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CQNG H6A xA HQI CHU NGHIA VI(:T NAM

DQc I?p - TV do - HC;\nh phuc
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Co

DE THI TUYEN SINH CAO HQC NAM 2009

TRUaNGD~IHQCSUPH~M
Mon thi: Coo sO'

Iy

thuy~t

Hoa h<}C

Thai gian lam bQi: 180 phUI( kh6ng ki thifi gian pha' di)

(Nguo-i thi kh6ng

su dl:lng tai liu nao khac

ngoai nf;5idung dii ghi trong dJ thi)

NQi dung d~ thi

(Di g6m 2 trang)

----- II ----Call I

phat bi6u nQi dung nguyen Ii phan d6i xLrng va ap dl,lng nguyen Ii d6 tim ham song
~ mo ta tr~ng thai ?a ban cua Li+ ( co trinh bay chi ti~t).
2. Cho nguyen to hoa hQC c6 Z=26, hay trinh bay:
a) Chi ti~t va k~t qua vi~t du hinh electron cua nguyen tu (co dung 0 lugng tlr).
b) Tinh ch~t hoa hQc di~n hinh dc,U1gdan chat cua nguyen t6.
c) Vi h~t c6 56 oxi hoa m\o (ion nao) b~n nh~t cua nguyen t6 d6?
d) Tim 56 h~ng ca ban cua nguyen tu va ion vua xet di6m c)

! 1. Hay

~ 3. a) Ap d~mg h~ thlic En

-13,6

Z:n

(theo eV), hay tinh cac!Ii

nang lugng E1, E2, E) theo

kJ.morl cho N+6.

b) C6 qui lu~t nflO lien h~ cac trj s6 En vai n ( n la s6 lugng tU chinh)? QuiJu~t d6 phan
anh quan h~ nao v~ du t?O nguyen tu?
Call II
~ 1. Thve nghi~m eho bi~t: CO ~- c6 hinh tam giae d~u, tam Iii C, 3 dinh Iii 3 0; cae lien k~t
C-O cung dQ dai; di~n tich h~ duqc giiii toa d~u tren cac O. Hay vi~t cong thlie du t"l.O
Le'Yis vii ap d,Vng mo hinh YSEPR ~iai thieh k~t q~a thvc nghi~m. do.
.
~ 2. Ap dVng dong thai thuyet lien keth6~ tr! (thuyet VB) vii thuyet abitan phan tu (thuyet
. MO) hay giai thich S\T hinh thiinh lien ket Hoa hQe (eo ve hinhday du) trong:
a) N2; b) CH4 (hinh tt! di~n d~u, tam lit C, 4 dinh la 4 H).
'f 3. Ap dVng mo hinh lwt chuy~n dQng t~r do trong hQP th~ hinh ehfr nh?t mQt ehi~u, hay
tinh:
./
a) Nang luqng h~ cae electron pi (e-n:) cua phfll1 tt! hexatrien,C6HIO,
m~ch bo' theo
kllmal;
b) 89 dili song (thea nana met, nm) eua v?ch ph6 http thv tucrng lmg S\T ehuy~h dOi 1
electrol1 tu HOMO len LUMO trong phan tu nay.
Bi~t: me = 9,11.10-31 kg; e = 3.108 m.sl; h = 6,626.10-)4 J.s; d = 0,140 nm.
Cau III

Sv phan huy metan

25C: Nhil

Clla

phon ung, 6H

6S ~ 1I = 80,67 J/K.mal.

C(rnn.graphil) + 2H2( khi)c6 cac s6 li~u sau day tC}.i

CH4( kl;r
~J

= 74,85 kllmal; Bi~n thi6n entrapi

CLIU

plHin lIng,

. Hay ttnh hang 56 can bfu1g Kp (; 298K .

