pail 1 2 AA projectile ean have the same range R for two angles of projection. Ift, and, be the times of flights in the two cases, then the product ofthe two times of flights is proportional 10 : 1 a) R? b @ Og 1 OR @R ‘An annular ring with inner and outer radit Ry and Ry is rolling without slipping with a ‘uniform angular speed. The ratio of the forces experienced by the two particles situated on the inner and outer parts ofthe ring, fis Re Ry oR. mi) 1 oR ‘A smooth block is released at rest on 8 45° incline and then slides a distance d. The time taken to slide is n times as much to slide on rough incline than on a smooth incline, The coefficient of friction is = One OH on @ny= ft ‘The upper half of an inclined plane with inclination @ is perfectly smooth, while the lower half is rough. A body starting from rest at the top will again come to rest atthe bottom if the coefficient of fricuion for tne lower hal is, siven by (@ 2sing (b) 2e08 » (©) 2tang @ tng Abllet fired into a fixed tanger loses half ofits velocity after penetrating Sem, How much further it will penetrate before coming to rest, assuming that it faces constant resistance 10 motion? % 10. @) 300m 46).20.em (© 15am (@ 10em Outof the following pais, which one does not have identical dimensions ? (2) Angular momentim and Planck's constanc () Impulse and momentum (6) Moment of inertia and moment of a force (@) Work and torque The relation between time t and distance x is ‘ax? bx, where aand b are constants, The acceleration is @ ~2aby? © -207 &) 267 @ 2a? ‘Acar starting from rest, accelerates atthe rate f through a distance S, then continues at ‘constant speed for time ¢ and then decclerates at the rate f/2 to come to rest. Ifthe total distance travelied is 15 S, then 1 (@ s=fe wm s=t fe Lp @ s-4fe 1 © Sa5ht AA particle is moving eastwards with a velocity ‘of Sms". n 105 the velocity changes to 5 ms northwards. The average acceleration in this time is: Gg 8 towards north-east (©) fms? towards north (© 20 Te inet nin ‘A parachutist’ after bailing out falis 50 m ‘without friction. When parachute opens, it decelerates at 2m/s". He reaches the ground with a speed of 3 mV/s. At what helghe, did he bail out ? @ 91m (© 293m (b) 182m @ tima. 4. 15. 16, A block s kept on frictionless inclined suriace with angle of inclination a. The incline is given an acceleration a to kecp the block stationary. Then ais equal to : @ g/tane (b) g coseca Or @ gana A spherical ball of mass 20 kg is stationary at the top of a hill of height 100 m. [trolls down a ‘smooth surface to the ground, then climbs up another hill of height 30 m and finally rolls down to a horizontal base at a height of 20 m above the ground, The velocity attained by the balls: (@) 40 mvs () 20 mvs (© 10mys (@ 10v30 mys A body A of mass M while falling vertically downwards under gravity breaks into two pars a body 8 of mass 4M and, a body ¢ of mass 2. The entre of mass ofbodes B and taken together shifts compared to that of body Atowards: (a) depends on height of breaking (©) does nt sit (©) bodyC @ body 8 “The moment of inertia of uniform semicirclar dise of mass Mand radius r about a. line perpendicular to the plane of the disc through. the cente is: @ Ame a ome ‘A panticle of mass 0.3 kg is subjected to a foree F a= ke with k=15N/m. What will be its {initial acceleration, ifit is released from a point 20 em away from the origin ? @ 3nvs? @) 15m © sms @ 10m/st ‘The block of mass Mf moving on the frictionless horizontal surface collides with the spring of 2 Zur @ Me a7. 19. 20. a. spring constant kand compresses itby length L. ‘The maximum momentum of the block after collision ror Dre a (@ Vek L © oy (© zero @m@ ‘A mass m moves with a velocity v and collides ‘inelastically with another identical mass. After collision the I* mass moves with velocity * in "8 a direction perpendicular to the initial direction of motion. Find the speed of the ‘second mass after collision oy &) Br OR Oy ‘A 20 cm long capillary tube is dipped in water. ‘The water tises upto 8 cm. If the entire arrangement is put in a freely falling elevator, the length of water column in the capillary tube willbe : (@) 8cm (b) 10cm © 4em @ 20cm WS is stress and ¥ is Young's modulus of ‘material of a wire, the energy stored in the wire per unie volume is: 28"5 # @ 28° oF x s o% oF ‘Average density ofthe earth (@) does not depend on g (b) is a complex function of g (© is directly proportional to g @) is inversely proportional to g A body of mass mis accelerated uniformly from resto a speed vina time. The instantaneous power delivered to the body as a function of time, is given by = ome22, Consider a car moving on a stsight road with a speed of 100 mys. The distance at which car can be stopped, is : [,, = 0.5] (a) 800m (b) 1000 m (© 100m (@ 400m 23. Which of the following is incorrect regarding the frst law of thermodynamics ? @) Ikis not applicable to any cyclic process (b) Ie ig a restatement of the principle of conservation of energy (©) It introduces the concept of the internal ‘energy @ introduces the concept of the entropy 24. AT shaped object with dimensions shown ig the figure, is lying ona smooth floor. A force F 4s applied at the point P parallel to AB, such that the object has only the translational ‘motion without rotation. Find the location of P ‘with respect 10 + ———— a —a ? ¢ @z we oF @t 25. The change in the value ofg at height habove the surface of the earth isthe same as ata depth {below the surface of earth, Whenboth dand h {ce muck smaller chan the radies of earth then Which one ofthe following is coorect? wank (a= (© d=2h @ dh 26. Apanicle of mass 10 gis kept on the surface of 4 uniform sphere of mass 100 kg and ra 110 em, Find the work to be done against the gravitational foree between them, to take the particle far away from the sphere : (you may takeG = 6.67 x10" Nav’/kg?) {@) 1334x107 I () 3.33107 J (©) 667x10% I (@) 6.67~10" 5 27. Agaseous mixture consists of 16 g of helium and ¢, 16 g of oxygen. The ratio 7F of the mixture is y (@) 1.59 @) 1.62 @ 14 (@) 154 28. The intensity of gamma radiation froma given source is. On passing through 36 mm of lead, it is redueed to 1/8 The thickness of lend, ‘which will reduce the intensity to /2will be: @ 6mm &) 9mm © 18mm (@) 2mm 9. The electrical conductivity of a semiconductor inereases when electromagnetic radiation of ‘wavelength shorter than 2480 nm, is incident on it. The band gap in (eV) for the semiconductor is : @ lav () 25 ev (©) 05 ev @ O7 ev ‘A Photocell is iuminated by a small bright source placed 11m away. When the same source of ight spaced Hm aay, he munber of electrons emitted by photocathode would = (a) decrease by a factor of 4 (b) increase by a factor of 4 (©) decrease by a factor of 2 @ Increase by a factor of 2 1. Starting with a sample of pure “Cu, 7/8 of it decays into Zn in 15 min. The corresponding hatte fs: @) 10min ©) 15min {© S min @ 7} min 82, tFradius ofthe #2 Al nucleus i estimated 10 be 53.6 fermi, then the radius of Te nucleus be nearly : (@ 6 emi (8) 8 fermi © 4 fermi (@) S fermi 33. The remperacure-entropy diagram of a reversible engine clei gtven nthe igure efficiency is : @ v2 ow 4 @ 2834, The figure shows a system of two concentric spheres of radii y and y, and kepe at ‘temperaturesT, and, respectively. The radial rate of flow of heat ina substance between the two concentric spheres, is proportional to : &-) a @ G4 m(2) © ap @G-) 85. A system goes from A to B via two processes 1 and Il as shown in figure, {F AU, and AU; are the changes in internal energies in’ the processes I and If respectively, then : () relation between AU and AU, cannot be determined (© AU, > au, (@ aU, < 40, 36. The function sin? (ae) represents = (@) a periodic, but_not simple harmonic, ‘motion with a period 2x/ (®) a periodic, but