62

40 1

GO

iS iS

SiRZ

iS .
( 5)

S iR Z

SiFZ

..

80-90

(6)

SiFZ

i
;;2 S
.

( 1 ) SiFZ
SiRZ
10Z

1)

)2

: 61 )3691(

)3

R.Castaing:

( 2)

SiFZ-SiRZ

SiFZ

A.

Fe+

)4

SiRZ

SiFZ

.tsnI
)5

IOZ

No.

1591

O.N.E.R.

nor1.J

&

M. G. Hobby:
154

)5691(

H.Ludering:

Arch.

.tunesiE

letS

53 )4691(

351

SiRZ

76
P
aris

Publicaton

G. .C Wood

( 3)

Thesi

)6

)7

GO .

.C.J

.J Charbonier
.siwnhcet

Beihft

A.Rahmel:

Z.Elektrochem.

Margerie:

iersG

61 )4691(

3 341
6 )2691(

36

(4 ) iS GO
iS

8)

UDC

b T

Influences

of
on

the

Mangane3e

Ce Il Nurnber

Eutectic
Ryohei

Synopsi:
As
etce on
rufls
on
with
the
fo gnilaevr

Silicon

Carbon

OZAKI

Dr.

in
Eng.

and
Gray

Akira

Cast
OKADA

a trap
fo the seidut
on the
mechanism
fo citeu
noitacifidilos
suoirav
seitrpo
fo gray
tsac
snori
the stcefe
fo carbon
were
detagisvn
by mean
fo countig
the citcetue
ec lI number

taeimretni
imersion
techniqu"
which
authors
had found
citcetue
ec lI s by the s'daetS
reagen
.t

( 62

Sulfur
Iron
Hidekazu

MIYAKE

which

strex
great
manganese
and
ec lI s revald
dearly
ot be elbatius
as a method
nocilis

4
2 01 5

72

fo
equivalnt
ot
gnisaerc
S
.serutaretil
disolve
rufls
ats

fo
l.t

The
resu tJ s obtained
were
as swolf
:
.1 The
etce fo carbon
and nocilis
on the llec
number
varied
yletacirtni
iS or C gnitsxe-oc
ni tsac
nori then
the lec
number
deirav
with
the
noitarv
(C.E
=C%+
iS %):
The llec
number
increasd
ylthgils
with
gnisaerc
3.9%
C.E
became
ot the
maximum
ta about
3.9%
C.E
and
then
decrased
3.9%
ot 4.3%
C.E
from
_2 The llec number
ni tsac
snori
contaied
3.2%
C 2.2%
iS 0.01.1 0% Mn
varied
yletacirtni
with
the
amount
fo manganese
and
rufls
sa showen
Then
the noitaler
amoung
the llec
number
ni thes
tsac
snori
and
manganese
and rufls
ni noituls
were
.derisnoc
These
devlosi
were
determined
by the curve
fo equilbrm
conetrai
fo manganese
iJJ n
oitaz
fo mangsulfide
ta 1
01 o.C
These
resu tJ s are as :swolf
( 1)
The devlosi
manganese
and rufls
searcni
a lec
number

.ylevitcepser
fo the llec
number
si remarkably
great
than
the tcefe
su fJ ur on esarcni

(2)

When

the
narower
on the llec
number.
( 3) When
the
ylanoitrp
with
gnisaerc
( 4)
Only
ni the
fo the
tsac
nori
pres
de ni it
.
mangansu
.3
nI tsac
snori
conte
gnisaerc
from
On
rufls
si <0.05%.
devlosi
rufls
si >0.05%.

amount

compartively
rufls

fo devlosi
depnding

range
amount
case
tn

su fJ ur si
on .eht
evitcpsr

fo devlosi
the
amount
fo tsac
nori
fo mangsulfide

fo the
3.2%
the other

rufls
fo devlosi

si

gniatoc

30.

over
.ruflus

over
can

0.03%

esarcni

hgils

same
amount
fo each
devlosi
ot 3.6%
decrase
the llec
hand
ti does
not
vary

the

0.03%
etce

below

fo

llec

with

the

amount
fo carbon
from
3.5%
ylthgils
with

and 0.01-0.5%
ni the
preivous
the
amount
manganese
and rufls

The

number

seirav

devlosi

ni

manganese
llec

number

devlosi
1t y seldrag

rufls

the

manganese
number
when
the llec
number

etce
on

fo manganese

the

fo
and
-yrc

searcni

the
and
the

and

llec

number
amount

the

rufls
amount
when

the

fo
carbon

fo devlosi
amount

fo

1.

