(Contoh 12.

1)
Sistem biner Acetonitril (1) / Nitrometana (2) mendekati hukum Raoult tekanan uap spesi
murni diberikan dan persamaan antoin:

A =
B =
C =

a.

Benzena
14.2724
2945.47
224

A =
B =
C =

Toluena
14.2043
2972.64
209

Buat diagram P vs x1 dan P vs y1 untuk suhu 100 C

T=
ln P1

sat

ln P2

sat

75
4.42133 P1
3.737258 P2

sat

83.20686

sat

41.9827

P= P2 sat +( P1 sat - P2 sat)x1

y1 = (x1 xp1 sat)/P
x1
0
0.2
0.4
0.6
0.8
1

P
41.9827
50.2275
58.4724
66.7172
74.9620
83.2069

y1
0
0.3313
0.5692
0.7483
0.8880
1

x= 0.6 berkesetimbangan dengan y=0.7483

p = 66.72 kPa
y = 0,6 berkesetimbangan dengan c' (sat. liquid dihitung dengan Dew P sbb:
y1 =
0.6
y2 =
0.4
P =
59.7419
x1 =
0.4308

b.

Raoult tekanan uap spesies

Dew P sbb:

Variabel berubah

A1
A2
A3

14.2724 B1
2945.47 B2
224 B3

Pjsat = P
T1

70 kPa

sat

T2

14.2043
2972.64
209

69.84 C

sat

89.58 C

75 C

p1 sat
p2 sat

4.4213
3.7373

X1

0.6796

Y1

0.8079

p1 sat
4.8795
4.7709
4.6780
4.5834
4.4868
4.3883
4.2485

t
89.58
86
83
80
77
74
69.84
X1
P=

83.21
41.98

kPa
kPa

131.56
118.02
107.56
97.84
88.84
80.50
70.00

p2 sat
4.2485
4.1276
4.0240
3.9183
3.8105
3.7003
3.5437

0.6 X2
70 kPa

In

0.4

P2sat

1.9819
1.9719
1.9711
1.9710
1.9710

44.0485
44.2163
44.2295
44.2306
44.2307

P1sat

4.4680

87.1795

Y1

0.7473

0.6790
0.6786
0.6786
0.6786

70.00
62.03
55.93
50.32
45.17
40.46
34.60

t
76.3093
76.4134
76.4216
76.4223
76.4223

Y2

0.2527

jawaban

In

P1sat

1.9819

87.3726

t
76.4901

0.6783
0.6786
0.6786
0.6786

x1=

1.9705
1.9710
1.9710
1.9710

0.2029

87.1705
87.1800
87.1795
87.1796

76.4192
76.4225
76.4223
76.4224

BUBBLE P
X1

Y1

2.5393E-15
0.1424
0.2726
0.4142
0.5686
0.7378
1.0000

4.772419081E-015
0.2401
0.4188
0.5789
0.7216
0.8484
1.0000

95
90

85

c'
80

b'

75
70

a
65
60
0

DEW T

0.1

0.2

0.3

0.4

0.5

95
90

85

c'
80

b'

75
70

a
65
60
0.3

0.4

0.5

0.6

0.7

0.8

0.9

a)

a12
v1
R
x1
p1sat
12
21

0.1258
0.7292

1
2

1.684769
0.894613

b)

437.98
76.92
1.987
0.25
92.59223

y1
y2

0.550942
0.449058

y1
y2

0.6
0.4

p1sat
p2sat

P
x1
x2
1
2

67.00987 kPa
0.434226
0.565774
1.312196
1.553087

P
X1
X2
1
2

96.38859
0.475996
0.524004
1.261456
1.621678

1238
18.07
353.15
0.75
47.3756867345

akhir (ln 1,2)

-0.7258161975

70.7863

dari soal
c)

a21
v2
T
x2
p2sat

100

92.592
47.376

x1
x2
T1
T2

0.15
0.85
355.06
372.7813

T
p1

370.1231 pers. Antoine

177.6112

p2
1
2

90.85939
3.091073
0.993405

p1sat
T

111.6542
357.8386

y1
y2

0.517697
0.482303

ITERASI
P
111.6542258568
109.1564696353
109.0378195598
109.0321230949

T
357.84
357.26
357.24
357.24

VANNES 467
K
K

T
353.15

A
16.678
16.2887

P1 sat
P2 sat

92.59223
47.37569

SUDAH DIKETAHUI

kPa

BUBL P

ITERASI
P
x1
x2
1
2
96.38859 0.475996 0.524004 1.261456 1.621678
96.68033
96.83804
96.9242
96.96908
96.99216
97.00393
97.00991
97.01294
97.01448
97.01526

