S GD & T BN TRE

TRNG THPT CHUYN BN TRE

M thi : 132

THI THPT QUC GIA LN 1 NM - 2016

MN : HO HC
Thi gian lm bi : 90 pht

Cu 1. T c sn xut t xenluloz l?
A. t tm.
B. t capron.
C. t nilon 6,6.
D. t visco.
Cu 2. Mt mu nc cng c cha cc ion: Ca2+, Mg2+, HCO 3 , Cl-, SO 24 . Cht lm mm mu nc cng trn l?
A. NaHCO3.
B. Na3PO4.
C. HCl.
D. BaCl2.
Cu 3. Dy gm cc cht c sp xp theo th t tng dn lc baz t tri sang phi l ?
A. Phenylamin, amoniac, etylamin.
B. Etylamin, amoniac, phenylamin.
C. Etylamin, phenylamin, amoniac.
D. Phenylamin, etylamin, amoniac.
Cu 4. Cho cc pht biu sau :
(a) nhit thng, Cu(OH)2 tan c trong dung dch glixerol.
(b) nhit thng, C2H4 phn ng c vi nc brom.
(c) t chy hon ton CH3COOCH3 thu c s mol CO2 bng s mol H2O.
(d) Glyxin (H2NCH2COOH) phn ng c vi dung dch NaOH.
S pht biu ng l ?
A. 2.
B. 3.
C. 4.
D. 1.
Cu 5. Cho m gam Fe phn ng hon ton vi dung dch HNO3 long (d), thu c 4,48 lt kh NO (ktc, sn
phm kh duy nht). Gi tr ca m l ?
A. 11,2.
B. 16,8.
C. 8,4.
D. 5,6.
Cu 6. Cho cc cp phn ng sau :
1. H2S + Cl2 + H2O
2. SO2 + H2S
3. SO2 + Br2 + H2O
4. S + H2SO4 c, nng
5. S + F2
6. SO2 + O2
Tng s phn ng to ra sn phm cha lu hunh mc oxi ha +6 l :
A. 2.
B. 3.
C. 4.
D. 5.
Cu 7. Cho cc cht sau y, cht c nhit si cao nht l ?
A. CH3OH
B. CH3CH2OH
C. CH3CH2COOH.
D. CH3COOH.
Cu 8. Kim loi M c th iu ch c bng phng php thy luyn, nhit in, in phn, M l ?
A. Mg.
B. Cu.
C. Al.
D. Na.
Cu 9. Este X c t khi hi so vi He bng 21,5. Cho 17,2 gam X tc dng vi dung dch NaOH d, thu c dung
dch cha 16,4 gam mui. Cng thc ca X l ?
A. C2H3COOCH3.
B. CH3COOC2H3.
C. HCOOC3H5.
D. CH3COOC2H5.
Cu 10. Trong qu trnh iu ch cc cht kh sau trong phng th nghim: H2, Cl2, SO2, HCl, NH3, NO2, O2. S
cht kh c th thu c bng phng php di ch nc (y nc) l?
A. 4.
B. 5.
C. 2.
D. 3.
Cu 11. Chia 39,9 gam hn hp X dng bt gm Na, Al, Fe thnh ba phn bng nhau :
- Phn 1: cho tc dng vi nc d, gii phng ra 4,48 lt kh H2.
- Phn 2: Cho tc dng vi dung dch NaOH d, gii phng ra 7,84 lt kh H2.
- Phn 3: Cho vo dung dch HCl d, thy gii phng ra V lt kh H2 (cc kh o ktc). Gi tr ca V l ?
A. 7,84.
B. 13,44.
C. 10,08.
D. 12,32.
Cu 12. Pht biu no sau y khng ng khi so snh tnh cht ha hc ca Al v Cr ?
A. Nhm v crom u phn ng vi dung dch HCl theo cng t l s mol.
B. Nhm v crom u bn trong khng kh v nc.
C. Nhm v crom u b th ng trong dung dch H2SO4 c ngui.
D. Nhm c tnh kh mnh hn crom.
Cu 13. t 13,0 gam Zn trong bnh cha 0,15 mol kh Cl2, sau phn ng hon ton thu c cht rn X. Cho X
vo dung dch AgNO3 d th thu c lng kt ta l ?
A. 46,30 gam.
B. 57,10.
C. 53,85 gam.
D. 43,05 gam.
Cu 14. un 6,0 gam CH3COOH vi C2H5OH d (xc tc H2SO4 c) thu c 4,4 gam CH3COOC2H5. Hiu sut
ca phn ng este ha l ?
A. 36,67%.
B. 20,75%.
C. 25,00%.
D. 50,00%.
Cu 15. Ancol etylic tc dng vi CuO nhit thch hp, sinh ra cht no sau y ?
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Trang 1/13 M thi 132

