omeca

Model Test-04 (Exam Code: 1904)

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omeca
Solution Of Model Test-4

01. GLvb, + = p Ges = q

q
q
2pq q( )
2pq pq

2
2
p
p p p p( ) p p 2 q

q
q
q2
q2

2
2
q AZGe, wbYq mgxKiY, x2 px + q = 0 hv c` mgxKiY| (Showed)
p p p p( ) p p 2 q
q

[j Kwi t wbYq mgxKiYi c_g g~j =
p

Ges

wbYq mgxKiYi wZxq g~j =

G KviYB bZzb mgxKiY Ges c` mgxKiY GKB| ]

p
r

x
x

02. 3 Gi weZwZi (r+1) Zg c`, t r 1 n C r .3 n r n C r .3 n r .2 r .x r

2

2
n
7
8
n
n 7 7
x Gi mnM = C 7 .3 .2 Ges x Gi mnM = C8 .3n 8.2 8
n

kZgZ, n C 7 .3n 7.2 7 n C8 .3n 8.2 8

n!
n!
3 2
7!n 7 !
8!n 8!

6
1
n 7 48 n 55 (Ans.)
n7 8
1 x 1
1
03. tan1
tan x
2(1 x 2 )
1

x
2

4
x
1

1
2 tan1
tan x
2 2x 2 4x 2
1 x
6x2 =2
1 x
2.
1
1
1 x tan1 x
x2 = x
(Ans.)
tan1
2
3
3
1 x
1

1 x
04.
A+B+C=1800
sinB=4sin3B

A=3B, a=2b
a
b

sin A sin B
2
1

sin 3B sin B

1
4

1
sinB= B=
2
6

sin2B=

6 2
6 3 2

(Ans)
=
6
6
3

A= , C=

sin3B=2sinB
3sinB4sin3B=2sinB
05. hnZz ewU x AK (4,0) we`ywU k Ki|
myZivs K`i x vbvsK = 4 Ges
K`i y vbvsK = ei evmva
awi K`i y vbvsK = k
ei mgxKiY, (x4)2 + (yk)2 = k2
x2 + y2 8x2ky + 16 = 0
y Ai LwZ Ask = 2 k216)

Y
(4, k)
(4, 0)

(4,k)

ckg Z,
2 k216) = 6 k2 16 = 9
k=5
wbYq ei mgxKiY, x2 + y28x 10y + 16 = 0 (Ans.)

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Model Test-04 (Exam Code: 1904)
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| x y 4|
4 1
06. (x 1) 2 ( y 1) 2 e
e=
16 4
2
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2(x2+y22x+2y+2)=e(x2+y2+8y+162xy8x)
8(x2+y22x+2y+2)=x2+y28x+8y+162xy
2(1+12+2+2)= e(1+1+8+1628)
7x2+7y28x+8y+2xy=0 (Ans.)
1
1

07. SA a
2
2
2
1 1
x y +1 =
awi, w`Kvi mgxKiY, x y + k = 0
Z
0
00k
1
2a 2.
DcK` _K w`Kvi `~iZ,
K=2
A
2
12 12
S (0, 0)
w`Kvi mgxKiY, x y + 2 = 0
2
2
2
2
2
wbYq mgxKiY, {(x 0) +(y 0) }(1 +1 ) = (x y + 2)
(x + y)2 = 4(x y +1) (Ans.)
x
y
x y
x y
x y
08.
+
=1I +
= 1 iLvi Q` we`yMvgx mijiLvi mgxKiY, 1 + k 1 = 0
a
b
b a
a b
b a

1 k
1 k
x + y (1+K) = 0 ...... (i)
a b
b a
x y
1
(i) bs iLv I +
= 1 iLvwU Awfb ne hw` ;
=
h k
h
1 = 1 + k k = 0 .............. (N) ........... (ii)
1
1
1
k = 0, (ii) I (iii) G ewmq cvB,
= Ges
=
a
h
k
1 1 1 1
(Proved)
a b h k
n

09. x y y x log x y log y x

n.y n 1.

