TRNG THPT CHUYN H LONG

THI TH
( thi gm 4 trang)

K THI TRUNG HC PH THNG QUC GIA NM 2016

Mn: HA HC
Thi gian lm bi: 90 pht, khng k thi gian pht
M thi 132

H, tn th sinh:..........................................................................
Lp :...........................................................................................
Cho KLNT: C = 12; N = 14; P = 31; O = 16; S = 32; H = 1; Li = 7; Na = 23; K = 39, Rb = 85,5; Be = 9; Mg
= 24; Ca = 40; Sr = 87,5; Ba = 137; Al = 27; Zn = 65; Cu = 64; Pb = 207; Ag = 108; Fe = 56; Cu = 64; Mn
= 55; Cl = 35,5; Br = 80.
Cu 1: Phn ng no di y thuc loi phn ng oxi ha - kh?
A. 2NaOH + SO2 Na2SO3 + H2O.
B. AgNO3 + HCl AgCl + HNO3.
C. 2NO2 + 2NaOH NaNO3 + NaNO2 + H2O. D. Ca(OH)2 + 2CO2 Ca(HCO3)2.
Cu 2: Phenol khng phn ng vi cht no sau y?
A. NaOH.
B. Br2.
C. NaHCO3.
D. Na.
Cu 3: Hirocacbon X iu kin thng l cht kh. Khi oxi ho hon ton X th thu c th tch kh CO2
v hi H2O l 2 : 1 cng iu kin. X phn ng vi dung dch AgNO3 trong NH3 to kt ta. S cu to ca
X tho mn tnh cht trn l
A. 2.
B. 3.`
C. 4.
D. 1.
Cu 4: C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni. S
trng hp xut hin n mn in ho l
A. 3.
B. 2.
C. 4.
D. 1.
Cu 5: Pht biu no sau y khng ng ?
A. Trong dy kim loi kim, i t Li n Cs nhit nng chy gim dn.
B. C th dng dung dch Na2CO3 lm mm tt c cc loi nccng.
C. Cc kim loi Na, K, Ca, Ba u c cu trc mng tinh th lp phng tm khi.
D. Mt trong nhng tc dng ca criolit trong qu trnh sn xut nhm l lm tng tnh dn in ca cht
in phn.
Cu 6: Khi chng ta n cc thc phm c cha cht bo, tinh bt hoc protein th phn ng ho hc xy ra u
tin ca cc loi thc phm trn trong c th l phn ng
A. thu phn.
B. oxi ho.
C. kh.
D. polime ho.
Cu 7: t chy hon ton hp cht hu c no sau y th sn phm thu c khc vi cc cht cn li?
A. Protein.
B. Cao su thin nhin. C. Cht bo.
D. Tinh bt.
Cu 8: Cho cc pht biu sau:
(a) nhit thng, Cu(OH)2 c th tan trong dung dchglucoz.
(b) Anilin l mt baz, dung dch ca n lm giy qu tm chuyn thnh mu xanh.
(c) nhit thng, axit acrylic phn ng c vi dung dch brom.
(d) iu kin thch hp, glyxin phn ng c vi ancol etylic.
(e) iu kin thng, etilen phn ng vi dung dch AgNO3/NH3 cho kt ta muvng.
S pht biu ng l
A. 3.
B. 4.
C. 5.
D. 2.
Cu 9: Nhng mt inh st sch vo dung dch Cu(NO3)2. Sau mt thi gian ly inh st ra, lm kh, thy
khi lng inh st tng 1 gam. Khi lng st phn ng l
A. 3,5 gam.
B. 7,0 gam.
C. 5,6 gam.
D. 2,8 gam.
Cu 10: Thnh phn ho hc chnh ca qung boxit l
A. FeCO3.
B. Al2O3.2H2O.
C. Fe3O4.nH2O.
D. AlF3.3NaF.
Cu 11: Ancol v amin no sau y cng bc?
A. (CH3)2CHOH v (CH3)2CHNH2.
B. (C2H5)2NH v C2H5CH(OH)CH3.
C. (C2H5)2NH v C2H5CH2OH.
D. (CH3)3COH v (CH3)3CNH2.
Cu 12: Kim loi st khng tan trong dung dch no sau y?
A. FeCl3.
B. H2SO4 long, ngui. C. AgNO3.
D. HNO3 c, ngui.
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Cu 13: iu kin thng, kim loi no sau y khng phn ng vi nc?