A. C2H4.
B. HCHO.
C. CH3CHO.
D. HCOOH.
Cu 16. Dung dch X c 0,1 mol K+; 0,2 mol Mg2+; 0,1 mol Na+; 0,2 mol Cl- v a mol Y-. C cn dung dch X thu
c m gam mui khan. Ion Y- v gi tr ca m l ?
A. OH- v 30,3.
B. NO3- v 23,1.
C. NO3 v 42,9.
D. OH- v 20,3.
Cu 17. Cho m gam glucozo tc dng vi lng d dung dch AgNO3/NH3 thu c 86,4 gam Ag. Nu ln men
hon ton m gam glucozo ri cho kh CO2 thu c hp th vo nc vi trong d th lng kt ta thu c l ?
A. 80 g.
B. 40 g.
C. 20 g.
D. 60 g.
Cu 18. Cho 200 ml dung dch amino axit X nng 0,4M tc dng va vi 80 ml dung dch NaOH 1M thu
c dung dch cha 10 gam mui. Khi lng mol phn t ca X l ?
A. 147.
B. 89.
C. 103.
D. 75.
Cu 19. S ng phn cha vng bezen, c cng thc phn t C7H8O, phn ng c vi Na l?
A. 2.
B. 4.
C. 3.
D. 5.
Cu 20. Cho cc th nghim sau :
(1) un nng nc cng tm thi.
(2) Cho phn chua vo dung dch Ba(OH)2 d.
(3) Cho dung dch NaOH d vo dung dch AlCl3.
(4) Cho kh CO2 d vo dung dch NaAlO2.
(5) Cho kh NH3 d vo dung dch AlCl3.
S th nghim thu c kt ta l?
A. 4.
B. 3.
C. 2.
D. 5.
Cu 21. Cht c th dng lm kh NH3 l?
A. H2SO4 c.
B. P2O5.
C. CaO.
D. CuSO4 khan.
Cu 22. Pht biu no sau y l ng ?
A. nhit thng, cc amino aixt u l nhng cht lng.
B. Cc amino axit thin nhin hu ht l cc amino axit.
C. Axit glutamic l thnh phn chnh ca bt ngt.
D. Amino axit thuc loi hp cht hu c tp chc.
Cu 23. Cho cu hnh electron ca cc ht vi m sau :
X : [Ne] 3s2 3p1
Y2+ : 1s2 2s2 2p6.
Z : [Ar] 3d5 4s2
M2- : 1s2 2s2 2p6 3s2 3p6
T2+ : 1s2 2s2 2p6 3s2 3p6.
Trong cc nguyn t X, Y, Z, M, T nhng nguyn t no thuc chu k 3?
A. X, Y, M.
B. X, Y, M, T.
C. X, M, T.
D. X, T.
Cu 24. ha tan hon ton 5,4 gam Al cn dng va V ml dung dch NaOH 0,5M. Gi tr ca V l ?
A. 200.
B. 400.
C. 300.
D. 100.
Cu 25. Hidrocacbon X th kh trong iu kin thng. Cho X li t t qua dung dch Br2 d thy khi lng
bnh ng dung dch Br2 tng 2,6 gam v c 0,15 mol Br2 phn ng. Tn gi ca X l ?
A. Vinyl axetilen.
B. Butilen.
C. Etilen.
D. Axetilen.
Cu 26. C bao nhiu aminoaxit l ng phn c cng cng thc phn t C4H9NO2 ?
A. 4.
B. 2.
C. 5.
D. 3.
Cu 27. Cht no sau y thuc loi ancol bc 1 ?
A. (CH3)3COH.
B. CH3CH(OH)CH2CH3.
C. CH3CH(OH)CH3.
D. CH3CH2OH.
Cu 28. Trong cng nghip, amoniac c iu ch t nito v hidro bng phng php tng hp theo phng trnh
ha hc :
N2 (k) + 3H2 (k)
2NH3 (k)
H < 0.
cn bng ha hc trn chuyn dch theo chiu thun ta phi ?
A. Tng nhit , gim p sut.
B. Gim nhit , gim p sut.
C. Tng nhit , tng p sut.
D. Gim nhit , tng p sut.
Cu 29. Dy gm cc ion u oxi ha c kim loi Fe l ?
A. Zn2+, Cu2+, Ag+.
B. Cr2+, Cu2+, Ag+.
2+
3+
3+
C. Cr , Au , Fe .
D. Fe3+, Cu2+, Ag+.
Cu 30. Phng php chung iu ch cc kim loi Na, Mg, Al trong cng nghip l ?
A. thy luyn.
B. in phn nng chy.
C. in phn dung dch.
D. nhit luyn.
Cu 31. Cho hn hp X gm 0,5 mol C2H5OH v 0,7 mol C3H7OH dn qua H2SO4 c nng thu c m gam hn
hp Y gm cc ete v anken. Cho Y vo dung dch brom d th thy c 1 mol Br 2 tham gia phn ng. Gi tr ca
m l ?