. Tlnh h~ng s6 can b~ng a 50C v6j gill thi~t nhi~t cua ph an (rng, t-.H~

11

khong phl,l

thuQc nhi~t dQ. Hay nh~n xet v~ chi~u cua phan ung t':li nhi~t do nay.
3. Tinh dQ phan ly a cua CH4 (; 2 ap sufit 0,01 bar va 1 bar ( cung (; 25C).
k4. Hay giai thich SIl thay d6i cu~ dQ phan ly: theo ap sufit va theo ca nhi~t do. S\I thay
dOl nay cOphu hgp v&inguyen ly dlUyen djch can bang Le Chatelier khong?
CauIV
\
Phan ling izome hoa xycloprapan thanh prapen duqc th\Ic hi~n (; 500C. Trang
mQt thi nghi~m, Sll chuy~n hoa cua xyclopropan dugc khao sat a cae ap sufit ban
d~u khac nhau va k~t qua dugc ghi trong bang sau:
Po(Torr)
200
200
400
400
600
Theri gian(giay)
100
200
100
200
100
P(Torr)
186
173
373
347
559
(Po la ap sut ban d~u va P la ap sut ~i thai di~m t cua xyelopropan)
I.Hay xac dinh b~e va hfu1g s6 t6e dQ eua ph an ung.
2.Xac dinh theri gian nlIa phan ung (tll2)

600
200
520

Cau v
Cho 2 oi~n ellc Ni2+(0,lM)/Ni va Ag+(O,lM)/Ag eung cae th~ khu tieu chuful lfin
lUg! la - 0,25V va 0,799V.
1. Hay thi~t l?p sa d6 pin hinh thanh tu hai di~n e\Ie off eho. Vi~t eac phan ling
xay ra tren tUng di~n qre va phan lIng t6ng quat xay ra trong pin.
2.Tinh suc oi~n o(mg E a 25C cua pin theo di~u ki~n off cho. Khi h~ d':lt tai
tr~mg thai can bing, sue di~n dQng E b~ng bao nhieu?
3. Tinh h~ng s6 can b~ng eua phan ung t6ng quat.

CONG H6A xA HOI CHU NGHlA VIET NAM

DQc [~p - Tl,! do - H~nh phuc
.>...t

DE THI TUYEN SINH CAO HQC NAM 2009

TRU<JNG D~.I HOC SU p~
HA. N(n
Mon thi: Toan cao clp 2
ThiJi gian lam bdi: 180 phtit (KhOng k !hili gian pMt d)
Ngttoi thi khong 811' d'l,mg tai li~tJ..

TN :

L~I L( L-ru,_,
N9i dung de till

Cau 2. Cho df;l.ngtoan phuong

y :: ~ "t lx-/. -A3
d~
5"
\11.

d'''

-= :t, - ') A-)

d'):

A.)

5"J1\..-t?

-7

a) Tim ,\ d f(x,

,,\...

x) la. d~g

toan phuong xAc dinh duong.

b) Vdi ,\ = 3, hay dua d~ng to~m phuong f(x,

~'" tJ] Cau

~~6cz-S

3. a) Tim giOi hf;l.n

1n
".

b) Tfnh tfch phan suy r(lng J =

:: - 6 f

~'"
,

~~

S~,--+-

1-

h )L-Cau
J

3 b lA

5. Tfnh di~n tfch hlnh ph~ng dU<;1cgidi

<t-

f3
e:au

e- ~

h().l1

( . q-~L
~

bdi c8.{;dl1C1ngcong

y2

-::..l~-t~

J -=

fl+oo z(z+t)(Z+2)'

Cau 4. TIm gia trlldn nba.t va nh6 Mat cua ham sO f(x, y) = x2y(4 - x - y)
trong mi~n dong D gi6i h~ bdi c& duong thing x = 0, y = 0, x+y = 6.

-:. If

~'t'

x) ve dl;\Jlg chinb t~.

L..t( ~~

x..

6. Gi8.i phuong trlnh vi phan

6x, x2

+ y2 =

16

or

I )