( ) 2011-2010

3 ( 03 )

3 3 ( 04 )

3 3

:
S1 S2
t = 0 V1 = 100mL S1 V2 = 100 mL
S2
( )
- 1

n( ) mmol

.
- 2

. S2 O2
SO2
8
4 2 :

- 3)
) .
( )

-4) ( ) ( ) .
) 2 1
) t = 80mn t =0
)t(mn

10

:
210 238
m0 = 1mg 1,66.1011Bq
( ) .
- 1 :
* * . * . .
- 2 210 .
. ( 210
) 84 ) 210

Tl
85

) " "
Bi
83
6/1

Pb
82

At
81

 - 3

0
A

A0 m0

A . t

) =f(t

ln

)
t1/2. 210
) 210 .

0,4

50

)t ( jours

:
D

B
2

R =100K

- 1 :
1 .
.
-2
) (t = 0 ) 2 ( )
.
) :
)(q
q(t) = 0 /
1
-3 :
) t = 0
. t1 =
) C E .
) . t =0
A

1 = 10 -6 c
:
20
25C pKe = 14
- 1 S1 HA = 0,010 mol/L 100mL
. 1 =143. 104 s.m-1
) HA .
)t (ms

) AH/A- :
-

) pKa AH/A

. 2

= 1

- 2 S1 1L S2
2 = 43. 104 s.m-1
) . S2
) .
- 3 10mL S1 + + ()
6/2

 pH
) .
) .
)

pH = 5,4

= 3,58.103 S.m2.mol-1

3 + = 35.103 S.m2.mol-1

:
F

- 1 ( + )
v =72 km/h
1
.
F . F = 2,4.104N
f (. ).
- 2 / 1 FC/A FA/C A C C A .
/ FC/A fC =2 fA :
mC = 1,6.104kg mA =8.103kg
:
- 3 .
) .
) .
:
Chl :
: 1 ( )
1L :
A

+2+ +2 = + + 2+ + 22

: 2 ( )
1L :
+ + 23 + = + 32
(.( eau de Javel 36
- 1 2 C0 = , .
- 2 :
: V1= 10mL
C = 10-1mol/L VE = 316mL
: 5mL 20 V2 =10mL
=15,8mL
) / 2 :
) C02 C01
.

) .

6/3

 :
:
. C3H7OH
- . .
- 3g 3g CH3COOH t
) -
) - . .
) - .
) - .
( -
)ne(mol
.
)0.03 (1
.
)(2
.
.
)t(h
-( 0.02 mol .
. C : 12g/mol H : 1g/mol O :16g/mol
:
: ( ) L , r E=6V
)U(v
R=10 .K
- 1
.
- 2)
t =0 ( )
1
) :
1
) i(t) = A (1-
. B A
)t(ms
10
- 3 1 .
- 4) ( L r )
) .
:
. 235 :
235
1
94

92 + 0 38 + + 3 0

- 1

53
55
- 2 .
94
38 . 235
- 3
- 4 Mev E1 . 235
6/4

54

 E 1g. 235
- 5 E 1Kg 42 MJ

( 42 )
NA= 6,02.1023 mol-1

94
m( 38
)=93.89451u

: 235

m( )=138.88917u , m(235
92)=234.99345u

(m( 10

) = 1,00728u
=1.00866 u ,
2
1u = 931,5 Mev/c El ( 235
92 ) = 1786 Mev

m( 11

:
C6H5COOH . 250C .
( )S m = 1,22 g 1L ( ) 1L
- .)S(
- .
- pH (S) 3,1
+
- Va = 20ml ) Na +HO )
.CB
pH VB

pH

) pH = f(t :

- .
- . . CB
- KA
(.)C6H5COOH/C6H5COO-
2

) VB(mL
2
:
t = 0 m = 10g h = 2m
= 0,10 s

G4

( 10 )
6/5

G2

G0

 ( 0,10m )

(1cm :)

- 1 :
G2
G3
G4
G5
G6
6,00

2
3
4
5

G1
)v(m/s
)a( m/s2

G0 xx .
. " " . - .

:
- Pb/Pb2+ //Ag+/Ag +
100mL + 0 = 0,20 mol/L
Ag
.100ml Pb2+ 0 = 0,20 mol/L ( K+ + NO3 - )
- 1 .
- 2
28
- 3 K= 6,8 .10
-4) I=0, 5 A t =1 h
.
)
) .
) .
M(Ag) = 107g/mol 1F = 96500 c :

2011 /5/26

6/6