1

0.4219

Tr
En Punto Critico

2
j

Vr
1

p
-0.33387
-0.33565
-0.33937
-0.34527
-0.3533
-0.35806
-0.36329
-0.36663
-0.36894
-0.37012
-0.37108
-0.3718
-0.37229
-0.37253
-0.3729
-0.37314
-0.37339
-0.37358
-0.3737
-0.37376
-0.37389
-0.374
-0.3741
-0.37418
-0.37425
-0.37431
-0.37436
-0.37441
-0.37446
-0.37449
-0.37453
-0.37456
-0.37459
-0.37461
-0.37464
-0.37466
-0.37468
-0.3747
-0.37471
-0.37473

q
0.004548
0.015631
0.033933
0.05753
0.084235
0.098193
0.112326
0.120835
0.126505
0.129336
0.131599
0.133295
0.134425
0.13499
0.135836
0.1364
0.136964
0.137415
0.137669
0.13781
0.13812
0.138373
0.138599
0.138768
0.138937
0.139077
0.13919
0.139303
0.139404
0.139471
0.139556
0.139629
0.139697
0.139756
0.139809
0.139857
0.139902
0.139941
0.139978
0.140012

0.125
Tri

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Pr
1

0.4
0.5
0.6
0.7
0.8
0.85
0.9
0.93
0.95
0.96
0.968
0.974
0.978
0.98
0.983
0.985
0.987
0.9886
0.9895
0.99
0.9911
0.992
0.9928
0.9934
0.994
0.9945
0.9949
0.9953
0.9957
0.9959
0.9962
0.9965
0.9967
0.9969
0.9971
0.9973
0.9974
0.9976
0.9977
0.9978

Pr,o
0.0051745
0.0277887
0.0868693
0.2004585
0.3833616
0.5044916
0.6469984
0.7431839
0.8118792
0.8476186
0.8768839
0.8992281
0.9143131
0.9219124
0.9333826
0.9410768
0.9488091
0.9550224
0.9585281
0.9604791
0.9647795
0.9683067
0.9714485
0.9738088
0.9761726
0.978145
0.9797247
0.9813059
0.9827303
0.9836806
0.9848693
0.9859001
0.9868522
0.9876858
0.9884403
0.9891158
0.9897517
0.9903083
0.9908254
0.9913028

A
0.01364
0.04689
0.1018
0.17259
0.2527
0.29458
0.33698
0.36251
0.37951
0.38801
0.3948
0.39989
0.40327
0.40497
0.40751
0.4092
0.41089
0.41225
0.41301
0.41343
0.41436
0.41512
0.4158
0.4163
0.41681
0.41723
0.41757
0.41791
0.41821
0.41841
0.41867
0.41889
0.41909
0.41927
0.41943
0.41957
0.41971
0.41982
0.41993
0.42004

B
0.00162
0.00695
0.0181
0.0358
0.0599
0.07419
0.08986
0.09989
0.10683
0.11037
0.11323
0.1154
0.11686
0.11759
0.11869
0.11943
0.12016
0.12075
0.12109
0.12127
0.12168
0.12201
0.12231
0.12253
0.12276
0.12294
0.12309
0.12324
0.12338
0.12347
0.12358
0.12368
0.12376
0.12384
0.12391
0.12398
0.12404
0.12409
0.12414
0.12418

r
-1E-005
-0.00016
-0.00092
-0.00309
-0.00757
-0.01093
-0.01514
-0.01811
-0.02027
-0.02141
-0.02235
-0.02307
-0.02356
-0.02381
-0.02418
-0.02443
-0.02469
-0.02489
-0.025
-0.02507
-0.02521
-0.02533
-0.02543
-0.02551
-0.02558
-0.02565
-0.0257
-0.02575
-0.0258
-0.02583
-0.02587
-0.0259
-0.02593
-0.02596
-0.02599
-0.02601
-0.02603
-0.02605
-0.02607
-0.02608

-0.10692
-0.09703
-0.08124
-0.06168
-0.04059
-0.03002
-0.01965
-0.01358
-0.00961
-0.00765
-0.0061
-0.00494
-0.00417
-0.00379
-0.00322
-0.00283
-0.00245
-0.00215
-0.00198
-0.00188
-0.00168
-0.00151
-0.00136
-0.00124
-0.00113
-0.00103
-0.00096
-0.00088
-0.00082
-0.00077
-0.00071
-0.00066
-0.00062
-0.00058
-0.00054
-0.00051
-0.00048
-0.00046
-0.00043
-0.00041

1 0.9979 0.9917406 0.42013 0.12422 -0.37474 0.140043

-0.0261 -0.00039
1 0.998 0.9920192 0.42019 0.12425 -0.37475 0.140062
-0.0261 -0.00038
1 0.9981 0.9924173 0.42027 0.12429 -0.37476 0.140091 -0.02612 -0.00036


