Adva PI Sol PDF

1
FIITJEE
JEE(Advanced), 2014
ANSWERS, HINTS & SOLUTIONS
FULL TEST V
PAPER-1
Q. No.
ALL INDIA TEST SERIES
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students from
Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
AITS-FT-V (Paper-1)-PCM(Sol)-JEE(Advanced)/14
PHYSICS
CHEMISTRY
MATHEMATICS
1.
2.
3.
4.
5.
6.
7.
8.
9.
A, B, C
B, C
B, C
10.
B, C
B, C, D
A, B
11.
C, D
B, D
A, B
12.
B, C, D
A, B, D
A, B, C
13.
A, C, D
A, B
A, B, D
14.
15.
16.
17.
18.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics
PART I
SECTION A
9
intensity of S1 = 9 times of intensity S2
4
Intensity of maxima =
S2P S1P = n
d2 x 2 x n
4.
sin =
= 9 I2
for maxima
d2 n2 2
x=
2n
, = sin1 2
2
4y 0
4y0
2mv 0 1 qE0 2

t
qB0
2 m
4m2 v 0
t2
q2 E 0 B 0
x = v0
6.
I1 I2
2m v 0
q E0B 0
y1 = A sin 1t
y2 = A sin 2t
( 1 ) ( 2 1 )
yr = 2A cos 2
t sin
t
2
2
Resultant amplitude Ar = 2A0|cos()t/2|

t
1
() t = s
2 2
4
t
1
( ) t = s
2 3
6
In one cycle of intensity of 1/2s, the detector remain idle for
1
1 1
2 s sec
4
6
6
1 1
In sec cycle, active time is = 1/3 sec
2 6
In 12 sec interval, active time is 12
7.
1/ 3
(1/ 2)
Ar
cycle
2A0
A0
2/3 s
3/4 s
5/6s
3.
1/6 s
1/4 s
1/3 s
2.
= 8 sec
Let 1 = 4eV, then 2 = 2eV

(E ) represent kinetic energy of most energetic electron.
E 2 = 2(E 1)
E = 6eV
1s
3
8.
Induced e.m.f. = Bv = 0.125 V
10 e 10 0.125 V
R
2
10
0.125
Force BI = 0.5
0.25 0.5N (given)
2
Solving v = 16 m/s.
current I =
11.
0 (a x)a 0 xak
d
d
0 a[a x kx]
=
d
a
= 0 a (k 1)x
d
aV 2
U= 0
a (k 1)x
2d
dU 0 aV 2 (k 1)
F=
dx
2d
aV 2 (k 1)
v 2 v 02 2Ax = v 20 0
x
md
aV 2 (k 1)x
aV 2
1
E mv 20 0
+ 0
a (k 1)x
2
2d
2d
a2 V 2 (2k 1)
1
Emax mv 02 0
2
2d
0.5T
0.25 m
10 V
0.5 N
2
V
Q
12.
P.D. same & electric field same

Charge will be kC
Energy will be kC 2
14.
P0 + 0.8 wgh + wg(2h) + 1.2 wg(3h) = P0 + 1.2 wgh2

6.4
1.2 h2 = h[0.8 + 2 + 3.6] = 6.4 h h2 =
h
1.2
P0 + 0.8 wgh + wg(2h) = wgh1 + P0
h1 = h[0.8 + 2] h1 = 2.8 h
h2/h1 = 40/21
15.
P0 +
1
w v 2 = P0 + 0.8wgh + wg(2h)
2
v2
gh[0.8 2]
2
v = 2 9.8 0.28 2.8 = 3.92 m/s
16-18. In the time interval t = 0 sec to t = t0 sec, till the time. The relative velocity is not zero the nature
of friction will be kinetic.
4
= 20 m/sec (i)
uAB 0i (20i)
N = 100 N Fk = 0.25 100 = 25 N
a A 4m / sec 2 i , aB 0m / sec 2 i
a AB a A aB 4m / sec 2 i
VAB uAB a AB t 0
F = 15 N
10 kg
Fk
10 g
t = 5 sec
When the relative motion between block A and belt conveyor will be zero, the nature of friction will
be static and its magnitude will equal to magnitude of unbalanced external force acting on the
block A and its direction will be I the opposite direction of unbalanced external force.
Friction force
kinetic in nature
25N(i)
Fr Frictional force
25 N
15N( i) Static in nature
5sec
O
t
15 N
SECTION C
1.
1
3
p j , n ai bj i
j
2
2

