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CARIBBEAN

EXAMINATIONS

JANUARY2015

COUNCIL

CARIBBEAN SECONDARY EDUCATION CERTIFICATE"'

EXAMINATION
CHEMISTRY
Paper 032 - General Proficiency
Alternative to SBA
2 hours 10 minutes

READ THE FOLLOWING INSTRUCTIONS CAREFULLY.

I.

Answer ALL questions in this booklet.

2.

Write your answer to EACH question in the space provided in th is answer

booklet.

3.

Do NOT write in the margins.

4.

You may use a silent, non-programmable calcuia,,z- t:: answer items.

5.

Return this booklet at the end of the examination.

6.

You are advised to take some time to read through the paper and plan your
answers.

7.

If you need to rewrite any answer and there is not enough space to do so on the
origina l page, you must use the extra lined page(s) provided at the back of th is
booklet. Remember to draw a line through your original answer.

8.

If you use the extra page(s) you MUST write the question number clearly
in the box provided at the top of the extra page(s) and, where relevant,
include the question part beside the answer.

DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO SO.

Copyright C> 20 13 Caribbean Examinations Council
All rights reserved.

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- 3Answer ALL questions.

I.

In each of seven experiments, a different volume of dilute sulfuric acid is added from a burette to
50 em ' of a 0.50 mol dm ' si lver nitrate so lution in a beaker.
In each experiment. the precipitate formed is filte red, washed, dried and we ighed.
The volume of sulfuric acid and the corresponding mass of the precipitate obtained are shown in
Figure I and are to be recorded in Table I .
2.5 cml sulfuric acid added

Expt #1 Mass or empty

container
10.0 cm3 sulfuric acid added

5.0 cm3 sulfuric acid added

Expt #2 Mass or container

Expt #3 Mass or container

+ precipitate

+precipitate

13.0 cm3 sulfuric acid added

15.0 cm 3 sulfuric acid added

Expt #4 Mass or container

Expt #5 Mass of container

Expt #6 Mass of container

+ precipitate

+ precipitate

+ precipitate

16.0 cm3 sulfuric acid added

Expt #7 Mass or container

+ precipitate

Figure I. Mass of precipitate obtained when different volumes of sulfuric acid are added

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01212032/JANUARY/F 2015

-4(a)

Write a balanced equation, including state symbo ls, for the reactio n between s ulfuric acid
and s ilver nitrate.

(2 marks)
(b)

Using the results shown in Figure 1, complete Table I to show the mass of the container
and the precipitate, and the mass of the precipitate obta ined in each experime nt.

Table 1: VOLUME OF SULFURIC ACID ADDED AND MASS OF PRECIPITATE FORMED

Volume of
Sulfuric Acid
Used
(cm3)

Mass of
Container
and Precipitate

Mass of
E mpty
Container

Mass of
Precipitate
Obtained

(g)

(g)

(g)

.................

2.3

2.5

2.3

5.0

2.3

10.0

2.3

13.0

2.3

15.0

2.3

3.9

16.0

2.3

3.9

Experiment
Number

(10 marks)
(c)

Using the axes provided on page 5, plot a gra h of them

..
volume of sulfuric acid added. Your gra h ~ ld .
ass of p~ec1p1tate obtained agai nst
p s ou mclude two mtersecti ng lines.
(4 marks)

(d)

Use the data from your graph to determine the MIN IMUM

to precipitate AL L the s il ver ions from th .

vol~me of s ulfuric acid required
e s11ver nttrate solution.
Volume o f sulfuric acid = ................................. cm3

(e)

(i)

(1 mark)

Calculate
the number of moles ofs"1lver .tons .m 50 c 3 0 f h
3
.
nttrate so lution .
m
t e 0.50 mol dm- s il ver

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(1 mark)

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- 6-

(ii)

Calculate the number of mo les o f sulfuric acid in ~he m~nimum volume you obtained
in (d) on page 4. (Make use o f the equation wntten '"(a).)

(2"~~~~)

(ii i)

Calculate the number of mo les of s ul furic acid in I dm of solution.

(1 ma rk)

(iv)

Ca lc u la te t he n umber of moles of s ilver precipitate (RMM

Experiment 4.

3 12) in

...............................................................................................................................
(1 ma rk)
( f)

Identify TWO possible sources of error in this experirne!<t.

(2 ma rks)
(g)

List TWO safety precautions that should have been taken during this experiment.

(2 ma rks)
Total 26 ma rks

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- 7-

A student carr1es
ld
. out a number of tests on a sample of Compound A and Compound B The tests
and merences
are recorded 1n
r-.
Table 2. Complete the table by inserting the observaf ons that wou
1
have been made based on the information recorded.

TABLE 2: RESULTS OFTESTS ON COMPOUNDS A AND B

Test
(i) To a solution of
Compound A, add
aqueous sodium hydroxide
dropwise until in excess.

Observation

Inference
_
AP, caz, Pb2+, Zn2+ possibly
present.

AP+, Pbz+, z nz+ possibly

(2 marks) present.
(ii) Heat the mixture from (i)
above.

NH 3 (g) was g iven off.

Hold moist red and blue

litmus paper at the top
of the test tube during
heating.

NH4- present in Compound A.

(2 marks)

(i ii) To a solution of
Compound A, add aqueous
ammonia solution dropw ise until in excess.

AP+, Pb2+, Zn2+ possibly

present.

Zn2+ present.

(2 marks)
(iv) To a solution ofCo~pound
A, add aqueous banum
nitrate.

SO42 or SO32 possibly

present.

Followed by aqueous nitric

acid .

SO4 2 possibly present.

(2 marks)

(v) To Compound B, add .

aqueous sodium hyd~o~lde,
a few pieces of alummiUm

and heat the mixture

carefully.
Hold moist red and blue
litmus paper a t the top of
the test tube

N02 given off.

Acidic gas given off. N0 3

(2 marks) present.

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Total tO marks

GO ON TO THE NEXT PAGE

r
3.

- 8-

You are provided with a bottle of sea water which also contains some sand.
(a)

Plan and design an experiment to recover the solid 'sea salt' from the mixture. Your answer
should include the following:
(i)

A suggested list of apparatus to be used fo r recovering the solid sea salt from the
sandy sea water

(4 marks)

(ii)

An outline of the steps for the procedure to be used

(4 marks)

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--,

-9(iii)

A list of the main ob

.
e xpenment
.
servatiOns tha t wouId be expected at EACH stage of the

(2 ma rks)

(b)

A student s uggests that solid se

.
. .
chloride io ns in the l"d
a salt contams chl onde 1ons. Outl ine a method to test fo r
so 1 sea salt .

.....................

..........................................

(2 marks)

Total 12 marks

ENDOFTEST
IF YOU FINISH BEFORE TIME IS CALLED, CHECK YOUR WORK ON TIDS TEST.

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