-0.03495
-0.03011
-0.02273
-0.01445
-0.00703
-0.0041
-0.00188
-0.00093
-0.00048
-0.00031
-0.0002
-0.00013
-9E-005
-8E-005
-6E-005
-4E-005
-3E-005
-3E-005
-2E-005
-2E-005
-2E-005
-1E-005
-1E-005
-9E-006
-7E-006
-6E-006
-5E-006
-4E-006
-4E-006
-3E-006
-3E-006
-2E-006
-2E-006
-2E-006
-2E-006
-1E-006
-1E-006
-1E-006
-1E-006
-9E-007

-8.64E-007
-7.04E-006
-1.94E-005
-2.58E-005
-1.75E-005
-1.03E-005
-4.07E-006
-1.63E-006
-6.57E-007
-3.53E-007
-1.87E-007
-1.03E-007
-6.37E-008
-4.83E-008
-3.01E-008
-2.08E-008
-1.37E-008
-9.30E-009
-7.29E-009
-6.31E-009
-4.47E-009
-3.26E-009
-2.39E-009
-1.84E-009
-1.39E-009
-1.07E-009
-8.55E-010
-6.71E-010
-5.29E-010
-4.46E-010
-3.56E-010
-2.88E-010
-2.34E-010
-1.92E-010
-1.59E-010
-1.33E-010
-1.11E-010
-9.36E-011
-7.94E-011
-6.77E-011

0.026592
0.087926
0.191174
0.337662
0.536539
0.663969
0.821501
0.939485
1.034767
1.090251
1.140192
1.18212
1.212938
1.229435
1.25586
1.27483
1.29514
1.312566
1.322917
1.328864
1.3425
1.354305
1.365378
1.374096
1.383224
1.391189
1.397827
1.404734
1.411208
1.415674
1.421447
1.426638
1.431603
1.436098
1.4403
1.444177
1.447939
1.451329
1.454565
1.457634

x1
0.987828
0.958372
0.908247
0.838826
0.749794
0.696118
0.633207
0.588382
0.553489
0.533671
0.51613
0.501613
0.49106
0.48545
0.476522
0.470155
0.463377
0.457593
0.45417
0.452209
0.447722
0.443852
0.440234
0.437393
0.434425
0.431842
0.429693
0.427461
0.425373
0.423935
0.422078
0.420411
0.418819
0.417379
0.416035
0.414795
0.413594
0.412513
0.411482
0.410504

x2
0.011915
0.040098
0.086363
0.146799
0.217128
0.25491
0.293987
0.317941
0.33409
0.342214
0.348735
0.353638
0.356913
0.358552
0.361012
0.362654
0.364297
0.365612
0.366352
0.366763
0.367668
0.368408
0.369067
0.36956
0.370055
0.370466
0.370796
0.371125
0.371422
0.37162
0.371867
0.372081
0.372279
0.372452
0.372609
0.372749
0.372881
0.372996
0.373103
0.373202

x3
0.00187
0.00848
0.02349
0.05017
0.09298
0.12316
0.16267
0.19357
0.21925
0.23448
0.24837
0.26015
0.26889
0.27359
0.28116
0.28662
0.29249
0.29755
0.30057
0.3023
0.30629
0.30975
0.31301
0.31558
0.31828
0.32064
0.3226
0.32466
0.32658
0.32791
0.32963
0.33118
0.33267
0.33401
0.33527
0.33643
0.33756
0.33858
0.33955
0.34048

Zv
0.9878
0.9584
0.9082
0.8388
0.7498
0.6961
0.6332
0.5884
0.5535
0.5337
0.5161
0.5016
0.4911
0.4855
0.4765
0.4702
0.4634
0.4576
0.4542
0.4522
0.4477
0.4439
0.4402
0.4374
0.4344
0.4318
0.4297
0.4275
0.4254
0.4239
0.4221
0.4204
0.4188
0.4174
0.416
0.4148
0.4136
0.4125
0.4115
0.4105

Zl
0.0019
0.0085
0.0235
0.0502
0.093
0.1232
0.1627
0.1936
0.2192
0.2345
0.2484
0.2602
0.2689
0.2736
0.2812
0.2866
0.2925
0.2976
0.3006
0.3023
0.3063
0.3098
0.313
0.3156
0.3183
0.3206
0.3226
0.3247
0.3266
0.3279
0.3296
0.3312
0.3327
0.334
0.3353
0.3364
0.3376
0.3386
0.3396
0.3405

ln(v)
-0.0121
-0.0408
-0.0875
-0.1476
-0.216
-0.2521
-0.289
-0.3113
-0.3262
-0.3337
-0.3397
-0.3442
-0.3472
-0.3487
-0.351
-0.3525
-0.354
-0.3552
-0.3558
-0.3562
-0.357
-0.3577
-0.3583
-0.3588
-0.3592
-0.3596
-0.3599
-0.3602
-0.3605
-0.3606
-0.3609
-0.3611
-0.3612
-0.3614
-0.3615
-0.3617
-0.3618
-0.3619
-0.362
-0.3621