1 k
1
1
k
+
Ges
=
+
Ges 1 = 1 + k
a b
b
k
a
........(iii)
1
1 1 1 1

b
h k a b

y n log x x n log y ...................(i)

dy
1
1 dy
log x y n x n
log y.nx n 1
dx
n
y dx

yn
nx n 1 . log y
dy
dy y n 1 nx n log y.y

nn

[je I niK xy viv Y Ki]

dx x
dx x n 1 n.y n .x log n
n 1
ny . log x
y

dy y n 1 n log x 1
dy y n 1 n.y.y n . log x

[from
(i)]

(Proved)
n 1
dx x n 1 n log y 1
dx x n.x.x n . log y

10. awi, I
1
=
2

x2 1

1
2

1
2

1
2

1
x
dx
1
2
x 2 1 2
x

p = x
I =

dx

( x 2 1) ( x 2 1)
x 4 x 2 1

1
2

1
x
dx
1
2
x 2 1 2
x

dx

1
2

x 2 1
4

x 2 1

1 2 dx
x

1
x 3
x

dx

1
2

x 2 1
4

dx
x 2 1

1 2 dx
x

1
x 1
x

1
1
1
1
nj, 1 2 dx dp ; q = x+ nj, 1 2 dx dq
x
x
x
x

dp
2

1
dq
1
x 2 1 1 x 2 x 1
1
p
1
q 1
tan 1
ln
c
=
tan 1

ln
c
2
2 q 1 2 3
3 2.2 q 1
2 3
3 x 4 x 2 x 1

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Model Test-04 (Exam Code: 1904)
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11.

dx

1 sin x cos x

dx

2 x
1 tan
dx
2

x
x
2 tan 2 tan 2
2
2

x
1 tan 2
2
1

x
1 tan 2
1 tan 2
2
2 tan

x
2
x
2

d tan
2

=
x
x
tan 1 tan
2
2

x
x

d tan d tan

x
x
2
2

ln tan ln 1 tan

x
x

2
2

tan
1 tan
3
2
2

1
1
3 +1
+ ln 1+ = ln 2 (Ans.)

3
3

5C

7C
P w 7 1 5 ; P w 10 1 7
C1 7
C1 10
B1
B2

= ln 1 ln2 ln

12. Here,

P(B1) = ;

P(B2) =
w
P
B2

.P( B 2 )
B2

w
w
w
.P( B1 ) P
.P(B 2 )
P
B1
B2

7 1

49
10 2
=
=
(Ans.)
99
5 1
7 1

7 2 10 2

13. (i) 5C1 4C3 = 20

h cKkjx (5) Zwor cKkjx (4)
(i)
1
3
(ii)
2
2
(ii)
3
1
14.

PC

(ii) 5C2 4C2 = 60

(iii) 5C3 4C1 = 40
gvU Mc msLv
= 20 + 60 + 40 = 120

2r 2 r 2

3r
W
R
T
W R T
W
2W
GLb,

R
PC PO OC
r
2
r
3r
3
3
W
2
, T
R
W (Ans.)
R
3
3
PC

2r 2 r 2

C
T r

B
r
O r

3r

W
R
T
W R T
W
2W

R
PC PO OC
3r r 2r
3
3
W
2
, T
R
W (Ans.)
3
3

GLb,

15.

gb Kwi, euvki IRb W

P LyuwUZ Pvc W1 Ges evSvi IRb euvki gawe`y O|

W1

O we`yi Pviw`K vgK wbq,

W1.OP W2. OR + (W1 + 325).0Q = 0
W1 4 W2(4 2) + (W1 + 325)4 = 0

W W2
PR = 3RQ
Avevi, PQ = 8

W2 + 325

2W2 + 4 325 = 0

PR + RQ = 8

W2 = 2 325 = 650 gm Wt

PR = 6 Ges QR = 2

evSvi IRb = 650 gm Wt (Ans.)

OR = OQ RQ = 4 2 = 2

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Model Test-04 (Exam Code: 1904)
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16.

Let, Avw`eM = u

gb Kwi, _vgvi c~e n wU Zv f` Ki|

02 = u2 2fnx. 2fx n = u2

u 9u

GKwU Zv f` Kivi ci eM = u
10 10

awi, Kb f Ges Zvi cyiZ x

2

81u 2 19u 2
9u
2
2

u 2fx 2fx = u
100
100
10
i j k
17. AB AC 3 2 1 3i 11j 13k
5 1 2

100
19 2
2
= 5.26
n = u n =
19
100

5wU Zv f` Kie| (Ans.)