r1 n 2(n p)p
r1
i b
(90i)
( i)
2( b)j ai bj
= (ai bj)
n p cos( i) b
3
i = 30
2
= cot i = 3
cos i = b =
4.
For collision the relative velocity of A with respect to B should be along the line AB
6.
Using condition of equilibrium

KL = (m1 + m2)g
Using COME
1 2
KL m1g(2L)
2
KL (m1 m2 )
m1 =
4g
4
3m1 = m2 = m2/m1 = 3
8.
If we place another similar cone on this one, net flux =
Q
0
Q
3Q
2Q
8Q
. This
0
50
50 200
must also be the flux associated with the lower cone when the
charge is raised through a height 2H because of symmetry.
Flux with the upper cone =
2H
H
+Q
5
9.
Velocity of first block before collision,

v12 12 2(2) 0.16
= 1 - 0.64
v1 = 0.6 m/s
By conservation of momentum, 2 0.6 = 2 v1 + 4 v2
also v 2 v1 = v1 for elastic collision
It gives v2 = 0.4 m/s
v1 = -0.2 m/s
Now distance moved after collision
(0.4)2
(0.2)2
& s2 =
2 2
22
s = s1 + s2 = 0.05 m = 5 cm.
s1 =
10.
By symmetry, no current will flow in arm along x-axis.
6
Chemistry
PART II
3.
More activated ring undergo EAS.
4.
Br
Br2
Me CH CH Me
Me
CCl4
CH
Me
CH
2NaNH2
Na/Liq.NH3
Me C C Me
Me
Br
5.
Me
st
1 titration
Meq. of NaOH
1
1
Meq. of Na2CO3 = Meq. of HCl = 50
=5
2
10
2nd titration
1
1
Meq. of Na2CO3 = Meq. of HCl = 10
1
2
10
Meq. of NaOH = 5 1 = 4
Meq. of NaOH Equivalent weight
Wt. of NaOH
1000
4 40
1000
= 0.16 g
6.
3
ii Zn/H O
i O
7.
CHO
CHO
CHO
NaOH dil.
Intramolecular aldol condensation
8NH3 excess 3Cl2 6NH4 Cl N2

6NaOH hot and conc. 3Cl2
5NaCl NaClO3 3H2O
Fe 2HCl
FeCl2 H2
Liberation of H2 prevents the formation of FeCl3.
Bond dissociation of F F is less than that of Cl Cl.
8.
(CH3)3SiCl is used to stop the growth of polymerisation of linear polymer formed from the
hydrolysis of (CH3)2SiCl2.
9.
Configuration of (B) is (2R, 3S)

Configuration of (C) is (2R, 3S)
10.
CH3
H3C
CH
2HIO4
CH2
OH
OH
OH
H3 C
O
CH3 H
OH H
11.
1. Addition of inert gas at constant pressure shifts the equilibrium in that direction which has
more number of gaseous moles.
2. Increasing the volume of the container shifts the equilibrium in that direction which has more
number of gaseous moles.
12.
Chemisorption unimolecular layer.
7
[Cu(NH3)4]2+ dsp2
[Ni(CN)4]2- dsp2
[CuCl4]2 sp3
23
[NiCl4]
sp
13.
14.15.
i O3
ii Zn/H2 O
Me
CH
CHO
Me
O
H3C
H3C
OH
H3C
i KCN/H
ii H3 O
H3C
C
H3C
CHO
CHO
C
H3C
CO2H
C
COONa
CHO
NaOH 50%
H /
CH2OH
CHO
D
16.18.
ZnS H2 SO4 ZnSO4 H2 S
A
White
3H2 S K 2 Cr2 O7 4H2SO 4 K 2 SO 4 Cr2 SO4 3 3S 7H2O