0.495142
0.504913
0.50984
0.512333
0.513594
0.514233
0.514556
0.51472
0.514803
0.514845

0.504858
0.495087
0.49016
0.487667
0.486406
0.485767
0.485444
0.48528
0.485197
0.485155

1.24079
1.230804
1.225905
1.22346
1.222232
1.221612
1.221299
1.22114
1.22106
1.22102

1.654216
1.671094
1.679676
1.684037
1.686248
1.687368
1.687936
1.688224
1.688369
1.688443

deltaP
-0.291735
-0.157714
-0.086158
-0.044883
-0.023075
-0.01177
-0.005982
-0.003035
-0.001538
-0.000779

B
3640.2
3816.44

16.678
16.2887

3640.2
3816.44

12
21

0.129503
0.790693

akhir

-0.256774

53.54
46.13

p1
p2
12
21
AKHIR
111.6542 57.11599 0.126882 0.746295 -0.227885
109.1565 55.8394 0.126757 0.744208 -0.226517
109.0378 55.77876 0.126751 0.744108 -0.226452
109.0321 55.77585 0.12675 0.744103 -0.226449

1
2
Y1
3.195283 1.004627 0.517697
3.200325 1.00516 0.086705
3.200567 1.005185 0.014197
3.200579 1.005187 0.002322

C
53.54
46.13

2-propanol
water

DEW P

BUBL T
Y2
0.482303
0.482303
0.913295
0.985803

deltaT
0.57
0.03
0.00

sistem Etanol (1)/

jika sistem sesuai
T=
P=
z1 =
z2 =
z3 =

A
B
C

metanol(2)/ 1-propanol (3) pada 70C dan 60 kpa komposisi over all z1= 0,5, z2= 0
dengan hukum rout, tentukan L, V, xi, yi
70 C
60 kpa
0.5
0.3
0.2

Etanol
metanol 1-propanol
16.6758 16.5938 16.0692
3674.49
3644.3 3448.66
226.45
239.76
204.09

ln P1 sat = 4.280826 P1 sat =

ln P2 sat = 4.828885 P2 sat =
ln P3 sat = 3.486982 P3 sat =
dew P (zi) = (yi)
P dew =
64.79683
P=
60
bubl P (zi) = (xi)
P bubl =
80.20894 kpa
K1 =
K2 =
K3 =

1.205002
2.084524
0.544786

72.30015
125.0715
32.68716
V
V

pers
0 1.336816
0.1 1.268723
0.2 1.212534
0.3 1.165625
0.4 1.126204
0.5 1.093031
0.6 1.065249
0.7 1.04229
0.8 1.023816
0.9 1.009695
1
1

0.92892
0.969952
0.986445
0.993713
0.997048
0.998605
0.999339
0.999687

per
1.006428
1.002435
1.001046
1.000475
1.000221
1.000104
1.000049
1.000023

V=
L=

0.997048
0.002952

y1 =
y2 =
y3 =

0.500251
0.300462
0.199508

i over all z1= 0,5, z2= 0,3, z3= 0,2

0.042303
0.01672
0.007314
0.003344
0.00156
0.000735
0.000347

x1 =
x2 =
x3 =

0.415145
0.144139
0.366213

2 KOMPONEN
Komponen
i=
methyl ethyl ketone
j=
toluene
t=
50
P=
25
tekanan dalam satuan kPa
T=
323.15
ij
11
22
12
R=
R=
B=
dB/dT =
Z=
HR/RT =
SR/RT =
V=
HR =
SR =

ij

zcij

0.323
0.249
0.262
0.264
0.2925
0.2565
8.314
8314
-1616.805
13.43234
0.984955
-0.055435
-0.040391
105850 cm3/mol
-148.9367 J/mol
-0.335809 J/molK