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Trang 2/13 M thi 132

A. 44,3.
B. 47.
C. 43,4.
D. 45,2.
Cu 32. Ha tan hon ton 4,92 gam hn hp A gm (Al, Fe) trong 390 ml dung dch HCl 2M thu c dung dch
B. Thm 800 ml dung dch NaOH 1M vo dung dch B thu c kt ta C, lc kt ta C, ra sch sy kh nung
trong khng kh n khi lng khng i, thu c 7,5 gam cht rn. Phn trm khi lng ca Al trong hn hp
A c gi tr gn nht vi gi tr no sau y ?
A. 65,8%.
B. 85,6%.
C. 16,5%.
D. 20,8%.
Cu 33. Thc hin cc phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr 2O3 (trong iu kin khng c
O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng),
sau khi cc phn ng xy ra hon ton, thu c 2,688 lt H2 (ktc). Cn nu cho ton b X vo mt lng d dung
dch NaOH (c, nng), sau khi phn ng kt thc th s mol NaOH phn ng l ?
A. 0,08 mol.
B. 0,16 mol
C. 0,10 mol.
D. 0,06.
Cu 34. Cho 7,2 gam bt Mg tan ht trong dung dch hn hp HCl (d) v KNO 3, thu c dung dch X cha m
gam mui v 2,688 lt kh Y (ktc) gm N2 v H2 c khi lng 0,76 gam. Gi tr ca m l ?
A. 29,87.
B. 24,03.
C. 32,15.
D. 34,68.
Cu 35. Nung nng hn hp gm 5,6 gam Fe vi 4 gam bt S trong bnh kn mt thi gian thu c hn hp X
gm FeS, FeS2, Fe v S d. Cho X tan ht trong dung dch H2SO4 c nng d c V lt kh (ktc). Gi tr ca V l
?
A. 8,96.
B. 11,65.
C. 3,36.
D. 11,76.
Cu 36. Tin hnh cc th nghim sau :
(a) Cho NH4Cl tc dng vi NaOH.
(b) Cho NH3 tc dng vi O2 d nhit cao.
(c) Nhit phn Cu(NO3)2.
(d) Cho HCl tc dng vi dung dch KMnO4.
(e) Sc kh CO2 qua nc vi trong d.
(f) in phn dung dch CuCl2 vi in cc tr.
(g) Dn kh CO d qua bt MgO nung nng.
Sau khi phn ng kt thc, s th nghim thu c n cht l ?
A. 5.
B. 6.
C. 4.
D. 7.
Cu 37. Cho cc pht biu sau :
(a) Cc amin u c kh nng nhn proton (H+)
(b) Tnh bazo ca cc amin u mnh hn amoniac.
(c) tch ring hn hp kh CH4 v CH3NH2 th ha cht cn dng l dung dch HCl v dung dch NaOH.
(d) lm sch l ng anilin th ra bng dung dch HCl sau ra li bng nc.
(e) Anilin c tnh bazo, dung dch anilin c th lm hng phenolphthalein.
(f) t chy hon ton 1 anken thu c s mol CO2 bng s mol H2O.
(g) Sobitol l hp cht hu c a chc.
(h) Trong cng nghip, axeton c sn xut t cumen.
S pht biu ng l ?
A. 6.
B. 4.
C. 7.
D. 5.
Cu 38. Hn hp X gm ba cht hu c mch h, trong phn t ch cha cc loi nhm chc OH, -CHO, COOH. Chia 0,3 mol X thnh ba phn bng nhau. t chy hon ton phn mt, thu c 2,24 lt CO 2 (ktc). Phn
