Calculation Table

For T=35C
s
t(sec)

Ca(gm
mole/ml)

Vt(ml)

dca/dt

ln(Ca)
7.92941
7.97703
8.05302

0.00036

0.0000007

60

20

0.000343256

-6.64E-07

120

50

0.00031814

-6.28E-07

180

100

0.000276279

-5.92E-07

240

140

0.000242791

-5.56E-07

300

190

0.00020093

-5.2E-07

360

230

0.000167442

-4.84E-07

420

260

0.000142326

-4.48E-07

480

300

0.000108837

-4.12E-07

540

330

8.37209E-05

-3.76E-07

600

350

6.69767E-05

-3.4E-07

660

380

4.18605E-05

-3.04E-07

720

400

2.51163E-05

-2.68E-07

780

420

8.37209E-06

-2.32E-07

-10.592
11.6906

840

430

-1.96E-07

#NUM!

900

430

-1.6E-07

#NUM!

-8.1941
8.32331
8.51255
8.69487
8.85739
9.12566
9.38802
9.61117
10.0812

ln(dCa/dt)

ln(Ca0/Ca)

14.1722
-14.225
14.2807
14.3398
14.4025
14.4694
14.5412
14.6185
14.7022
14.7937
14.8943
15.0062
15.1323
15.2765
15.4452
15.6481

0
-0.04763
-0.12361
-0.26469
-0.3939
-0.58315
-0.76547
-0.92799
-1.19625
-1.45862
-1.68176
-2.15176
-2.66259
-3.7612
#NUM!
#NUM!

Graphs for Differential Method

Vt(ml)
500
400
300
200
100
0
0

100

200

300

400

500

600

time(sec) --->

700

800

900

1000

Ca(gm mole/ml)
0
f(x) = 0x^2 - 0x + 0
R = 0.99

0
0
0
0
0

100

200

300

400

500

600

700

800

900

1000

time(sec) ---->

ln(-dCa/dt)
-12

-11.5

-11

-10.5

-10

-9.5

f(x) = 0.31x - 11.84

R = 0.96

-9

-8.5

-13.6
-8 -13.8-7.5
-14
-14.2
-14.4
-14.6
-14.8
-15
-15.2
-15.4

time(sec) --->

Graph for Integral Method

ln(Ca0/Ca)
0

f(x) =
- 0x 200
100
-0.5 0
R = 0.92
-1

300

400

500

600

700

800

900

-1.5
-2
-2.5
-3
-3.5
-4
time(sec) --->

Calculation Table
For T=47.5 C
t

Vt
0
30
60
90
120
150
180
210
240
270
300

0
50
130
200
270
330
370
410
430
480
490

(ln(Ca
dCa/dt
Ln(Ca)
dCa/dt)
ln(Ca0/CA)
0.00036 -0.0000002 -7.92941 -15.4249
0
0.000323
-1.91E-07 -8.03704
-15.471
-0.10763
0.000264
-1.82E-07 -8.23771 -15.5193
-0.3083
0.000213
-1.73E-07 -8.45393
-15.57
-0.52452
0.000162
-1.64E-07 -8.73018 -15.6234
-0.80078
0.000118
-1.55E-07 -9.04864 -15.6798
-1.11923
8.82E-05
-1.46E-07 -9.33632 -15.7397
-1.40691
5.88E-05
-1.37E-07 -9.74179 -15.8033
-1.81238
4.41E-05
-1.28E-07 -10.0295 -15.8712
-2.10006
7.35E-06
-1.19E-07 -11.8212 -15.9441
-3.89182
0
-1.1E-07
#NUM!
-16.0228
#NUM!

Graphs:
For Integral Method
ln(Ca0/CA)
0
50
-0.5 0 f(x) = - 0.01x
R = 0.91
-1
-1.5
-2
-2.5
-3
-3.5
-4
-4.5

100

150

200

250

300

time(sec) --->

For Differential Method:

Vt(ml)
600
500
400
300
200
100
0
0

50

100

150

200

time(sec) --->

250

300

350

Ca
0
0

f(x) = 0x^2 - 0x + 0
R = 1

0
0
0
0
0
0
0

50

100

150

200

250

300

350

time(sec) --->

(ln(-dCa/dt)
-12.5

-12

-11.5

-11

-10.5

-10

-9.5

f(x) = 0.14x - 14.39

R = 0.89

time(sec) --->

-9

-8.5

-15.1
-8 -15.2-7.5
-15.3
-15.4
-15.5
-15.6
-15.7
-15.8
-15.9
-16