AB I AC K mwbwnZ ev ai AswKZ mvgvwiKi dj = AB AC = 3 2 112 132 = 299 (Ans.)

18.

L.S = fog(x) = f

x 3 3 x 3
=2
3= x 3 +3 = x
2
2
1

R.S = gof (x) =g(2x3+3) =(x3) 3 = x

19.

L.S = R.S (Showed)

aib = (x33xy2)i(3x2yy3)

(a ib) x iy

a+ib = x3iy3+3x2iy3xy2
= (x33xy2)+i (3x2y y3)
a=x33xy2 ; b=3x2yy3

20. Mean1= 100/5 = 20, Standard Deviation =

Mean2= 103/5 = 20.6, Standard Deviation =

= x33x2(iy)+3x(iy)2(iy)3
= (xiy)3
a ib x iy (Showed)

10
1.414
5

29.2
2.42 > 1.414 So, YEAR 2013
5

1
1
1
1

(1.5 1)

v 0.50
0.40 0.40

v
v = 0.80 m (Ans.) Again, m =
1.6
u
dN
I curie = 1Bq = 3.71010 decay / sec
22. Here,
N = 8.5834581013
dt
T = 26.8 min = 1608 sec;
But, When N=6.0231023, m=214 gm
21.

1 1
1 1 1
1
v u f
r1 r2

ln 2
]
T 12

= 4.310610-4 sec-1 [ =

dN
N [without considering sign]
dt
3.71010 = 4.310610-4N
23. gb Kwi PzovZvcgvv = T2

When N = 8.5834581013,
214 8.583458 1013
gm
6.023 10 23
N = 3.0497410-8 gm

Again,

Avgiv Rvwb, T1P1

P
T2 1
P2

T2 P2

T1

11.4

1.4

2
=
1

288

m=

T2 = 236.260K
myZivs Zvcgvv cwieZb
= 236.2602880
= 51.740
myZivs Zvcgvv 51.740 Kge|
(Ans.)
4

P1 = 2 atm
P2 = 1 atm
T1 = (15+273)
= 288K
= 1.4

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Model Test-04 (Exam Code: 1904)
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24. nA ~ nB = 5 ; i kjvKvi fi evovj Kcv nvm cvq| G Kcv nvmi mv_ mv_ exU msLvI Kg hvQ|
AZGe nA>nB. nAnB = 5 nA256 = 5 nA = 261 He (Ans.)
P R
P
10

25. Avgiv Rvwb,

R S =
10 = 8.33
P = 10 , Q = 12 , R = ?
Q S
Q
12
S = 20 || 20 = 10
C0
3 108
26. eidi cwZmivsK nj

1.304
C
2.3 108
1
1
sin c
0.767 c sin 1 0.767 50.050
1.304
27. h 1 h 2

2T 1 1 2 (7.3 102 ) 1
1
3

2.4805 10 m 2.4805 mm
g r1 r2
1000 9.81 3 103 6 103

28. Here, E = 16t 0.04t2

(i) When, t = tn,

dE n
0 16 0.08t n
dt
16
tn =
= 2000C
0.06
C1 4 r1
Q
29. C1 =
= 61013

V
C 2 4 r2
C2 = C1

r2
r1

(ii) When, t = ti,

Ei = 0 = 16 ti0.04ti2
16
400 0 C (Ans.)
ti =
0.04

2 r13 = r23 ; r2 =

Q = Q 2V =

1
( 2) 3

r1

C2 = C1

1
(2) 3 r1

r1

= 7.561013

2Q
= 793.7 V
C2

30. G cvwbi wwZkw = icvwiZ we`yr kw

Pt
= 10204kg [G mgq, t = 1sec]
gh

mgh = Pt m

31. KvVi UzKivi cwZwUZ AaK kw LiP nq| GKwU Zv `qvji mvgb mshy _vKj m AaK kw Zvi

LiP ne Ges evwK AaK kw LiP ne `qvj cek KiZ|

20

AaK kw LiP Ki `qvj 2 = 10 cm cek Kie| (Ans.)