D
S O 2 SO 2
2H2 S SO2
2H2 O 3S
ZnSO4 2NaOH Zn OH2 Na2 SO4
Zn OH 2 2NaOH Na2 ZnO2 2H2 O
Solub le
1.
SECTION C
A present in corners and face centre.
B present in alternate tetrahedral voids.
1
1 15
No. of A per unit cell = 6 6
8
2 4
No. of B per unit cell = 4 1 = 3
15
x:y
:3 5: 4
4
x+y=5+4=9
2.
All the compounds undergo hydrolysis.
3.
Let the number of -particles emitted be x and the number of -particles emitted be y.
4x = 238 206 = 32
x=8
2x y = 10
2 8 y = 10
y = 6.
8
4.
CH2Cl
Cl
H3C
Cl
CH3
Cl
CH3
Cl
Total number of isomers = 7.

5.
H3C
CH
CH2
CH2
H2C
OH
CH
CH2
CH3
CH3
OH CH3
CH3
H3C
CH
HC
H3C
OH
CH
CH2
2
CH3
CH3
OCH3
6.
PCl3 3H2 O H3PO3 3HCl

dibasic
Number of moles required to neutralise H3PO3 = 2

Number of moles required to neutralise HCl = 3
Total number of moles of NaOH required to neutralise the solution = 5.
7.
12
C xH12 g x O2 g xCO2 g 6H2O g

4
Initial moles of gaseous reactant taken = 1 + (x + 3) = x + 4

Final moles of product formed = x + 6
Number of moles increased = 2
Pressure Number of moles.
2
2
% of pressure increased
100 , 20
100 , x = 6.
x 4
x 4
8.
N2O, NO and CO are neutral oxides remaining are acidic oxides.
9.
The following compounds give positive iodoform test

O
H3C
CH
CH3 , H3C
CH2
OH , H3C
O
CH3 ,
OH
CH3 ,
CH CH3
OH
10.
In the following compound sulphur has +6 oxidation state

H2S2O7, H2SO4, H2SO5, H2S2O8
9
Mathematics
PART III
SECTION A
2.
Let origin be centre of larger circle and O be the centre of smaller circle.
Equation of (1): x 2 y2 2
Equation of (2):
x 2 2 y 2 1
5
7
A ,
4 4
x xC
y yC
xB A
, yB A
2
2
2
2
xC yC 2
y
(1)
2
5
7
yC
4 2
4 1
AC
3.
7
2
Let B (0, 0), C (a, 0), A (h, k) and P , .

d A, BC
d P, BC
d B, AC
d P, AC
Equation of AC is kx h a y ka 0
(2)
ka
k h a ka
B
(0, 0)
C (a, 0)
Equation of AB is kx hy 0
d C, AB
d P, AB
Solving,
ka
k h
ha
k
,
3
3
4.
Orthocentres of triangles formed by three tangents and corresponding normals to a parabola are
equidistant from axis of parabola.
5.
Number beginning with 2 and not divisible by 5 is 6! 120 = 600

Number beginning with 3 and not divisible by 5 = 600
Number beginning with 5 and not divisible by 5 = 720
Total = 1920
Number beginning with 6 2 and not divisible by 5 is 120 24 = 96
Total = 2016
2017th number is 6325789
6.
PQ T
QTPT QP PQ
PQ is symmetric
10
PQP 1 QPP 1 Q
P 1PQP 1 P 1Q
QP 1 P 1Q
P Q
1
8.
QT P 1
P1Q
P ui i2 2
P ui k i2 2
u1, u2, .., un are mutually exclusive events.