-8E-007 -5.80E-011 1.460524 0.409585 0.373293 0.34135 0.4096 0.3413 -0.3622

-8E-007 -5.23E-011 1.462402 0.408987 0.373351 0.34191 0.409 0.3419 -0.3622
-7E-007 -4.48E-011 1.465145 0.408116 0.373433 0.34274 0.4081 0.3427 -0.3623

ln(l)
-0.01209888
-0.04076369
-0.08747083
-0.14756079
-0.21601981
-0.25212326
-0.28896142
-0.31129026
-0.32623575
-0.33372087
-0.33971337
-0.34420975
-0.34720812
-0.3487075
-0.35095678
-0.35245642
-0.35395615
-0.35515598
-0.35583091
-0.35620587
-0.3570308
-0.35770575
-0.35830572
-0.3587557
-0.35920569
-0.35958068
-0.35988067
-0.36018066
-0.36045066
-0.36063065
-0.36085565
-0.36105065
-0.36123065
-0.36138815
-0.36153064
-0.36165814
-0.36177814
-0.36188314
-0.36198064
-0.36207064

FO
-5.924E-012
0
-6.609E-012
-6.434E-014
-1.099E-014
-1.751E-011
-7.838E-011
-7.067E-013
-1.510E-014
-1.267E-009
-4.162E-010
-7.233E-011
-1.196E-011
-3.001E-013
-8.448E-013
-3.433E-013
-5.884E-015
0
-8.438E-015
0
0
-4.550E-010
-1.310E-014
-6.532E-011
-1.665E-014
0
-7.255E-011
-4.441E-015
-1.288E-014
-1.126E-011
-7.960E-014
-6.661E-015
-3.819E-014
-4.996E-015
-3.997E-015
0
0
0
0
0

dFO/dPr
190.540014
34.1827563
10.1849515
3.93425676
1.71330375
1.13571125
0.72726686
0.53124848
0.41169043
0.35297558
0.3053552
0.26851886
0.24299348
0.22980667
0.20930973
0.19503052
0.1801074
0.16758012
0.16025017
0.15607547
0.14659523
0.13848722
0.13096219
0.12508753
0.11898193
0.11369034
0.10930431
0.10476386
0.10052802
0.09761597
0.09386513
0.09050378
0.08729899
0.08440543
0.08170781
0.07922345
0.07681819
0.07465522
0.07259349
0.07064086

Pr,j+1
0.00517452
0.0277887
0.08686928
0.20045847
0.38336162
0.50449165
0.64699835
0.74318385
0.81187924
0.84761861
0.87688395
0.89922811
0.91431312
0.92191243
0.93338256
0.94107682
0.94880913
0.95502242
0.95852811
0.96047906
0.96477955
0.96830672
0.97144848
0.97380882
0.9761726
0.97814504
0.97972472
0.98130593
0.98273033
0.98368062
0.98486926
0.98590011
0.98685224
0.9876858
0.98844035
0.98911575
0.98975169
0.99030833
0.99082538
0.9913028

0.375

Vol Liq
0.3864081
0.40675341
0.43260893
0.4671931
0.51740932
0.55336046
0.6034019
0.6459322
0.68412211
0.70818927
0.73113783
0.7514269
0.76697892
0.77553865
0.78960559
0.79998426
0.81136716
0.82136426
0.82740715
0.83091406
0.83905706
0.84622252
0.85304202
0.85848107
0.86424245
0.86932625
0.87360443
0.87809522
0.88234204
0.88529393
0.88913507
0.89261482
0.89596565
0.89901976
0.90189026
0.90455359
0.90715164
0.90950381
0.91175986
0.91390913

Vol. Vapor
203.629089
45.9837618
16.7285314
7.81113905
4.17245731
3.12763929
2.34884238
1.96342844
1.72707119
1.61180676
1.51936139
1.44885989
1.40070591
1.37610008
1.33827618
1.31226444
1.28540984
1.26315014
1.25025392
1.24295331
1.22649848
1.21256739
1.19976004
1.18984628
1.17962389
1.17083304
1.16359606
1.15615248
1.14925333
1.14453592
1.13849092
1.13310388
1.12799473
1.12340608
1.11914649
1.11523937
1.11147369
1.10810063
1.10489726
1.1018741

-0.36215314
-0.36220564
-0.36228064

0 0.06880565 0.99174056 0.91594036 1.09904227

0 0.06761355 0.99201919
0.9172656 1.09720779
0
0.0658755 0.99241732 0.91920599 1.09454022
1
1

