PAPER Adva PII Sol PDF

1
FIITJEE
JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
CRTI
(Paper-2)
Q. No.
ALL INDIA TEST SERIES
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AITS-CRT-I(Paper-2)-PCM (Sol)-JEE (Adv)/14
PHYSICS
CHEMISTRY
MATHEMATICS
1.
A, B, D
2.
A, D
3.
B, C, D
4.
A, D
5.
A, D
B, C, D
6.
B, C, D
A, B, C
7.
A, B
A, D
8.
B, C
A, B, C, D
9.
B.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
2.
vmax = mg/k
mv max 2mg
Fav =
T 4
3.
W=
4.
Work done by all the forces on the block equal to change in kinetic energy.
6.
No effect of a and g on time period of spring pendulum.
7R3
4S
3R2
2
p
r
dr
=
4p
+
(4)(4S)
R 0 r
3
2
2R
7.
8.
1 1 8R
= R 2 2
3 1
1 3 9
1
1 1 3R
= R 2 2
2 1
4
1 2
3 1 27
2 1 32
1
x
dx
Work done by friction F ds mgcos
cos
0
= mg x = 20 J
mg
cos
dx ds
ds
dx
9.
Field inside the conductor is zero
10.
Charge distribution is shown in figure.
s1
11.
( 3mg) /(m / )
12.
s2
0
2mg /(m / )
3
0
2
2m g
2
=
m/
5
g
2
dy
3
13-14. If the bike does not slip, path of both the wheel
must be parallel with its direction as shown in the
figure.
R1 = /tan
Front
wheel
Rcm =
Net friction force f =
p0A = ma a = p0A/m
16.
p0A = ma m = m/5
m m = 4m/5
Chemistry
c.m.
Rcm
mv 2
2mv 2 tan
R cm
4 tan2
15.
R2
2
4 tan2
R1 =
2
2 tan
Rear
wheel
R1
PART II
SECTION A
2.
H3C
CH3 H
H
C
CH3
PCl
5
CH3
H
Cl
CH3
CH3 Cl
anti conformer
3.
Thermal stability of nitrates of alkali metals increases down the group. MgO is basic; SnO is
amphoteric and B2O3 is acidic oxides.
4.
Cell reaction is:
Tl s Cu2 aq
Tl aq Cu s
Tl
0.0591
0
Reaction quotient Q
and Nernst equation is Ecell Ecell
logQ; at 298 K
2
n
Cu
+
To increase Ecell, Q should be decreased. Which is decreased by decreasing [Tl ] and increasing
2+
[Cu ].
5.
Statement B is true for weak electrolytes only and in case of C osmosis never stops so dilution
on solution side continues and no limiting value of equivalent conductance of solution is obtained.
6.
Pb3 O 4
4HNO3
Before reaction 0.05 mole
2 mole
After reaction
1.8 mole
2Pb NO3 2 PbO2
0.1 mole
2H2 O
0.05 mole
residue
2Pb 8NaOH
2Na 2 Pb OH 4
HNO3 NaOH NaNO3 H2 O
Moles of NaOH used to neutralise excess of HNO3 = 1.8 mole

Moles of NaOH used with Pb(NO3)2 = 0.4 mole
Total NaOH used = 2.2 mole.
4
7.
8.
1
Coagulating power
Less is the gold number, better is the protection power.
8
Maximum capacity or volumes of balloon 480 548.57 ml
7
Also, V1 = 480 ml, T1 = 278 K, n = 1 mole
(A) The balloon will burst at a minimum temperature (T2) when volume becomes 548.57 ml.
Using Charles law
V
V
1 2
T1 T2
Coagulation value
480 548.57
278
T2
T2 = 317.71 K
or T2 = 44.71oC
Hence (A) is incorrect but (C) is correct.
o
(B) Pressure of the gas at 5 C having 1 mole and V = 480 ml
PV = nRT
480
P
1 0.0821 278
1000
P = 47.5 atm
Hence (B) is also correct.
(D) Since V increase with increase in temperature from 5oC to 44.71oC, at which balloon bursts
and therefore pressure remains constant. Thus pressure of gas inside the balloon when it
bursts is 47.5 atm. Hence (D) is incorrect.
Hence (B, C) are correct.
Solution for the Q. No. 9 & 10
B is CO2(g) the compound A is a ZnCO3 and C is oxide of Zn, as it is white when cold and turn
yellow on heating. D is CaCO3 which form Ca(HCO3)2 which exist in solution only.
Solution for the Q. No. 11 & 12
OH
OH
Since A react with NaOI, it must be O
CH2Cl
other side products are

OH
OH
O
O
OH
OH
OH
CH2Cl
and less likely to be
; B is
H 2C
;
C
COCl
CH2NHMe
OH
OH
while C is
CH
HO
CH2NHMe
5
13.
The above paragraph shows that compounds (A to D) are

CH2 Cl
H2 C
COOH
H 2C
CH2 Cl
(A)
COOC2H5
CH3COOH H2C
COOC2H5
(D)
COOH
(C)
(B)
In above problem concerned reaction is:

COOC2H5
i Py,
CH O + H2C
COOC2H5
Benzaldehyde
CH
ii H3 O
iii
CH
COOH
Cinnamic acid
(E)
(D)
Hence (B) is correct.