Vcij

R=
y1 =
y2 =

Tcij

Pcij

267
535.5
41.5
316
591.8
41.1
290.81234612 562.94662269 41.281148126

83.14
0.5
0.5

Trij

B0ij

B1ij

Bij

dB0/dT

dB1/dT

0.6034547152 -0.8638495014 -1.2958971385 -1375.793108 2.509733 9.981248

0.5460459615 -1.0280810277 -2.0445634154 -1872.0279415 3.254677 16.78593
0.574033109 -0.942683439 -1.6310816073 -1609.6999736 2.858036 12.9439

dB/dT
11.4867
15.4802
13.38123

R=
P=

83.14
140

ij

Tcij
11
22
12

y1=
y2=
Pcij

Vcij

a=
b=
a/bRT^1.5=
bP/RT=
V=

176.1944674

GR/RT=
HR/RT=
HR=
SR/R=
SR=

-0.36701662
-1.46106201
-5466.92876
-1.09404538
-9.09698736

337
58.155

Tpr=
Ppr=

1.335312
2.40736

Zo=
w=

Zij

304.2
73.83
94
369.8
42.48
200
335.4 54.6183271242 140.4001

0.682 Z1=
0.188

Wij
0.274
0.276
0.275

0.224
0.152
0.188

ij

Trij
B0
11 1.4792899408 -0.142542
22 1.2168739859 -0.225262
12 1.3416815742 -0.180678

ij

aij
bi
11 64595311.506 29.67938
22 182923119.91 62.70625
12 111456420.81

Trij (11)= 1.479289941

Trij (22)= 1.216873986
Trij (12)= 1.341681574

B.
Tpc=
Ppc=

0.5
0.5

117607818.262
46.1928167211

B=

-91.04125

3.2079896423
0.1728542042

z=
h=

0.659322
0.26217

R=

0.205

8.315

dari Tabel E2

z=
V=

0.72054
192.554

T=

450

B1
Bij
0.105787 -40.71169
0.063578 -156.0403
0.08895 -83.70652

VLE DARI PERSAMAAN PANGKAT 3

Ex-13.3
Komponen
P buble
yang diketahui xi
metana
0.1
P dew
yang diketahui T
etana
0.2
propana
0.7
T
50 F
Ki diperoleh dari fig 14.4 dengan data suhu dan tekanan trial untuk mencari tekanan dgn kondisi yi/Ki
100
150
124.9425002282
Komp.
yi
Ki
yi/Ki
Ki
yi/Ki
Ki
c1
0.1
20
0.005
13.2
0.0075757576 16.0567
c2
0.2
3.25
0.061538
2.25
0.0888888889
2.689
c3
0.7
0.92
0.76087
0.65
1.0769230769
0.7622

1
0.827408
1.1733877234
sehingga dew P =
124.9425 psia

Ki diperoleh dari fig 14.4 dengan data suhu dan tekanan trial untuk mencari tekanan dgn kondisi yi/Ki
380
400
386.1682242991
Komp.
xi
Ki
Kixi
Ki
Kixi
Ki
c1
0.1
5.6
0.56
5.25
0.525
5.49
c2
0.2
1.11
0.222
1.07
0.214
1.1
c3
0.7
0.335
0.2345
0.32
0.224
0.33

1
1.0165
0.963
sehingga buble P =
386.1682 psia
Ex-13-4
P=
komp.

200 psia
zi

c1
0.1
c2
0.2
c3
0.7

1
Sehingga fraksi uap=

Ki
10
1.76
0.52
0.272162

v
0.35
0.274
yi
yi
0.240964 0.2885170225
0.278041 0.2913328478
0.4375 0.4191230656
0.956505 0.9989729359

0.272161984 0.272162
yi
xi
0.2899006284 0.02899
0.2916700586 0.165722
0.4186977304 0.805188
1.0002684174
0.9999

kanan dgn kondisi yi/Ki = 1

124.9425002282
yi/ki (x)
0.006228
0.074377
0.918394
0.998999

kanan dgn kondisi yi/Ki = 1

386.1682242991
Kixi
0.549
0.22
0.231
1

Kixi 1
i

yi

Ki 1
i

ziKi

1 V ( Ki 1) 1
i