Densidad liq
densidad vap
2.5879374843
0.0049108897
2.4584920004
0.0217468071
2.3115565291
0.0597781107
2.1404425485
0.1280223017
1.9327058286
0.2396669218
1.8071403273
0.3197299645
1.6572702119
0.4257416376
1.5481500929
0.5093131886
1.4617273438
0.5790149268
1.4120518856
0.6204217693
1.3677311707
0.6581712618
1.3308014412
0.6901978629
1.3038167911
0.7139257388
1.2894263907
0.7266913335
1.2664550602
0.7472299202
1.2500245911
0.762041531
1.2324876459
0.7779619898
1.2174866247
0.7916715267
1.2085948319
0.7998375248
1.2034938947
0.8045354494
1.1918140551
0.8153291808
1.1817222665
0.8246964335
1.1722751964
0.833500003
1.164848055
0.8404447011
1.1570827187
0.8477278327
1.1503161245
0.8540927402
1.1446828346
0.8594047649
1.1388286581
0.8649378138
1.1333473403
0.8701301776
1.1295683465
0.8737165729
1.1246885168
0.8783557126
1.1203040517
0.8825316185
1.1161142222
0.886528967
1.1123226084
0.8901500655
1.1087823535
0.8935380729
1.1055176915
0.8966684908
1.1023515268
0.8997064071
1.099500613
0.9024451159
1.096780027
0.9050615218
1.0942006903
0.907544701

0.1

curva coexistenc

1.2
1
0.8
0.6
0.4
0.2
0
0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.

1.0917741441
1.0901967805
1.0878954291
1

0.9098831103
0.9114043905
0.9136256277
1

250

200

150

100

50

0
1

a coexistencia

0.8

0.9

1.1

Tc(CH4)
Pc(CH4)
Vc(CH4)

190.3 K
4.64 MPa
0.0062 m3/kg

P vs T(CH4)

4.5
4
3.5
3

vdw
CH4

2.5
2
1.5
1
0.5
0
50

100

150

200

Tr
0.4
0.5
0.6
0.7
0.8
0.85
0.9
0.93
0.95
0.96
0.974
0.98
0.985
0.99
0.992
0.994
0.9962
0.998
1

T
76.12
95.15
114.18
133.21
152.24
161.76
171.27
177
180.79
182.69
185.35
186.49
187.45
188.4
188.78
189.16
189.58
189.92
190.3

Datos Matematicos
Pr
P
0.00517 0.0240097764
0.02779
0.128939545
0.08687 0.4030734712
0.20046 0.9301272873
0.38336 1.7787979339
0.50449 2.3408412549
0.647 3.0020723522
0.74318 3.4483730644
0.81188 3.7671196892
0.84762 3.9329503415
0.89923
4.172418418
0.92191 4.2776736949
0.94108
4.366596442
0.96048 4.4566228425
0.96831 4.4929431649
0.97617 4.5294408534
0.98487 4.5697933696
0.99202 4.6029690533
1.000
4.64

Matematicos
Vr(Liq.)
0.386408
0.406753
0.432609
0.467193
0.517409
0.55336
0.603402
0.645932
0.684122
0.708189
0.751427
0.775539
0.799984
0.830914
0.846223
0.864242
0.889135
0.917266
1.000

V(Liq.)
0.0023957302
0.0025218711
0.0026821754
0.0028965973
0.0032079378
0.0034308348
0.0037410918
0.0040047797
0.0042415571
0.0043907735
0.0046588468
0.0048083396
0.0049599024
0.0051516672
0.0052465797
0.0053583032
0.0055126374
0.0056870467
0.006200000

Vr(Vap)
203.6291
45.98376
16.72853
7.811139
4.172457
3.127639
2.348842
1.963428
1.727071
1.611807
1.44886
1.3761
1.312264
1.242953
1.212567
1.179624
1.138491
1.097208
1.000

V(vap)
1.262500354
0.285099323
0.103716894
0.048429062
0.025869235
0.019391364
0.014562823
0.012173256
0.010707841
0.009993202
0.008982931
0.00853182
0.00813604
0.007706311
0.007517918
0.007313668
0.007058644
0.006802688
0.006200000

(liq)
417.4092716653
396.5309677984
372.8316982479
345.2326691138
311.7267465483
291.4742463439
267.301647088
249.7016278891
235.7624747995
227.7503041329
214.645393747
207.9719984958
201.616869529
194.1119184997
190.6003655646
186.6262449489
181.4013736809
175.8381904004
161.290322581

(Vap)
0.792078986
3.50754954
9.6416307642
20.6487583332
38.6559551357
51.5693491132
68.6680060599
82.1472884875
93.3895043261
100.068027304
111.32223595
117.208279595
122.909924358
129.763782168
133.015553785
136.730295594
141.670276233
147.000708145
161.290322581
T (K)
90.685
95
100
105
110
115
120
125
130
135
140
145
150
155
160
165
170
175
180
185
190
190.3