A. Li.
B. K.
C. Sr.
D. Be.
Cu 14: Cho 8,24 gam -amino axit X (phn t c mt nhm COOH v mt nhm NH2) phn ng vi dung
dch HCl d th thu c 11,16 gam mui. X l
A. H2NCH(C2H5)COOH.
B. H2NCH2CH(CH3)COOH.
C. H2N[CH2]2COOH.
D. H2NCH(CH3)COOH.
Cu 15: Ion X2+ c cu hnh electron trng thi c bn l 1s22s22p6. S ht mang in trong ion X2+ l
A. 16.
B. 18.
C. 20.
D. 22.
Cu 16: Cho anehit acrylic (CH2=CH-CHO) phn ng hon ton vi H2 (d, xc tc Ni, to) thuc
A. CH3CH2CH2OH.
B. CH3CH2CHO.
C. CH3CH2COOH.
D. CH2=CH-COOH.
Cu 17: t 3,36 gam kim loi M trong kh quyn clo th thu c 9,75 gam mui clorua. Kim loi M l
A. Cu.
B. Zn.
C. Fe.
D. Al.
Cu 18: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). Bn knh nguyn t ca cc
nguyn t tng dn theo th t
A. M < X < R < Y.
B. Y < X < M < R.
C. Y < M < X < R.
D. M < X < Y < R.
Cu 19: Khi thc hin cc th nghim cho cht kh (kim loi, phi kim,) phn ng vi axit nitric c thng
to ra kh NO2 c hi, gy nhim mi trng. hn ch lng kh NO2 thot ra mi trng, ngi ta nt
ng nghim bng bng tm dung dch no sau y ?
A. Mui n.
B. Xt.
C. Cn.
D. Gim n.
Cu 20: Ho tan m gam Fe trong dung dch HNO3 c, nng d th thu c 8,064 lt kh NO2 (sn phm kh
duy nht, ktc). Gi tr ca m l
A. 8,96.
B. 6,16.
C. 6,72.
D. 10,08.
Cu 21: Trong cng nghip, iu ch kim loi Ag, Cu gn nh tinh khit (99,99%) ngi ta s dng
phng php no sau y?
A. thu luyn.
B. nhit luyn.
C. in phn nng chy. D. in phn dung dch.
Cu 22: Thy phn hon ton 0,1 mol mt este no (trong phn t c s nguyn t cacbon bng s nguyn t
oxi) cn dng va 200 ml dung dch NaOH 1M. Cng thc phn t ca este l:
A. C2H4O2.
B. C3H4O3.
C. C4H6O4.
D. C6H8O6.
Cu 23: Thc hin cc th ngim sau iu kin thng:
(1) Cho kim loi liti vo bnh kh nit.
(2) Sc kh hirosunfua vo dung dch Zn(NO3)2.
(3) Sc kh clo vo dung dch FeBr3.
(4) Cho dung dch NaOH vo dung dch phenol (C6H5OH).
S th nghim xy ra phn ng l
A. 4.
B. 1.
C. 2.
D. 3.
Cu 24: un nng 7,2 gam CH3COOH vi 6,9 gam C2H5OH (xc tc H2SO4) th thu c 7,04 gam este. Hiu
sut ca phn ng este ho l:
A. 66,67%.
B. 50,0%.
C. 53,33%.
D. 60,0%.
Cu 25: Cho 0,78 gam kim loi M ho tr II phn ng ht vi dung dch H2SO4 long, d th thu c 268,8
cm3 kh khng mu (ktc). Kim loi M l
A. Ca.
B. Mg.
C. Pb.
D. Zn.
Cu 26: Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht c
sp xp theo chiu tnh axit tng dn l:
A. (Y), (Z), (T), (X).
B. (X), (Z), (T), (Y).
C. (Y), (T), (Z), (X).
D. (T), (Y), (Z), (X).
Cu 27: Dn lng kh CO d i qua ng s ng m gam oxit st t nung nng. Sau khi phn ng xy ra hon
ton th thu c 5,88 gam st. Gi tr ca m l
A. 12,18.
B. 8,40.
C. 7,31.
D. 8,12.
Cu 28: Cng thc phn t ca triolein l
A. C54H104O6.
B. C57H104O6.
C. C57H110O6.
D. C54H110O6.
Cu 29: Trong cht no sau y nit va c tnh oxi ho, va c tnh kh ?
A. NH4Cl.
B. HNO3.
C. NH3.
D. NO2.
Cu 30: Cht tham gia phn ng trng gng l
A. xenluloz.
B. saccaroz.
C. fructoz.
D. tinh bt.
Cu 31: Hn hp X gm propan, etylen glicol v mt s ancol no n chc mch h (trong propan v
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etylen glicol c s mol bng nhau). t chy hon ton 5,444 gam X ri hp th ton b sn phm chy vo
bnh ng dung dch Ba(OH)2 d thy khi lng bnh tng ln 16,58 gam v xut hin m gam kt ta trong
bnh. Gi tr ca m gn vi gi tr no sau y nht?
A. 45,70.
B. 42,15.
C. 43,90.
D. 47,47.
Cu 32: Cho 0,35 mol bt Cu v 0,06 mol Fe(NO3)3 vo dung dch cha 0,24 mol H2SO4 (long). Sau khi cc
phn ng xy ra hon ton, thu c lt kh NO (sn phm kh duy nht, ktc). C cn dung dch thu c
khi lng mui khan l:
A. 52,52 gam.
B. 36,48 gam.
C. 40,20 gam.
D. 43,56 gam.
Cu 33: Ln men m kg glucoz cha trong nc qu nho c 100 lt ru vang 100. Bit hiu sut phn ng
ln men t 95%, ancol etylic nguyn cht c khi lng ring l 0,8 g/ml. Gi thit rng trong nc qu nho
ch c ng glucoz. Gi tr ca m gn nht vi gi tr no sau y ?
A. 17,0.
B. 17,5.
C. 16,5.
D. 15,0.
Cu 34: Nung 13,44 lt (ktc) hn hp X gm axetilen, propilen v hiro (t l mol 2: 1: 3) trong bnh ng
bt Ni mt thi gian th thu c hn hp kh Y c t khi hi so vi X l