P u1 P u2 ........ P un 1
k 12 2 22 2 32 2 .......n2 2 1
6
k
n n 1 2n 1 12n
A event of drawing a white ball
2
4
6
2n
P A k 12 2
k 22 2 .
k 32 2 .
..... k n2 2 .
2n 1
2n 1
2n 1
2n 1
k
2
2
2
2
1 .2 2 .4 3 .6 ..... n .2n 2.2 4.2 6.2 ..... 2n.2
2n 1
2.k
13 23 33 ........ n3 2 1 2 3 ..... n
2n 1
2
2
2k n n 1
n n 1
2n 1
4
2.6 n2 n 1 4n n 1
4 2n 1 n n 1 2n 1 12n
2
Lt P A Lt
1
1
1
3 1 4 2 3
n
n
n
2
1
1
1
2
2 1 12 2 3
n
n
n
n
3
4
cos
12
12 2
sin x
cos x
sin
9.
10.
|z1| = |z2| = 1; |z1 + z2| = 1

z1 z2 z1 z2 1
|z1 + z2| = |z1| |1 + ei| = 1
|z2 z1| = |z1| |ei 1|
11.
100
x1 x100 1
2
50
x1 d x100 1
2
11
12.
Let y < x
y
x

x xy
R
13.
1
1 R
(a + b) = x, then x 3 21x + 20 = 0
Which has roots 1, 4, 5
SECTION C
8.
2 1 3 5 7 ...... a 2 1 3 5 7 ...... b 2 1 3 5 7 ...... c
a 1 a 1
b 1 b 1
2
1 2
2
1 2
2
2
2
2
a 1 b 1 c 1
c 1 c 1
2 2 1 2 2
a 6 and a b c 21
a = 7, b = 5, c = 9
ab 2
3
9.
10.
C1 8P6
C1 8P6 3P2 7P5

9
P7
a11 a12 1 1 1 1 a11 a12

a
21 a22 2 1 2 1 a21 a22

a11 2a12 a11 a21
a11 a12 2a12 a22
7
12
..... (i)
..... (ii)
a21 2a22 2a11 a21

a21 a22 2a12 a22
From (ii), a11 a22
a21 2a12
2
a11a22 a21a21 a11 2 a12
a11 2a12

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1

ALL INDIA TEST SERIES

Resultant amplitude Ar = 2A0|cos()t/2|

Let 1 = 4eV, then 2 = 2eV

Induced e.m.f. = Bv = 0.125 V

P.D. same & electric field same

P0 + 0.8 wgh + wg(2h) + 1.2 wg(3h) = P0 + 1.2 wgh2

Using condition of equilibrium

If we place another similar cone on this one, net flux =

Flux with the upper cone =

Velocity of first block before collision,

By symmetry, no current will flow in arm along x-axis.

More activated ring undergo EAS.

Intramolecular aldol condensation

8NH3 excess 3Cl2 6NH4 Cl N2

Configuration of (B) is (2R, 3S)

Chemisorption unimolecular layer.

ZnS H2 SO4 ZnSO4 H2 S

3H2 S K 2 Cr2 O7 4H2SO 4 K 2 SO 4 Cr2 SO4 3 3S 7H2O

All the compounds undergo hydrolysis.

Total number of isomers = 7.

PCl3 3H2 O H3PO3 3HCl

Number of moles required to neutralise H3PO3 = 2

C xH12 g x O2 g xCO2 g 6H2O g

Initial moles of gaseous reactant taken = 1 + (x + 3) = x + 4

N2O, NO and CO are neutral oxides remaining are acidic oxides.

The following compounds give positive iodoform test

In the following compound sulphur has +6 oxidation state

Let B (0, 0), C (a, 0), A (h, k) and P , .

Number beginning with 2 and not divisible by 5 is 6! 120 = 600

u1, u2, .., un are mutually exclusive events.

|z1| = |z2| = 1; |z1 + z2| = 1

2 1 3 5 7 ...... a 2 1 3 5 7 ...... b 2 1 3 5 7 ...... c

C1 8P6 3P2 7P5

a11 a12 1 1 1 1 a11 a12

21 a22 2 1 2 1 a21 a22

a21 2a22 2a11 a21

a11a22 a21a21 a11 2 a12

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