Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC PREMISE 200 SL (NEW)/ 200 L IDLT/A 118 \Version_1 / F Revision Date: 25.06.2004 102000007361 Print Date: 21.07.2004 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product information Trade name PREMISE 200 SL (NEW)/ 200 L ID LT/ A, Product code (UVP) (04982193, 05689376, 04958608, 04982177, (04982207, 04982231, 05235952, 05257085, (05425077, 04982215, 05591325, 06072917 Usage insecticide ‘Company Bayer CropScience SA 16, rue Jean-Marie Leclair 69009 Lyon France Emergency telephone number +33(0)4.72.85.25.25 Telefax +33(0)4.72.85.27.99 Numéro INRS +33(0)1.45.42.59.59 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical nature Soluble concentrate (SL) Imidacloprid 200 g/t Hazardous components Chemical Name ‘CAS-No.7 | Symbol) | Rephrase(s) | Concentration Pa] EINECS No. Imidacioprid 138261-41-3 | Xn R22, R52 17,80 NeMiethyr2-pymoidone | 672504 | Xr RIES 4030 212-828-4Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC PREMISE 200 SL (NEW)/ 200L IDLT/A 218 Version 1 / F Revision Date: 25.06.2004 sv2000007381 Print Date: 21.07.2004 3. HAZARDS IDENTIFICATION Risk advice to man and the environment No particular hazards known, 4. FIRST AID MEASURES: General advice Move out of dangerous area. If the patient is likely to become unconscious, place and transport in stable sideways position. Remove soiled or soaked clothing immediately Inhalation Move the patient to fresh air and keep at rest. Call a physician immediately. Skin contact Wash off immediately with soap and plenty of water. Take medical treatment. Eye contact In case of contact with eyes rinse thoroughly with water. Call a physician immediately. Ingestion Do not induce vomiting. Wash out mouth with water. Call a physician immediately. Notes to physician Treatment Treat symptomatically. Monitoring of respiratory and cardiac functions. Gastric lavage, then charcoal (carbo medicalis) and sodium sulfate. 5. FIREFIGHTING MEASURES Suitable extinguishing media water spray ‘carbon dioxide (C2) foam sandEnvironmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC PREMISE 200 SL (NEW)/ 200L IDLT/A 3/8 Version 1 / F Revision Date: 25.06.2004 so2000007381 Print Date: 21.07.2004 Specific hazards during fire fighting In the event of fire the following can be released hydrogen chloride (HCI hydrogen cyanide (hydrocyanic acid) carbon monoxide (CO) ‘sulphur dioxide (S02) nitrogen oxides (NOx) ‘Special protective equipment for fire-fighters In the event of fire and/or explosion do not breathe fumes. Use breathing apparatus. Further information ‘Contain the spread ofthe fre-fghting media. Do not allow run-off from fre fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES Personal precautions. ‘Avoid contact with spilled product or contaminated surfaces. Wear personal protective equipment. Unprotected persons must be kept away. Environmental precautions Do not discharge into the drains/surface water/groundwater. Methods for cleaning up ‘Take up with absorbent material (e.g. sand, earth or a proprietary absorbent material). Pack spilled material in suitable containers for recovery or disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations Additional advice Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13,(ung) pesonsep aq rsnut paueajo oq youuED yerp STUDUETEE ured Bursn a19}2q Pue AjareIpoUTU SUMO} paxLOS J0 Po[!Os BAOTOY, ‘ABpyHOM Jo Pus auf ye pu sye9sq 210J9q spuEY YSEAA, ‘Ajareredas soupoy> Surysom doy ‘Bunpoy> pure S940 “UryS YIM 1EIUCD Ploay sounseout 9Uo1SKH, sossuyi Ages uonsaioid a4, S9A0[8 1UEISISAX — 1HAALOS uorsaioud puryy quawidinba aansojoud jeuosieg NOWOSLOYd TWNOSHAd / STONLNOD FUNSOdXA “8 seqeq sewskjod pepniyxa0a (2uarkujehod Aysuep yBu)) 3d seuoyew aiqeins, ‘2.0%-0 eumesodusoy eBes015 ‘Augers o6e1015 ‘syms®uipoay jeutue pue xuUp ‘pooy woy Aeme dooy ‘Be10}5 uouRuoo Uo eoIApYy “yeurequco jeur6uo ut a101S “s0e/d peyeiquanfem Pue [009 ‘Aup e u! peso ANYBRA Si8UFEUOD deay ‘Sfourewoo pue seare eBe10}s 40) sJuaWesINbey, aBes01g Uuone|quen ysneyxe ajeudoidde yum papinoid eae ut AUO as Suypuey ayes uo eoupy Suypuey 3OVYOLS GNV ONMGNVH *Z VOO'LO'LZ ‘8d Julie +8€L00000201 ~O0Z'GO'SZ “BIE UOISIASY 4 / | UOISIEA, sv V/17Gl 1002 (MAN) 1S 002 3SINIYd O/8S/1007 eAansauiq Oa oF SuIps0988 LATHS VLVC ALAAVS: o 9IUAING [BJUILUUOALAUT a é N<{> wit) ¢ m‘UONEINULO} JE|LUIS e YM PayONpURD ySeL ‘6x8 000"s < (Wes) OST ‘UoRe|MUIO} Je|LUIS © YUM ParoNPUOD 1591 Ow €'9 < (es) 0507 ‘Ayprx0) uoneeyut aynoy Uone;nuuoy emus @ ya PeronpuCD ISO, SyyOus 9¢z'z < (es) 057 faptnoy ye enoy NOLLVIWMONI TVDI90109IXOL “tL ‘SuonIpuod JeULIOU Jepun 9/qeIg "suoNINAIsUI paquosasd ‘1 Surpioooe poypursy put poi01s way suondees snopseZeY ON suonowas snopsezey ALIALLOVIY ONY ALITIGVLS ‘Ob aigenyes Ajayajduoo Sane weNb/ANIANIOS 9.0218 mu zit e0 fysuog esuis nia 2. 