ALUMUNIUM

Data Kuantitatif
Bauksit (50%)
NaOH

1300 kg
40 kg

massa bauksit

1300 kg x 0,5
650 kg
Massa
BM

mol bauksit

mol NaOH

Massa
BM

650 kg
102 kg/kmol

40 kg
40 kg/kmol

TEMBAGA
Data Kuantitatif
CaO
H2O

760 kg
400 kg

mol CaO

Massa
BM

760 kg
56 kg/kmol

mol H2O

Massa
BM

400 kg
18 kg/kmol

CaO
m

13.57

13.57

6,373 kmol
m

1 kmol

Komponen
NaOH
Al2O3
Al(OH)3
Al2O3 (pure)
H2O
Na3AlO3
Total

13,57 kmol

22,22 kmol

mol
1
6.373
0.3333
-

3NaOH
1

Al2O3
6.373

0.0000

6.3730

Input
BM
40
102
78
102
18
143.948

massa
40
650.046
25.9974
716.0434

mol
6.0397
0.3333
1
0.3333

Output
BM
40
102
78
102
18
143.948

massa
616.0494
33.9966
18
47.97787
716.0239

H2O

Ca(OH)2
-

22.22

Komponen
CaO
H2O
Ca(OH)2
Total

13.57

13.57

8.65

13.57

mol
13.57
22.22
-

Input
BM
56
18
74

Massa
759.92
399.96
1159.88

mol
8.65
13.57

Output
BM
56
18
74

massa
155.7
1004.18
1159.88

3H2O
-

Al(OH)3
0.0000

Al2O3 (pure)
-

Na3AlO3
-

0.0000

0.0000

1.0000

0.0000

0.3333

0.3333

Industri Alumunium
Komponen

massa (kg)

Bauksit (80% Al2O3)

