Q no 1

(a) moles of CH3-CH = CH2 reacted = 1.4/42 = 0.033 [1]

maximum moles of CH3-CH(I)-CH3 that could be formed = 0.033 [1]
maximum mass of 2-iodopropane that could be formed = 5.61 g [1]
percentage yield 4.0/5.67 x 100 = 70.5% [1]
(b) iron + nitric acid iron nitrate + hydrogen [1]
2 (a) impure copper [1]
(pure) copper [1]
(soluble) copper salt or Cu2+ [1]
(b) Cu - 2e Cu2+ or Cu Cu2+ + 2e [2]
(c) (i) cathode [1]
(ii) pure foil: gets further copper deposit/increases in thickness/gets less shiny [1]
impure foil: copper removed/decreases in thickness/appears cleaner [1]
3 (a) carbon has gained oxygen from iron (III) oxide[1]
(b) (i) carbon monoxide + water carbon dioxide + hydrogen[2]
(ii) 80 [1]
(c) (i) chlorine gas[1]
(ii) zinc metal [1]

4 molten potassium iodide

NOT aqueous

[1]

hydrogen
oxygen
water used up or solution becomes more concentrated or sodium chloride remains
NOT no change
If products are given as hydrogen, chlorine and sodium hydroxide then 2/3

[1]
[1]

copper
oxygen (and water)
sulfuric acid

[1]
[1]
[1]

accept hydrogen sulfate

aqueous or dilute or concentrated potassium bromide

accept correct formulae

[1]

[1]

5 (a) 72/24 = 3 and 28/14 = 2

Mg3N2
accept just formula for [2] even with incorrect or no working
NOT ecf

[1]
[1]

(b) Al4C3 + 12H2O = 4Al(OH)3 + 3CH4

For Al4C3 ONLY [1]

[2]

(c) (i) silicon is limiting reagent

0.07 moles of Si and 25/160 = 0.156 moles of Br2
because 0.14 (2 0.07) < 0.156
If 80 used to find moles of Br2 the mark 1 and 3 still available
arguments based on masses can be used

[1]
[1]
[1]

(ii) 0.07
NOT ecf

[1]

[Total: 8]

6 (a)

1st, 3rd and 4th boxes down ticked (aqueous sodium chloride, copper and graphite)

[3]

(b) insulator

[1]

(c)

(i) anode

[1]

(ii) negative electrode: zinc

positive electrode: chlorine

[1]
[1]

(iii) graphite
allow: carbon

[1]

7 (a)percentage of oxygen = 31.6% [1]

(b)calculate the number of moles of atoms for each element
number of moles of Ti = 31.6/48 = 0.66
number of moles of O = 31.6/16 = 1.98 accept2 [2]
(c)the simplest whole number ratio for moles of atoms:
Fe : Ti : O
1 1
3
[1]
(d)
formula is FeTiO3 accept TiFeO3[1]