not simple harmonic, motion with a period x/ (© a simple harmonic motion with a period 2x/o (@ a simple harmonic motion with a period xo 37. A Youngs double sit experiment uses a monochromatie souree. The shape of the interference fringes formed on a screen is : (@ hyperbola (b) circle (© straight line (4) parabola 28, Tosinge me tng trBecguiry 04s (00% = 2d Yc he pte feo velocity of particle 1, with respect to the velocity of pantcle 2 is: oy (O) oF @ 89. A fish looking up through the water sees the outside world, contained in a circular horizon. he refractive index of water is $ and the ish is 12 cm below the water surface, the radius of this circle in em is : 5 36 @) 3607 © @ OF © 365 @ ws 40. Two point white dots are 1 mm apart on a black paper. They are viewed by eye of pupil diameter 3 mm, Approximately, what is the maxirmum distance at which these dots can be resolved by the eye ? (Take wavelength of light = 500 nm) @ 5m ) 1m © 6m @ 3m 41. A thin glass (refractive index 1.5) lens has optical power of- 5 D inair. ts optical power in a liquid ‘medium with refactive index 1.6 will be @ 1D ) -1D © 25D (@ -25D 42. The diagram shows the energy levels for an electron in a certain atom. Which transition shown represents the emission of a photon with the most energy ? @ ll 45. tenes enerots ecco dob Sebago @: 2 mV @n 4 = _ OF 844, In_a common base amplifier, the phase difference between the input signal voltage and ‘output voltage is @s Or oF 45. in a full wave rectifier cireult operating from 502 mains frequency, the fundamental frequency in the ripple world he (@) 50He @) 25H (©) 100 Hz @) 707 He 46. A nuclear, wansformation is denoted by X¢0, a)» 2L. Which of the following is the nucleus of element X 2 (@ Bc © YB (© 3B @ PBe 47. A moving coll galvanomerer has 150 equal divisions. Is current sensitivity is 10 divisions per miliampere and voltage sensitivity is 2 divisions per milivot. In order that each division reads 1V, the resistance in Obm's needed to be connected in series withthe coil © wero vill be + @ 10 (b) 10° (© 99995 (2) 9995 48. Two voltameters, one of copper and another of silver, are joined in parallel. When a total charge q flows through the voltameters, equal amount of metals are deposited. If the electrochemical equivalents of copper_and silver are % and 2, respectively, the charge ‘hia lows through the silver votameter @—t o 4 oat 49. In the circuit, the galvanometer G shows zero deflection. If the batteries AandB have negligible internat resistance, the value of the rosiscor R will be: soon { : R wf 8 @ 200 @) 1000 (© 5000 (@ 1000 50. Theo sources of equal emf are connected to an external resistance R, The terial resistances of the two sourees are Ry and Ry (Ry > R,) Ifthe potetial ciflerence across the souree having Ineral esistange ier, chen (a p- Ba2 +) 2 © RaR-% OR SL. A fully charged capacitor has a capacitance. tis discharged through a small coil of resistance wire embedded in 2 thermally insulated block of specific heat capacity s and mass m. if the temperature of the block is ralsed by AT, the potential difference V across the capacitance is: @ St wm mee msAT amsaT oma fim 5. One conductingl/-tube ean slide inside another as shown In figure, maintaining electrical ‘contacts between the tubes. The magnetic field ls perpendicular co the plane of the figure. If each tube moves towards the other at a constant speed ¥, then the emf induced in the circuit in terms of B, land v, where 1 is the ‘wideh of each tube, will be @ Bh (b) - By (©) zero (@) 2B 58. A heater colli cut into two equal parts and only tone part is now used in the heater. The heat generated will now be : (a) doubled (b) four times (© one-fourth ——_(@) halved 54, Two thin, long, parallel wires, separated by a distance d carry a current of (A in the same ditection. They will :(a) attract eachother wit afore of Ha (2 atracceah ter wit fore of 2 (b) repel each other force of Eo (b) repel with a ab 2 (© ateract each other with a force of Ha xd?) a) repel each other with a force of Hl, @ repel each o as 188. When an unpolarized light of intensity Ip is incident on a polarizing sheet, the intensity of the light which des no get tense i: @ 5h Fh (© 2er0 @ b 56. A charged ball B hangs from a silk thread 5, which makes an angle 0 with a large charged conducting sheet P, as showin in the figure. The surface charge density o of the sheet is proportional to: 2 +4t+HH tate @) cos (b) cot 8 © sn@ = @ tan 87.Two point —_ charges a Pgand 24 ae loewel at ¢=0andx = feat te loeten of 2 poate he ‘Satsarwhich he ners fell duet hese ‘wo pn cherries to a0 owt Oe @ 40 ‘58. Two thin wire rings each having a radius R are placed at a distance d apart with their axes ‘coinciding. The charges on the two rings are + q and ~q. The potential difference between the centres of the two rings is : 59. A parallel plate capacitor is made by stacking n ‘equally spaced plates connected alternatively. If the capacitance between any two adjacent plates is, then the resultant capacitance is @ @-1C ® @+ne oc @ ne ou 62. 64, 6s. When two tuning forks (fork and fork 2) ate sounded simultaneously, 4 beats per second are heard. Now, some tape is attached on the prong of the fork 2. When the tuning forks are sounded again, 6 beats per second are heard. If the frequency of fork 1 is 200 Hz, then what ‘was the original frequency of fork 2? (a) 200 Hz (b) 202 He © 196K. (@) 204 He If. simple harmonic motion is represented by fx @= OF (© 2a @ ava ‘The bob of a simple pendulum is a spherical boliow ball filled with water. A plugged hole near the bottom of the oscillating bob’ gets suddenly unplugged. During observation, till water is coming out, the time period of oscillation would : (@) first increase and then decrease to the original value (b) first decrease and then increase to the original value (© remain unchanged (@ increase towards a saturation value ‘An observer moves towards a stationary source of sound, with a velocity one-fifth of the velocity of sound. What is the percentage ‘increase in the apparent frequency ? @ Zero ) 0.5% © 5% @ 20% If lp is the intensity ofthe principal maximum in the single slit diffraction pattern, then what will be its intensity when the slit wideh is doubled? @) 2g Ol ® 4, @F3 ‘Two concentric coils each of radius equal to 2x cm are placed at right angles to each other, 3 Aand 4 Aare the currents flowing in each coil. respectively. The magnetic induction in Wh/th?® at the centre of the colls will be : Gig = 4x «107 Wo/ Am) @ 12x10° @) 10% © sx105 (@ 7x1066. 67. 68. 69. 70. 7. ‘Acoil of inductance 300 mH and resistance 20 is connected to a source of voltage 2V. The current reaches haf ofits steady state value in: (@) 0.058 @) ols © 085 @ 03s ‘The selfinductance ofthe motor of an electric fanis 10H. ln otder to impart maximum power at 50 Hz, it should be connected to a capacitance of: (@) 4uF © our © IMF @ 2F ‘An energy source wil supply a constant current into the loa, i its internal resistance is: (2) equal to the resistance ofthe load (©) very large as compared to the load (© 210 (@) non-2evo butless than the resistance of the Toad A Greuit has a resistance of 12. and an impedance of 15 ©. The power factor of the circuit will be: (@) 08 @ 04 ( 125 (@ 0.125 The phase difference between the altemating eurrentand emfisx/2. Which ofthe following cannot be the constituent ofthe ézeult? (@) Calone ORL OLe (@ L lone ‘Auniform electric field and a uniform magnetic field are acting along the same direction in a certain region, IFan electron is projected along the direction of the fields with a certain velocity, then (a) its velocity will decrease (b) its velocity will merease © it will warn towards right of direction of motion @ it will turn towards left of direction of motion 172. A.charged particle of mass mand charge qtravels fon a circular path of radius that is perpendicular to a magnetic field B. The time ‘taken by the particle to complete one revolution is: @ a & BoB @ 2 wm 73. In a potentiometer experiment the balancing. ‘with a eel is at length 240 cm. On shunting the cell witha resistance of 20, the balancing length ‘becomes 120 em. The intemal resistance of the cells: @ 19 (b) 05a 4a @ 20 74. The resistance of hot tungsten filament is about 10 times the cold resistance. What will be the resistance of 100 W and 200 V lamp, when notin use? * @ 4a () 209 (©) 4002 (@) 2000 78. A magnetic needle is kept in a non-uniform ‘magnetic field. It experiences : (@) a torque but not a force (b) neither a force nor a torque (©) a force and a torque (@) a force but nota torque mee 76. 