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碳氟表面活性剂在分光光度分析中的应用iii:全氟辛酸钠 (speo) 溴化十六烷基三甲铵 (ctab) 混合胶束微环境的性质
碳氟表面活性剂在分光光度分析中的应用iii:全氟辛酸钠 (speo) 溴化十六烷基三甲铵 (ctab) 混合胶束微环境的性质
48, 365-371
III. (SPFO)
(CTAB)
. CTAB SPFO
. SPFO CTAB .
(SPFO 07F15000Na)
C1: So(III) EOAB( 6B)-SPFO-TPB( )~
105L.mol-1.om-1)C1\ Al(III)-EOAB-SPFO-OTAB
(pH5.08x=660n 8tJonm =2 .58 x 105L.mol- 1 .om- 1) .
(pH5.76 max = 643 e~3 =2.72 X
SPFO-c-Sf( ).
Al(III)
1 6- 3 (DPH) SPFO
OTAB . DPH p
;.
. Ohaopadhyay DPH
CSJ
DPH DPH
DPH .
JlIJ
PBS():
0.15mol.L-1NaOl,
pH 7 .2. DPH(Sigma ): 1
2x10- 3 mol.L-1Hs P0 4
x 10- s mol.L-l .
850
:.
:
10 mL 1 mL 2 x
PBS
25 0 lh .
llS8 4 7 . II 1989 8 ( 5. .
.366.
ACJrA
CH MICA
SINICA lYIN
DPH
DPH
( 2 0)
. DPH
.
4.0
3.0
"
'"
2.
c
1. 0
200
2
~
400
420
/nm
440
460
300
'AAn
L=?
4HNom
---AHU
"hd
AU
600
DPH PBS .
3 Dioxane-HIIO DPH
.DPH
. d
120
E41.
8 d DPH
p d 20 DPH
..
90
.3
60
40
DPH
. 2 DPH CTAB
SPFO-CTAB
30
DPH .
o
3
20
40
60
80
Dioxane(%. w/w)
100
Dioxane-H~O DPH
-CTAB
ex359nm em430nm
DPH
4 DPH C'l'AB
SPFO-.OTAB . SPF-CTAB
CTA:B DPH
OTAB . Al(III) - EOAB-SPF-OT AB
20
4
40
60
t/min
80
100
.387.
120
DPH
0
ex 859 m em 430 nm , 25
2.5x10- 8
DPH
Al (III) - EOAB-OT AB .
6 DPH
I ; I1.
0.30
P 25 50min
P DPH
.
25 0 1h
20
SPF -O TAB
DPH 6 OTAB
5xl0- 4 4x lO- s mol.L-l
CSPll'O:CTAB CSPll'O:
CCTAB 1:1 P
-OTAB NaOA<rOTAB
DPH 6.
6 NaOAo
OTAB P
. SPFO OTAB
SPFO -F E
.
-OTAB
-H OTAB
CZICCT
CTAB SPFO
NaOAo DPH
DPB:
nm.
COTAB ,mol.L-l
1-5x LO-4
2-1x10- 3
3-2x10-S
4-4 xl0- S
5-4 X 10-8
6-1xl0-S
7-2xl0-8
-4: xl0-'
SPFO;
SPFO;
SPFO;
SPFO;
NaOA
.. 888.
ArA
. NaOAc
CTAB .
ESR
(ES.""
ESRi
. ESR ESR
C6J
p .
5NS SPFO-CTAB ESR
1 (:)( 10
6J
1
?
z6.51o[(r
e ;
. p ;.
.
b
Ilr.
5NS(SYVA ) :
1mL 3
p
12h ESR .
'1
.&.
,/
'1
5NS
Dioxane-H.20 ESR .
Vpjane:VHO'
323-
LL
.,
v- -
7 5NS ESR
a.
Sx10-Smol.L-~
OTA.tl
b.1 ;-Bmol.210TAE
X 10-4
mo 1. L-l 8PF;
::ZZEZE.
5 N8: 2 x 10-5 mol. L-l
ESR
7c 5NS ESR
. (1 % 5NS
. C'l'AB SPFO-CTAB (
'7 a b) ( 7 5NS ESR
C02H
11e .
.389.
SPFO E52
OTAB .
OTAB .
NaOAo SPFO OTAB OTAB
Q Fourier
lH
19F
lH TMS p (HMO)
'li
cf{ctzh-(ctzvcF24f0
ONa
-10
20
-30
4/ppm
-40
50
-' "_J
CT AB--SPFO 19FNMR
8PFO: 0.025mol.L-l;
'AB: a. 0; b. 2.5x10-'mol.L. 1. 25x10- 8 mol.L
d. 2.5xl0- 8 mol.L-l;5 X 10-8 mol. L-l
NaOAo SPFO.
OTAB
.a70.
k'
_j
..
-N(CH
a
3.0
2.0
1.1.)
8/ppm
CTAB-SPFO lHNMR
NaOAc .
OTAB SPFO
SPFO OTAB 3
OTAB p 3 .
.
[1]
1990 8 ( 7
t: 2]
1989, 8( 5.
[3 J Ohattopadhyay, A.; London. E" Anal. Bioch87Tl. , 1984, 189, 408.
[4 J Akhada, Y. DieZectric Prerties 01 Biry SoZution , Oxford, Pergaman
[5J 1984(1) , 1.
(6] " 4". 1980.
Pr:
N. Y.,
11
p. 285.
ArA
.371.
IU. The
Microenvironmen1 Proper;ies of e
Sodiu Perfluorooctanoae
(SPFO) and
Mixed Micelle of
Cylrimehylammo:ium
Bromide (CTAB)
Li, Min Zheng, Yong-Xi.
(Depf emist'1' Tsight(J Umve'1'S Beij-'g)
Abstra o1i
Our previo rep
or
have
ind
ia
$
ed
hat A
l(
E
IH
o
r
So(
m
))-EOAB(Erihrome
zurol
B)-SPFO-OTAB(pH=5
)8
ystem
i8 a SUp
erB
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