.2

)'
11)
y C

1)

(P)

relg

eiZ

iS C

iS Fe-C

J2) I

3.9%C

02(

iS .

-60

P 1

iS

elgiZ
r

iS

)Il
5)

Boyes

7)

iS

iS C

rJ!iJ

0.52%

4.09%

P J

C.E

Dawson

8)

3.45-

% alJ iS %)

(C.E=C

.
U A R

L X

C-

Merchan

T.

4.7%C.E.

)C(
(Mn)

(S)

)iS(

1t O) 3.0-

) 4_0%

( 72 )

C.E

28

40 1

C.E.

C iS

.
P 30 1

C iS

;;1.0

iS C C.E

.2

C. E

3)

C.E.

Si%

.1

C%+ljs

( 1 )

79.3(
% C .1 00%

iS 0.07%

Ni ;90.0

Cu 0.023%

0.010%

V 0.06%

Tl 04

.SIJ(

P 0.013%

Mn 0.05%

0.09%

Mo 0.005%

2
75.0%

)iS

As)

.SI}(

1
77.5%

%P)

Mn)

.SI}(

Al

Cr ;210.0

(
P

Mn 0.1%

2.9-3.3%
3.5%

C 1.9-2.9%

C.E.

C.E

C.E

(3.1%

C .1 9% )iS

C.E

C 24.

2.9%

400g

25mmx50mm

P
t 90

Rh

.
09 oC/min
.
4mm

x 40mm

x 50mm

40g

.1 8
58.2

0.1
0.1

14.2

0.12
0.1
1.0
0.1

3.07
82.3

.1 93

60.3
3.28
3.29

8.2
2.39
19.2

C.E.

810.

0.9
0.1
0.1
0.8

3.50
3.65

-1
1-

3.68
3.80

-1

3.87
3.92
4.02

1.42
5.42
24.
23.5

4.08
4.26

23.
2.3

0.18

101.0

)mc/oN(

80.

1.0

0.18

2.1 5
2.5
5.2

C iS .

C iS

1 .

C.E.

C 10 2/1
1
350 o C

450
1

0.13
0.1

3
2kg

2.45

J 1 *

1 9 .

%Si

.1 59

C.E.

C iS

3.7%

Mn

58.2

iS

4.3%

C.E

iS

38.2
3.05
2.85

C.E.

I I I I

5
6

Mn )

2*
*'2
3
4

1
24.8

(%)

(%)

3.5%

3.9%

C.E.

C.E.

3.9%
;;3.4

C.E.

C.E.

()

.
. C.E.

( 2 )b(

45x

( 2 (a)

2kg

h421

63 11)

( 2 )
2) .

( 3 )
( 28

+
!
r
.
l
l
i
lfI
IIII

92

C.E

f
C.E3.9%

1)

C.E

C.E

C.E.3.9%

(a)

4.23%

C.E.

(b)

05.3

C.E.3.9%

C.E.

C.E.

2
() x45x

C.E

C.E.

.3

3.5%-4.3;

C.E.

9.3

C.E.

C.E

3(a)

iS 3(b)

C iS

iS C

C.E

().

JW

2)

34. % C 0.42-3.49%

~ 162

1
83

42

iS

Bunin

Samarin

Bogachef

C 5 C 4 C 3 2C
)

.3

C.E.3.57-4.25%
3.9 6- C.E.

3.9%

C.E.

C.E.