12
7

. Dn ton b Y qua bnh ng

dung dch AgNO3 trong NH3 th thu c 12 gam kt ta v hn hp kh Z. Hp th ht Z vo bnh ng dung

dch brom d th thy c m gam brom phn ng. Gi tr ca m l
A. 24,0.
B. 16,0.
C. 19,2.
D. 25,6.
Cu 35: Cho H3PO4 tc dng ht vi dung dch cha m gam NaOH, sau phn ng thu c dung dch X c
cha 2,51m gam cht tan. Cc cht tan trong dung dch X l
A. Na2HPO4, Na3PO4. B. NaH2PO4, Na2HPO4. C. Na3PO4, NaOH.
D. NaH2PO4, Na3PO4.
Cu 36: Cho cc phn ng sau:
t
(a) X + O2 x
Y

t
(b) Z + H2O x
G

t
(c) Z + Y x
T

(d) T + H2O Y + G.

Bit X, Y, Z, T, G u c phn ng vi dung dch AgNO3 trong NH3 to kt ta; G c 2 nguyn t cacbon.
Phn trm khi lng ca oxi trong T l
A. 53,33%.
B. 43,24%.
C. 37,21%.
D. 44,44%.
Cu 37: Cho 47 gam hn hp X gm 2 ancol i qua Al2O3, un nng thu c hn hp Y gm ba ete; 0,27
mol olefin; 0,33 mol hai ancol d v 0,42 mol H2O. Bit rng hiu sut tch nc to mi olefin i vi mi
ancol u nh nhau v s mol ete l bng nhau. Khi lng ca hai ancol d c trong hn hp Y (gam) gn
gi tr no nht ?
A. 14,5.
B. 17,5.
C. 18,5.
D. 15,5.
Cu 38: Cho cc cht: Na2O, CO2, NO2, Cl2, CuO, CrO3, CO, NaCl. S cht tc dng vi dung dch NaOH
long, d iu kin thng l
A. 4.
B. 3.
C. 5.
D. 6.
Cu 39: Cho cc pht biu sau:
(1) Phn ln cung cp cho cy trng nguyn t photpho di dng P2O5.
(2) dinh dng ca phn kali c nh gi theo phn trm khi lng ca K2O.
(3) Phn amophot c thnh phn ho hc chnh l (NH4)2HPO4 v KNO3.
(4) Nitrophotka l mt loi phn phc hp.
(5) Phn ure l loi phn m tt nht, c iu ch t amoniac v CO2 iu kin thch hp.
(6) Thnh phn ho hc chnh ca phn supephotphat kp l Ca(H2PO4)2 v CaSO4.
S pht biu ng l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 40: Ha tan hon ton 24 gam hn hp X gm MO, M(OH)2 v MCO3 (M l kim loi c ha tr khng i)
trong 100 gam dung dch H2SO4 39,2% thu c 1,12 lt kh (ktc) v dung dch Y ch cha mt cht tan duy
nht c nng 39,41%. Kim loi M l
A. Cu.
B. Zn.
C. Mg.
D. Ca.
Cu 41: Cho cc phn ng sau ( iu kin thch hp):
:4
1. FeS2 + HCl
2. SiO2 + Mg 1