Datos experimentales

P( Mpa)
Vl(m3/kg)
Vv(m3/kg)
0.01169
0.00221
3.98176
0.01983
0.00224
2.45048
0.03441
0.00228
1.47885
0.05643
0.00231
0.94022
0.0882
0.00235
0.62454
0.13232
0.00239
0.43048
0.19158
0.00244
0.30615
0.26896
0.00249
0.22359
0.3676
0.00254
0.16702
0.49072
0.00259
0.12717
0.64165
0.00265
0.09839
0.82379
0.00272
0.07716
1.04065
0.00279
0.06117
1.2958
0.00288
0.04892
1.59296
0.00297
0.03935
1.93607
0.00309
0.03176
2.32936
0.00322
0.02563
2.77762
0.00339
0.02058
3.28655
0.00362
0.01628
3.86361
0.00398
0.01243
4.52082
0.00499
0.00796
4.5992
0.00615
0.00615

l(kg/m3)
452.488688
446.428571
438.596491
432.900433
425.531915
418.410042
409.836066
401.606426
393.700787
386.100386
377.358491
367.647059
358.422939
347.222222
336.700337
323.624596
310.559006
294.985251
276.243094
251.256281
200.400802
162.601626

v(kg/m3)
0.25114522
0.40808331
0.6762011
1.06358086
1.60117847
2.32298829
3.26637269
4.47247194
5.98730691
7.86348982
10.1636345
12.9600829
16.347883
20.4415372
25.4129606
31.4861461
39.0167772
48.5908649
61.4250614
80.4505229
125.628141
162.601626

Tc(H2O)
Pr(H2O)
Vc(H2O)

373.946 C
217.755 atm
0.05594804 litros/mol

35

D vs T(H2O)

30
25

VDW
H2O

20
15

VDW
Ar

10
5
0
10

100

1000

Tr

T
0.4
0.5
0.6
0.7
0.8
0.85
0.9
0.93
0.95
0.96
0.974
0.98
0.985
0.99
0.992
0.994
0.9962
0.998
1.00000

149.5784
186.973
224.3676
261.7622
299.1568
317.8541
336.5514
347.76978
355.2487
358.98816
364.223404
366.46708
368.33681
370.20654
370.954432
371.702324
372.525005
373.198108
373.94600

Pr
0.00517452
0.0277887
0.08686928
0.20045847
0.38336162
0.50449165
0.64699835
0.74318385
0.81187924
0.84761861
0.89922811
0.92191243
0.94107682
0.96047906
0.96830672
0.9761726
0.98486926
0.99201919
1.00000

Datos Matematicos
P
Vr(Liq.)
1.12677777
0.3864081
6.05112729 0.40675341
18.9162206 0.43260893
43.6508335
0.4671931
83.4789104 0.51740932
109.855579 0.55336046
140.887126
0.6034019
161.831999
0.6459322
176.790765 0.68412211
184.57319 0.70818927
195.811417
0.7514269
200.751042 0.77553865
204.924183 0.79998426
209.149118 0.83091406
210.853629 0.84622252
212.566464 0.86424245
214.460206 0.88913507
216.017139
0.9172656
217.75500
1.00000

V(Liq.)
0.02161878
0.02275706
0.02420362
0.02613854
0.02894804
0.03095943
0.03375915
0.03613864
0.03827529
0.0396218
0.04204086
0.04338987
0.04475755
0.04648801
0.04734449
0.04835267
0.04974536
0.05131921
0.05594804

Vr(Vap)
203.629089
45.9837618
16.7285314
7.81113905
4.17245731
3.12763929
2.34884238
1.96342844
1.72707119
1.61180676
1.44885989
1.37610008
1.31226444
1.24295331
1.21256739
1.17962389
1.13849092
1.09720779
1.00000

V(vap)
11.3926484
2.57270135
0.93592854
0.43701792
0.23344081
0.17498529
0.13141313
0.10984997
0.09662625
0.09017743
0.08106087
0.0769901
0.07341862
0.0695408
0.06784077
0.06599764
0.06369634
0.06138663
0.05594804

liq
46.2560884
43.94241515
41.31613063
38.25768603
34.54465659
32.30033308
29.62159554
27.67121231
26.12651567
25.23863009
23.78638181
23.04685545
22.34259844
21.51092147
21.12178133
20.68138077
20.10237565
19.48587976
17.87372712

 vap
T
0.0877759
0.3886965
1.06845764
2.28823569
4.28374116
5.71476614
7.60958985
9.10332495
10.3491548
11.0892494
12.3364083
12.9886826
13.6205224
14.3800471
14.740399
15.152056
15.6994903
16.2901934
17.8737271

Datos Experimentales
P
V(v)
99.9740
161.8900
208.5300
255.6400
299.5000
318.3800
337.8900
349.3900
356.2100
360.1700
364.9100
367.1800
368.5200
370.7000
371.1300
371.9800
372.8300
373.66
373.9460

1.0000
6.3400
18.2800
43.1200
84.1600
109.0000
140.3200
161.9200
175.9600
184.6000
195.4000
200.8000
204.0400
209.4400
210.5200
212.6800
214.8400
217.0000
217.7550

30.1430
5.2828
1.9937
0.8185
0.3935
0.2866
0.2022
0.1607
0.1378
0.1246
0.1086
0.1005
0.0954
0.0861
0.0840
0.0795
0.0742
0.0664
0.0559

