Course IO3-¢ CHEM Lecturer Dr. Block Day Thucsela Sana lO, Notes Taken By_Camillé Bichop Total # of Pages 5° Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW 0. Quantum Mechanics Intro Resumed harmonies & nodes are real for mater =the Sunchons are labeled # (ps) ~they only start 4o have physical merring ler caleulohons ex. [Y)* is the probability distnbahon for pasihen 1, Atomic Orbitels Every allowed standing wave is an orbits] Quantum i Name Symbol Aceptoble Values Sign Gicance Principle, QuNe n W213, orb tal size, E \debnes e7 Menet") Angalor Momectham i Ojhieeetl orbital shape defines, win, €~ "subshelly Magnebe 8M mM BI,..0- 42 orbital spabol onen tahon each combnahen of n, J, ancl my deGnes on orb. ta] polation’ 2 letec used. ex. “Yp subshel| All of the orbitals with ney & del 4 orbitals ove in the BA subshell? yd, so mtr Ald > F orbitals Page_| of _5Course CHEM |03-6 Lecturer Dow Block Day Tharse Date !O/IS/15 Notes Taken By C2mille~ Bishop Total#of Pages 3 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW Clicker QI. How many subshells are in the n=4 electron shell? Correct answer: B.A formulos; in? orbitals per shell #1 Wer “ subshell of J 2, Representahons of Orb. tals Probab: lity Dens. Distibuton "Sho 2 £ Pan an electron at a parhealar locaton -Shows odds o Radial Probability Funchoa- shows the odds of Fading the e7 ata parhealoe distence from the nucleus Contour/ Boundary Surfece Representation all areas of & certain “Shows 9 surface connecta probabl-ty density yo; Co f-1 |) C® &) 12 Bx Go \=0; s-orbital sphere or Concentric spheres nodes ~ 9 location where a standing wove’s amplituce iO. we ol nodes in 8 orbtals = h-l (all radial nodes) total % of redial nodes is n-S-| not responsible for these draw: “4 Page_2 of +Course CHEM 103-6 Lecturer Dc. Block Day — ——— Date JOMS//S” ei Notes Taken By_Camille Bishop Total # of Pages_2 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW el! p-orbiols ~peanut-shoped ; 3 perpendicular onentatons N= 2: d-orb tals shapes ot ~double olumbbells 2 a peanut + donut tre’ Simplest 9-2: f-orbitels / = mony lobed Clover / Clicker QL Which of the Sollowmg orb.tals r could have +e pode prose) 4 distr bution Shown here « \ [2-3 rn Z| NN r 3p: le gw of redial nodes) n-J-[ = 3-I-1= 1. =| a 3,Orbtel Enerqes & Cceupdton so far) H-orbi tals Clem only n matters for E) more thon Lem ‘-some available QNM.5, orbitals, shapes ~new E lerel arrongements -now f matters (spec beat, higher => hgher é) my stil doesn't change E =s0 all orbitals in 3 Subshel| have egal Page_3 of _5_Course CHEM 102-6 Lecturer Do Block Day Thursday ate IOISHIS Notes Taken By Camille Bishop Total # of Pages i Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW Ef n4, N07 E ofae3, bead diagonal Imes shar the progression of E lets ex. Sp Hd > 55 4p > BA Ps Electon Spin L Yth QM. Ms possible voles 12, Renew! Ist QA ~ Species the shell Ist2 2d Que suabshel | Ist, dod, L Bed QWs orbital All QNs- «© Clectron al, 2 Paul: Exclusion Prne-ple ~ Mo 1 @ in an atom can have the some 4 Ms 4, Electron Conbigueatens ~ the lowest E e> conGgurotion is te one for which orbitals are Giled by~eS from fhe lovest Forty os Caubbou pracele") Page 4 of 5Course CHEM 103- Lecturer De. Block, Day “Thucsda Date JO/IS//s Notes Taken ByComille Bishgs Total # of Pages _5 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW &. Boron, Fe! 2 ” is | ia ap B's Clectron confiquedbon in our notation ’ 1522s? 2p! orbital diagram” [= an orbital 4 = spa tae | = spa -Sen = label the subshells = always show ail orbitals ia ony subsbell that has at least | em B HALT kas 2p Page Sof 5