CET-304 Tubular Reactor - Run 1 Results

Sample
Number

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31

Sample
Time

15:16:24
15:17:39
15:18:08
15:18:39
15:19:08
15:19:39
15:20:09
15:20:38
15:21:09
15:21:38
15:22:09
15:22:39
15:23:08
15:23:39
15:24:08
15:24:39
15:25:09
15:25:39
15:26:09
15:26:38
15:27:09
15:27:38
15:28:09
15:28:39
15:29:08
15:29:39
15:30:08
15:30:39
15:31:09
15:31:38
15:32:09

Elapsed
Time

0:00:01
0:01:16
0:01:45
0:02:16
0:02:45
0:03:15
0:03:46
0:04:15
0:04:46
0:05:15
0:05:45
0:06:16
0:06:45
0:07:16
0:07:45
0:08:15
0:08:46
0:09:15
0:09:46
0:10:15
0:10:46
0:11:15
0:11:45
0:12:16
0:12:45
0:13:16
0:13:45
0:14:15
0:14:46
0:15:15
0:15:46

Hydroxide
concentration
in tank
[mol/dm]

Acetate
concentration
in tank
[mol/dm]

Hydroxide
Flowrate
Fa
[cm/min]

Acetate
Flowrate
Fb
[cm/min]

Residence
Time
Tr
[s]

Measured
Conductivity

0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050

0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050
0.050

40.1
40.1
40.1
40.4
40.4
40.3
40.3
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.3
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.4
40.3
40.4
40.4
40.4

39.9
40.0
40.0
40.3
40.2
40.2
40.2
40.3
40.3
40.6
40.2
40.3
40.3
40.2
40.3
40.3
40.3
40.3
40.2
40.3
40.3
40.3
40.3
40.2
40.2
40.3
40.2
40.2
40.3
40.2
40.2

299.9
299.4
299.6
297.5
297.8
297.9
297.9
297.6
297.3
296.4
297.5
297.5
297.6
297.8
297.6
297.5
297.3
297.3
297.6
297.3
297.5
297.5
297.5
297.8
297.6
297.3
297.8
298.1
297.6
297.6
297.6

7.021
7.031
7.031
7.002
6.963
5.859
4.951
4.551
4.404
4.385
4.385
4.385
4.395
4.404
4.404
4.404
4.404
4.395
4.395
4.385
4.385
4.365
4.365
4.375
4.375
4.365
4.355
4.365
4.355
4.355
4.355

Page 1

[mS]

CET-304 Tubular Reactor - Run 1 Results

32
33
34
35

15:32:38
15:33:09
15:33:38
15:34:09

0:16:15
0:16:46
0:17:15
0:17:45

0.050
0.050
0.050
0.050

0.050
0.050
0.050
0.050

40.4
40.4
40.4
40.4

Page 2

40.3
40.2
40.3
40.3

297.5
297.6
297.6
297.3

4.355
4.346
4.346
4.355

CET-304 Tubular Reactor - Run 1 Results

Temp of
Reactor

Notes

[C]

Sodium
Hydroxide
Feed Conc
[mol/dm]

Ethyl
Acetate
Feed Conc
[mol/dm]

Calculated
Initial
Conductivity
[mS]

Calculated
Final NaOH
Concentration
[mol/dm]

Calculated
Final Acetate
Concentration
[dm/m]

25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0
25.0

0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025

0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025

5.247
5.239
5.236
5.242
5.242
5.239
5.239
5.239
5.239
5.223
5.247
5.242
5.239
5.242
5.234
5.242
5.244
5.239
5.244
5.244
5.242
5.242
5.242
5.242
5.244
5.239
5.242
5.242
5.239
5.244
5.249

0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000

0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025
0.025

Page 3

CET-304 Tubular Reactor - Run 1 Results

25.0
25.0
25.0
25.0

0.025
0.025
0.025
0.025

0.025
0.025
0.025
0.025

Page 4

5.242
5.244
5.239
5.239

0.000
0.000
0.000
0.000

0.025
0.025
0.025
0.025

CET-304 Tubular Reactor - Run 1 Results

Calculated
Final
Conductivity
[mS]

Current
Sodium Hydroxide
Concentration
[mol/dm]

Current
Sodium Acetate
Concentration
[mol/dm]

Conversion
of Sodium
Hydroxide
(%)

Production
of Sodium
Acetate
(%)

Conversion
Factor

1.945
1.932
1.928
1.936
1.936
1.932
1.932
1.932
1.932
1.920
1.945
1.936
1.932
1.936
1.924
1.936
1.941
1.932
1.941
1.941
1.936
1.936
1.936
1.936
1.941
1.932
1.936
1.936
1.932
1.941
1.949

0.038
0.039
0.039
0.038
0.038
0.030
0.023
0.020
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.019
0.018
0.018
0.018
0.018
0.018
0.018
0.018
0.018
0.018
0.018

-0.013
-0.014
-0.014
-0.013
-0.013
-0.005
0.002
0.005
0.006
0.006
0.007
0.006
0.006
0.006
0.006
0.006
0.006
0.006
0.006
0.006
0.006
0.007
0.007
0.007
0.007
0.007
0.007
0.007
0.007
0.007
0.007

-53%
-54%
-54%
-53%
-52%
-19%
9%
21%
25%
25%
26%
26%
25%
25%
25%
25%
25%
25%
26%
26%
26%
26%
26%
26%
26%
26%
27%
26%
27%
27%
27%

-54%
-54%
-54%
-53%
-52%
-19%
9%
21%
25%
25%
26%
26%
26%
25%
25%
25%
25%
26%
26%
26%
26%
27%
27%
26%
26%
26%
27%
27%
27%
27%
27%

-0.35
-0.35
-0.35
-0.35
-0.34
-0.16
0.10
0.26
0.34
0.34
0.35
0.35
0.34
0.34
0.33
0.34
0.34
0.34
0.34
0.35
0.35
0.36
0.36
0.35
0.36
0.36
0.36
0.36
0.36
0.37
0.37

Page 5

X/(1-X)

Estimated
Specific Rate
Constant
K

Calculated
Specific Rate
Constant
K

1.95

-0.03
-0.03
-0.03
-0.03
-0.03
-0.02
0.01
0.04
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.06
0.07
0.07
0.06
0.06
0.07
0.07
0.07
0.07
0.07
0.07

CET-304 Tubular Reactor - Run 1 Results

1.936
1.941
1.932
1.932

0.018
0.018
0.018
0.018

0.007
0.007
0.007
0.007

27%
27%
27%
27%

Page 6

27%
27%
27%
27%

0.36
0.37
0.37
0.36

0.07
0.07
0.07
0.07

CET-304 Tubular Reactor - Run 1 Results

Log(K)

1/T

0.00
0.00
0.00
0.00
0.00
0.00
-1.85
-1.35
-1.22
-1.21
-1.20
-1.20
-1.21
-1.22
-1.22
-1.22
-1.21
-1.21
-1.21
-1.20
-1.20
-1.18
-1.18
-1.19
-1.19
-1.18
-1.18
-1.18
-1.18
-1.17
-1.17

0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04
0.04

Page 7

CET-304 Tubular Reactor - Run 1 Results

-1.17
-1.17
-1.17
-1.18

0.04
0.04
0.04
0.04

Page 8