V(liq)
0.018798
0.019893
0.021083
0.022793
0.025261
0.026845
0.029178
0.031215
0.032910
0.034209
0.036290
0.037628
0.038588
0.040693
0.041251
0.042633
0.044636
0.048340
0.055948

v
0.0332
0.1893
0.5016
1.2217
2.5416
3.4895
4.9456
6.2243
7.2595
8.0238
9.2056
9.9532
10.4857
11.6174
11.9029
12.5770
13.4827
15.0607
17.8737

l
53.1971
50.2689
47.4316
43.8731
39.5867
37.2509
34.2724
32.0359
30.3859
29.2321
27.5558
26.5760
25.9148
24.5743
24.2418
23.4560
22.4034
20.6868
17.8737

Tr
0.4
0.5
0.6
0.7
0.8
0.85
0.9
0.93
0.95
0.96
0.968
0.974
0.978
0.98
0.983
0.985
0.987
0.9886
0.9895
0.99
0.9911
0.992
0.9928
0.9934
0.994
0.9945
0.9949
0.9953
0.99566
0.9959
0.9962
0.99646
0.9967
0.99691
0.9971
0.99727
0.99743
0.99757
0.9977
0.99782

Pr
0.00517452
0.0277887
0.08686928
0.20045847
0.38336162
0.50449165
0.64699835
0.74318385
0.81187924
0.84761861
0.87688395
0.89922811
0.91431312
0.92191243
0.93338256
0.94107682
0.94880913
0.95502242
0.95852811
0.96047906
0.96477955
0.96830672
0.97144848
0.97380882
0.9761726
0.97814504
0.97972472
0.98130593
0.98273033
0.98368062
0.98486926
0.98590011
0.98685224
0.9876858
0.98844035
0.98911575
0.98975169
0.99030833
0.99082538
0.9913028

Vrv
23.7377625
10.0393531
5.50962248
3.47809294
2.3719248
1.98809343
1.66860054
1.49588288
1.38382902
1.32721972
1.28079306
1.24473451
1.21976554
1.20689673
1.18696601
1.17315278
1.15879885
1.14682804
1.13986212
1.13590863
1.12697104
1.11937495
1.11236776
1.10692788
1.10130411
1.09645602
1.09245659
1.08833517
1.08450807
1.08188728
1.07852422
1.07552275
1.0726722
1.07010801
1.06772574
1.06553899
1.06342855
1.06153638
1.05973785
1.05803911

Vrl
0.6671799
0.66944612
0.67559597
0.68847212
0.71298189
0.73285624
0.76214153
0.78777899
0.81104722
0.82575033
0.83976642
0.85214007
0.86160657
0.86680861
0.8753431
0.88162733
0.88850636
0.89453584
0.89817474
0.9002845
0.9051775
0.90947618
0.91356122
0.91681495
0.92025724
0.92329098
0.92584125
0.92851557
0.93104204
0.93279666
0.93507805
0.937143
0.93912983
0.94093888
0.94263841
0.94421467
0.94575087
0.94714085
0.94847328
0.94974196

v
0.04212697
0.099608011
0.181500639
0.287513881
0.421598526
0.502994469
0.599304612
0.668501533
0.722632629
0.75345475
0.780766252
0.803384166
0.819829688
0.828571309
0.842484105
0.852403899
0.862962544
0.871970305
0.877299093
0.8803525
0.887334248
0.893355707
0.898983261
0.903401224
0.908014409
0.912029286
0.915368179
0.918834589
0.922077047
0.924310713
0.927192899
0.929780426
0.932251247
0.934485109
0.936570101
0.93849217
0.940354669
0.942030836
0.943629597
0.945144646

l
1.498846108
1.493772188
1.480174616
1.452491648
1.402560178
1.364524106
1.312092259
1.269391554
1.232973828
1.211019807
1.190807327
1.173515999
1.160622527
1.153657207
1.142409185
1.134266113
1.125484346
1.117898196
1.113369104
1.110759985
1.104755702
1.099534016
1.094617395
1.090732646
1.086652685
1.083082171
1.080098773
1.076987864
1.074065361
1.072045
1.069429448
1.067073005
1.064815496
1.062768282
1.060852164
1.059081193
1.057360905
1.055809173
1.05432596
1.052917571