14.
Since compound (C) is CH3COOH. So,

O
O
H3C
H3C
C
O
C
H3C
OH
P4 O10
H2 O
C
O(ethanoic anhydride)
H3C
OH
O
(F)
Hence (B) is correct.

15.
(A) That is path independent e.g. U q w; U is state function, while q and w are path
functions.
(B) Work is a type of energy in transit, i.e. which appears only on surface/boundaries.
(C) w & q are not completely interconvertible.
16.
(A) Work is path function.

(B) Initially there is no opposing force but opposing force increases gradually due to diffused gas.
(C) W = ab; (area inside the curve)
a = 3 litre, b = 1 atm.
17.
Le-chateliers principle is applicable and for (R) Ptotal = PCO2 , which is equal to Kp for the given
reaction.
20.
Isodiaphers are those atoms for which (n-p) is equal. Isoesters are those species which contains
equal number of atoms as well as equal number of electrons.
6
Mathematics
PART III
SECTION A
1.
Normal vector to plane P1 3 k

Normal vector to plane P2 2i 4j 3k
a 2i j
angle between a and vector i 2j 2k is given by

cos =
=
2.
2i j i 2j 2k
5 9
.
2
f(x) = f(x)
Integrating log f(x) = x + k
f(x) = ex+k
f(0) = 1
1 = e0.ek
k=0
f(x) = ex
g(x) = x f(x) = x ex
1
I e x x e x dx e x x dx e2x dx
0
e2 1 3 e2 3 e2
e (e 1)

.
2 2 2 2
2
3.
n (S) = 64C3
Let E be the even of selecting 3 squares which from the letter L
No ways of selecting squares consisting of 4 unit squares = 7C1 7C1 = 49
Each square with 4 unit squares forms 4L shapes consisting of 3 unit squares
n (E) = 7 7 4 = 196
196
p (E) = 64
C3
4.
x2 + 9y2 + 25z2 = 15yz + 5 zx + 3xy

(x)2 + (3y)2 + (5z)2 (x) (3y) (3y) (5z) (x) (5z) = 0
1
2(x)2 2(3y)2 2(5z)2 2(x)(3y) 2(3y)(5z) 2(x)(5z)
2
1
= (x 3y)2 (3y 5z)2 (x 5z)2 0
2
x 3y = 0, 3y 5z = 0, x 5z = 0
1
1
5
1
1
1
and
and
x 3y
3y z
5z x
1 1
1
5
2

x z 3y 3y y
1 1 1
, ,
are in A.P. and x, y, z are in H.P.
x y z
7
5.
When z = n + 1 we can choose x, y from {1, 2, , n}

when z = n + 1, x, y can be chosen in n2 ways and z = n, x, y can be chosen in (n 1)2 ways
and so on
1
2
2
2
n + (n 1) + + 1 = n(n + 1)(2n + 1)
6
ways of choosing triplets
Alternatively triplets with x = y < z, x < y < z, y < x < z can be chosen in
n+1
n+1
n+1
C2,
C3,
C3 ways.
There are
n+1
C2 + 2(n + 1C3) = n + 2C2 + n + 1C3 = 2(n + 2C3) n + 1C2.
6.
z = zei
z = zei
2
zz = z z, z, z are in G.P.
2
(1)
(2)
z z
2cos2
z z
z2 + z2 = 2z2 cos 2
z + z = 2z cos .
7.
8.
c
3
1
1
2
2
3
4
= c c = 6, 1.
1
1
1
1
x and cos = y
2
x
2
y
1
since xy > 0 x +
2 or 2
x
1
y+
2 or 2
y
cos =
cos = 1, cos = 1
(1)
or
cos = 1, cos = 1
(2)
cos cos = 1
(cos + cos)2 = 4
+ is an even multiple of .
sin( + + ) = sin(2n + ) = sin
Also, sin = sin = 0
9.
IAB =
C (z3
, IAC =
2
2
i
z 2 z1
z z1 2
4
e
| z 2 z1 | | z 4 z1 |
I (z4)
z3 z1
z z1 2
4
e
| z3 z1 | | z2 z1 |
z2 z1 z3 z1 z 4 z1
| z2 z1 || z3 z1 |
(z1) A
2
| z 4 z1 |2
z z2
D 1
B (z2)
8
10.
11.
z2 z1 z3 z1 AB AC
IA 2
z 4 z1 2
AB AC
=