7 78. ‘The oxidation state of Crin[Cr(NHl,),Cl]* is: @o oH (© 42 @ +3 Which one of the following eypes of érugs reduces fever ? (@) Tranquitiser (b) Antibiotic (© Amtipyretic__(@) Analgesie Which ofthe following oxides is amphoteric fn character ? @) $20, (© 00, ©) sio, @ C20 79. Which one of the following species is diamagnetic in nature ? @ i HG Hy @ He 80, Ifa isthe degree of dissociation of Na,$O, the van't Hoff factor @) used for caleulating’the ‘molecular mass is (@ 1-20 (b) 14 20 @l-a @l+a 81. Which of the following is a polyamide ? (@) Bakelite (b) Terylene (©) Nylon-66 @ Teflonas. 86. a7. 88. 89. Due to the presence of an unpaited electron, fre radicals are (a) cations (b) anions {© chemically inactive (a) chemically reactive Fora spontaneous reaction the AG, equilibrium constant (K) and, will be respectively (@) -¥e, > 1,-ve 0b) ve, <1,-ve (9 +e, >1,ve (@) -ve,>1, He Hydrogen bomb i based on the principle of (a) arial radioactivity (0) nuclear fesion (@) natural radioatvcy {@) muclear sion An oni compound has aunt cell consisting of Aons atthe comers of a cube and Bons onthe Centres ofthe faces ofthe cube, The empiial orm for this compound would be @ Ag () ABs AB @ AB “The highest electicat conductivity of the following aqueous solutions is of {a} 0.1 Mdiflioroncetic acid (6) 0.1 M fluoroacetic acid (©) 0.1 M chloroacetic acid (2) 0.1 Macetic acid Lattice energy of an ionic compound depends upon : (@) charge on the ion and size ofthe ion () packing of ions only (©) size of the ion only (2) charge on the fon only Consider an endothermic reaction X -> ¥ with the activation energies £, and E, for the backward and forward reactions respectively. In general (@) there is no definite relation between F, and © E=F (© By> By By < ky Aluminium oxide may be electrolysed at 1000°C to furnish aluminium metal (Atomic rmass~27 amu; I faraday~ 96,500 Coulomb). ‘The eathode reaction is APY +36 —> at ‘To prepare 5.12 Kg of aluminium metal by this method would require: 90. on. 92. 93. 95. (2) 5.49% 10! C of electricity (©) 5.49% 10" C of electricity (© 1.83% 107 Gof eeccrcity (@ 5.49% 107 6 of electricity The volume of a colloidal particle, Vo as ‘compared to the volume ofa solute particle ina true solution Vg, could be Ye wo? Ye ea0? @ #10 © #-10 Ye wage ve © Fat ofa ‘Consider the reaction : Ny + 3H, —> 2NH, carried out at constant temperature and pressure. If AH and AU are the enthalpy and internal energy changes forthe reaction, which of the following expressions is true ? G@)aH> au (b) aH HCl< HF > HBr () Hl < HF > HBr < Hi (©) HF > HCl > HBr > Ht (@ HU > HBr> HCl> BE Calome! (Hig,Cl) on reaction with ammonium hydroxide gives (@) Heo @) Heo (© Nps Hel (@) Haniel ‘The number and type of bords between wo carbon atoms in calcium carbide are = (3) two sigma, wo pi () two sigma, one pi (©) one sigma, two pi (@ one sigma, one pi “The oxidation state of chromium in the final product formed by the reaction between KI and acidified potassium dichromate solution is @ +3 (by 42 © 46 @ +4 Insilcon dioxide : (@ there are double bonds between silicon and oxygen atoms () silicon atom is bonded to two oxygen au. 1s. nas. 120. 121. 122. 123. (© each silicon atom is surrounded by two ‘oxygen atoms and each oxygen atom is bounded to twa silicon atoms (@ each silicon stom is surrounded by four oxygen atoms and cach oxygen atom is bonded to two siticon atoms ‘The lanthanide contraction is responsible for the fact that: (2) Zr and Zn have the same oxidation state () Zr and Hf have about the same radius (©) 2r and Nb have similar oxidation state (@ Zrand ¥ have about the same radius ‘The IUPAC mame of the co-ordination compound Ks{Fe(CN), is: (a) Tripotassium hexacyanoiton (1) (b) Potassium hexacyanoiron (1) {€) Potassium hexacyanoferrate (il) (@) Potassium hexacyanoferrate (1) In which of the following arrangements the order is not according tothe propery indicated against it? (@) Li 0.is 4 parameter, is of order and degree as follows : (2) order 2, degree 2 (b) onder 1, degree 3 {© onder degree | (@) order 1, degree 2 ABC is a triangle. Forces B, @, W acting along 1A,1B and IC respectively are’ in equilibrium, here 1, is the incentre of ABC. Then Beg: Re: (@) cos A: cos B: cos () cos 4: 008 8 cos $ 2008 3 + e085 Ae gin Begin © (© sin $sin Fz sin $ @ sin A:sin B: sinc |. Ifthe coefficients of rth, (r+ 1)thand (r+ 2)th terms in the binomial expansion of (+ y¥"are Jn AP, then m and r satisfy the equation (a) m? —m(4r—1) + 47? + 2=0 (0) m2 = m(are 1) 4 4? 2=0 (© m—m@4r+ D+ 4 +20 (@ mt ~ mear—1) + 47? -2=0 In a wane POR, ZR ~F, af tan(5) and tan (Qam hereof? vend 20, tia? @orese Gee Gescts Wheater13, Ifthe leters of the word SACHIN are arranged inal possible ways and these words are written ‘out as in dictionary, then the word SACHIN appears a serial umber (a) 602 @) 603 (© 600 @ 601 14, The value of 9C, + 3, %"Cyis: @) *c, &) *c, © Cy @ Fey xs. was[d SJanare[} 9] nen wi oe oF te wing Bos all 21, by the bin of athena inaction? @) At=2 As -DE ) AT=n A+ (n-2)E (© AN =2"1A-@-1yT (0 Arana t0-DI 16 ecw o?n* (2))" a she cottiet of inf ox —(35)] then «and b satisfy the elation (@) abet & Fa1 © avba1 @ a~b=1 17. Let f:(1,1)-> 8, be a funetion defined by Fexyw tan 25, then f is both one-one and ono when B she interval: @(-3.3) w[-3.3] [o3) @ (03) 18, If, and ate two non-zero complex numbers such that}, + le 2d hen arg, ~ args, equal 0 @) 0 @s and] | =1, then # lies o& (@) a parabola © acircle (b) a straight tine @) anellipse 20. 21. 22, 23. 27. Ia? +B + 2 =—2and lsdx (+B ye Aree f)=|0+@x Lee Cee e Gedy a+b eee then f(x)is a polynomial of degree (2 3 @o @1 ‘The system of equations axtytrna-1 x+ay+zea-1 xtytazea-1 hhas no solution, if is : @1 (b) not ~2 (© elther—2or1 (a) ~2 ‘The value of afor which the sum ofthe squares of the roots ofthe equation x7 ~(a~ 2x a~-1= Oassume the least value (a2 3 ©o @1 If the roots of the equation x* — br + c= O be ‘two consecutive integers, then b — 4cequals : @i b) 2 oO3 @ -2 Suppose f(2) ie deren st x1 ad Ji £0. h)~5 thon 7" Cea @ 6 ) Ss o4 @ 3 a jeden ral 11f0)=~ 2a PGosterreti skier (@) f@)=5 (b) f(6)<5 © f@)<8 @) f@)28 Wf ie» relvahed difereniable fonction satisfying | f()- ON Gr -yP, my eR and f(0)=0, then fel) equals: jt (oy 2 ©o @- If x is so small that x’ and higher powers of x may, be neplected, ‘then dear -(iehs ED pay be sprit2B. ttx= 3 ahy= Eben Fe where ghe are in AP and Jat <1,J6] < Ile} <4, then x, y, 2a in: (a) HP () Arithmetico-Geometric Progression (ar @ @ 29. Ina wiangle ABC, let C= 4/2, if ris the 30. a1 32, 34, inradius and R is the circumradius of the iangle ABC, then 2(¢-+ R) equals : @era ) at bee jars @ bre eos! x - cost =a, then 4x? — Ary cose + y? is equal to (@) -4sin?a(b) 4sin? a 4 @ 2sin 20 If ina AABG, the altitudes from the vertices A,B,C on opposite sides are in HP, then sin A, sin B, sin are in (a) HP (b) Arithmetico-Geomeric Progression (o AP (a) oP The normal tothe curve x= (cos 0+ Osin 0), y = a(sin O~ 6 c0s 0) at any point "(is such that (2) itis at a constant distance from the origin (0) it passes through (a x/2,~a) (©) it makes angle x/2+ Owith the x-axis @ it passes through the origin AA function is matched below against an interval where itis supposed to be increasing. Which of the following pairs is incorrectly matched ? Interval Function @ cra rors 6 o(ad] attest OR«) | ae — ae? 128 +6 @ C20) peers’ et aandB be the distinee roots of ax! + by +c0, then BE + is equal to @he-p — m-Sa-pF @o ofe-¥F 38. 