0.99793 0.99174056 1.05644666 0.95094035 0.94656932 1.051590667

0.998 0.99201919 1.05541443
0.9517219 0.947495096 1.05072711
0.9981 0.99241732 1.05391255 0.95286577 0.948845328 1.049465763

a3

a2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

a1
-579.763832
-107.95757
-34.5346469
-14.9656936
-7.82550943
-5.94658009
-4.63679697
-4.03668621
-3.6951308
-3.53932768
-3.4212053
-3.33619465
-3.28115166
-3.25410515
-3.21411618
-3.18783753
-3.16185827
-3.14128753
-3.12979866
-3.12344133
-3.10951866
-3.09819187
-3.088172
-3.08068683
-3.07322702
-3.0670298
-3.06208461
-3.05715057
-3.05271944
-3.04977035
-3.04608959
-3.04290462
-3.03996878
-3.03740318
-3.03508453
-3.03301205
-3.03106328
-3.02935955
-3.02777872
-3.02632051

a0
p
386.509222
71.9717136
23.0230979
9.97712907
5.21700628
3.96438673
3.09119798
2.69112414
2.46342053
2.35955179
2.28080353
2.22412977
2.18743444
2.16940343
2.14274412
2.12522502
2.10790551
2.09419168
2.08653244
2.08229422
2.07301244
2.06546125
2.05878133
2.05379122
2.04881801
2.04468653
2.04138974
2.03810038
2.0351463
2.03318023
2.03072639
2.02860308
2.02664586
2.02493545
2.02338969
2.02200803
2.02070886
2.01957304
2.01851914
2.01754701

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

q
-193.254611
-35.9858568
-11.511549
-4.98856454
-2.60850314
-1.98219336
-1.54559899
-1.34556207
-1.23171027
-1.17977589
-1.14040177
-1.11206488
-1.09371722
-1.08470172
-1.07137206
-1.06261251
-1.05395276
-1.04709584
-1.04326622
-1.04114711
-1.03650622
-1.03273062
-1.02939067
-1.02689561
-1.02440901
-1.02234327
-1.02069487
-1.01905019
-1.01757315
-1.01659012
-1.0153632
-1.01430154
-1.01332293
-1.01246773
-1.01169484
-1.01100402
-1.01035443
-1.00978652
-1.00925957
-1.0087735

1
1
1

0 -3.02498468 2.01665645
0 -3.02413504 2.01609003
0 -3.02292184 2.01528123

0 -1.00832823
0 -1.00804501
0 -1.00764061
l

r
193.254611
35.9858568
11.511549
4.98856454
2.60850314
1.98219336
1.54559899
1.34556207
1.23171027
1.17977589
1.14040177
1.11206488
1.09371722
1.08470172
1.07137206
1.06261251
1.05395276
1.04709584
1.04326622
1.04114711
1.03650622
1.03273062
1.02939067
1.02689561
1.02440901
1.02234327
1.02069487
1.01905019
1.01757315
1.01659012
1.0153632
1.01430154
1.01332293
1.01246773
1.01169484
1.01100402
1.01035443
1.00978652
1.00925957
1.0087735

-193.254611
-35.9858568
-11.511549
-4.98856454
-2.60850314
-1.98219336
-1.54559899
-1.34556207
-1.23171027
-1.17977589
-1.14040177
-1.11206488
-1.09371722
-1.08470172
-1.07137206
-1.06261251
-1.05395276
-1.04709584
-1.04326622
-1.04114711
-1.03650622
-1.03273062
-1.02939067
-1.02689561
-1.02440901
-1.02234327
-1.02069487
-1.01905019
-1.01757315
-1.01659012
-1.0153632
-1.01430154
-1.01332293
-1.01246773
-1.01169484
-1.01100402
-1.01035443
-1.00978652
-1.00925957
-1.0087735

193.254611
35.9858568
11.511549
4.98856454
2.60850314
1.98219336
1.54559899
1.34556207
1.23171027
1.17977589
1.14040177
1.11206488
1.09371722
1.08470172
1.07137206
1.06261251
1.05395276
1.04709584
1.04326622
1.04114711
1.03650622
1.03273062
1.02939067
1.02689561
1.02440901
1.02234327
1.02069487
1.01905019
1.01757315
1.01659012
1.0153632
1.01430154
1.01332293
1.01246773
1.01169484
1.01100402
1.01035443
1.00978652
1.00925957
1.0087735

-7180199.2
-45306.0509
-1392.9459
-99.2585242
-10.9447197
-3.85912664
-1.30336847
-0.62565301
-0.35153001
-0.25022488
-0.18259477
-0.13858933
-0.11210617
-0.09965816
-0.08192357
-0.07069862
-0.05993161
-0.05163634
-0.04709114
-0.04460295
-0.03922028
-0.03490828
-0.03114368
-0.02836181
-0.02561515
-0.02335286
-0.02156029
-0.01978292
-0.01819621
-0.01714515
-0.01583888
-0.01471353
-0.01368029
-0.01278055
-0.01196998
-0.01124752
-0.01056997
-0.00997901
-0.00943185
-0.00892813

1.642792651
1.738277619
1.869975513
2.035016774
2.238471465
2.3606862
2.505397322
2.610158391
2.692965557
2.740569427
2.783083062
2.818557809
2.844519082
2.85838024
2.880533939
2.896402316
2.913362437
2.927890591
2.93651164
2.94146061
2.952802043
2.962612536
2.971806132
2.979040846
2.986611709
2.993214586
2.998715759
3.004436793
3.009797338
3.013495302
3.018273254
3.022568867
3.026676204
3.030394282
3.033868593
3.037074881
3.04018499
3.042986659
3.045661348
3.04819817