hai tc dng vi Na d, thu c 0,672 lt kh H2 (ktc). un nng phn ba vi lng d dung dch AgNO3 trong
NH3 thu c c 21,6 gam Ag. Phn trm s mol ca cht c phn t khi nh nht trong X l ?
A. 20%.
B. 40,00%.
C. 35,29%.
D. 30%.
Cu 39. T 5 kg go np (c 81% tinh bt) khi ln men s thu c bao nhiu lt cn 92 0 ? Bit hiu sut ton b
qu trnh ln men t 80% v khi lng ring ca ancol etylic l 0,8 g/ml
A. 2,000 lt.
B. 2,500 lt.
C. 2,208 lt.
D. 2,116 lt.
Cu 40. Hn hp X gm 2 andehit n chc A v B (MA < MB v s nguyn t C trong B khng qu 4). Cho 13,48
gam X tc dng hon ton vi AgNO3 d trong dung dch NH3 th thu c 133,04 gam kt ta. Mt khc cho
13,48 gam X tc dng ht vi H2 (Ni, t0) thu c hn hp Y. Cho Y tc dng vi Na d thu c 3,472 lt H2
(ktc). Phn trm khi lng ca A trong hn hp X c th l ?
A. 33,38%.
B. 44,51%.
C. 55,63%.
D. 66,76%.
Cu 41. Hn hp Z gm 1 ancol no mch h 2 chc X v 1 ancol no n chc mch h Y (cc nhm chc u bc
1) c t l s mol nX : nY = 1 : 3. Cho m gam hn hp Z tc dng vi natri d thu c 6,72 lt H 2 (ktc). Mt khc
cho m gam hn hp Z tc dng vi CuO d un nng sau khi phn ng kt thc thu c 38,64 gam hn hp
andehit v hi nc. t chy m gam hn hp Z cn bao nhiu lt O2 (ktc) ?
A. 43,008.
B. 47,040.
C. 37,632.
D. 32,310.
Cu 42. Ha tan ht m gam hn hp rn X gm Mg, Cu(NO3)2, Fe, FeCO3 vo dung dch cha H2SO4 v 0,045 mol
NaNO3, thu c dung dch Y ch cha 62,605 gam cc mui (khng c ion Fe 3+) v thy thot ra 3,808 lt (ktc)
hn hp kh T gm N2, NO2, N2O, NO, H2, CO2 c t khi so vi H2 bng 304/17 (trong T c cha 0,02 mol H2).
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Trang 3/13 M thi 132

Cho dung dch NaOH 1M vo dung dch Y n khi thu c lng kt ta ln nht l 31,72 gam th dng ht 865
ml. Mt khc, cho 94,64 gam BaCl2 va vo Y sau cho tip AgNO3 d vo th thu c 256,04 gam kt ta.
Bit cc phn ng hon ton. Cho cc pht biu sau :
(a) Gi tr ca m l 27,200 gam.
(b) Phn trm khi lng Fe trong hn hp l 20,950%.
(c) Th tch kh CO2 (ktc) trong hn hp kh T l 1,792 lt.
(d) Khi lng Cu(NO3)2 trong m gam hn hp X l 7,520 ga.
(e) S mol H2SO4 tham gia phn ng l 0,544 mol.
(f) Tng khi lng cc kh (N2, NO, N2O, NO2) trong hn hp T l 2,52 gam.
S pht biu ng trong cc pht biu trn l ?
A. 3.
B. 4.
C. 2
D. 5.
Cu 43. Hn hp X gm Al, MgO, Al2O3 trong oxi chim 41,989% khi lng hn hp. Cho m gam hn hp
trn tan ht trong dung dch cha 1,0 mol HCl thu c dung dch Y v a mol H 2. Rt t t dung dch NaOH vo
dung dch Y cho n d ta c th sau :

