| CrO,Ch+H,0* Name Condition Example | BretCS, Causes Br to go on ring 1 iH 4 ‘Compound should be See “Bey H:O A Bry + HO more —- | activated than a benzene br _ Reduces group ey # Sn+HCl l ‘Se + Hor Removes Diazo group Ng. £1 CuCH#Hel “Sy CuCl i | a 1 HAH of NaS or ‘Special reagents which reduce only 1 NO2 group NazS Converts toluene to benzaldehyde‘Substitutes allylic carbon with aldehyde ] a NBS NES i “= 2 * oe Nae, 1a Recuces carbonyl group ta hatone or aldehyde wRo 1 Famoves daze group Nes, atl HyPOs = “Sy _HsPO: I Cd aad | | LAH, or NaBH, Teulon anleaeat : ; 5 | Rut (Litwum Removes halogen from RX and adds R dialleylcuprate(|]) | jaca “Adda Mg between REK Reduces oll to comessponding alkanes } Red P+ Hi |Alcoholic KOH | Removes HX fram compound and ads double ond Indust | Ramaes all Hi Reduces alkyne to alkene Hi, PdBaSO, or S$-Quinaline (Lindiar’s | catalyst) or BH THF Replaces © of Carbonyl with rnettiyl Ph.P=CH, a ee ine ————* esch, i KC nO Neel NOX 4, —> OWOM (oxymercuration, Hye CHy demercuration) aa (i) Hgt@Ac), « ie Bie ae THF-H,O on iiN@BH-OHOs0, + H-O- ‘Gives syn wcinal ditialide from alkene NaHSO, or HOOH Cold Dilute < | ie Kino, po on c— Sook, (Hydroxylation) Ghee arti weinal Jal Gy Per-formic acid % y ~ | . (Anh fe Sask Hydroxylation) | OH Hr in presence ‘Anti Markonka's ‘of HO; (only for - HBr) pl * ge Py Replaces ‘=’ with either C=O ar COOH Hot Alkaline gta a pa ee KiMnO, Sp 4 me a R ‘Adds methyl in cycle manner R CHa. ZnCu1 () Ale KOH 4 (ithianei, H H—> HOS=—=cH H H x, CCl ‘Adda beth 3 af compound having Gauble ar tiple band ls R. R Cold Da KMnG, SS ee TCO o —_ é fg Hot Kin, Ry — RE R K o o | -crsoy Super Leading Group LiAIH,-ether Reduces ester to alcohol NaBH,- ROH |pratic Reduces to alcohol bit cannot act on ester solvent) (Causes cleavage and reduction of ester Heat, High Q Gr,02-Cu,0 2 Pressure ® o—R, ——P a on FRY OHKlin, H" (or) K,0r,0, HY tary ‘Oxidises alcohol to. acid H:Cro. PCC (Pyridine ms ¥ cl ch \ Solvent C3. Restricted omdation of alcohol. Forms aldehyde: on f MnOz special oxidising agent for alcohol =——* ‘OH ‘OH HI for 1 degree Hi-O7 CH, FH oa ve It 3 He, + HG ford degree Hye-O7"™CH, +H) ——% HAC, + HC-OH carbon 1 Hs Ke Hi 'Cane HI contains: HAC -CH, ——® HAC | HyC—OH very less water CH Hypoo? ae iRolbe's Reaction)i) Alurmeniuin iso, butoxide i)propan-2-ol (MPV Reduction) Reduces ketone to alcohol Aluminiumiso butoxide ~ eo —— > “Sei ae propan-2-al | This is reaction of compounds which don't have alpha hydrogen Cannizaro i si Reaction a Te L. + H.C-oH wo NAOH : 2. (Cross Cannizaro3 Intramolecular G4 50%, ss Cannizaro coh NaOH = ¢—oH o 9 Reverse of MPV oxidises alcohol to carbonyl iAlurnenium ots al isobulode cH aM ii) Acetone ia Mats MyGe (Oppenaur 4,—C-OH = =_—_____» o=o Oxidation) 4 Me Hye me RO (Claisen fi a 4 Schrredt meen + [| — Ly peacton Ginnamaldehyde i) Acetic ee anhydride fe —=cH— . H.c— Ch, ae eee ijsodium acetate > (Perkin's reaction) HO Co his Cinnamic: Acid(Name of Reagent Conditions Example of its Use r = | kyr) with Sees agent, used commonly | Warm gently for oxidising secondary alcohols to conc. H,50, | ketones. Excess conc. KK Dehydrating agent, used to | H)SO4 dehydrate alcohols to alkenes. | Free radical reaction, used to | cl, Ultra Violet light : | als) — igh convert alkanes to haloalkanes. | Room temperature, /Electraphilic addition, converts | Br In CCI | is rE in the dark alkenes to dihaloalkanes. | Nickel catalyst, 300 Hale) and 30 Hydrogenating agent, used to | = atmospheres convert benzene to cylcohexane. | pressure | ie) Nickel catalyst, 150 | Reducing agent, used to convert rae c alkenes to alkanes Tin in pietii Reducing agent for converting hydrochloric acid nitrobenzene to phenylamine. Acidified KMNO4 Room temperature Oxidising agent, converts alkenes to diols. NaOH in ethanal Reflux Elimination reaction, converts haloalkanes to alkenes.| | Aqueous NaOH | Nucleaphilic substitution, converts Refl ii haloalkanes to alcohols, Used to make grignard reagents th Reflux aera with haloalkanes. | Chlorinating agent, reacts with OH | Pls Room temperature |group in alcohols and carboxylic | acids | HNO; and H,50, $50 JAdds NO, group onte benzene ring. | Cl, and AICI Warm gently Adds Cl group onto benzene ring. CH;CH,CL and wasinigently Adds CH)CH; group onte benzene ALCL; ring, HCI and NaNO, Below 5 C Forms diazonium salts with phenylamine.