88 quiod ysei eiep Kioyes onewore sn0p0 wunoig wot sn0}00 4897 ‘pint tuo sousreoddy ‘S3lLWadOUd TWOINSHO GNV TWOISAHd “6 ‘YOOZ LOLZ BIE JUL Feez00000201 ¥OOT'90'Sz “IEC UOISINOY 4/1 UOISJEA 8S v/17GI 1002 (MAN) 1S 002 3SINSYd OA/RS/LOOT PAndeNG Sa OF Bumps LAAHS VLVG ALAAVS 90UdI9S JB] UILUUOALAUEnvironmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC PREMISE 200 SL (NEW)/ 200L IDLT/A 6/8 Version 1 / F Revision Date: 25.06.2004 so2000007221 Print Date: 21.07.2004 Skin iritation non-iritant (rabbit) ‘Test conducted with a similar formulation. Eye irritation slight initant effect - does not require labeling (rabbit) Test conducted with a sirriar formulation. Sensitization Non-sensitizing (guinea pig) OECD 406, Buehler test ‘Test conducted with a similar formulation 12. ECOLOGICAL INFORMATION Ecotoxicity effects Toxicity to fish LCS0 (Rainbow trout (Oncorhynchus mykiss)) 211 mg/l Exposure time: 96 h The value mentioned relates to the active ingredie imidactopri, Toxicity to daphnia C50 (Water lea (Daphnia magna)) 85 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient imidacloprid Toxicity to algae C50 (Desmodesmus subspicatus) > 10 mg/l Growth rate Exposure time: 72 h The value mentioned relates to the active ingredient imidactoprid 13, DISPOSAL CONSIDERATIONS Product Dispose of by incineration in an authorised special waste incineration plant. Comply with local legistation, For larger quantities contact manufacturer. Waste key for the unused product (020108 agrochemical waste containing dangerous substancesSAFETY DATA SHEET according to EC Directive 2001/58/EC PREMISE 200 SL (NEW)/ 200 L IDLT/A 718 Version 1 / F Revision Date: 25.06.2004 102000007381 Print Date: 21.07.2004 14. TRANSPORT INFORMATION ‘ADR Not dangerous goods GGVE Not dangerous goods evs Not dangerous goods IATA_C Not dangerous goods TAP Not dangerous goods. IMDG Not dangerous goods RID Not dangerous goods 15. REGULATORY INFORMATION Classification: Hazard warning labelling not compulsory Classement FRANCE (décision de la Commission des Toxiques) Classification’ Not classified ‘S-phrase(s) $2 Keep out of the reach of children 13 Keep away from food, drink and animal feedingstufts. 849 Keep only in the original container. Exceptional labelling To avoid risks to man and the environment, comply with the instructions for use. Further information WHO.classification: Ill (Sightly hazardous) Legistation on the control of Legislation des Installations Classées pour la Protection de ‘major-accident hazards Environnement (Loi du 19/07/76 modifiée et Décret du 21/09/77 involving dangerous ‘modifié)- Rubrique(s) de la Nomenciature:, Rubrique n° 155: Depots substances de produits agropharmaceutiques.Environmental Science SAFETY DATA SHEET according to EC Directive 2001/58/EC PREMISE 200 SL (NEW)/ 200L IDLT/A 8/8 Version 1 / F Revision Date: 25.06.2004 102000007381 Print Date: 21.07.2004 Occupational diseases Table number(s) 84 Health effects caused by organic solvents in occupational applications. ‘Occupational health precautions. Not concerned. 16, OTHER INFORMATION Further information Text of R phrases mentioned in Section 2: R22 Harmful if swallowed, 36/38 Inttating to eyes and skin. R52 Harmful to aquatic organisms. ‘The information provided in this safety data sheet has been provided according the requirements from the French modified decree “arrété du 5 janvier 1993". This sheet complements the technical sheet but does not replace it. The information contained in this sheet is based on knowledge of the product at the date of publication and is given in good faith. Users are further reminded of the possible Tisks of using a product for purposes other than those for which it was intended. The user is fully responsible for taking all the necessary precautions whilst using the product. The aim of the statutory tegulations indicated is to help the user to full his obligations regarding the use of hazardous products. This lst should not be considered as exhaustive. It does not exonerate the user from futfiling other existing legal obligations in addition to those mentioned, relating to the use and storage of the product. ‘This remains solely the responsibilty of the user. ‘Changes since the last version will be highlighted in the margin. This version replaces all previous versions.