3. Si + NaOH(c)

4. SiO2 + NaOH(c) t
t
t

5. CuO + NH3

6. Ca3(PO4)2 + C + SiO2

7. Ag2S + O2 t

8. H2O(h) + C t
Sau khi cc phn ng xy ra hon ton, s phn ng to thnh n cht l
A. 5.
B. 6.
C. 3.
D. 4.
o

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Cu 42: Cho t t dung dch cha a mol Ba(OH)2 vo dung dch cha b mol ZnSO4. th biu din s mol
kt ta theo gi tr ca a nh sau:

A. 0,10.
B. 0,12.
C. 0,08.
D. 0,11.
Cu 43: Ha tan hon ton 25,3 gam hn hp X gm Mg, Al, Zn bng dung dch HNO3. Sau khi phn ng kt
thc thu c dung dch Y v 4,48 lt (ktc) kh Z (gm hai hp cht kh khng mu) c khi lng 7,4 gam.
C cn dung dch Y thu c 122,3 gam hn hp mui. S mol HNO3 tham gia phn ng gn vi gi tr
no sau y nht?
A. 1,91 mol.
B. 1,85 mol.
C. 1,81 mol.
D. 1,95 mol.
Cu 44: Trong phng th nghim, kh C c iu ch bng b dng c nh hnh v:

Kh C c th l dy cc kh no sau y?
A. NO, CO2, C2H6, Cl2. B. N2O, CO, H2, H2S. C. NO2, Cl2, CO2, SO2. D. N2, CO2, SO2, NH3.
Cu 45: Tripeptit X v tetrapeptit Y u mch h. Khi thy phn hon ton hn hp gm X v Y ch to ra
mt amino axit duy nht c cng thc H2NCnH2nCOOH. t chy 0,05 mol Y trong oxi d, thu c N2 v
36,3 gam hn hp gm CO2, H2O. t chy 0,01 mol X trong oxi d, cho sn phm chy vo dung dch
Ba(OH)2 d, thu c m gam kt ta. Bit cc phn ng u xy ra hon ton. Gi tr ca m l
A. 29,55.
B. 23,64.
C. 17,73.
D. 11,82.
Cu 46: Hn hp X cha 3,6 gam Mg v 5,6 gam Fe cho vo 1 lt dung dch cha AgNO3 a M v Cu(NO3)2 a
M thu c dung dch A v m gam hn hp cht rn B. Cho A tc dng vi NaOH d thu c kt ta D.
Nung D ngoi khng kh n khi lng khng i thu c cht rn E c khi lng 18 gam. Bit cc phn
ng u xy ra hon ton. Gi tr m l
A. 31,2.
B. 38,8.
C. 22,6.
D. 34,4.
Cu 47: t chy hon ton m gam hn hp X gm CH3OH, CH3CHO v C2H5CHO cn dng va 0,6 mol
O2, sinh ra 0,45 mol CO2. Nu cho m gam X trn phn ng vi lng d dung dch AgNO3 trong NH3 th khi
kt thc cc phn ng, khi lng Ag thu c l
A. 43,2 gam.
B. 16,2 gam.
C. 27,0 gam.
D. 32,4 gam.
Cu 48: Cho cc dung dch: axit glutamic, valin, lysin, alanin, etylamin, anilin. S dung dch lm qu tm
chuyn sang mu hng, chuyn sang mu xanh, khng i mu ln lt l:
A. 2, 1, 3.
B. 1, 1, 4.
C. 3, 1, 2.
D. 1, 2, 3.
Cu 49: Hn hp X gm Mg, MgO, Ca v CaO. Ha tan 10,72 gam X vo dung dch HCl va thu c
3,248 lt kh (ktc) v dung dch Y. Trong Y c 12,35 gam MgCl2 v m gam CaCl2. Gi tr ml
A. 33,3.
B. 15,54.
C. 13,32.
D. 19,98.
Cu 50: Cao su bunaS v cao su buna N l sn phm ng trng hp ca buta-1,3-ien vi
A. stiren v amoniac.
B. stiren v acrilonitrin.
C. lu hunh v vinyl clorua.
D. lu hunh v vinyl xianua.
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TRNG THPT CHUYN H LONG

P N THI TH

K THI TRUNG HC PH THNG QUC GIA NM 2016

Mn: HA HC
Thi gian lm bi: 90 pht, khng k thi gian pht
M thi: 132

1C

2C

3A

4B

5C

6A

7A

8A

9B

10B

11B

12D

13D

14A

15D

16A

17C

18B

19B

20C

21C

22C

23D

24A

25D

26C

27D

28B

29D

20C

31A

32D

33C

34A

35B

36D

37B

38C

39A

40C

41B

42A

43A

44C

45C

46A

47D

48D

49B

50B

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