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Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science
& Technology (NIIST), CSIR, Thiruvananthapuram-695 019, India
E-mail: mlpreddy55@gmail.com
Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of
Science, Bangalore - 560012, India
*mlpreddy55@gmail.com
Figure S1. 1H and 13C NMR spectra for the ligand HL.
Complex 1
Complex 2
Complex 3
Complex 4
Complex 1
Complex 2
Complex 4
Figure S5. Thermogravimetric plots for complexes 1, 2 and 4.
Figure S7. Luminescence decay profiles (298K) for complexes 1 and 2 excited at 355 nm and
monitored at 612 nm and 545 nm, respectively.
Figure S8. Low temperature (77K) luminescence decay profile of complex 1 excited at 355
nm and monitored at approximately 612 nm.
Figure S9. Low temperature (77K) luminescence decay profile of complex 2 excited at 355
nm and monitored at approximately 545 nm.
Figure S10. 5D0 and 5D4 decay profiles (298K) for complex 4 excited at 355 nm and emission
monitored around 612 nm for 5D0 and 545 nm for 5D4.
Table S1. Infra-red vibrational frequencies for the carboxylate functionalities of the ligand
and complexes 1-4.
as(C=O) cm-1
HL
1699
s(C=O) cm-1
(C=O) cm-1
1434
----
1643,1594
1426,1400
217, 194
1643,1594
1424,1404
219, 190
1643,1594
1428,1402
215, 192
1646,1595
1428,1405
218, 190
Table S2. EDS Analysis Results for the complex {[Eu0.5Tb0.5(L) 3(H2O) 2]}(4)
Complex
Element
Wt %
{[Eu1/2Tb1/2(L)3(H2O)2]}n(4)
Eu
50.7
Tb
49.3
Eu/Tb
(EDS)
Eu/Tb
(cacld)
1.02