36. 37. 39. By (og y-logx+1) , then the stn fie een @ie(3)=0 @ ba(2) ee x (9 stee(2) +07 @ ye(2) =o ‘The line parallel to the x-axis and passing through the intersection ‘of the lines ‘ax + Dby + 3b = and br = 2ay - 340, where be, ois: (a) above the x-axis at a distance of (2/3) from it. (b) above the x-axis at a distance of (3/2) from it. (© below the xaxis ar a distance of (2/3) from it. (@ below the xaxis at a distance of (3/2) from it. AA spherical iron ball 10 om in radius is coated with a layer of ice of uniform thickness that melts at a rate of 50 cm°/min, When the thickness of ice is 15 em, then the rate at which the thickness of ice decreases, is © gheawmin 5 @ Zewmin (©) qggem' @) fem © gggewmin af envimin 5 {foes ddeis equal to Let f:R-R be a diferentable function baving f(0=6,5'= (gg) Ten i (eo: 1 2 oa toa Let f(x)be a non-negative continuous function such that the area bounded by the curve (x), axis and the ordinates x = n/4and Dai is (sino $cosp+ V3) then F(3) is:a. 42. 43. 45, 46. a7. @(1-$+48) (1-9-3) of ttn =ftten ha ae +1) @ ($+¥8-1} Jade ana = [2° ax then: heh Ohh 1 Obl irk ‘The area enclosed berween the curve yoo, G+ and the co-ordinate axes 4 3 ©2 @1 ‘The parabolas y? = 4x and x? = 4y divide the square region bounded by the lines x = 4, y= 4 and the co-ordinate axes, Wf S,,S,,S, are respectively the areas of these parts numbered from top to bottom, then SS, : Sy is: @) dined () 2512 @ 1:2:3 @u:de1 If the plane 2ax ~ day + 4az+6=0 passes through the mid point of the line joining the centres, of the spheres xis y? +2 + 6x—By —2=13 and xbsy? +a? 10x + 4y 22 8, then cequals: a2 @)-2 ot @-1 ‘The distance beoween the ine ¥F=d-2j+ 3k+ad-j+ 4k) and the plane #-(@+ s}+ f)=sis 10 3 ® 5 © ® ox oy? For any voor, the value of (2 xij + xi? + (a x toy is equal to: aa? 28? wor @ 38” UW nonzero numbers 6 te fn HP, then the sight tine © always passes Ahough a fixed point. That poinc i (1-4) © a-9 OEL-2 MCL 51. sa, 54, {fa vertex ofa triangle (1,1 andthe rid poins oftwo ses thigh his were are(~1, 2) and (3,2) “obese so : 3) (45) eC wf HT the ciecies x? + y? + Qax + gy + ax 0 and xtny? Bare dy2=0 interne in oto Gistiiee pois P and Q, then the line Se + by ~ a= Opasses through P and@ for (@) exacdy wo values of @ (©) infinitely many values of (©) novalue ofa (2) exactly one value of a ‘Acirele touches the x-axis and also touches the circle with centre at (0, 3) and radius 2. The Toeus ofthe entre ofthe ciel (@) parabola (b) a hyperbola © acircle (@) anellpse 1 4 eile passes through the point (6) and cuts the cree x? + y? = p orthogonally, then the equation ofthe locus of is centre is = (2) 2ax + hy ~ (a? +B + p?}=0- (©) x? + y? = Barby + - BF ph)=0 (6) ae » aby = (a? B+ (8) x8 yy! Bax ~ diy + (a + ped ‘an ellipse has OB as semi minor axis, F and its foct and the angle FOP" isa right angle. Then the eccentricity of the ellipses ; . os o} : , 3 OF ‘The locus of & point P(x, moving under the condition thatthe line y= a x + is a tangent vo the iyperbola 2 — e {a) a hyperbola (b) a parabola (© neice (a) an elise Wf the angle between the tine Xt1yeV_5-2 and the pane 2e~y +-Vi + 4~Olssuch tharsin O= 3. The value of is 4 3 @-3 oF 3 5 o-3 ws‘55. The angle between the lines 2x = 3y = 56. 87. 59. o1. and 6x=-y=-42is (a) 30° &) 4" © 90° @o lLet_A and B be «wo events such that PAUB-LpAnsyel and Pa=!, where & stands for complement of event A “Then events Aand Bare (@) mutually exclusive and independent (Independent but noe egualy key (©) equally likely but not independent (@) equally hey and mortalyexlsive “Three houses are available in a locality. Three persons apply for the houses ach apis for fone house without consulting. others. The probeblty thea the thee apply forthe same fuse is @) 7/9 (b) 8/9 ow @ 28 A random variable X has Poison dsebtion with mean 2, Then POX > 1.5) equals 3 3 @s o a 3 OS oo ‘Two points A and B move from rest along a straight line with constant acceleration f and J respectively. IFA takes m sec more than B and describes ‘unit more than B in acquiring the same speed, then : @ Uf =f sm + Fm sin? Ut fim? = F'n © (f~f0mt Alizard, at an initial distance of 21 em behind an insect, moves from rest with an acceleration ‘of 2 em/s? and pursues the insect which is crawling uniformly along a stright line at a speed of 20 cnvs. Then the lizard will catch the insect ater : (@ 24s @ ars 1s @.205 ‘The resultant R of two forces acting on a paricleis atrighcangles toone of them and its ‘magnitude is one third ofthe other force. The ratio of larger force to smaller one is : (@) 3:22 3:2 © ava @21 62. 66. 67. -&Bexivjea—ok and Seyisjeaex-yyk. then fa BE depends on (@) neither nor y (b) both xand y © onlyx @ onlyy Leta, b and che distinct non-negative numbers, If the vectors aitaj+ck,irk and i+ J+ ble lie in a plane, then cis: (@) the harmonic mean of cand (b) equal to zero (© the arithmetic mean of a and (@) the geometric mean of a and b 1a, B, e are non-coplanar vectors and his areal number, then D+ B) 2B ve B+ eS By ie: {@) exactly two values of (©) exactly three values of & (©) no value of (@) exactly one value of & A and Bare two like parallel forces. A couple of ‘moment H Ties in the plane of A and B and is contained with them. The resultant of A and & after combining is displaced through a distance H © xarm 2H oe i O74 a a5 ‘The sum of the series wedge 2 16-41" 64-61 © wis: Ex} = 400 and E x, = 80. Then a possible value velocity w at an angle of 60° with the horizontal. When itis moving in a direction at right angle tots direction atO, then its velocity is given by70. na. 72. a) a Os oF @% 3 Jf both the roots of the quadratic equation x2 = hor K? + k = Se Oare less than 5, then -elles in the interval (a) (4.5) ©) 2,4) © Gx) @ 65) Hf G0, dy, sess Qe. are in GP, then the determinant Woga, Hoga, loxa, 2 a=lloga,.y loga.4 loge. 5 Noga, ¢ 1OEG.7 IgG. 9 J equal to: @2 m4 @o @1 ‘A seal valued function f(x) satisfies the functional equation Fx y)= FO) SO)- fle-») fle y) where a is a given constant and f(0). F2a— x)is equal t0 : @ fen ©) f@+ fe-x) © foo @ -fe) 1 the equation xP AX eect =O, 4 0, n® 2, hasa positive root x = a, then the ‘equation manieetwet | 74. 75. aga" + (n= Tay"? + positive root, which is (a) equal toa () greater than or equal toa (©) smaller than @ (@) greater than +a =0 has a EX ax, 0>Q is @ Oy oF @ an ‘The plane x+2y—2=4 cuts the sphere 4 PsP axte-2-0 ina dice of radius @2 m2 1 @3 If the pair of lines ax? + 2(a+ bay + by®=0 lie along diameters of a circle and divide the ‘ire into four sectors such that the area of one of the sectors is thriee the area of another sector, then: (@) Sa + 2ab+ 3b? = 0 () 32? + 10a + 38? =0 (©) 30? 2ab+ 36? =0 (@) 30? — 1008 + 38? = 0we PHYSICS AND CHEMISTRY MV uswers 2@ 2@ 2 @ 460 5@ 60 72 @ & © 9 G@ 10 () I @ 32 () 33 &) 1 35 @ 36 @ 7% ©) 1B 19 &) 2 © BW @ 2 w 2a mw © 25. (6) 26. ic) 27.) Be). LB) 33 ©) BAe) |) 8K), GB) 3.) AD.) M1. 4% @) YG), 49. (0) 50.) SL @) 52 @) 5) BOS) 57. G@) 5B. (b) 5%.) 6D.) BL) Gt) BR.) BG) 6.) 66.) G7) BO). TL @) «TR 73. (0) 74 (@) 758 (©) 76 (@) 77. (© 7% @ 78 ©) 8. ©) BL.) 82.) 83.) BA OH) BS.) BE. a) BT a) BBR) 89. G) 90.) OL fb) 92) 9B) 98H) @) 97, (@) 98. G@) 99. (b) 100.) 301. Go) 102, (>) 108. a) 104. 105. (4) 206. @) 107. (@) 108. (©) 109, {c) 110, @ ML &) U2 © 33. @) © 5. @ M6 @ 17. © 118 ©} 119. &) 120. ©) 12. ©) () 123, @) 124) 125. Ge) 26) 127.) ZR) 123. @) © WL © 132 ©) 133. ©) 134 |) 138) 138. 