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The following information has been provided electrolyte temperature = 25°C Cu(aq) + 2€ > Cus) Exe’ = 0.337 V SHE 2W(aq) + 26 > Hye) Exy?=0.0 V SHE bulk concentrations: Co. june = 0.55 mol/L, Cp. 20 mol/L. Pu atm ‘mass transfer coefficients: kpc. = 5.6x 10 cm/sec Kaur = 7.4 x 107 cm/sec Based on this information, answer the following questions: 2) Determine the limiting current densities for Cu** and H* reduction, 'b) Sketch the cathodi> portion of the i-E curve for an electrolyte containing Cu** and 1H” ions under the conditions specified above. Assume that the kinetics of the Cn? and H' reduction reactions are relatively fast ©) 1fan industrial process for copper plating is operated at an overall cathodic current density with magritude of 400 Am’, determine what should be the current efficiency. ‘What should be the cathode potential? 4) If the applied cathodic current density is raised to 650 A m?, what would the ‘current efficiency now be? Branca: Cathie Prion iH£ Plo Ge Boe Grbarng Ge oa Ht 3) Gr ena" are peodands —. Whats Gate Nore ond tly, to Nee (grout (Oya eG? =a l= Biker ducts 7 uso cocks =a 2 doce Corse — Corts) BH Virwting Gurrtok dena ding 1 Cartel 20 © Loe WIRE Knorr Gortte Numaicct wobwon: NED Dera, Kmene = S.txIo*Cmfgec Gas Mute 0S rat 2 ban -2 (aguas C Eburs a) 55 uf) (4) ¢ = SSy > See = HTK Bs - Sas cure \alt ne —> ny . tae DFW be Yo waco] Faw (Gotu Carsd) | Nummoricad Ninlato 1=2 — "lent SEA Moc Cafyutic= 120 oL = —F howe Corot =— (aeussah) (.08*)(t29) (\s°) =H OG AL = RSIS BL uch Lapin La B) Babe —skebtinng C-B tune, Cabuabs Cree for ach reackren: GM eae —y Gl) pate + Baye Che +B da Catal on} 39 +(g 314%) Fr. Bee at} —= = 0.530 USHER QW tae7 Sth : Ge Hert Op = .o +fawlar) y w Bn (ox) aa Sees ee Arie came ov God apstanaton Care =A i lee gobs Stes Jake qos el Mer Reena! Quy aera cy ae CoE canal Pee let = Lately, i dec & fe Ts PAHO > Neto hea Note: Whan no LE noa se yoy Goh rducion ocoue Wren & CnooN SHE, botr Oat ond tH recualion occur Dy Was Stead “Prk Wiaches pit SS “Thora, Guam “Tae die He potion toth, e0.dion ws ©) Apphed Gament donadiy = Hoo An To find oud Where vie Gt eparting wit -reapaet Ws Cofhaly, Simply THA cH [= Hoo Mn ont grleriychun Cutt, Thies corrpards Je ph, Cathode prkatnol Gs Es. Spoaly O2* yedacGan occun ah Bk, “ umes spfucsanes Far Ga pedndbaan = loo), d) Aplisd oenak dunndly, = So Blot a Once again , rod ae [A =es0 Me oon pled. Thi erteapore che ph &. Cathode prbabead Gr nt Ex W Recing sdachors orbs pumped h Clreck ot ee a) So Aft. The whichode ok boy CaYrode | ond aurade vovot erat Wir downed, Moxamum rola ot Which Oi pehuckian Conhtasber seg swt (4 en) rant WY Yr emdicing whichon {4d Gonne from ? — oa neu wthodk qodion. Shs provi US Af Connann Yow cotnds preatnad ShofX instadranamesly. in onter Jie find omathar Cathode -eadinn Ovuiowsly, SHEE ym tre negobiee deat . Sots cotade pelusbel S pez hag a Sein vedmchian qooKen GIF cre > th nha Gist) Cancun and prosdy Hee Terai chen lie Gs LX (le) [SHURA — [Uy] =bSo SABE = SoMa Pee Via) = Sue PA Le) SSeS Slay Tre we

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