32. = + +

+ 2 2

= + 2 2 = + 2 2 = = 1

33. Avgiv Rvwb, m1 v1 m 2 v 2 mv

18 0 12 v 2 30 48
v2

30 48
120 ms 1
12

34. Avgiv Rvwb, E T 4 T 4

GLvb,
m1 = 18 kg
m2 = (3018) kg = 12 kg
v1 = 0 ms1 ; v=48 ms1 ; m=30 kg

1000
E
T 363.71K (Ans.)
=

5.7 108

35. (i) x(t = 2) = 6cos(32+/3) = 3m (iii) f = 2x = 923 f = 272 m/sec2

(ii) Here, A = 6m, = 3, x = 3m

v(t = 2) =

A 2 x 2 = 3

36 9 v = 93 m/sec
5

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Model Test-04 (Exam Code: 1904)
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36. (a) Avgiv Rvwb,
V A2 x 2

(b)

1
2

E KA 2

1
2
2
3
A 2 42
1
5

4

(m 2 )A 2
2
2
4
2
A 3
2
2

1
9 A 16
(50 1) 5 2 = 54

2
2
16 A 9
(Ans.)

E = 625 J (Ans.)
A = 5 (Ans.)
10
VP V B 0.80 10
V
37. B = v v = P =
= 40; v = 40
8
2 10
Pvc `qvi c~e fi = Pvc `qvi ci fi
V
=
V
V V 40
V 39V
ev, =
=
=
= 11.692 103kgm3
V = V v = V
=
39
40
40
V 39
V
40

38. y = y1 + y2 y = 20 sin t + 21 cos (t + 6) y = 20 sin t + 21 sin (t + 3)

1

Here, Phase difference = 3 A = 202 212 2 20 21 cos = 35.511 m.

3

= tan

20 sin

3 = 0.5095c y = 35.511 sin (t + 0.5095c)

21 20 cos

39. 680 nm Zi `Ni Kgjv iOi Avjvi GKwU dvUbi kw,

E hf

6.631034 3 108
hc

J 2.925 1019 J

68010 9

40. (i) Fm = q V B

2.925 1019
eV 1.828 eV
1.6 1019
`Lv hvQ G cwigvb mvwWqvgi KvhvcK Acv Kg|
ZvB, AvjvK Zwor wqv c`kb Kie bv| (Ans.)
E

(ii) Accordingly,
Fcp = Fm
mV 2

qVB
r
31
5 10 7
r = mV 9.1 10 19

= qVB [ V B]

= 1.610-1951070.5
Fm = 41012 N (Ans.)

qB

1.6 10

r = 5.6875104 m

[ q = 1.610-19 C; V = 5107 m/sec]

B = 0.5 T

0.5

(Ans.)

41. (i) Green (Green color has the most wide range 500-575 nm among the all visible colors.)
(ii) cvb wmwiRi n1=3, n2=4

1
1
1
1
RH 2 2 109678( 2 2 ) 5331 569 cm 1 1.8756 104 cm

3
4
n1 n2
1

42. (i) AgCl Ag+(aq) + Cl (aq)

ini: Solid
0
0.01
equi: Solid-s
0+s
0.01+s
Ksp= [Ag+] [Cl]

1.8 10 10 s (0.01 s)
[ 0.01>>s, 0.01 s 0.01]
10
8
1.8 10 s 0.01 s 1.8 10 molL1
8
1
1L NaCl `eY AgCl Gi `veZv 1.8 10 molL
(ii) Ksp=s2 s 1.8 1010 s 1.3 105 `veZv nvm= 1.3 105 1.8 1010=1.3 105
6

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Model Test-04 (Exam Code: 1904)
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V
100
10
0.1098 g
(V K D S )
(100 100 90)
1
100 ] Separated amount= (100.1098) = 9.89g
[With respect to Acetone, K D
0.01
44.
N2
+
3H2
2NH3

43. W1 w

t = 0:
t =t:

1
1x
10.25= 0.75

4
43x
430.25=3.25

0
2x
20.25=0.5

0.52
1
2 0.1553mol 2 L2
3
0.75 (3.25) V
45. (a) 0.01 ml 1 M H+ H 0.01 1 2 10 4 P H log( 2 104 ) 3.69
24.99 25
0.1 1
(b) 0.1 ml 1 M OH OH
2 10 3 POH log( 2 103 ) 2.69
24.99 25
KC

