CHE60103 Stoichiometry & Processes Application Tv Tutorial 2 TAYLOR'S, uN IERSITY FACTORS FOR UNIT CONVERSIONS Quantity Equivalent Values Mass Length, ‘Volume Force Pressure Energy Power Lkg = 1000 g = 0.001 metric ton = 2.20462 lb = 35.27392 02 Liby = 1602 = 5% 10" ton = 453.593 g = 0.453593 kg 1m = 100em = 1000 mm = 10% microns (ym) = 10° angstroms (A) = 39.37 in. = 3.2808 ft = 1.0936 yd = 0,0006214 mile Vin, = 1/3 yd = 03048 m = 30.48em 000L = 108 cm? = 10° mL 35.3145 £9 = 219.97 imperial gallons = 264.17 gal = 1055.68 qt 118 = f78in3 = 283317 em* 1N = kgm? = 108 dynes = 10° g-cos? = 0.22481 Iby 1 Tby = 32.174 loys? = 4.4482.N = 4.4482 x 10° dynes, atm = 1,01325 x 10° Nim? (Pe) = 101.325 kPa = 1.01325 bar 1.01325 x 10° dynesiom* = 760 mm Hg at 0°C (tore) = 10.335 m HO at 4"C 14.696 tbylin? (psi) = 33.9 ft HzO at 4°C 29921 in. Hg at °C 1 = Nem = 10? ergs = 107 dyne-cm = 2.778 x 10-7 kWh = 0.23901 cal = 0.7376 f-by = 9.485 x 10-' Bru 1 W = 1Jis = 0.23901 calls = 0.7376 ft Ibis = 9.486 x 10°* Bowls = 1341 X10 bp lft 4805 gal = 0.028317 m? = 28.317 L 2.20462 ta Tange Te aor wenn gonaCHE60103 Stoichiometry & Processes Application T TREE Tutorial 2 41. Using dimensional equations, convert (@) 3 wk to mitseconds (0) 38. sto miiesth (6) 554 mi (day.kg) to cmtXming) (0 35°F t0°C (e) 109°CtoK (760 mileshh to mis {6} 921 kal? to Iba (8) 537x140" kulmin to hp. (0) The weight in Ibof a 25.0-4on object ) The mass in kg of an object that weights 25 newtons (() The weight in dynes of a 10-1on object (not metric tons) 2. Estimate the required cylinder volume for five hundred Ib of nitrogen 25°C at a pressure such that the gas density is 11.5kam. 3. Anoil pipelines across Alaska is 4.5 fin diameter ad 800 miles long. How many barrels of oll are required to fil the pipeline? 4, The specific gravity of gasoline is approximately 0.70. {2) Determine the mass (kg) of 50.0 liters of gasoline {b) The mass flow rate of gasoline exiting a refinery tanks is 1150 kg/min, Estimate the volumetric flow rate in itersis. (c) Gasoline and kerosene (specific gravity = 0.82) are blended to obtain a mixture with the specific gravity of 0.78, Caloulte the volumetic ratio (volume of gasoline/volume of kerosene) of the two compounds + in the mixture, assuming Vjtena = Vgasotine + Vierosene « (Assume thet the volume Kerosene is, tom) 5. Assume the price of gasoline in France is approximately 5 French francs per Iter and the exchange rate is 5.22 francs per US dollar. How much would you pay, in dollars, for 50.0kg of gasoline in France, assuming gasoline has a specific gravity of 0.70, What would the same quantity of gasoline cost in the United States ata rate of $1.20 per gallon? 