337. © © 139, ) 140.) AME) 2a), |) 345.) (©) 187, 14K) 148.) 150. (o) + No option fe matching oe MATHEMATICS. _ Lo 2@ 23@ 4@ 5@ 6 72 @ & @ 2 ©) 10 ©) 12 @) 1 @ 22 @) wh @ 18 @ 16 @ VG) WW) 18.) 2A 2-2) 2M) 2.) 26.) 27) H-Bond 33. (0) 38 Ga) BH) BK.) BB} BD. tw} AD.) AL ©) 82.) 43.) A) AB) AG) AT.) 49. (©) 50. G@) 51 @) BZ) SG) SA) HD 57. © 5B) 5). OH) CL) HO] 6. (©) 66. ©) 62 © & @ 88 & M2 © MW 2 © Bo © 7 © 7% @HINTS e SOLUTIONS 1. A projectile can have same range if angles of projection are complementary ie, 0 and {90° ~ 0) Thus, in both cases : rot Eqs. (D and (H) 4u? sin Ocos@ Hence, tt) thermal conductivity 36. 38. wa re del fae at ae Ji, 4aK (i) Rate of heat ow = Bote TMs wankonde ‘The change in internal energy does not depend ‘upon path followed by the process. It only depends on initial and final states. Henee, AU, =U. Here, y = sin? wt oe ole oe y Gf = 2esin at cos wr = wsin 20 #Y og? £2 ~ 267 cos 20 at @y For SHIM, 2 a — ae” Hence, function is not SHM, but periodic From the y-c graph, time peviod is Taz Given : +01 sin (100 2¢ + 3) . 2 Sh ay, -01 «100 mens (100. + 3) on storsn (toon + $03) s oe wat0nsin (00.0 + £) ei yuo » Y2 ay, = 03 sin at = 01 sin (at +2)ence, phase difference 1 s_,)(1 4 RIVE E) -© (b6= 4b - = (00s 8) -ce + =H. So ™ =Re| 3] = 0.2Rhe ser me al Fa ay *Rhe| asa “ i “3 3 rhc=-0.9 Re $ Rhc=~0.9 Rk “Thus, II transition gives most energy. transition represents the absorption of energy: 43. We know or AB =44. In common base amplifier the input signal is. amplified but remain in phase with output signal Given f = 50 Hz 1 ted, is Tr For fll wave rectifier 7, = 5 = sh, fi=100 He 46. 3x4 no Lt He implies that A+1 > A and Z4+0= > Zz Tha soon 4. ral sae ecto eee 23D gas pals dtaton vse 70m 75a 75mv Calvanometer resistance ¢= 75 = 502 ‘Required full scale deflection voltage, V=12150=150¥ Let resisance to be connected in series is R bok s v = VaiR46) 150= 15x10 (R + 5) = 10 =R+5 = R=10000 -5= 9995 m=aq 49. The galvanometer shows zero deflection. ie., current through XY is zero 000g ¥ av ‘Asa result potential drop across Ris 2V cireuit can be redrawn as 500.8 12 500+ R Voltage across R, V = IR = aap? eR 300+R > 1000+ 2R=12R = R=1000 50. Ry = Ri +Re+R R, fe Feta tp oe RR eR According to the question, Rit Rat R=2Ry a e-(o" 0 Th eer sort cpio mat nemaFrom Eqs. (I) and (1), we have va Han gst H, ae ry Hy 54. The force per unit length between the two wires is F_ito 2i? To and 2 The force will be attractive as current directions in both are same. 35. [=I cos? 8 Intensity of polarized light k 56. Hlectric field due toa charged conducting sheet of surface charge density ais given by E = ©. 8 f+t++s444] mg where, tq = permittivity in vacuum and 5 relative permitivity of medium. 37. 58. Here, electrostatic force on B ao nee [FB of B is shown in figure. In equilibrium, T cos @=mg Qo and T sin 9-22 ° 8h ‘Thus, 29. emg an Ovo or oxtan 0 Suppose that a point B, where net electric Field is zero due to charges 8qand~29 Thus, at distance 21 from ovigin, net electric feld will be zero. Yq potential due to charge + gon ting A+ potential due to charge — gon ring B +a = “861. 1 ‘Similarly, Vy wal Potential difference V, ~ Vj (ats In? Each plate is taking part in the formation of wo ‘capacitors except the plates at the ends. A ‘These capacitors are in parallel and n plates form (n ~ 1) capacitors. ‘Thus, equivalent capacitance between A and B =@-DC ‘The frequency of fork 2 = 200 + 4=196 or 204 Hz Since, on attaching the tape on the prong of fork 2, its frequency decreases, but now the number of beats per second is 6 ie, the frequency difference now increases. It is possible only when before attaching the tape, the frequency of fork 2 is less than the frequency of tuning fork 1. Hence, the frequency of fork 2 is 196 Hz, @x a af) We know a Ci) ‘Spherical hollow ball Milled with water =a From Eqs. () and (i), we have Spherical hollow ball al filet with water nef Spherical boliow ball nea and Tot Hence, time period first increases and then decreases 10 the original value. 120 = y= 32-64 m/s Given : 5) ‘When observer moves towards the stationary source, then mn 320 Hence, percentage increase (“) (285522 6s (p10) 204and 0-3 (2) For principal maximum 6-0 ‘Hence, intensity will remain same . Anx107 x4 BIO W810 Wo/m? Hoh Fo aR AE X1O7 3 5305 Woy? 2x 0.02% = B= BR + Ba 66. The current at any instant is given by TehpQ-e™y LR he phi Faka-em) 1 qos ity pmb 3/2 1 Re 2v Haina =150 6.693 x10" 10395 s = 0.1 § 67. Given :L=10H, f = 50 Hz For maximum power Xe=X, 68. nm 72. ppt 4 50 «50 «10 =01 x10 Fal pF E = constant ‘where, R = external resistance rreinternal resistance =0 Power factor R cos p28 4 #-t -o8 1. na circuit having C alone, the voltage lags the current by 5. 2.1m circuit containing Rand, the voltage leads the current by 3. 3.1m LC ciruit, the phase difference between current and’ voltage ean have any value between 0 to 5 depending on the values of Lande. 4.IM a citeuiteontaining & alone, the voltage leads the current by 5 when E, VandB are all along same rection, then magnetic force experienced by electron is zero while electric force is acting ‘opposite to velocity of electron, so velocity of electron will decrease. Magnetic force F = q vB of)‘The time taken by the particle to complete one revolution, 76. (CrCH,),CI" Let oxidation state of r= NK =0 cat Net charge=+1 [ Grevn, ,Cl)" +4 xO42-Tm +1 x=3 79. Antipyretic drugs reduce fever. Analgesic releives in pain, antibiotics net against bacterial infections while tranquilisers are used against ‘mental disorders [A species is amphoteric if itis soluble in acid (behaves as a base) as well as in base (behaves asap acid). SnO, +4HCl—> SnCl, + 24,0 Bowie aed Sn0, +2NaOH—> Na,SnOy + H,0 79. A species is said to be diamagnetic if it has all electrons paired m0 Electronic (configuration fais ol? lout jot ee? Species Magnetic Hieciveaa| behaviour Paramagnenc Peramagnetic biamagnetc [Peramagnete 74. 78. 80. a1. 82, 84, Poe 100 4000 400 Reid = 400 Magnetic needle is placed in non-uniform magnetic field. It experiences force and torque ‘both due to unequal forces acting on poles 1Na,S0,— 2Na* + SO van't Hoff factor =[1 + (y - Dal where y is the number of fons from one mole solute, (in this case =9 ), « the degree of dissociation. i-a+ 24) Nylon-66 is a polyamide of hexamethylene diamine (Cil,),(NH,), and adipic acid (Git) (COOH), (ach reactant has six-carbon chain hence trade code (66) is used.) Free radicals have unpaired electrons but ate neutrals and ate reactive, cu, +éH, — cH, —cH, 2.303RF log Ky AG" =~ nF, {fa cell reaction is spontaneous (proceeding in forward side), it means Kgq>1 and Boy =+ ve Thus 3G°=~ ve 4}H> {Hes 2fe+ energy Ie isthe principal Hydrogen-bomb. Unit cell consists of A ions at the comers. ‘Thus number of fons of the type aad reaction of Unit cell consists of 8 ions at the cemtre of the six faces.86. 87. 89. ‘Thus number of fons of the type 6 Ba$os {Bach comers is shared by 8 cubes and each {ace is shared by 2 faces) ‘Thus formula is ABs. Fluoro group causes negative inductive effect increasing ionisation, thus 0.1 M difltoroacetic acid has highest electrical conductivity. Ho Fe G+ 6+ 0-e Greater the charge, smaller the radius, greater the polatising power and thus greater the covalent nature. This leads to increase in lattice energy. X— Yisan endothermic reaction AH = + ve y he, é | lan LW = energy of activation of backward reaction E, = energy of activation of forward reaction Alf = heat of reaction Thus E,=B, +H Thus E,>Ey AP* + Se al w=2Q ‘where w = amount of metal SZ kg= 5.12% 10g 12 electrochemical equivalent eae: Equivalent weight Atomic mass 96500“ Electrons x 96500 27. 