Course Chor }03 Lecturer _Dv. Blocic
Day Tuesday Date Lol zolis,
Notes Taken By Lyndsey Total # of Pages__4
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Exam a- {0lat dunng class
Election Configurations (cont.)
{. Electon Conhg-! Specifics and Inttvpretetiom
BL SE, We 15235298 357 39? how do we distribute
orital diagom: O TH TT a ue | tte vemainiag 2¢7?
Ie as
2p
options: Fi ~on - cur on- nc
Hund's Rule: fov deqenevate seat He lowest energy
2 configuretaon is the One Khert moaxdrimnius
e with parallel spin
Condensed Electron Conhguratrons
[ie] =
[Ne] = [s7as*ap® -oe- GRARIRM CH eT as*ap®
Cards [We] 35% 3p%
[krJ= [av] ¥s*3dP 4%
so Si [ue] 3s73p% -oe- (vel fav) mil)
3s 39
For tons ~winite out euctrnl conhigurntien omc acd
ov Subtract es as needed
By She = [er] 5824a?
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Core eS + Llachons tnat dont participate in bonding
= Novle gas core and any full d or + subshebts
Valence e: veerens that can pavticpate in bonding
— all non-cocé 2ecrens
- Fwsr eltcrrons To be ionized
ext Sis (eJ3s*4p?
Coee~ valence ee
a ae commen a4 cP 4nd
Ger Cav 45h adap notahon: [Av] 3A“ As 40
torte ~ yaltnae Cote” are
now next 10
each other
» Le Jdal?5s? 59%
So [eJHanss Se
ore” valena e
pb: LreJ4e"6a’ us? et
Va
core e7 valenwe
Transition metals: any of ne lO elements pew penod
that have Some d- electrons, out NO
Subsequent p~ €ecrrons
Lanmandes i the 1d elements stavring with lanthanum
Acrinides + the 14 2lements staring with achiaamLecturer
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Total # of Pages
a. Electron Configurations and the Penodic Table
~ elements are grouped accordwrg to raiv
highest -energy occupied Subshell
S~ block 3 w ”
Also Called “main group clments
p- bloc Iso Called in group
d-bloue- transihen metals
£- block - lantnaniaes [actinides
2 Can use poviodic tatola 1 assign em fo ovbrtals|subshells
- Ippendix D Shows all ground State 2elechon conbguratrers
~ Special cases i Lnow!
crs [acd 3a°'s Aung oF al Filing
Mo: [ev] Sd* 5s" Aesubshell (5
uevgerically favorable
Cu, Ag, Aus Caovregas ns (nnd
* ONY ions with mG many elechons witl follow
Wese Configurations [iso electone ions")
-otnev special Cases:
pq. Led uae
et: Le] 4e Sa bs’
previously>
rmefals on tre leet |
Grows /columins on peviodic TABIE Nave Simla”
OLN CAR PIO EVTVES
non-metals on te ngit
on
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ewhy is Cs >RO>AK FNarle reactuity 7
“LLNS (0 A grup have Matering valence e's
Vawr of A changes, ut F and type of em dees
3. Effective Nucteav Charge
recall: £, = KOQz « low Eg 6 more Stabs le
° + O° (adie ite Clhargesyrepel
ean one
Z ls Hucartomic and * petween nuckus and an es
he macttay Groage Eel T with charge on nucteus
LN
Zou is tne ottechve nuclear becomes mere negatwe
Onarga Felt by ane after — DLE ly wen higher 4 [higher n)
Considenng he wpulsion oF
the other en
MSCrERMING Constant “
uv appwamehon: Ze > E-S”
and S=#e7s in Shells of lower 9
oi) what 15 Zey Por & Ss-e7 im Po? [aal
Po Is2as*ape 3s spuds? dpe dd SUE BS*5pE BA Us? pt
Wer a5
Ze = FA~0O = 22 — why it's AirHeut Fy Come
4 parherpate 1a bending
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Xl winat 1s Ze for a valence e& in Ph7%
8a total e | 4 valence em (n=b)
S=78, 30 Beg 74
Comprcahons: - radial distnbutien Faunce ns
= Some corals Wavesome eT dansity
Way The nucleus ; Lee Other eT
Clouds Stren Less eftectwely
4, Trends and Nuanws Of Cet
Legg pemodictrends (Fou highest -19 €~ 5)
—Zere tends 0 T aciwss a peviod
(ut Mis change Nappens slowly im transcher metals)
Tere Moreases Siigity as you move down a qrouP
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