.245%S(

:x 382

~2.85%

0: 3.05~3.07 % C
" 3.28~3.2qoy' C

02 L
8.2 9.2 0.3 1.3 2.3 33
.0( 1 0'

18 0.2
1b(

2. 42. 02. 5.2 0.3

%

( a )
( b )

M n S

Mn S

%Si

% Si

C 6

X:l.88~J.q5

:2. 85~2ql

-93.2:0

iS

)3154.

S Mn

)61 Mn

Mn

17)18)

S Mn Mn S

C.E

. elgiZ

( ;;9.3

C.E

( 9.3

S)

(Mn

19)

Mn

3.9%

15%

C.E.

MnS

( 29

03

04 1

01
1
MnS

l Mn

C C

Mn

(2 )

2) .
2

S .

. J
S y
Mn

Mn

i Mn
S MnS

MnS
Mn S .
Mn

0.01 1.0% S 0.01 0.5~

)32

y Mn

.
.1

( 1 )

OB

(3.72%C
O
.04%Si
0.01~ Mn 0
.28%P
0
.15%
S 0.35%
Cu Cr 0.1%
i
N 0.5%
V0.04~
iT )10.0
%
0.57(
)iS 8.42(
2 .2
%P)
( 3 ) 2.3
9C 2.2~ Si (C.E 3.9%)

P O.l~

(
7.5%

Mn)

%
9.81(

)S
Mn S 1.0%
Mn
0.5%
S 63
.
1 4g

Mn S
1
054 0 C 01 1
053 0 C 25mmx50m
nI

450

9
0

. 4mm

x 40mm

(
-1

y 2

Mn S Mn

x 50mm
( 03 )

1 iS

1P

n I S

Nojcm

13

04. 07-0.46%

S 0.3%

Mn

04. 0-0

4. 7% Mn 0.027%

0.106~ S

0.393%

S 0.84-0.95%

0.205%

S .O

367%

Mn

S .

( 1 ) S

( 2 ) Mn

.1-0.
S 4 0

M n 5 0
1.

015%

M n 0.09-0.13%

0.27-0.30%

Mn 0.16-0.18%

.0:.

-01

0
15%Mn

90 31.0

:0-01

:x .06/ 081 %Mn

0 0
72 -0 03 % n
4 -1 ~ 40 4- 7 %

i :. 0.54 -0 95 % Mn
"'

-0.016%S 0.021-0.029~ S Mn

Mn

:..
25

Mn

0
21-

:x 00
54-0

016%S
027%S

061%5

3IJ %S
10.85- .0 7Z 3 %S
0:367-39%5

0: .00
97-

:lL

030

2.0

40. 0

it'

.40
6.0
%

0
8

0.1

~f

11 n
6 Mn S (

( 13

x9x

23

4
0 1

0.097-0.13%S

Mn

Mn

393%

1<1-

....
.../-.../

6-5

0.95%

117

. 0.185-0.273%S

-0.

@:

: Sn -;
SnN: Ri7

6-4@

Mn

0.09%

0.45%

@r
o

0.92%

64@

Mn 74.0

n
u
u

%Mn

0.28%

Mn

S 0.17%

l 111

;160.-450.

Z3

Mn

763.0

5-6

S Mn

.
y Mn

4-6

-6

3-6O

9x 6 .
.3

0
16-2

0.0

Mn

. Mn
S j
Mn

S MnS
Mn

5.0

O.J

7 1
01 o C 2.2%
iS
MnS l Mn S
Mn S

S Mn
MnS

1-6

(x

4)
2
-5 MnS
3-

)12 C + =(MnS)

log

K=.-9763jT+5

791

.1;;6 iS S

log
MnS

isf

z0.65

MSi

Mn S 1
01

S
MnS

Mn S

..

O Mn S

5
-3

OB

(3.2%

C 2.2%

iS 3.9%

C.E.)

Mn

MnS

1
01

2.2%Si

7
. Mn
.

Mn

Mn

S M nS

0.139%S)

MnS

Mn

S f
71.0(
MnS

).
Mn

Mn

Mn

MnS
S

Mn S

19)

MnS
MnS

(0.06%

(A )

MnS

MnS

Mn S

..