Gi tr ca m gn nht vi :
A. 15,0.
B. 14,0.
C. 15,5.
D. 14,5.
Cu 44. in phn dung dch cha 0,15 mol Fe(NO3)3; 0,25 mol Cu(NO3)2 vi in cc tr cng dng in
2,68A trong 8 gi thu c dung dch X. Ly dung dch X ra khi bnh in phn v yn cho n khi phn ng
kt thc thu c dung dch Y v c kh NO thot ra. Dung dch Y c th ha tan ti a bao nhiu gam Cu ? (bit
NO l sn phm kh duy nht ca cc phn ng trn).
A. 15,60.
B. 16,40.
C. 17,20.
D. 17,60.
Cu 45. Rt t t dung dch cha a mol HCl vo dung dch hn hp cha a mol NaHCO 3 v b mol Na2CO3 thu
c (a + b)/7 mol kh CO2 v dung dch X. Hp th a mol CO2 vo dung dch hn hp cha a mol Na2CO3 v b
mol NaOH thu c dung dch Y. Tng khi lng cht tan trong 2 dung dch X v Y l 59,04 gam. Cho dung dch
BaCl2 d vo dung dch Y thu c m1 gam kt ta. Gi tr ca m1 l ?
A. 19,70.
B. 29,55.
C. 23,64.
D. 15,76.
Cu 46. Nhit phn hon ton m gam KClO3 vi xc tc MnO2, lng kh thot ra oxi ha 1,26m gam hn hp Fe
v Cu thu c hn hp X gm cc oxit. Cho hn hp X tc dng vi dung dch HNO 3 d thu c dung dch Y v
0,896 lt NO (ktc, sn phm kh duy nht). C cn dung dch Y thu c 175,76 gam mui khan. Gi tr ca m l
?
A. 40,18.
B. 38,24.
C. 39,17.
D. 37,64.
Cu 47. X, Y, Z, T l cc hp cht hu c sinh ra t cc phn ng :
t
CH 2 CH CH 2 OH CuO
X ....
0

t
CH 3OH CuO
Y ....
0

men
C 2 H 5OH O 2

Z ....

CH 2 CH 2 KMnO 4 H 2 O
T ....
Hn hp R gm X, Y, Z, T trong T chim 19,62% khi lng hn hp R. t chy 9,34 gam hn hp R cn V
lt O2 (ktc) thu c hn hp CO2 v H2O trong khi lng CO2 nhiu hn khi lng H2O l 11,3 gam. Gi tr
ca V l ?
A. 9,744.
B. 9,968.
C. 10,192.
D. 10,416.
Cu 48. X l ipeptit Val Ala, Y l tripeptit Gly Ala Glu. un nng m gam hn hp X v Y c t l s mol nX
: nY = 3 : 2 vi dung dch KOH va , sau khi phn ng kt thc thu c dung dch Z. C cn dung dch Z thu
c 17,72 gam mui. Gi tr ca m gn nht vi ?
A. 12,0 gam.
B. 11,1 gam.
C. 11,6 gam.
D. 11,8 gam.
Cu 49. t chy hon ton m gam hn hp X gm propandial, axetandehit, etandial v andehit acrylic cn 0,975
mol O2 v thu c 0,9 mol CO2 v 0,65 mol H2O. Nu cho m gam hn hp X trn tc dng vi lng d dung dch
AgNO3 trong NH3 th thu c ti a bao nhiu gam Ag ?
A. 54,0 gam.
B. 108,0 gam.
C. 216,0 gam.
D. 97,2 gam.

