192636.074

0.000907828
0.00090782
0.000907812
0.000907803
0.000907795
0.000907787
0.000907779

+ 4H2
B
9.08E-03

C
-2.16E-06

D
0

1.45E-03

1.21E+04

1.05E-03

-1.16E+05

4.22E-04
-0.009248

0
2.16E-06

8.30E+03
-106700

(D/2To2)

Total
-0.60015689 -2.77237751 -42.91268277
Ea
9.83305E-13
1.49043E-12
3.69517E-05
1.423111707
2006.001104
408810.7244
24201386.14
617159353.3
8621253879
77070974411
78630912422
80219715827
78788485923
78946348551
79104500786
79262943107
79421675996
79580699933
79740015401
79899622884
80059522864
79437565284
79453457484

(-H/RT)
-56.7247573
-56.3749546
-42.281216
-33.8249728
-28.1874773
-24.1606948
-21.140608
-18.7916515
-16.9124864
-15.3749876
-15.3610231
-15.3470838
-15.359628
-15.3582332
-15.3568386
-15.3554443
-15.3540503
-15.3526565
-15.3512629
-15.3498697
-15.3484766
-15.3539109
-15.3537715

(ALn T)
55.89912138
55.95980986
58.78225867
60.97152005
62.76027685
64.27264917
65.58272566
66.73829502
67.77198704
68.70707522
68.71599026
68.7248972
68.71688131
68.71777229
68.71866319
68.719554
68.72044474
68.72133539
68.72222597
68.72311646
68.72400687
68.72053381
68.72062288

(BT/2)
-1.38E+00
-1.39E+00
-1.85E+00
-2.31E+00
-2.77E+00
-3.24E+00
-3.70E+00
-4.16E+00
-4.62E+00
-5.09E+00
-5.09E+00
-5.10E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.10E+00
-5.09E+00
-5.09E+00

Por partes
2
(CT /6)

(D/2T )

0.03206089
0.03246
0.05770667
0.09016667
0.12984
0.17672667
0.23082667
0.29214
0.36066667
0.43640667
0.43720049
0.43799504
0.43727992
0.43735935
0.43743878
0.43751823
0.43759768
0.43767714
0.4377566
0.43783608
0.43791556
0.43760562
0.43761357

-0.60015689
-0.59277778
-0.3334375
-0.2134
-0.14819444
-0.10887755
-0.08335938
-0.0658642
-0.05335
-0.04409091
-0.04401085
-0.04393101
-0.04400286
-0.04399487
-0.04398688
-0.04397889
-0.04397091
-0.04396292
-0.04395494
-0.04394696
-0.04393899
-0.04397011
-0.04396931

-2.77237751
-2.36266254
14.3757119
24.7113139
31.7800451
36.9430034
40.890385
44.0113193
46.5428173
48.6380033
48.6571328
48.6762294
48.659044
48.6609548
48.6628653
48.6647754
48.6666852
48.6685947
48.6705039
48.6724127
48.6743212
48.6668762
48.6670672

79469352595
79485250618
79501151553
79517055401
79532962163
79548871838
79564784428

-15.3536321
-15.3534927
-15.3533534
-15.353214
-15.3530746
-15.3529352
-15.3527959

68.72071194
68.72080101
68.72089008
68.72097914
68.72106821
68.72115727
68.72124633

-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00
-5.09E+00

0.43762151
0.43762946
0.43763741
0.43764535
0.4376533
0.43766124
0.43766919

-0.04396851
-0.04396771
-0.04396692
-0.04396612
-0.04396532
-0.04396452
-0.04396372

48.6672581
48.6674491
48.66764
48.667831
48.6680219
48.6682128
48.6684038

Total
-45.68506028
-45.27534531
-28.53697089
-18.20136882
-11.13263767
-5.96967932
-2.02229780
1.09863652
3.63013456
5.72532058
5.74445007
5.76354663
5.74636121
5.74827202
5.75018249
5.75209264
5.75400246
5.75591195
5.75782111
5.75972995
5.76163845
5.75419342
5.75438439

5.75457534
5.75476630
5.75495725
5.75514819
5.75533914
5.75553008
5.75572102

Del Smith van Ness

Componente i Gf,i (KJ/Kmol)
SO2
-300194

Hf,i
(KH/Kmol)
-296830

-1

A
5.699

vi

O2

-0.5

3.639

SO3

-371060

-395720

8.06

3.28
0.5415

N2

0
-70866
H
Ln KeT0

0
-98890

-1.03E+05
28.60300326
-15.44459844

T (K)

Ln KeT

KeT

HRx,T

1/t

Ea

0
100
200
298
400
500
1000
900
910
920
925
930
935
940
936
937
938
939
940
960

#DIV/0!
106.128666
48.0887476
28.6030033
18.413327
12.4566047
0.60967248
1.91504745
1.77136693
1.63086182
1.56176778
1.49342941
1.42583457
1.35897136
1.41240378
1.39900215
1.3856296
1.37228603
1.35897136
1.09860539