MnS

.1.

Mn

1
054

( 23

0% Mn 0.5%

S 6o

f.

l Mn

S 'I nS

I' n

10.
0.1
310.
510.
0.14

MnS

3 MnS

1.0
90.
31.0
80.
0.4

410.
120.
950.
0.14
691.0

Mn 8
S Mn

.3.2%C
Mn

71.0
71.0
71.0
0.1
60.

S Mn

I 26.0

650.
670.
931.0

i 29.0
34 4.
9.83

21.0
71.0

610.
120.
930.
640.

80.
61.0

1
2
3
4

MnS

510.
720.
0.23
620.
240.
681.0

0.8
2.0
0.39
75.0

8
0

0.1
01.
10.

I 50.
I 1.0
i 0 2
4

25.0
82.0

130.

I 29.0

09.
68.0
58.0

S
. (3.6%

C .)

i84

3.2%C

23.8
6.72
6.03
32.0
0.43

:.

O.O!O ~0.OI6%S
O.021~ 027%5

X: . 06
50
0
59%3
0:

711 %
0273%

:. 0
-4/0 . 03%610
. . ;aOZ5~O.029%S

x .:0240
0
5%3
3%201.0
;'"
0
402 01' 5

[}

0 :

061

I 4.72
I 2.6
I 5.42
32 4.
6.2

0.1

Mn

MnS

7 S

8 MnS
Mn

Mn S

MnS
MnS

7.32
27.9
24 4.
2.3
5.82
8.24
)i1

350
1

S S

Mn

0 4. 3
0.4
0 4. 0
0.3
0.2
0.4

MnS

0.3
72.0
2.0
0.18

.
Mn

20.

. S Mn

1
2
3
4
5
6

Mn S

21
. 9
5.42
9.72
9.43
41
. 5

10.
80.

9.02
23.0
3.82
1.23
5.74

1
2
3
4
5

Mn

Nojcm

610.
620.
0.58
1.0
372.0

i )

( 1 ) MnS

Mn S

9
S (

Mn )

. S 10.
0.015%

(3 )

( Mn 9.0

43

0
4 1

84

84
44
V

hh~

8 t

6
3

'-

;. 23

.
b02

01.0

51.0

02.0

20f

52.0

01.0

2.0 52.0

510

;%

9 S
( Mn )
l MnS

01

S ()

0.03%

S MnS

0 .4%)

S 0.03%

MnS

Mn 0.3%

( 21-

S .

( 2 ) MnS

Mn

MnS

S 0.03%

J.
Mn

y S

9 0 . 9 MnS

S .

( 1 ) ii( )

MnS

) Mn S

28

S 0.03%

MnS

01 S 0.03%

Mn S

Mn

. Mn

S 0.03%

S Mn

MnS

.
0.03%

MnS

5 O 0.97-15
%Mn

90.

%Mn

59.0

S 5
10.

Mn 04. 7
Mn

. MnS

)7

Mn S 5

0.015%

MnS

MnS

Mn

()

SO.111%

0.09%

) MnS

MnS

S MnS

MnS

nosilA

. 974.0

relgiZ

MnS

32l DE )42YS

MnS

( 43

401.

0.076%

Mn(

0.046%

Mn ({)

4 MnS

)02

S 0.104%

Mn

S
9620.

53

. 0.95%
)

MnS

Mn

Mn (

S 0.01%

;;08.0

Mn 8 .

0.05%

(3)

C.E)

Mn S C

J S

C MnS

3.2%C

.
( 3.9%
iS

C.E)

C 2
.3

( 4.3%
S 0.5%

C.E.)

3.2%C

9 .

. 9 MnS
3.2%C

Mn

3.2%

C.E

MnS

C 3.6%C

;;50.0

19)

;;6.3

2 C.E.

MnS

Mn

Mn

1
2
3
4
5
6

16.3
36.
36.
36.
46.3
3.64

52.

