modelo de wilson a presion constante

PRESION(kPa)

101.33

DATOS DE WILSON
SUSTANCIA
Acetato de metilo(1)
Metanol(2)

a12
79.84
40.73

a21
-31.19

813.18

hallamos la Tsat para cada sustancia

Tsat1(C)
Tsat2(C)
56.8694824 64.5550692
x1= 0; 0,1; 0,2; 0,3; ; 1
X1=
0.1
hallando una temperatura distribuida entre las temperaturas de saturacion para cada X1
n
X1
Tn
Tn(K)
Psat1
0
0.1
63.78651
336.78651
128.28363
1
0.1
59.82715
332.82715
112.24077
2
0.1
59.62955
332.62955
111.48398
3
0.1
59.61949
332.61949
111.44554
4
0.1
59.61898
332.61898
111.44358
5
0.1
59.61895
332.61895
111.44348
6
0.1
59.61895
332.61895
111.44347
7
0.1
59.61895
332.61895
111.44347
8
0.1
59.61895
332.61895
111.44347

AHORA QUE TENEMOS LA TEMPERATURA PARA CADA X1, procedemos a encontrar Y1

X1

T(c)
T(K)
0
65.55507
0.1
59.61895
0.2
56.96407
0.3
55.41914
0.4
54.47832
0.5
53.9071

Psat1
338.55507
332.61895
329.96407
328.41914
327.47832
326.9071

Psat2
136.01085
111.44347
101.66533
96.29749
93.14088
91.26497

105.38346
83.17389
74.59095
69.94700
67.23955
65.63901

0.6
0.7
0.8
0.9
1

53.60699
53.5707
53.88555
54.79201
56.86948

326.60699
326.5707
326.88555
327.79201
329.86948

90.29154
90.17439
91.19479
94.18405
101.32999

64.81100
64.71147
65.57926
68.13233
74.29939

340
338
336
334
332
330
328
326
324
322
320
0

0.2

A1
101.33
101.33
101.33
101.33
101.33
101.33
101.33
101.33
101.33
101.33
101.33
101.33

B1
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015
14.4015

C1
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17
2739.17

A2
223.12
223.12
223.12
223.12
223.12
223.12
223.12
223.12
223.12
223.12
223.12
223.12

B2
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938
16.5938

3644.3
3644.3
3644.3
3644.3
3644.3
3644.3
3644.3
3644.3
3644.3
3644.3
3644.3
3644.3

R(cal/mol.K)
1.987

DATOS DE ANTOINE
sustancia
A
B
1
14.4015
2
16.5938

uracion para cada X1

Psat2
12
98.30369
83.88050
83.20976
83.17572
83.17398
83.17389
83.17389
83.17389
83.17389

21
0.53449
0.53478
0.53480
0.53480
0.53480
0.53480
0.53480
0.53480
0.53480

C
2739.17
3644.3

M1
0.58152
0.57318
0.57276
0.57274
0.57274
0.57274
0.57274
0.57274
0.57274

223.12
239.76

M2
0.58104
0.58130
0.58132
0.58132
0.58132
0.58132
0.58132
0.58132
0.58132

1
0.95815
0.95732
0.95728
0.95727
0.95727
0.95727
0.95727
0.95727
0.95727

2.28098
2.29698
2.29778
2.29783
2.29783
2.29783
2.29783
2.29783
2.29783

os a encontrar Y1
12

21
0.53435
0.53480
0.53500
0.53512
0.53519
0.53524

M1
0.58523
0.57274
0.56710
0.56380
0.56178
0.56056

M2
0.53435
0.58132
0.62800
0.67458
0.72112
0.76762

1
1.00000
0.95727
0.91342
0.86914
0.82471
0.78028

2
2.83337
2.29783
1.91566
1.64027
1.43842
1.28904

1.00000
1.01156
1.04535
1.10173
1.18332
1.29521

0.53526
0.53526
0.53524
0.53517
0.53501

0.55991
0.55983
0.56051
0.56245
0.56689

0.81410
0.86058
0.90705
0.95352
1.00000

0.73595
0.69188
0.64841
0.60621
0.56689

1.17861
1.09856
1.04361
1.01100
1.00000

T vs X
T vs Y

0.2

0.4

0.6

0.8

1.2

1.44569
1.64765
1.92075
2.29433
2.80829

C2

V1
239.76
239.76
239.76
239.76
239.76
239.76
239.76
239.76
239.76
239.76
239.76
239.76

V2
79.84
79.84
79.84
79.84
79.84
79.84
79.84
79.84
79.84
79.84
79.84
79.84

R
40.73
40.73
40.73
40.73
40.73
40.73
40.73
40.73
40.73
40.73
40.73
40.73

a12
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987
1.987

a21
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19
-31.19

813.18
813.18
813.18
813.18
813.18
813.18
813.18
813.18
813.18
813.18
813.18
813.18

Psat2
1.01152
1.01156
1.01156
1.01156
1.01156
1.01156
1.01156
1.01156
1.01156

Y1
0.00000
0.25272
0.38440
0.46764
0.52887
0.58050

Psat1
tn+1
83.88050
109.46176
83.20976
111.34324
83.17572
111.43837
83.17398
111.44321
83.17389
111.44346
83.17389
111.44347
83.17389
111.44347
83.17389
111.44347
83.17389
111.44347

l tn-tn+1 l
59.82715 3.95935713
59.62955 0.19759852
59.61949 0.01006425
59.61898 0.00051312
59.61895 2.6163E-005
59.61895 1.3340E-006
59.61895 6.8017E-008
59.61895 3.4680E-009
59.61895 1.7684E-010

0.63013
0.68433
0.75138
0.84573
1.00000