6. AL25°C, an aqueous solution containing 35.0 wt% SO, has a specific gravily of 1.2588. A quantify ofthe 36% solution is needed that contains 195.5 kg of HS, (@) Calculate the required volume (L) ofthe solution using the given speaitic gravity (b) Estimate the percentage error that would have resuited if pure component specific gravitas of HS0, (8G = 1.8255) and water had been used forthe calculation instead of the given specif gravity of the mixtureCHE60103 Stoichiometry & Processes Application Tutorial 2 7. Liquid toluene is lowing through pipe at arate of 175 mith. (2) What isthe mass flow rate of this steam in kg/min (0) What isthe molar flow rate in mols? 8. Amixture of methanol and methyl acetate contains 16.0 w% methanol. (@) Using a single dimension equation, determine the g-moles of methanol in 200.0 kg ofthe mixture (b) The fiow rate of methyl acetate in the mixture isto be 100.0 Ib-mole, what must the mixture flow rata in oadh? 9. Armisture is 10.0 mole % ethyl alcohol, 75.0 mole% ethyl acetate (CaHs0z) and 18.0 mole% acetic acd. Calculate the mass fractions of each compound. What is the average molecular weight of the mixture? What \would be the mass (kg) of sample containing 25.0 kmol of ethyl acetate? 410, A suspension of calcium carbonate particles in water flows through pipe. Your assignment isto determina both the flow rate and the composition of this slurry. You proceed to collect the stream in a graduated cylinder for 1.00 min; you then weigh the cylinder, evaporate the colected water, and reweigh the oyinder. ‘The following results are obtained: Mass of empty cylinder: 65.0 gram Mass of oyinder + collected siury: 565 g Volume collected: 486 ml Mass of cylinder after evaporation: 215 9 Caloulate (@) The volumetric flow rate and mass flow rate ofthe suspension (©) The density of the suspension (@) The mass fraction of CaCOs inthe suspension ‘11. A gaseous mixture of CO, COz, CHe, and Nos analyzed with a gas chromatography. The output appears on asstip-chart recorder, as shown here. For each of the three species the area under the peak is approximately proportional tothe number of moles ‘ofthe indicates substances in the sample. from other information, itis known thatthe molar ratio of methane (CH) to nitrogen is 0.200. (2) What ae the mole fractions ofthe four species in the gas? (0). Whatis the average molecular weight of the gas?CHE60103 Stoichiometry & Processes Application Tutorial 2 UNIVERSITY T Tayo. 12, Biomass combustion — buming of forests, glasstands, agricultural wastes, and other biological matter ~ is recognized as a serious threat to the environment, The table below shows the distribution of carbon ‘containing compounds released to the almosphere worldwide from all combustion sources as well as the portion coming from biomass burning. ‘Compound Metric Tons C, ellsources | Metric Tons C, % from biomass CO 8700 a co. TiO, FE CH 380 10 ‘The numbers in the middle column reflect annual quantities of carbon released to the atmosphere in the indicated compound: for exemple, 8700 metric tons of carbon (8.7 x 10® kg C) was released in carbon ioxide.Determine the combined ennual release (in metric tons) of all three species resulting from biomass combustion and the average movecular weight ofthe combined gasesHe StrichionBtey st Processes Application EN FUNDAWENTAL oF MATERIAL BALANCES Txtondl_ 2 TUTORIAL 2 SOLUTION © (9) sues to miliStonds, 2 L.8ik nto! eee eae $4 miles 60 mates) O-00018T «a5 da milesfloge Neatnute. Tow. ‘f+ a 4 3¢4T2 Xo” hau) ming ca (3) 35°F > “c tz (35-2), i = 6b 7% %© bofe tok TH = ter 15 * 3e2s K CF