—————— 2=2 a Dre a= pe +£e 2 242" ee me ne eporimtat: a ee eae (aka the dette conitathm CnegYy Of. below) Fc) od 0 app lenin AA Pn : neglect = y= [Apel] KEI) Symmebie spin fn. antapomehe coord. fo veel Versa Ground stake : V; by, are fhe Same Ca=t Cemeo), SO jead one tern: s —elGrK) a -&, rg (pele) Ee 2 E,=2 (-2)= 4 Au, (Ef )=-sengev A 30% wer... fet oprrectiou : tent L a a perturbation, hen el) JE sy = Cy lElb>= Zz (yee newt page) East Exe 2-41 F2= -2.95 AY = 248 EV. the error in down to SK!How tb calrulste Ele) : cat t = 2 caer £5 ¥,*C0,0) Nig lex, @) me~ 4 ) <1 K=min(r, &) 7 Jtewai p Ph: 456 ) mn) NG wy L lr Kidh AN, = Ke ; a= ne ee py eal | 40 Sn 2 ope : x + bar J (og) % vatenn Me fan) leg) ae U ftom dy dom a only fle b-0 m=0 ferm jurvives / we 222k 22414) Fie {Ss ae = [fete OO" dnd = | sae ? = ffBi gO G8 go cts = yy 2 S>- 2. [ett “Hy (fe eh Last frettan) 2 VJ ’ 7 2 fs oh, (£ face Js ete.) = = Pl i, “tle, [diss sje 2) syssne”s) = = ea (- gt-2s,)e 8! + 2Ge- 8) Is, = - Ef far-r Lars att) = $2 in atomic vith (Au Bw a7zevVariational Princo le. A fonction thet eep & frctimal ff lle fork variethon, of the fenotimel uinishs rier Cab fonction ch question: Slxtye dato f= Slxtj+ OClazy *) <4, Clapeel mechiniet XL 1 He tagectong SO [Md Ll it) 2 te todo 4, wee Peipien The prinaple of Ctl oko <> Lalor’ Lt laf | In GM, yi) (andiy P*P)) shawl wirinene Sly} 2S ple-y ty £y., fs= | dy (A-E)y/V=0 should bold for am ax library Jal dy (}-bly=o. Schrodengor's equakon dérwed MWLet'p apply fhe. varcadonal prineyo te b a speesfe clan off fonctions : yk 0) =(We YE) 2 HEY (é) “ Lo £ 7.0, the Same tymncdived and sgmmehsed Jon m My we VE utd befare. anobhtr ptr fr te wave - function of. Ha form, ep Ce) Cand Cntar Combinehy ) u the se ~ cena pz WB: ig) pos) = ENR) | I( Hy a ncereia eee) + Vere) Talegrabeg pe(%) out ( fee) di x ty =€4) Die yilh) SID + (~&)> E. =E,+ Sef dg NC, Cd + < gab Ce) | at(H -E) + yee) olp@)> £ 100%) > 1A CR) > < by R14 a) | st E) tlle) > LY, > ©. ésym)| (ye)> =< dy G| HG) + hat v,,-E | y,@)> + © sy. 1 )>= = +¢dy ln) [da ACh + Has # My ~ Ee [ys (n= (Qe )> LIB G)I4)> leads t excl ty the same eg. (HEA) (t we tha, rnp Y fp the variallts Xj and h abu) 2ereing tt coeffeiad ff 2, Hivefore Esyenm = Hy ty +26 > Cag mm = = My, thet I~ J — L% dk x, | The “pence =) pre shade has & a higber energy flan fis spake pened shh, a we have Seen before /SER eee eee speegfe rout, CA us Cro fhe variation bo a specif claw off functions: Yh, A= 24 oH) The phapecal lee ; the _verelwing ff te nucleus Me electrons from each ofher, Heerefore, te “ef fetwe' pareleic charge 2yf 4 Ces, flan il actual aha $e Z. with tis fenoton insdead of solrug fee Harbec- Look eyutdon , we Gin hp calewlele te abric | triryy ws a ferctn of Peff end toh fod ty thal yored E (ey) He nininutn volal. NB: Becaap wel lini fed beer claot af fection fe bir we fod iu poing le & higher than Med menue Ontify achewlle cn prineple by he Kaybrec- Fick netivd, and Sl/ hyhor than Ce actual cnenyy of atin. fe He =

+

= <¢| BE - 2 Ip) = = - 2 The ry - depenclnd part irtegrakel ott, nd fe v,— deptnclut part iy bade pm ee vivel Pheerem | (we: p(B )= (Bit 070" cs 0 bom Me suubon for & Heaton arith He | reuctic henge 2eff) |

= ag UD)= sy EU) = eed Tht, cp Ui, rategy + 2 ty) a Py O ban, Lp lip =feg ~ 224. Be.AA dhe. Covloukec otek Wes conpaded in (ee. previews Laecfture | Lo lies >= F A Uys tle Cy LHlp> = 2 Gee 20) FH = Wy 222y +2 2y, Vawiahon of fh, a. ka. CL reinégncemn pearth, 2 yes = a u_-92@ 2 = I2y ~221 229) & (% a2 oy they) ey PFO 2 = 2-f 7 2-H FF = 16875 E lep)= ey - 222 2 ey w= 2.85. =~ 24 TeV Ona a (OSA errr compared & tre, bot valet YW Bp oe Uf MB: Lf the Me prcloie heargyl where 2f hen pur reult would be enact ly the.) eaprtdtbon of the plertur bation teerg [ oboe): E(zy) =2y-2ty ts aga ty t cy off Appin US ovrecdirs