NaOH (76%)
Al2O3 dalam bauksit
H2O dalam NaOH
NaOH
H2O
Al2O3 produk
m
b
s

m
BM
massa

m
b
s
BM
massa

Neraca Massa pada Kalsiner

BM
1300
40
1040
30.4
9.6
1800
1000

102
18
40
18
102

6NaOH
59.0635
58.8235
0.24

Na3AlO3
19.6078
19.6078
-

2Al(OH)3
19.6078
19.6078
78
-

Neraca massa pada elektrolisa

Data Kuantitatif
Al2O3 (99% Al2O3)
Coke
mol Al2O3

mol Coke

Industri Tembaga
Data Kuantitatif
CaO
H2O

mol CaO

mol H2O

mol

10.1961
1.6889
0.24
100
9.8039
Al2O3
10.1961
9.804
0.39

3H2O
100
58.8235294
41.1764706
Al2O3(pure)
9.8039
9.8039
102
1000

2Na3AlO3
19.608
19.608

3H2O
29.4118
29.4118

3NaOH
58.8235
58.8235

Al(OH)3
19.6078
19.6078

3H2O
29.4118
29.4118
18
529.4118

=
=

2250 kg
600 kg

Massa
BM

Massa
BM

2250 kg
102 kg/kmol

22,059 kmol

600 kg
12 kg/kmol

50 kmol

760 kg
400 kg

Massa
BM

Massa

760 kg
56 kg/kmol

400 kg

13,57 kmol

22,22 kmol

BM

18 kg/kmol

22,22 kmol

Al2O3
Na3AlO3
H2O
Total

Komponen
Na3AlO3
H2O
NaOH
Al(OH)3
Total

Komponen
Al(OH)3
Al2O3(pure)
H2O
Total

7.647
-

102
144
18

mol
0.333
100
-

Input
BM
144
18
40
78

mol
0.333
-

Input
BM
78
102
18

779.994
779.994

massa
47.952
1800
1847.952

massa
25.974
25.974

m
b
s
BM
massa

2Al2O3
22.059
22.059
102
-

Komponen
Al2O3
C
Al
CO2
Total

m
b
s
BM
massa

C
16.9115
16.9115
12
-

Komponen
C
CO2
CO
Total

CaO

3C
50
33.0885
16.9115
12
202.938

mol
22.059
50
-

4Al
44.118
44.118
26.98
1190.304

Input
BM
102
12
26.98
44

CO2
33.0885
16.9115
16.177
44
711.788

mol
16.9115
33.0885
-

massa
2250
600
2850

2CO
33.823
33.823
28
947.044
Input
BM
12
44
28

H2O

massa
202.938
1455.894
1658.832

Ca(OH)2
-

13.57

22.22

13.57

13.57

13.57

8.65

13.57

Komponen

Input

Komponen
CaO
H2O
Ca(OH)2
Total

mol
13.57
22.22
-

BM
56
18
74

Massa
759.92
399.96
1159.88

7.48
0.333
0.5

102
144
18

mol
99.001
0.999
0.333

Output
BM
144
18
40
78

mol
0.1665
0.4995

Output
BM
78
102
18

762.96
47.952
9
819.912

massa
1782.018
39.96
25.974
1847.952

massa
16.983
8.991
25.974

3CO2
33.0885
33.0885
44
1455.894

mol
16.9115
44.118
33.0885

Output
BM
102
12
26.98
44

mol
16.177
33.823

Output
BM
12
44
28

Output

massa
202.938
1190.304
1455.894
2849.136

massa
711.788
947.044
1658.832

mol
8.65
13.57

BM
56
18
74

massa
155.7
1004.18
1159.88

Alumunium
Data Kuantitatif
Komponen
Bauksit (80% Al2O3)
NaOH (76%)
Al2O3 dalam bauksit
H2O dalam NaOH
NaOH
H2O
Al2O3 produk

massa (kg)

BM

1300
40
1040
30.4
9.6
1800
1000

102
18
40
18
102

mol

10.1961
1.6889
0.24
100
9.8039

Neraca Massa Reaksi 3

m
b
s
BM
massa

2Al(OH)3
19.6078
19.6078
78
-

Al2O3(pure)
9.8039
9.8039
102
1000

3H2O
29.4118
29.4118
18
529.41176

Neraca Massa Reaksi 2

m
b
s
BM
massa

Na3AlO3
19.6078
19.6078
144
-

3H2O
100
58.82353
41.17647
18
741.1765

3NaOH
58.8235
58.8235
40.0000
2352.9412

6NaOH
59.0635
58.8235
0.24
40
9.6

Al2O3
10.1961
9.804
0.39
102
40

2Na3AlO3
19.6078
19.6078
144
2823.5294

massa (kg)

BM

mol

Neraca Massa Reaksi 1

m
b
s
BM
massa

Reaksi Elektrolisis
Data Kuantitatif
Komponen
Al2O3 (99%)
Coke

2250
600

102
12

22.059
50

m
b
s
BM
massa

2Al2O3
22.059
22.059
102
-

3C
50
33.0882
16.9118
12
202.9412

4Al
44.118
44.118
26.98
1190.2941

m
b
s
BM
massa

C
16.9118
16.9118
12
-

CO2
33.0882
16.9118
16.1765
44
711.7647

2CO
33.824
33.824
28
947.05882

Tabel Neraca Massa

Komponen
Bauksit
Al2O3 dalam Bauksit
NaOH
H2O
Na3AlO3
Al(OH)3
Al2O3
C
CO2
CO
Al
Total

Al(OH)3
19.6078
19.6078
78.0000
1529.4118

3H2O
29.4118
29.4118
18
529.41176

Komponen

Input
mol
massa
1300
10.1961
1040
59.0635 2362.541
100
1800
22.059
2250
50
600
9352.5412

Input
mol
massa

3CO2
33.088
33.088
44
1455.8824

Total

2850
12202.541

Output
mol
massa
260
0.39
40
0.24
9.6
41.1765
741.176
19.6078 2823.529
19.6078 1529.4118
9.8039
1000
16.1765
711.765
33.824
947.059
44.118
1190.294
9252.835

Output
mol
massa

2849.1176
12101.953