IA AB
z2 z1 z3 z1 AD 2 AC
2

(Since AB = 2AD)
IA AD
z4 z1 2
z4 z1 2 (1 + cos ) sec = z2 z1 z3 z1
Equation of the tangent is
x
y
sec tan 1
a
b
2
2
Normal is ax cos + by cot = a + b
2
2
2
2
The normal at P meets the co-ordinate axes at G a b sec , 0 and g 0, a b tan

a
2
2
PG2 = a b sec a sec b tan 0 2

a
PG2 =
b2
a2
b2 sec 2 a2 tan2
12.
When tan = 0
b2
PG =
a
13.
When 1 all rounder and 10 players from bowlers and batsman play number of ways
= 4C1 14C10
when 1 wicket keeper and 10 players from bowlers and batsman play number of ways
= 2C1 14C10
when 1 all rounder 1 wicket keeper and 9 from batsmen and bowlers play number of ways
= 4C1 2C1 14C9
when all eleven players play from bowlers and batsmen then the number of ways
= 14C11
Total number of selections = 4C1 14C10 + 2C1 14C10 + 4C1 2C1 14C9 +14C11.
14.
If 2 batsmen dont want to play then the rest of 10 players can be selected from 17 other players
17
number of selection = C10
19
If the particular bowler doesnt play then number of selection = C11
17
19
Total number of selection = C10 + C11
15.
Slope of tangent at any point P(x, y) is
dy
y
dx
dy
= ky y = ek(x 1)
dx
Since a(y 1) + (x 1) = 0 is normal at (1, 1) k = 1
Hence f(x) = y = ea(x 1)
16.
Area bounded =
a a 1 e
0
1
1
a
dx = a e sq. units.
a
2
a x 1
9
17.
k2
k2
(P) Limit is easily reducible to cos ec 1 by LHospital rule which exist if
1.
2
2
2
(Q) kx + (3 2k)x 6 = (kx + 3)(kx 2)
3
3
3
4 5 k .
k
4
5
(R) (2k + 1, k 1) is an interior point
2
2
(2k + 1) + (k 1) 2(2k + 1) 4(k 1) 4 < 0
6
0<k<
.. (1)
5
Centre (1, 2) and point (2k + 1, k 1) must lie on opposite side of chord x + y z = 0
2
k<
.. (2)
3
2
0<k<
3
5
5
(T) x > , 4 < x < 4 x , 4

2
2
16 x 2
log5
1
2x 5
16 x 2
51
2x 5
x ( , 9) [ 1, )
x [ 1, 4]
18.
I=
tx 2
dt
du
x t = u, then dx =
I=
19.
e u
du
t
eu du
2 t
x2
dx = 2 e x dx .
r1r2r3
s2 144
r
4(r2 + r3) + r2r3 = 2r2r3 = 144
r2r3 = 72, r2 + r3 = 18 r2= 6, r3 = 12
r sa 1
a6
r1
s
2
Similarly b = 8, c = 10
ABC is right angle triangle.
3
Smallest angle is sin1
4
1
=
6 8 = 24 sq. units
2
R=5
|r2 r3| = 6
r1r2 + r2r3 + r3r1 =
10
20.
(P) Equation of normal is y = tx + 2at+ at3 at P(t)

It intersect the curve again at point Q(t1) on the parabola such that
2
t2 t
t
2
Again slope of OP is MOP
t
2
Also, slope of OQ is
MOQ
t1
Since MOP MOQ 1
4
tt1
tt1 = 4
2
t t 4
t
t2 = 2
(Q) P(1, 2), Q(4, 4), R(16, 8)
Now, ar(PQR) = 6 sq. units
(R) Equation of normal from any point P(am 2, 2m) is
y = mx 2am am3
11 1
It passes through ,
4 4
3
4m + 8m 11m + 1 = 0
4m3 3m + 1 = 0
Now, f(m) = 4m3 3m
f(m) = 12m2 3 = 0
1
m
2
1 1
Since f f 0 has 3 normals are possible.
2 2
(T) Since, normal at P(t1) if meets the curve again at (t2), then
2
t 2 t1
t1
Such that here normal at P(1) meets the curve again at Q(t)
1
t = 1 3
2

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1

ALL INDIA TEST SERIES

AITS-CRT-I(Paper-2)-PCM (Sol)-JEE (Adv)/14

No effect of a and g on time period of spring pendulum.

Field inside the conductor is zero

Charge distribution is shown in figure.

Net friction force f =

Cell reaction is:

Before reaction 0.05 mole

2Pb NO3 2 PbO2

Moles of NaOH used to neutralise excess of HNO3 = 1.8 mole

Since A react with NaOI, it must be O

other side products are

and less likely to be

The above paragraph shows that compounds (A to D) are

In above problem concerned reaction is:

Hence (B) is correct.

Since compound (C) is CH3COOH. So,

Hence (B) is correct.

(A) Work is path function.

Normal vector to plane P1 3 k

angle between a and vector i 2j 2k is given by

x2 + 9y2 + 25z2 = 15yz + 5 zx + 3xy

When z = n + 1 we can choose x, y from {1, 2, , n}

The normal at P meets the co-ordinate axes at G a b sec , 0 and g 0, a b tan

PG2 = a b sec a sec b tan 0 2

Slope of tangent at any point P(x, y) is

(T) x > , 4 < x < 4 x , 4

r1r2 + r2r3 + r3r1 =

(P) Equation of normal is y = tx + 2at+ at3 at P(t)

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