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Trang 4/13 M thi 132

Cu 50. X, Y, Z l ba axit cacboxylic n chc cng dy ng ng (MX < MY < MZ), T l este to bi X, Y, Z vi
mt ancol no, ba chc, mch h E. t chy hon ton 26,6 gam hn hp M gm X, Y, Z, T (trong Y v Z c
cng s mol) bng lng va kh O2 thu c 22,4 lt CO2 (ktc) v 16,2 gam H2O. Mt khc, un nng 26,6
gam M vi lng d dung dch AgNO3/NO3 sau khi cc phn ng xy ra hon ton, thu c 21,6 gam Ag. Mt
khc, cho 13,3 gam m phn ng ht vi 300 ml dung dch NaOH 1M v un nng, thu c dung dung dch N. C
cn dung dch N thu c m gam cht rn khan. Gi tr ca m gn nht vi ?
A. 22,74.
B. 24,74.
C. 18,74.
D. 20,74.
------------- HT ------------

S GD & T BN TRE
TRNG THPT CHUYN BN TRE
M thi : 132

P N THI THPT QUC GIA LN 1 NM - 2016

MN : HO HC

11

21

31

41

12

22

32

42

13

23

33

43

14

24

34

44

15

25

35

45

61

26

36

46

17

27

37

47

18

28

38

48

19

29

39

49

10

20

30

40

50

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Trang 5/13 M thi 132

NH HNG GII MT S CU KH
Cu 9: nh hng t duy gii
MX 86
n X 0,2
CH3COONa
CH3COOC2 H3
Cu 10: nh hng t duy gii
Cc cht kh tha mn l: H2, O2
Cu 11: nh hng t duy gii
Na : a
a 3a 0, 2.2
a 0,1

a 3b 0,35.2

b 0, 2
Ta c: 13,3 Al : b
Fe : c
23a 27b 56c 13,3
c 0,1

BTE

n H2

0,1.1 0, 2.3 0,1.2

0, 45
V 10,08
2

Cu 13: nh hng t duy gii

AgCl : 0,3
n Zn 0,2
n ZnCl2 0,15 AgNO3
Ta c:

53,85

Ag : 0,1
n Cl2 0,15
n Zn 0,05
Cu 31: nh hng t duy gii
n anken
H O 1
2
n anken 1

Ta c: n Br2 1
0,5 0,7 1
ete
0,1
n H2O
2

BTKL

0,5.46 0,7.60 m 1,1.18

m 45,2(gam)
Cu 32: nh hng t duy gii
D thy 7,5 gam l Fe2O3 v Al2O3.

Fe : a

56a 27b 4,92

Al : b

Ta gi 4,92

Na : 0,8
Fe2 O3 : 0,5a

Dung dch B cha Cl : 0,78

7,5
b 0,02
BTDT
Al2 O3 :

AlO2 : 0,02

a 0,03

80a 51(b 0,02) 7,5

%Al 65,86%
b 0,12

Cu 33: nh hng t duy gii

Cr : 0,06
n Cr2O3 0,03 BTNT BTE
BTNT.Al
Al : 0,04

NaAlO 2 : 0,1
Ta c:
n

0,12
Al O : 0,03
H2
2 3

n NaOH 0,1(mol)
Cu 34: nh hng t duy gii
C kh H2 Dung dch khng cn NO3-.
N 2 : 0,02
Ta c: n Mg 0,3
n Y 0,12
H 2 : 0,1

BTE

n NH
4

K : 0,065

0,3.2 0,02.10 0,1.2

NH : 0,025

0,025
X 24
8
Mg : 0,3
Cl : 0,39

BTKL

m 24,03(gam)
Cu 35: nh hng t duy gii
n 0,1
0,1.3 0,125.6
BTE
Ta c: Fe

n SO2
0,525
V 11,76(lit)
2
n S 0,125

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Trang 6/13 M thi 132

Cu 36: nh hng t duy gii

Cc th nghim tha mn l: (b), (c), (d), (f).
Cu 37: nh hng t duy gii
Cc pht biu ng l: (a), (c), (d), (f), (g), (h) Khng lm hng phenolphtalein.
C6H5NH2 c tnh baz nhng rt yu (yu hn NH3)
Cu 38: nh hng t duy gii
+ Mi phn c 0,1 mol v n CO2 0,1 Cc cht ch c 1 nguyn t cacbon.

