Course CHEM 103-G Lecturer Dr. Block Day Thursdo. Date /Q/22/15- Notes Taken By Cam tle Bish Total # of Pages 4 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW 1. Momic BLon.e Sizes def nitions Non-bonding atomic rad. “sphalf the minimum distence between colliding atoms = Real ly makes sense for noble gases Really only m Cnt, mosptern c+) bonding Plomic radius? half the olistence hetveen the nuclei of bonding atoms =much more usable ey Yj, dat +r what we can measure CAs wht we can infer Ex! S-F bond length in SE,? | | Fy ep! 142k > 20.714 Chasep! 198 herr, 2094k scl; 01k Perr, =2.0138 Lonztonk SF sept dG rie. 1738 Periodic. trends: A. Yin 8 Qroup, hgher n=? higher r B. wha 2 period, higher Zegvalence =? Smaller Page I of YqCourse CHEM 103-6 Lecturer De. Block Day thursdau Date J0/22/15~ —hucsday HOM 2sIe Notes Taken By Camille. Bishoy Total # of Pages 4 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW C.transition metals are complicated D, (A) outpaces (B) for most main Group elements Ext ty O48 — Zotvatene &7 ie 0.73K Leg valence *G Tone radii ~ cations of an element are smaller than the neural atom the,c neutral ates anions are larger thon . =>smaller r ~for isoelectronic Species; larger Z p22 2 lpe> Ops 2 Meare > Go? ——— Clicker Ql, Which dtow or ion hos the lacgest rods? Ake BBe C,Br Se 1, Toni zation Energy (TE) | ~the E required te remove 0 6 Gy an atom or | ion thats in the gas phase } Ist TE: the E required te remove Ist 27 fom an atom Ex. Clay Clan + €7 SE #1251 kmol = Ist TE Qnd TES E required to remove. Ind e- “big T in JE when removing 3 Core Ponodic. trends for TE _ A,wha a gap, high n— low IE Bowlin d period: more Zeg—more LE Page a of. 4Course CHEM |03-6 Lecturer Do. Blecle Day Thursdou Date 10/22/15" ty Notes Taken ByComlle Bishop Total # of Pages 4 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW C, transition metals change slow! D. excephers te (B)! when ion bhon leaves behind a; half-full subshell o Lull subshell stable. Goes oes ex. Ist TEg, = 894 blmol — leaves Is22s' beh. ad ist TEg = 801 b/mwl — leaves |5? 255" bebuercl other examples. Group VA ad 2A medals -glkal: metals lose F.cst e7 very eas: ly ~low TE expla.ns high ceachuchy -alkal.ne earth metals have reactivities Similar to alkali metals, but are more subdui Noble gases- huge Ist TE (remanng 2 core e- always regures lots of E) 2” confiqurahors & ion. zahon -remove Grom the highest Shell Ist, then hughest enecgy subshel| as a Qnal prior bx, Fes [Ar]3dds? Ph: [xe Tes 74 MSuleypa a mosk (Fo2t TA] 34° py Dieses? lores Fe": [Ae] 3d Phi! xe] 4b 5, Ww Choker @2, What is the em configuraten of alt? [Ac ]3d3 Cot TArN4s' 3d > (remember the except on) ec 38) LAr] 343 Page 3 of 4Course CHEM 103-G Lecturer Do Block Day Tharsdoy Date fda dS Notes Taken By Camille. Bish. Total # of Pages 4 Submit a Single-sided Copy to the Undergraduate Office NO NOT STAPLE - ONLY WRITE NOTES INSIDE THE SQUARE BELOW 3. @ AKia. ties =n asseciated w/ adding an @- 40 someth.n . Ex, Ola) + e7 — 0G) ab= HHL bedhnas =e Baty of O 2 akaty is <0 for mast neutral elements e paty >O for elements w/ fall shells (noble. ases) ee yew wf Fall sabshells (Be, Mg, at dnd one w/d half-full subshell (W) Periodic trends for e7 athaity: usually no large change as You yo down 2 group ~halogéns have large Jem ofan. ~henly dependent on potern’ of Fling shells or subshells Clicker Q3. Who wants an 27 most (6, bas fe lowest eon ty) A.Meon 8B. Chlonde C. Chlerae EB. Alvcwvisaceting Clicker QU, Whreh trend ener ally otturs wf sing valence. electon efecte wuclear charge® f A. Dnereasing Lirst ion, zdhon CEA snudent pten | Renew Q's on poweports me f . wait Ute Bee His diagrom helps ifastale Ql