01.

710.
90.
210.
01.
01.
610.

410.
520.
350.
201.
402.
04. 03

710.
90.
210.
01.
01.

1
2
3
4
5
6

95.3
16.3
3.60
3.60
36.
16.3

83.2

01.

92.

90.

21.0
41.0
01.
31.0
21.0
31.0

610.
620.
50.
301.
502.

21.0
41.0
01.
01.
50.

1
2
3
4
5
6

06.3
06.3
16.3
06.3

71.0
2.0
12.0
2.0
12.0

920.
350.
401.
402.
04. 72

.*

06.3

90.

693.4

| (

|
)

iS

01.

3.9%

52.

0.05%

(%)

C)

4 ;;6.3(

C.E)

Mn S C

. 7

4 MnS

( ;;9.3

Mn

( 8 S )

2.2%

3.6%

Mn S

0.2%

Mn S

MnS

MnS

2 C.E

C 3.6%

S 8 S

0.2%

S 3.2%

C
( 4.3%

: MnS
: MnS l
Q:MnS

( 53

02.
71.0
02.
41.0
70.

S
520.
350.
201.
402.

610.
620.
50.
80.
261.0

920.
240.
260.
61.0

O
O

O
O

N n
6.81
4.2
0.82
0.92
4.1 0

2.81
3.2
8.72
3.4
2.83

8.1
0.32
7.03
0.23
5.43

63

40 1

C C.E.

( 4 ) S 0.03%

MnS

Mn S MnS

.3

MnS

Mn S 3
.2

t Mn

20) S

S 0
.5

)62 41l C )72

)52

3.6%

C S 0.05%

W. Ol :dleifd

: 4
3 )2691(

1 297-8

37 )5691(

01 93-1

)4
0211

JO
oO

040

!?

11

11

11

.J 8 )0691(

IJ] : 2 )8591(

)5

R.Zieglr:

)6

8
2 )6591(

iersG

)7

J.W.Boyes:

)8

J.V.Dawson:

)9

ni

11

BCIRA.

2 291-7

)1
)2

)3

4 58 94

15 )4691(
01 )2691(

1 9-16

9 )1691(

2 632-91

11

W.

6 904-3

BCIRA.J

J.V.Dawson

1 4
06-

Ol d dle

: BCIRA.J

H.D.Marchant

)1

: 34 )2691(

C iS Mn

)21

J.FWalace:

842-1

69 1( )169

T.AFS

.L .I oleirT

)01

9
0
6-85

IJ] : 1
3 )7691(

)31

: 3 )1691(

..

)41

11

38 )691(

3 431-62

)51

J]

11

53 )3691(

9 71-5

C iS

.1

. 3.5%

3.9%C.E.

4.3%C.

0.01-

(3.2%

.1 0 Mn

C 2.2%

Mn

)iS

)61

J.W.Boyes:

)71

]1

)81

J.W.Boyes:

: 38 )691(

)12

: 43 )7591(

C MnS

S .

)2

S Mn

A.lison:

)42

Foundry

Trade

.S

.J 42 )0391(

A. DY SY : Ame .r Foundrym.
.S

Mn S

)62

T.Hughel:

iL q
uids

)72

F.Neumann

H.Schenck

iersG
)

: 91

)941(

26-5

B.F.Dyson:

( 63

J.Metals

597

)52

( 3 ) S 0.03%

43

814-7

2 0215 25-71

J.Chipman:

C.W.Sherman
)2591(

)32

21 8
0-14

6 31-5

)7591(

( 1 ) Mn S

( 2 ) S 0.03%

5 975-86

01 )2691(

: 39 )7691(

Mn S Mn

BC lR A.J

0
1 85-1

)91

3 34-6

1 )3691(

J] 35 )3691(

)02

0.01-0.5%

01
1

BCIRA.J

2 91

.2

6 827-3

S J

iS C C.E.

8 )0691(

2 132-

T.AIME.

47 )0691(

27
)3691(

52

)3691(

752-6
W.Paterson:

8 752-6