X1
23.73776254
10.03935312
5.509622484
3.478092941
2.371924802
1.988093432
1.668600541
1.495882882
1.383829015
1.327219717
1.280793064
1.244734515
1.219765538
1.206896726
1.186966014
1.173152776
1.158798845
1.146828045
1.139862115
1.135908627
1.12697104
1.11937495
1.112367764
1.106927879
1.101304109
1.096456019
1.09245659
1.088335172
1.084508072
1.081887276
1.078524222
1.075522749
1.072672205
1.07010801
1.067725736
1.065538991
1.063428548
1.061536376
1.05973785
1.05803911

1.00832823 -1.00832823 1.00832823 -0.00846752 3.050585616 1.056446663

1.00804501 -1.00804501 1.00804501 -0.00817498 3.052138032 1.055414433
1.00764061 -1.00764061 1.00764061 -0.00775782 3.054403652 1.053912551

X2
0.667179902
0.669446123
0.675595966
0.688472117
0.712981885
0.732856236
0.762141529
0.787778993
0.811047224
0.825750326
0.839766415
0.852140065
0.861606574
0.86680861
0.875343103
0.881627326
0.888506361
0.894535839
0.898174735
0.900284502
0.905177496
0.909476183
0.913561217
0.916814954
0.920257239
0.923290981
0.925841252
0.928515569
0.931042036
0.932796664
0.935078047
0.937143002
0.939129834
0.940938883
0.942638412
0.94421467
0.945750874
0.947140852
0.948473279
0.949741963

X3
-24.4049424
-10.7087992
-6.18521841
-4.16656502
-3.08490664
-2.72094962
-2.43074202
-2.28366183
-2.19487619
-2.15296999
-2.12055943
-2.09687453
-2.08137206
-2.07370528
-2.06230906
-2.05478005
-2.04730515
-2.04136383
-2.03803679
-2.03619307
-2.03214848
-2.02885108
-2.02592892
-2.02374278
-2.02156129
-2.01974694
-2.01829778
-2.01685068
-2.01555005
-2.01468388
-2.01360221
-2.01266569
-2.01180198
-2.01104683
-2.01036409
-2.0097536
-2.00917936
-2.00867717
-2.00821107
-2.00778101

0.950940353 -2.00738696
0.951721898 -2.00713627
0.952865768 -2.00677826

250

250

P vs V (H2O)

200

200

150

150
VDW
H2O

100

0.01

0.1

100

50

50

0
1

10
100

100

10

20

V vs T(H2O)

10

1
10

0.1

0.01

100

VDW

1000
H2O

250

60

P vs (H2O)

vs T(H2O)
50

200

40
150

VDW
H2O
VDW Ar
Ex H2O

100

30
20
10

50

0
10

100

0
0

10

20

30

40

50

60

T(H2O)

250
200

P vs T

VDW

1000
H2O

150

ter

100
50
0
50 100 150 200 250 300 350 400

 vs T(H2O)

VDW
H2O

100

1000

P vs T

00 250 300 350 400

terico

1.2

1000

Pr vs Vr
1
Binodal
Vapor

0.8

100

Binodal
Liquido

0.6

Liq
metaesta
ble

0.4

Vap
metaesta
ble

0.2

10

1
0.3

0
0.1

10

100

1.2

1000

0.1

Pr vs Tr

1
0.8
0.6
0.4
0.2
0
0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.1

0.4

0.5

0.6

00

1.2

Vr vs Tr

00
0.8
binodal
liquido
0.6
binodal vapor
liq
metaestable
0.4

10

1
0.3

0.4

0.5

0.6

0.7

0.8

0.9

0.2

1.1

0.1

0.5

r vsTr

2.5
2

binodal
liquido
binodal vapor
liq
metaestable

1.5
1
0.5
0
0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.1

1.5

Pr vs r

Binodal
Vapor
Binodal
Liquido
liq
metaesta
ble

0.5

al
o
al vapor

estable

1.5

2.5

Metano

0.001

0.01

P vs V (CH4)

4.5

P vs (CH

4
3.5

2.5

VDW
CH4

1.5

0.1

500

10

300

V
C

200

V
A

0
0.001

0.01

0.1

10

100

vs T (CH4)

400

0.5

100
0
10

100

10

P vs (CH4)

4
3

VDW
CH4

VDW
Ar

1
0
0.1

10

100

1000

vs T (CH4)

10

1
VDW
CH4
VDW
Ar

60
0.1
0.01

P vs T(CH4)

4.5

V vs T (CH4)
80 100 120 140 160 VDW
180 200
CH4
VDW
Ar

3.5
3
2.5
2
1.5

100

1000

0.001

1
0.5
0
50

100

150

200

P vs T(CH4)

vdw
CH4

100

150

200