PH = 142.69 = 11.30

[ NH 4 NO3 ]
[ salt ]
8.54 log(1.8 10 5 ) log
[base]
[ NH 3 ]
[ NH 4 NO3 ]
[ NH 4 NO3 ]
[ NH 3 ]
log
3.796
103.796
1.6 10 4
[ NH 3 ]
[ NH 3 ]
[ NH 4 NO3 ]
47. H = H (1 C-H + 1 Cl-Cl) H (1 C-Cl + 1 HCl)
= (410.03 + 238.49) (326.35 + 426.77) = 104.6 kJ
48. (i) NO2+ > NO2 > NO2
(ii) 26Fe2+ : [Ar] 3d10 4s0 Here d2sp3 hybridization is present and all electron are in pairs. So
diamagnetic.
49. (i) 2Br + Cl2 Br2+ 2Cl chvq mviYxZ Cl2 Mvm Br2 Gi Dci AewZ| myZivs Cl2 Gi mwqZv Br2
Acv ewk| ZvB Cl2, Br cwZvcb Kie|
(ii) F2 + H2O HF + O2
Cl2 + H2O HCl + HOCl
Br2 + H2O No Reaction
I2 + H2O No Reaction
1000W 1000 1000

55.56mol / L
50. S
M V
18 1000
1000W
51. e1V1S1 e2V2 S 2 2 V1
1 25 0.1 W 0.1325 g
106 V1
0.556
100 29.56%
Impurities = 1.8810.132510 = 0.556 g So, % Impurities =
1.881
52. 2 NaCl
Na + Cl2
e1V1S1 e2V2 S 2
2(23+35.5)
35.52
1000 1.2
117g
1 V1
6 V2 0.05
58.5 V1
117g NaCl produces 71g Cl2
71 1.2
V2 68.37ml
g 0.728 g
1.2g NaCl produces =
117
[Drcv`]
E Fe
8.316 298 1 = 0.77 + .0414 = 0.729
RT
E Fe
53.
ln
ln [wewqK] =0.77
3 =
3
Fe
Fe
1 96500
5
F

46. POH = PKb + log

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Model Test-04 (Exam Code: 1904)
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54. (i) Anode : Pb + HSO4 PbSO4 + H+ + 2e

Cathode: PbO2 + H+ + HSO4 + 2e PbSO4 + H2O
(ii) Atomic mass of Li is 7, So very lighter in weight.
55. Molecule in 16g CH4 6.023 1023 Nos
6.023 1023 0.16
Molecule in 0.16g
6.023 10 21 NosMolecul e 6.023 10 22 Nos electron
16
[10 electrons are present in 1 CH4 molecule]
56. 2 mol nvBWvRb Mvmi gvU MwZkw =
=

R = 8.314 JK1 mol1

2 [n=2]

3RT
2

3 8.314 298
2 7432.716J = 7.4328 KJ
2

Avevi, cwZwU AYyi Mo MwZ kw =

T = 25+273 = 298 K

3RT 3 8.314 298

2N
2 6.02 1023

4 Mvg nvBWvRb =

4
= 2mol|
2

= 617.3351023 J
57.

300C
(a) 2CCl4 + 3HF CF2Cl2 + CFCl3 + 3HCl
(C + FeCl2)
(b)

N2

HO3S
HO3S

N2Cl +

+ HCl

OH
OH
H O

C HO + H2N R
HC = N R
cvBgvix Avwgb
wmd viK

58. (a)

H O

CHO + H2N

HC = N

AvivwgwUK cvBgvix Avwgb

(Avwbj hM)
(b) (i) [OC(CH2)8CONH(CH2)6NH]n + 2nH2O
(ii) [OCH2CH2OC

59.

C+2nH2O]n

KOH(aq)

Mvp H2SO4

Mvp H2SO4

HCl

KCl

H2O

150C AwaK AvjKvnj

(i) CH3CH3+Cl2 CH3CH2Cl CH3CH2OH CH3CH2OSO3H CH3CH2OCH2CH3 + H2SO4.

(ii) CH3CH2OCH2CH3 + PCl5 2CH3CH2Cl + POCl3.

60. i)

CHO

NHNH2
CH=NNH

CH3

COOH
(ii)

+ NaOH

+ H2O

CaO
1H2O

CH3Cl
Dry AlCl3