3.96505 27, 5.1210" = 27 a5 *Q Size of eolodal particles ~1to 100 nm (say 10 am) 4 vende? Size of true solution particles ~ 1 nm 4 We=zn0y Ye 19? yr 91. AH = AU + An,RT AH = enthalpy change (at constant pressure) AU = internal ene-gy change (at constant volume) (given reaction is exothermic) ‘An, =mole of (gaseous products ~ gaseous reactants) Thus 44 T,) is shown below : wy ad ‘Atboth temperatures, distribution of molecules ‘with increase in velocity first increases, reaches ‘a maximum value and then decreases 98. 2NOs()=— 2NO(g)+ O3(g) K, = 1.8% 10 at 184°C (= 457K) R= 0,00831 ks mol? x100. 101. 102. 103, Kary” where, (gaseous products — gaseous reactants) =3-2-1 K, =1.8 x10 0.00831 «457 6.836 «10° >1.8 x10 ‘thus K,>K. Reaction is exothermic. By Le-Chatelier principle, a reaction is spontaneous in forward side (in the direction of formation of moreCIR,) fF, is added, temperature is lowered and CIF, is removed, eo 10-109 Antilog of 0.6 is = 4 DY ]= 4x 10% M ‘There are two different reactants (say Aand B) A+ B— product ‘Truss 2 bimolecular reaction, dx 1" & = cane ittscondaereson «(=n or K(B} itis frst order reaction. ‘Molecilarity is independent of rate, but is the sumof the reacting substances thus it cannot be ‘unimolecular reaction. Toa lay = Mae 344M. During electrolysis, noble metals (inert metals) ike Ag, Au and PE are not affected and separate as anode mad from the impure anode. icon ~ Srcora + Nits Nivea 910+ 426.2~ 126.5 3007 Remains unchanged. aya (Bm) 2s (2p Dad wa In the absence of any field, 3d in (D) and (E) will be of equal energy. 104. As we go down in the group, ionic character increases hence, melting point of halides should Increase but NaC] has the highest melting point {@00"C) dle to its high laste energy. 105. Variation of K, with temperature’ is given by van't Hoff equation. an as’ 108 Ks =~ S30SRF * AB Slope of the given fine is + ve indicating that term Ais positive thus Af ve. ‘Thus reaction is exothermic. 106. Following reaction takes place uring Dessemerzation 20u,0 + Cu, —+ 6Cu + $0 107. Molecule | Structure | Hybridisation | Lone ‘central | pair stom 7 L pd om ™ F—S—F f F F \ if a rotor ew F ° 2h i 2 | oe te spa’ i P 108. Mixing the soles together can cause coagulation since the charges are neutralised. 109. Hypophosphorus acid (H,PO,) is a monobasic ‘acid and has only one ionisable H, two H-atoms are directly attached to phosphorus. Thus the correct statement is (€) a npo-k i $ 120, Conjege basi fomed by los of Ht, OH” —+0* + Ht Cet (0* is the conjugate base of OFm1. 112, us. a4. us. us, 47. 18. 119. Aqueous solution of AlCl, is acidic due to hydrolysis, AlCl, + 3H,O = AICOH), + 3HICL On strongly heating AI(OH), is converted into ADs 2AKO8), 45 A1,05 + 31,0 In a group, AG;* (AX) changes from - ve to + vedownwards. HF (g)4G =~ 273 .20 bd mot" HI(g)AG=4 1,72 13 mot ‘Thus HF is thermally stable and HI not. ‘Thus HF > HCL > HBr > HI Hg,Cl, + 2NH, > HgNH,Cl + Hg + NH,CI ie a ‘cat (Calelum carbide) is ionic Ca, —> Ca? +c c CE has one oand two xbonds, CeO} + 14H + 6» 260 + 7140 + 31, x0} is reduced to". Thus final state of Cris + 3 Hence, @) I \ o 66 AK AN ope Po Lanthanide contraction, cancels almost exactly the normal size increase on descending a group of transition elements, chus Nb and Ta and, Zr and Hf have same covalent and ionie radi, Ky(Fe(OM) (Oxidation state of Fe in anion = + 3 ‘Thus itis potassium hexacyanoferrate (IU). (@) Metallic radii increase in a group from top tobottom. ‘Thus Li < Na < K F and decreases along a group ‘Thus! < Br < F< Clis true. (© Tonisacion enthalpy increases along a period left to sight but due to presence of half illed orbitals in N, ionisation enthalpy ofN > 0. ‘Thus B CH CHC CH, + CH, CH cH br ‘addon product 1, 4addon product ‘Additon is through the formation of allylic carbocation CHysaCHCHCH, <> cHyctmntr, (ray ‘cram eres) oes) ‘Under mild conditions (temperature = ~ 80°C) Kinetic product is the 1, 2addition product and under vigorous conditions emp.» 40°O thermodynamic produetis the 1, 4-addition product. ‘Thus ‘-bromo-2-butene is the major product Under given condition. faci is weak, its conjugate base (nucleophile) is strong and vce versa. wo cit, —c—o ° Js a conjugate base of i cxcon cy (B) CHO" isa conjugate base of CHOH GD) (CYCN™ is a conjugate base of HCN (HIT) one —_)—26; racrugaebs © oY sony Acidic natuze of IV > > I > and nucleophility of B> C> A > D In Sy2reaction, nucleophile and alkyl halide react in one step. i \/ a lal alae x ‘Br | R k ‘Thus tenia caibon is under ster hindrance {Bur rencton doe ot ake place wd (O30) bond beat * i “y a, a ical R R which is then Sy1 reaction. 1129. Synthesis of RNA/DNA from phosphoric acid, ribose and cytosine is given below ‘Thus ester linkages are at C,' and C, of sugar ‘molecule. : betta C G ot eting BNE ae sa 180, Out of the given acids, strongest is HCOOH, highest X, value) Since pk, =~ log Ky ‘Thus lowest pK, is Of HCOOH. 181. (A) 2-methyl pentane "25 five types of rwonocleriated compounds 2, 2€imethytbutane 2° 5 three types (© 2, 3imethylburane 5 ewo types (©) mhexane 2+ three types 132. Itis Corey House synthesis of alkanes. 133. Wurtz reaction is used to prepare alkanes from allyl halides : 2R—X+2Na 28M, Rp + 2Nax135. 136. ‘There are two chiral C-atoms (*) ‘Thus optical isomerism is possible, Nii, NO, group eon with @ No, i main, 6 CHC group is also electron withdrawing. OCD) phenyl groups also electron withdrawing. @)Benzylis electron-repelling group increases basic navure. ‘Thus most basic compound is benzylamine. orw at, Son, =", cu,cH,on non cit, —cH = cH, — cH,cucn, on (2 alcohol through 2 carbocation CHyCLICH, om, —c an, =" ci1,),co11 Ch, (@* alcohol) through 3* carbocation (CH,),& Hy | cH, —cH—cnt non’ | anne GioH— gic, eatoaton Laie sae 142 2° alcohol Hy atta 8 at reutfearion Tasha ae (6) 137, 188. 139. 140. aa. 142, 143. 14a, Teint £04) eh, Guawaten —sovingies, — = ie cipsicancy + aya, Dale ptean nin stan fact meta saat seer cme a ot Sere aera tee See eet = acemae 7 i wl rene dL sae Best leaving group (poorest nucleophile) iscl®, oS roger leon Hydrogen atom is in 1s! and “these 35, 3pand 3d orbitals will have same energy ‘wart 1s ombital Lanthanide contraction is due to poor shielding, of one of 4f electron by another in the sub-shell, (a) a in strong field ‘unpaired electron: ‘Magnetic moment = Jnja > 2)BM V3 BM = 1.73 BM seo tonte ect(b) din strong/weak field (OW is more activating than —CH, in Te 6 paitecting, thus —CHO goes to ortho watt 0H) TTT 29 147. Formation of XY is shown as nad y+ %—> 2x Magnetic moment = VIS = 9.87 BM AH = (BE),— + BEy_y ~ 2BE),_y (© d* inweak field i @BofxX—Y~a ae then (3) of (© —x)=a = v= oBetc¥ ILD AH, (XY) =~ 200 ned = 400 (for 2 mol X¥) ‘Magnetic moment = V24 = 4.90 BM (@) a* in strong field = 400: 800 1a The bond dissociation energy of, 800 ky mol a us. NILHS()— NHYG)+ HSC) Magnetic moment = 8 = 2.88 BM towaty os 8 mas. sequllivian d=) 54x) chy Or, + ri ai ‘Toral pressure at equilibrium ea a ses I enamine 5+ x+ x= 0.84 2 x=017 atm <> om wm 3 Pity ~ 0.804 0.17 0.67 atm on Phys = 0.17 atm Eno! Ky Pay Pays oH 67x 0.1 149 element |percentage| sien, 4 cel, + on Reine Tenant, = 0 he K 607 pawl ou ou x “ser ced CoH ° 28.68 How i Empirical formula = CH,N,O & by Empirical formula weight 12+ Gx 1)+ x14) +16 ou ~60 no de sg “i fre Mel. formula weight _ 60 10 i imap. formula weight ~ 60 Coie ‘Molecular formula = CH,N,O 4 Given compound gives biuret test. Thus given ‘compound is urea (NH,),C0,eypont, + cones, + NHCONHCONH, + NH, —*, Violet colour are 180. A > Pro wity ° ttertinee (=) : aftertiy — fg « ( $ 1. Key Idea : IFC i mid point of AB and P be the PAs PB 2 Let P be the origin outside of AB and ¢ is mid point of AB, then origi, then B= Be PAY PB Bo 2 i 2PC- PA + Pie 2. Theco-ordinates of? are (1, 0).A general point Qon y?= 8x is (2r4, 40) Mid point of PQ is 8,30 and (On potting the value of from Eq. (i) in Eq. i), swe get ae ane 2 ahai? 42, So the locus of (h, k)is y? ~ Ax + 20. 