#DIV/0!
1.23337E+46
7.66792E+20
2.64318E+12
99267318.5
256941.7591
1.83982872
6.787260857
5.878883903
5.108275253
4.767241221
4.452338275
4.161329325
3.892187563
4.105813004
4.051155498
3.997341833
3.944357322
3.892187563
2.999979305

#DIV/0!
-9.48E+04
-98101.92793
-98890
-99070.1348
-98993.10559
-97483.69889
-97852.38783
-97816.34823
-97780.10846
-97761.91552
-97743.67492
-97725.38742
-97707.05375
-97721.72435
-97718.05945
-97714.39271
-97710.72414
-97707.05375
-97633.27176

#DIV/0!
0.01
0.005
0.003355705
0.0025
0.002
0.001
0.001111111
0.001098901
0.001086957
0.001081081
0.001075269
0.001069519
0.00106383
0.001068376
0.001067236
0.001066098
0.001064963
0.00106383
0.001041667

#DIV/0!
-1.0254E+49
-1.275E+24
-6.5487E+15
-3.3012E+11
-1067987990
222509.033
163238.474
171924.779
179708.355
183307.736
186733.425
189999.552
193118.978
190634.783
191264.246
191888.038
192506.251
193118.978
204349

R
To

8.314
298

P (Bar)
5.697093487 T (K)

1
2

100
938

SO2 + O2

Del Smith van Ness (PDF pag 745)

B-3
8.01E-04

C-6
0.00E+00

D5
-1.02E+05

5.06E-04

-2.27E+04

1.06E-03

-2.03E+05

5.93E-04
2.00E-06

4.00E+03
-9.00E+04

Ln Ket
28.60300326

H/RTo

(-ALn T0)

41.46877999 3.084976123

Pci

Tci
78.8

50.5

430.8

wi
0.251

Pri
1.269035533

154.6

0.021

1.98019802

491

0.41

1.219512195

82

Por partes
(-BT0/2)
(-CT02/6)
0.000298

(-D/2To2)

-0.50645241

44.0476017

Por partes
J
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844
-15.44459844

(-H/RT)
123.5769644
61.78848219
41.46877999
30.89424109
24.71539288
12.35769644
13.73077382
13.5798862
13.43227874
13.35967182
13.28784563
13.21678763
13.14648557
13.20266713
13.18857677
13.17451646

(ALn T)
2.493699656
2.869038854
3.084976123
3.244378052
3.365210285
3.740549484
3.683496764
3.689480251
3.695398342
3.698333309
3.701252453
3.704155946
3.707043952
3.704734781
3.705312997
3.705890597

(BT/2)
1.00E-04
2.00E-04
2.98E-04
4.00E-04
5.00E-04
1.00E-03
9.00E-04
9.10E-04
9.20E-04
9.25E-04
9.30E-04
9.35E-04
9.40E-04
9.36E-04
9.37E-04
9.38E-04

(CT2/6)

Chart Title
35
30
25
20
15
10

y = 11884x - 11.289
R = 1

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

(D/2T2)
-4.4975
-1.124375
-0.50645241
-0.28109375
-0.1799
-0.044975
-0.05552469
-0.05431107
-0.05313681
-0.05256392
-0.05200023
-0.05144557
-0.05089973
-0.0513357
-0.05122618
-0.05111702

1.22E+02
6.35E+01
4.40E+01
3.39E+01
2.79E+01
1.61E+01
1.74E+01
1.72E+01
1.71E+01
1.70E+01
1.69E+01
1.69E+01
1.68E+01
1.69E+01
1.68E+01
1.68E+01

10
5
0
0

0.0005

0.001

0.0015

0.002

0.0025

0.003

0.0035

0.004

SO3

Tri
2.177344475

Bi
-0.037938857

Bi'
0.132450103

Ln
-0.002735765

0.99726797

6.067270375

0.059532873

0.138911497

0.020382048

1.02059118

1.910386965

-0.066092273

0.127654627

-0.008779907

0.99125852

k
ke
Total
-15.44459844

0.983895914 duda signos exponente

3.932507779
T=m/y-B
1.19E+04

t
Total
106.12866559
48.08874760
28.60300326
18.41332696
12.45660472
0.60967248
1.91504745
1.77136693
1.63086182
1.56176778
1.49342941
1.42583457
1.35897136
1.41240378
1.39900215
1.38562960

11.289
938.8323297

Pci

78.8

938.8323297
50.5

82

Tci
430.8
154.6
491

wi
0.251
0.021
0.41

Conversion
Componente i
SO2

ni0

vi

O2
SO3
N2

kp
ke

0.9
ni

-1

yi
0.1 0.02816901

-0.5

0.63

0.18 0.05070423

0.9 0.25352113

0
-0.5

2.37

2.37 0.66760563
3.55
1

0.1 ky
3.99687378

39.9687378

937.629751

Pri
1.269035533
1.98019802
1.219512195

Tri
Bi
2.17927653 -0.03776735
6.07265414 0.05956615
1.91208214 -0.06588084

Bi'
Ln
0.13247446 -0.00262991
0.13891183 0.02037483
0.12769681 -0.00862624

0.997373547
0.9839465
1.020583816 3.93250778
0.991410856