a b c 0,1
HCOOH : a
a 0,02
Na

HCHO : b
a c 0,03.2
b 0,04
CH OH : c
Ag
c 0,04
3

2a 4b 0, 2

% n CH3OH 40%

Cu 39: nh hng t duy gii

Ta c:
n TB

5.0,81
5.0,81

n ancol 2.
.0,8
m ancol 1,84(kg)
162
162

m ancol 1,84
2,3

2,3
Vancol 920
2,5(lit)
d
0,8
0,92
Cu 40: nh hng t duy gii
n H 0,155 n X 0,31
HCHO : a

M X 43, 48

Ta c: 2
RCHO : b
m X 13, 48
a 0, 2
a b 0,31

b 0,11
30a (R 29) b 13, 48
CH C CH CHO
2

Vi loi ny ta nn th s nhanh hn gii h v s C trong B khng qu 4 nguyn t. Ta th li cho n chc:

Ag :1,02
(chun ri)

m 133,04
CAg C CH 2 COONH 4 : 0,11
Cu 41: nh hng t duy gii
HO CH 2 R CH 2 OH : a Na
Ta c: Z
2a 3a 0,3.2
a 0,12
R 'CH 2 OH : 3a

Vancol

BTKL

n O 0,6
mZ 38,64 0,6.16 29,04(gam)
29,04 0,6.17 0,36

1,32
CH 2 :
14

Dn Z v OH : 0,6
H : 0,36

CO2 :1,32
1,32.2 1,8 0,6

n O2
1,92
V 43,008
2
H 2 O :1,8
Cu 42: nh hng t duy gii
+ Ch (c H2 nn NO3- phi ht).
BTNT.Na
D kin ban u c li nht l n NaOH 0,865
n Na 2SO4 0,455

n H2SO4 0,455 (e) l pht biu sai.

Mg 2 ,Cu 2 , Fe 2 : a(mol)

NH 4 : b(mol)
Z s cha

2a b 0,865

Na : 0,045
2
SO 4 : 0, 455
BTKL

m(Mg,Fe,Cu) 31,72 (0,865 b).17

BTKL

m Z 31,72 (0,865 b).17 18b 0,045.23 0, 455.96 62,605

Cu,Fe,Mg

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Trang 7/13 M thi 132

BTNT.H

b 0,025
n H2O

0, 455.2 0,025.4 0,02.2

0,385
2

a 0, 42(mol)
BTKL

m 0, 455.98 0,045.85 62,605 0,17.

304.2
0,385.18
17

m 27, 2(gam) (a) l pht biu ng.

BaSO4 : 0, 455(mol)

Xt kt ta 256,04 AgCl : 0,91(mol)

BTKL
BTE
Fe 2 : 0,18(mol)
Ag : 0,18(mol)
Mg 2 : x

x y 0, 42 0,18 0, 24
x 0, 2

17, 44 Cu 2 : y

24x 64y 7,36

y 0,04
2
Fe : 0,18
Fe : t
Vy hn hp u cha: 14,88
FeCO3 : 0,18 t
BTKL

56t 116(0,18 t) 14,88

t 0,1
BTNT.C

n CO2 0,1
VCO2 2,24 (c) l pht biu sai

%Fe

0,1.56
20,59% (b) l pht biu sai
27, 2

mCu(NO3 )2 0,04(64 62.2) 7,52(gam) (d) l pht biu ng

m(N O
x

y)

0,17.

304.2
0,02.2 0,1.44 1,64
17

(f) l pht biu sai . Vy tng cng c 2 pht biu ng.