3, Key Idea : The relation among Mean, Mode and Median of any frequency distriburion is ‘Mode = Median ~ 2 Mean . Given that Mean = 21 and Median = 22 : Mode~ 3 Median 2 Mean (22)-2(21) 65-42 4, Since, (3,3), (6, 6), (9, 9), (2,12) 6R=> Ris reflexive relation. Now (6,12)€R but (12, 6)¢R, s0 it fs not a symmetic relation, aaoiies4 tae Also (3, 6), (6,12) €R => (3, 12) eR = Ris transitive relation. Note : Any relation Is said to be an equivalence relation, if it is reflexive, symmetric and transitive relation simultaneously 3» Key Idea : JfA is any square matrix, then AA? 21 and AY Since, A? -A+1=0 = AMAR ATAGATI=0 (Pre multiply given relation by A” = AA)A-A A+ AT =0 > A-1+A4=0 > AlsI-A . Since (x1) + 8=0 = (e-1) =~ 8=¢-2) = roots of (x ~ 1)are -2, ~20 and ~26* = roots roots of x ate —1, 1~ 20 and 1 ~ 20? Note :f1, © and 0? aro cube roots of unity, then“hs Ql = xs de LP ected Hi [tan ef = 5 tant «Key Mea + The parametric co-ordinates of @ point that ties on an ellipse “+ Fpl are (aos. b sin 0). Let the co-ordinates of the vertices of rectangle ABCD —are_—-A(acos 0, bsin 0), B(-acos0bsin 0), Caos, —bsin 0) and D (a 00s Q,~ bsin 0), then length of rectangle, AB = 210s 0 and breadth of rectangle, AD = 2b sin @ Area of rectangle = AB x AD 2a cos 0x 2b sin = Area of rectangle, A= 2absin 20 ...() A (a coe, bch) (acoso, sinoy (acoso, —b sy = 2x 2ab cos 20 on puting formas oii = Maximum Area of rectangle = 2absq unit. (From ()) Alternate Solution From Eq. () ‘Acea of rectangle, A = 2absin 20 = Aesin Wand~1 $ sin 201 ‘Ais maximum when sin 20: = Maximum area of rectangle = 2absq unit, 9. Key Idea : The differential equation ofa family ‘ofcwrves ofn parameters isa differential equation. (of maxima order Equation of family of curves is ya2e(x4 Ve) o On differentiating Eq. (2 with respect to, then 2yy = 2e = c= ‘On putting the value of c in Eq. (i), we get Yad +n) = OF 2m xP =40nF ‘The degree and order ofabove equation ae 3 and 1 respectively. ‘10. Key Idea : If three forces acting on a particle ep iti equilibrium, each s proportional othe sine of he angle between the other two. R any This theorem is known as Lami’ theorem.Ina 4 ABG, I is the incentre ry ; 1,8 L346 Simitarty, ZAC 245 and cara SS by Lams theorem a i BIC” win ATC BGR wsn(§-4)sain() ba wea cobs Key ns hess em of A+ y)" is “C,, (2) fa, b, care in AP, then R in AB u © Gare eA ir reeDs mrs (my _ 2 cen r+ Du-7+ m=) Gane sr erem +? -2mr4 mor =20nr-P + r+m—red) = 47 — 4mr—m—-2+ m=O = mt -m(r+1)+ 4-220 Key Idea : if « and [i are the roots of the auton + he + e=0 dere Be and op= 13. als Q sic, (8) ond ea ($ ) ae st a? + be be=0 equation P anQ@-_8 tan $+ tan $=—2 ani n ron Que id tan F tan $=£ Also, (SP, Q,R ate angles ofa tangle) R, PQ. aa 2 = ~bea-cacmasb Alternate Solution 2 stan? tan tan 5+ tan 5 tan coath In SACHIN order of alphabets is A,G.H,LN,S. Number of words start with A= Si, so with ©, HI, N, Now words start with S, and after chat ACHIIN are in ascending orders of position so 5:5t= 600 words are in dictionary before words with $ start and position of this word is 601.=5IC, + Sic, + 8c, + Cy + Mey + My (G4 pan 7C,) 84 oq4 Mey + Mey + MC S44 Moy + Mey+ MC 56, + Mey + cy + Cy MC, is. 4-[} 9] » ar-[ Q]eanbe vested y inuction Now, g opt by open oft Soft eo n2a] na-o-t=[t ("5 92a] te) 16. Mey Aden :The(¢+ 3h nthe epson oes arG, ee. Let x” is contained in (r+ 1)th term in the expansion of(ax?+ B)". (BY Tay 22-Sr=7 Brels res uuu é ie F + Coefficient of x’ T.= "Cs in the expansion of & oS cay Similarly, coefficient of x°” in the expansion of (ets t7, nce rete2 = wre = untae and fet? 2 s, fooe(-§.5) Function is one-one onto. 18. Lets) = +1, and 2 =x, +0 ‘Now given that Va. eol=lal +12, = fern Ort? = p+ yi + ide yd map +x} + 2mxat Wt E+ aye saps yi+xdeyd + 2V@d + DGG + yD = Gym tyya)= ed + yDOE+ YD = dxdt yiyt + texan dad + yy} + xfyh+ vid 2 mya Ke =0 y; u = ANE tp — arg z= 0 Alternate Solution lat ad=l% 14/4) ‘On squaring, we get lated? =(a]+tate = [a |? #]29)? + 2Re (22) __slaP tle? +21 alle = Re@H)=la lll => [nl | cos @, -62)=1 4221= ,-0,=0 = arg )—arg(,)=0 s9, ee 521) 4 lies on a circle of kw and = lies on a perpendicular bisector of segment with end points, and za, fk =1. 5 and|w/=1 ag Given that w = 2a lel-f al = Tlie on Lbisetr of 0,0) and (, So, zlies on a straight line, Alternate Solution we -and|w 21 3 > 1 = 3}2| =| 32~i] Letz=x+iy 3[x+iy|=13@4H)- = 3G + y4) = ex? + Gy -1F = 9x? + y= 9x7 + Oy? +1 6y led x O+Hx a+ex a+eyx 140 x a+e)x a+@)x +b x ite x 29. fx)= Applying Cy -»G, + C2 +65 ratxrxrb xsxter foelxedxsieBrexscx xe@xexeb rele ex arAx aredy 1B x Gees ase 12x L+@s Breen Arby, eax o[ts@seeeeDx 148 x ate LIB eeDe Cede 42x h ari x aryl sh 1eBe aeeysl f aviyx 1+ex Ry > Ry — Ry, Rp Ry -R, lo ‘o x=] =p 1-x xo] fh aseyx 1+ea| o x1 xa =(-1F = fais of degree 2. 21. The system of given equation has no solution, if j@ 11 a a aj-o h 4 al e+211 > +2 a 1-0 as21a C9040, +65) jbo. a = (@+D/0a-1 0 |-o 0 0 a-1 (Ry > RyRy RyRy “RY = (a+2(a-1% «0 = a=1,-2 22. But a = 1 makes above three equations same. So, the system of equation have infinite solution, So answer is a =~2 for which the system of equations has no solution. Let « and be the roots of equation x? =(@-2)x-a-1=0, then a+Psa-2 and afe-a-1 Now, a? +B? = (a +B) - 2a = +B (a2 + 2041), oP s pad? + 4—aat 2042 3 ate ptad— 2046 = a? +p =@-17 +5 ‘The value of a? +f? will be least, ifa—1= 0. =) ast Alternate Solution S@ @+B=(@-2and B= ~a-1 +B? = (a +B) -2aB = (a-2F + 200+ @ 246 = S'(@=2a~2 ‘On putting f"(@) = 0 for maxima or minima.Now /"(a)=2 = fo q)=2>0 © f(@)is minimum ata=1, 23. Key Idea : If the roots of the equation x7 Fe + c=0 are consecutive integers, then the value of b? — 4cis always 1 Letnand (n + Ibe the roots of x* ~ bx + ¢= 0 thenn + (n+ 1) =band nin+ D=e BB 4e=(2n+ 1? ~ anf +1) = ants dn 1 An? An 24. f'Q= fi Nom, fin, £5.00 fi aaters fared and in Man be fate oniy,iffa)=oand fim, £0, So F's fim AAEM 5 28. Given that, f(1)=~2 and f (0922 & ee dy > 2dx 10 on 22 pe S(6)~ fC) 210 $(6)210+ fa) f(6)28 Alternate Solution 1D suse te vuuuug = S(6)~ fQ)210 : W6s2210 Fm Ul-S0 ewes 26, tin LOLOL ia xy] If iso F'Q)=0 JO) = constant FO)-0 fO)=0, fj)=0 vueued )**-) se a-n? Fb AGG) 3S + higher powers of x. igher powers of x greater than x? can be neglected). Peltards = xe T-a Similarly, i ye Now, o, 6 care in AP = =a ~b ~carealsoin AP. > 1-a1—b,1~care also in AP. Aare in HP. Tee > x,y, sate in HP. Alternate Solution 29.30. aL and = 2rmatb~e (On adding Eqs. (D and (i) = 2¢r+R)=arb Key Idea : eos? x easy cos" Gy F f=? f=¥7). hada? wy? + x8y? = hcos? a + xy? = day cos 4x2 day cost + y?= Asin? Since in ABD : AD = €cos(90°-B) AD=csin B ‘Similavly, BE =asin C andCF =bsin A ‘AD, BE, CF are in HP. s-esin B, asin C, bsin A are in HP, 1 1 Sin€ sin B’ SA SAC’ Sin Bsin A are in AP. = sin A, sin B, sin Care in AP. Alternate Solution 32, ar(4 Be) =} xB «AD 1 2 = acdnaxansan=22 Sinn, BE = 24 anace = 28 + AD, BEC sein HP. 14 Lareinu. = abcareinaP = sin sin, sinG are in AP. Key Idea : Equation of normal at any point (xp 9n)on any curve is py) Given that x = a (cos 6+ O sin 0) ae $= a sin 0+ sin 0+ 0.cos 6) 6 eas 0 and y=a(sin 0-Ocos 0) y > Spr acos 0- cos 8+ Bain dy co = a0sino dys dd de * dx/d0 sap sma cx ontn ($9) ycninovabow= cos §@—a cos 0-0 sin &) eran > sin 0y~asin? 0+ a0 cos sin 0 == x 08 0+ accos? 0+ a Osin Gens 0 > xeosO0+ysin Ona It is always at a constant distance ‘@ from origin. (@) fda x + 6x7 +6 FG) = Se 4 12 =e (e+ 4) ty yt th et 2 xeo,- 90.)36. (b) f(x) 3x? 2 +1 4 4 Tt 3 F'0),=6x-2 = pessovee(t.<) Tiss wrng 1 = cos (ax? + br + 6) oF wees ay @ @ = fin 5 & BY Fey sn? (See-ee-0)) mn -fa ~BF (fe-ow-m) Note : If «and fi are the roots of the equation ax? 4 ox+c=0, then this equation can be rearittenas 2 (¥ ~ a) (x~p)=0. 