Te0 miles A, > onfs 760 wiles | Ahwt | 60% at Ms 33475 m/s leur | 2600 les. SD aayky 5 Noy ns Fr 421 kg | 2.2046 Ib, dy 5-31 xP KS hp BET xp? KI | 000d min | 1k O25 b> Ibe 25 |b, Balleft 5 Ca ta? 58.01 Ib, A on 3 ft et x 1.341 41D kp = bole Ci 1 Ys 4 = 25 Ibe 2 lt F te. x“6 2NS Ih sen | 1 Heal = ASHI \ iW 5.6066 om [s™ eit 4 Pty > dyes (0 ton 4. S066 omlS* | HUa + 10 dy 05 = F110 ye Gtiean G © sel = I\a3 226+ 566 Ib,, ® afivker wh end, oe ie sft & long miles C 00 piles 5290 fF O78 barrel 2 1 46 Ho? bacrels © (465 ge 607 cra ky | BOL] 2-02) m3 OHI ky Aine y ow \ lihersc% 150K lain > ies {ooo file = 2] sl), (9 Sree 29.82 Tue = 1 4kae 56 susdine 207 SG=_p “g Sle Peg See = O78 3 ASSining Volume for Kecasene 15 | te Volume fic gasolie is Ng Con¥) ~ Malus’ wats Kerosen® S pS2q [led | 1 cov’ =>. i bay JaSaline i : Vg? —3 tas [yor = envy) ? Volune (*) 195.5 Ht | Uy Selstion | ne {saute | 0.35 by thsQy, | L256 Lond kg {n> = GEY bob * pw o.by js weer ” 085 fom 0 © satin Total Velune 7 b give : SG tsa, lass solution [ Hey pie Hest OMe Late 0.65 kes HO 035 kg HS, bon = bhoty LF Zeek ZT mre > Hor bY 3 icine panei ck 2 WF L Hae = SAL +Orweon Tole | ge Velen tn = mass Fram tables find SG and MW a = mass Flot S62 0.86 ae Ve Velunat Mus q2159/ i . : ml Vs volumebic Hoy rate (9%) W055 ffow rate ? 0.Sbb Hovoky | | h h G0 nin = (bh waler flow vale > 7 156-43 mol @® Oo - Ueto wittire 200k baw Bayh o Weet hed fed up ink gratl> V cteal mol Fog foo 0S 4 metianol = $36. 33 mol Uy Solution "4 iio CYB aaa attte # (00 themolefloe So tat etnae « TH OF lon] Mitte ~ Mallet,’ 100 [bergole- (496 1 Tbe sehtion, y Ib . -3 [ben fess mol | 085 My rttyl qtatsle m6 lhe109 pool an ete Foe L et lal Ceavend —9 75 mole, ethyl acetate, Dye] i G woe acetic «A Lat coott Crcalcolate He otis fraction of etch Competed Wass fraltion, = Mampatnk =X M pstal ‘ Ml = HotT$1 no MW catty = 94-1 gla! MW cares = 60.05 $l] Meatgd = [male Gite = WOT g iol ” = itt Oa, TS wole Sted | 4-7 eee betsy rol Matoot * 15. mol SHC | 66.05 2 990.15. onl s 1463 41 Total mass = 40-14 t blots + Wes 4 < serie ts 5 Peau HOTS gees DOS TIE Sa5A5 7466-40 Xeatedr = (6015 5 race ay Keatycoot = 390-154 L ID: w 5 One 0 Tot 9qe 2 Oey (O-824)# bapa com alte TUE IS : — Lifroy vy Bite wleculat atignt rn = Caer. be Calculated ans (v9 wel using mate Fiachon a = eat yoo mas postion 14:68" (vy mass) Cyl 2 > 25 Kool aston! cyte | be Karol wixtare 90.64 | tos | lnal = ashy wee ['5 [isin | Bel Cio, Wa5S or Subpe,Sion = Seq ~b54 = 520g Wass fr CaCOs = aisy- 65g EPs Valug® = 45S ml Time = [mimte, Oy Ve onl _ ese ee mm = 40g Lvaincte ~ Plat © pasty = wey - Wosh FSS me ——(2) W085 Fraction of (Oval x28) + (6.28 x4H) $6.54 ylh) + (o.4b3x28) © Fgh *@ (21210 x04) ¢ tks a - =f faley C Ea eg (140! xo2b Jee | este co Ht = GT xp® fay : 6.67 xt ky c< (3.8 xloF 60-1) by C teks chy ae ae = S01 pt ey c oT xi nt ja moles [28 aay Chef Farol Hh by ~ = 244i” kasd Coe 2 asd tle’ Knol Gol tt ty ¢ = BA y IF temolhole fraction, = 248 AAO 238.00" £317 ys = dls a RSH” Shae 36eb ge = 0.075 Ghee Btw BWAyoS + 238 yp! 42. woe (2b Gb KOS 5 oT ygh Twekicha — _ seileeeegs Sag Me Zym- FOU Ke Coots ype) + (56) it) data sll .