Cu 43: nh hng t duy gii
Al : x

+ Nhn vo th ta thy HCl d 2a mol. Gi X Mg : y

O

14a
4a
2a 2n Mg 2 2y
y
3
3

Na :16a

BTNT.Al
Ti 16a:
Cl :1

n Al(OH)3 x 16a 1

AlO2 :16a 1
4a
44a
44a
x 1
0,36
x
0,64
3
3
3
1 2a 2a

0,5 2a
2

x 16a 1
BTNT.H
X

n Trong
O

%O

0,5 2a 16

0, 41989
44a
4a
0,5 2a 16 27( 0,64) 24.
3
3
Mg
:
0,08

a 0,06
m Al : 0, 24
m 14, 48(gam)
O : 0,38

Cu 44: nh hng t duy gii

Fe3 : 0,15
2
Cu : 0, 25
Cu : 0, 25
BTE
Ta c:

H 2 : 0,075
NO3 : 0,95
n 0,8(mol)
n H 0,8 0,15
e
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Trang 8/13 M thi 132

Cu ,Fe

n NO

0, 65
0,1625
4

Fe2 : 0,15
BTNT.N
Dung dch cui cng cha
NO3 : 0,7875
mCu 15,6(gam)
BTDT
2
Cu : 0, 24375

Cu 45: nh hng t duy gii
Rt HCl:
a b

ab

6a 8b 0
3a 4b 0
7

Na : a 2b

Dung dch X cha: Cl : a

BTDT
HCO3 : 2b

Na : 2a b

BTDT
Hp th CO2: Y HCO3 : t

2a b 4a t
t 2a b
BTNT.C
2
CO3 : 2a t

Na : 2a b

BTKL

23(3a 3b) 61(2a b) 60b 35,5a 59,04

Y HCO3 : 2a b
BTNT.C
2
CO3 : b

3a 4b 0
a 0,16

m1 0,12.197 23,64
226,5a 190b 59,04
b 0,12

Cu 46: Phn tch hng gii

m
3m
96m
BTKL
n O2
.1,5

mO
Ta c:
122,5
245
245

12m

BTKL BTE

1, 26m 0,04.3
m 39,17
62 175,76
245

Fe,Cu
NO3

Cu 47: Phn tch hng gii

CH 2 CH CHO

HCHO
Ta c: 9,34
CH3COOH
HO CH 2 CH 2 OH : 0,03(mol)
Dn bin gi nh
HCHO : a
CO2 : a 3b 0,06

Dn R v 9,34 C3 H 4 O : b

H 2 O : a 2b 0,09
C H O : 0,03
2 6 2
30a 56b 7, 48
a 0,1

44(a 3b 0,06) 18(a 2 b 0,09) 11,3

b 0,08
BTNT.O

0,4.2 0,35 0,24 2n O2

n O2 0,455
V 10,192

Cu 48: Phn tch hng gii

Gly K : 2a
Ala K : 5a
Val Ala : 3a

17,72
Ta c:
Gly

Ala

Glu
:
2a

Val K : 3a
Glu K 2 : 2a
BTKL

17,72 a(113.2 127.5 155.3 223.2)

a 0,01

m 0,03(89 117 18) 0,02(75 89 147 36) 11,14

Cu 49: Phn tch hng gii

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Trang 9/13 M thi 132

BTNT.O
X

n Trong
n CHO 0,9.2 0,65 0,975.2 0,5
O

n Ag 1
mAg 108(gam)

Cu 50: Phn tch hng gii

Bi ton ny cng rt nhiu ch, chng ta cn trit khai thc nhng d liu mang tnh then cht. Ri da vo
suy lun tip.
+ V M c trng bc nn chc chn X phi l HCOOH (vy axit u no n chc)
+ Nhn thy c khi lng hn hp, s mol CO2, H2O.
BTKL
ng

n Ophn

1.44 16,2 26,6

BTNT.O
1,05(mol)
n Otrong M 0,8(mol)
32

n CO2 1
1 0,9

n este
0,05(mol) , n Ag 0,2 n HCOOH 0,05
+ V
n

0,9
2
H2 O
BTNT.O
nYZ
+

n Y 0,1(mol)
0,8 0,05.6 0,05.2
0,2
2
n Z 0,1(mol)

Bin lun:
Nu Y, Z khng phi l CH3COOH v C2H5COOH th s mol CO2 > 1 (v l)
HCOOH : 0,05

CH 3COOH : 0,1
BTNT.C
NaOH,BTKL

m 24,74
C 2 H 5COOH : 0,1
HCOO C H (OOCCH )(OOCC H ) : 0,05
3 5
3
2 5

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132

Trang 10/13 M thi