3 ee -Y (log y ~ log x +1) wy (Ol) Now put =e ix > Borextt 2 ysix = Pacer rat cept te t loge de = dt eit ae Tlogt “x tog (2) =x Key Idea : If, and L, are ovo lines, then the ‘equation of line passing through the point of intersection of Ly and L will be Ly + 2b, = 0. Equation of a line passing through the intersection of lines ax-+ 2by + 3b=0 and bx ~ 2ay ~ 3a=0is 37. (ax + 2by + 38) + Mbx ~ Bay ~ 30) =O...) Now, thistine is parallel co x-axis, so coefficient ofx=0-9 a+ b= 0- 6m puting his vale in, (we ge Mardy 3). ade ky 30 = Wy + ab + dty + Ba? =0 > 2G + ayy + 30 + a4)=0 - yd 3 href th ete ine blow wi 2 disace$ fom Alternate Solution Equations of given lines are ax + 2by + 36=0 and be ~ ay ~3a=0 (On solving Eqs. (f) and (i), we get 3 oy a i) : rnc efmesecon tis 3,2) As ei ies pel mo © ean oni (r5)-00-0 3 > ya} ‘Thus the requised line is below x-axis at a distance 3 from x-axis. &0 55 eaduin Given thac «50 en /mis er 50h ayia >) e™ log =1 J a Cer dogs} +1-2108% gy + dog xy F “Ja, ! Required area A= f° log, G+ bd Ocxel xel 4. 44. Putx tent de=de As ff loge dt =[t loge =(¢-e-04 a1 Key Idea : Area of region Bounded by y* = 4ax and y2 = Aby is 192 oq unit. Now, y= S)= ee Key Idea: Centre of sphere sta yha sy duce Bye Due d=0 Cu, -w), Equation of first sphere is 22+ y? 2? + 6x ~By—22=13 whose centre is (3, 4,1) ‘and equation of second sphere is xP yP4 2? 10K 4 4y— 22-8 whose centre is (5,~2, 1), ‘Mid point of -3, 4, 1)and (8, -2, 1)is 1, 1. Since, the plane passes through (1, 1,1). 2a-3a+ 4a+6=0 6 >a--2 i)4. Lines parallel to plane as 2,1 =e akr-ds sje hy=0. Bre ene point on the tine is So Staght Ine X+ + 2-0 aways pases G12, 42,4443). For h=0 a point on a this line is (2, ~ 2, 3)and distance from ‘through a fixed point a 48. Key Idea! If AGy, 91), Bp ys) and Fede jek )=5 or x4 5y+e05 Cvs, ya) are the vertices of a triangle, then the gef2tScar3- coordinates of the centroid will be a (Stages tpt) bra 10) aan Let and ae mid pons of AB and AC. So co-ordinates of B and C are (~3 3) and (5 3) 46, Since (@ xi)-@ xi respectively xO =1aP- e120 ee Similadly, (@ <3? =|8P- and @ «fey =[2P ‘en ‘cs3) Gxif s Bait + @ xe? Centoid of triangle ‘ 5 : w (atte e ye yetys =31 8? -@l + of +) -( . 3 ) 9/8? -1aP -(ope Ee) =2/a)* 28? ef, 2 pvmont toto 03) 49. Key Idea: If$, = 0 and; = Oare two circles, ie Misqinad tsk then the equation of line passes through the repegeded fa Bence oa et nd Bai-(ai addr afontd uation of eles are aka Sesteyi ede ve tes Gxiveded and S; =x?+y?~3ax+ dy-1=0 Rxdted respectively. Similetty, (@ xFP = a + af Chord through intersection points P and Q of and @xyPeohe the cirdes §, = Oand S, = O18 5, -S, = 0 Gai Sax+(e-dy+a+1=0 Baie + Bad + 0) ‘Thisequation represents parabola. Thus locus of the eenreof the cree is a parabola. Key Idea : Tivo circles ey? + Axe Byt gad and x24 y? 4 2px Ory sq 20 orthogonal, ten 258s Bilan 4 +6 Let the circle is x* + y? + 2ex + 2fy +e=0, Ircuts circle x* + y? = p* orthogonally, si. So, c= p? and it passes through (a, b). a +b? + 2ga4 2fb+ pi =o So, locus of (- g, - f is @ + 2ax ~ aby + pao 2ax + aby (a + B+ py <0 Alternate Solution lat the centre of required cil i 8, /, This citcle ext the cele x#492= pe orthogonally. The cente and radius of circle 2° y= pt are(@, O)and p respectively, 4 fopte (argh +4 fF mgs flap sats 92+ 20g 4 + f+ bf = pleats BP 4 20g + 2bf =0 “Thus the loeus of entre fs Zax + 2by ~(@+ P+ =O sa, 52. ZEBF = 90°%=> OBR’ = 45* Alternate Solution = and are Gd of an eps, whose co-ordinates are (ae, O)and (ae, O)respectively snd cordnaes of Bae 9 _ Spe ofa = and ope of8F'= 10h 290° 28 a1send Key Idea : A line y mms + is tangent to Iyperbla % Yat, peat? = Line y = ox + Bis tangent, = au? — 2. So locus of (a, f)is y? = a?x? — BF yb Since this equation represents a hyperbola, s0 locus ofa point P¢a,P)is a hyperbola. Since the angle between the line and plane is same as angle between the line and normal to the plane sin 9= G+ 2)+ 2h. Basieh > 2 Be Ke Ee57. between a and line plane apts By tat + dy = Os given by [ate + bbe + ore reed fale oe “The given equations can be reviten as sino=| 3 + Angle between the nes is ven by “Yara 36 Vas Ite 9 o = =o VavisT 3 0='90° Note : Ifa, ,.6, and 3).B.¢2 are d's. of two lines thon the angled between them is given by 8, + Bd + cP a ee Ae I Given that aon.) 1 payed PACE) = 1, PANB)= 4h P~= + 1 = vam! = 1 a)=Pee manD=} ; é 1 3 = PO)= 5 and P(Ay~F Clearly P(A.B)= P(A) PB) so the events A and B are independent events but not equally likey. Note : Two events d and B are sei to equaly likely, P(A) = PCB) and known as independent ceronts, PAB) = PAPE) Person 1 has three options to apply. Similarly, person 2 has three options co apply and person 3 has thre options to apply. ‘Tora cases = 3° Now, favourable cases = 3 (An either all has applied for house 1 oF 2 or 3) Sommabtiy= 3 =}, 88, Key Idea : In a poisson distribution, P(x =n) (= mean) P(X =1>1.5)= P(2)+ PB)+...0 =1-(PO)+ PA) 442272), 3 2) 3 59. Key Idea : is initial velocity of any parle ‘and ai aceleration, then veusat where vis a speed of particle after seconds, Wehave van f+ m) vast Now, vente 2 fe= seem Sen pita 1 sage oo) neato mare (vi) 1 fU'eF 1 pe ene Ore SR FFF (vii) ae (vii) ‘So from Eqs. (vii) and (viii) fmt Buf Gu TE = fin =anc f’=f) 660. Let zard catch the insect © and distance covered by insect ~$ time taken by insect, ¢ = 5 @ Distance covered by inard = 21+ 5 esha. = 214-20 =¢? (using Ba. () = ~ 20-21 = feaner-21 > t-21)+16-2)=0 So @ene-2n=0 = t=218, 61. Key Idea : If Ris a resultant oftwo forces Pand Qacting on a particle, then RsinB ogg a Reina Bite +B) Sin(a + BY62, Q ven thatR = 2 JAC +h) Aa +b) Nay + b,)} rene § oa. POS MG? GE a Raine aq. Bin 90° | ie | 4 byte Byte by > bby ds! & G) So, no real value of 4 exists, Alternate Solution DAH 2B. Bes BB 2 MELB) CBD AB G+) BRB. BBE > BRB xe) > He oF = No real value of h exists, 65. Let the resultant of A and B is displaced by x. ‘Then change in net momentum of A and B= applied momentum, fet Bead ft - A+B ApBlvingCs Cy #6 66. Welnow that six 11 | iy x 14x] ™ ry oft ited =10+x)-x=1 ‘Thus{X Be] does not depend upon neither x Key Idea : if three vectors &,B and @ are coplanar, then BB )=a, ‘The given points lies in a plane, if athe ase Lei a es gL 67. Ya>0. 1.2.3. nth arent en ao i a 2A glo ‘Mot rahpower> mah omer of Attn Shes ab 0, Therefore cis GM of a and b. tay (ttt '68. 69. Given BAY ‘W is making an angle 60° with horizontal Capwards) ‘Therefore V should be at 30° with horizontal (downward) as shown in fig. Ser 7. Key Idea : f both roots of ax? + bx +6= are less than a, then b?-4ac20, f(a)>0 and ie Hix Let fxaxt Dec + Ka k= 5 73. a x Da ak? 4k? + k-9) == 4k+ 2020 = kss ea) ® Also <5 and f(6)>0 From (ii), k< 5 From (ili), 25~ 10k + k? +k -S>0 > Kk? -9k + 20>0 * Ke = Sk ~ 4k + 20> 0 > (k-S)(k-4)>0 a k<4 andk>S w) From (i), (Hii) and (iv) = ke4 Since, 0). 03y0--, Ogres ate OPathen Loa 1085119844. 31-1 FORGy em aE i ». a atd aad So, Aslarad avad a+ 5d jas 6d a+7d a+ 8¢] aontying GA jad asad d 2i)-0 jas oa a 2a] (Since two columns are similar) Given f(x — y)= f(2) FO - fla~ x) flay) Let y = f@=F@x-Gor = 1=1-G@yr = feay=0 Ja~ x)= fla~(x-a) = f@ f(x-a)- fla~@) fx) o- fey feta e=G, Faraz + (n= Day tt =0 So definitely its derivative is zero between O and So, f(x) has a positive root smaller than & . of SEE a, aso oof tT fF a “ ref, SEX ae wot hee On adding Bas.) and (id a eft bate? * Gea)74, . oft cox 75. Equation of pal of tines is 21m fT cot x de ax? + 2(0+ B)xy + by! =0 eae f (SF a Since 4am = On a [e@ 2, a ‘Angle between lines is given by all" **)] = aeleen = one Since the centre of sphere tye axeee 2 AB tan = Ta al radius of sphere I ft, = = 2a by -ab ange tee Tae Distance of plane from centre of sphere = dab + 2ab=4(c? +B + ab) = 3a? + 38? + 2ab=0 3 F4e1) ve So radius of circle = 1-2 2 BOn18_ fr ae