Series ONS SET-1 alsa. code No. 96/1/C waa. Roll No. Wart as a safer H qe-ys woe far | Candidates must write the Code on the title page of the answer-book. 10.15 aa feat SET on the title page of th ° Fra ata ar a fe ea wets F fee Ys 16 FI © Weta dF afet cea at ik feu 7a ate TR ST OTA SRO & FETs Te fers © Bras a a fm ee wes Gi 26 WHE BUA ar sar ferent YS HTS eel, WET aT EI Bra fer © ye et & fer is fie a re fe nt) eo a faa ale aafa & chr 3 sacafan 4 ae oe ae ferg7 * Please check that this question paper contains 16 printed pages. * Code number given on the right hand side of the question paper should be written * Please check that this question paper contains 26 questions. 10.15 FB 10.30 FS Wh BA Hae WeH-Ta aH WS atk ga 1 answer-book by the candidate. * Please write down the Serial Number of the question before attempting it. * 15 minute time has been allotted to read this question paper. The question paper will be distributed at. 10.15 a.m, From 10.15 a.m. to 10.30 a.m., the students will read the question paper only and will not write any answer on the answer-book during this period. Tarr fears (tahae ) CHEMISTRY (Theory) Freie Ra : 3 0S MIRTH HF: 70 Time allowed : 3 hours Maximum Marks : 70 56/U/C 1 YEARS P.T.O. QUESTION PAPER.COMarea Faas @ weit weF sifrart B1 (i) WRT Wem a5 ae oie Tg-aae we & ik Wee WET & fer 1 sie B) (ii) Wer Gen 6 410 we ay-saa WeF & site Wee WEF ferg 2 aie 1 (jv) WRT Wen 11 322 TH Ht ag-omia wer & ik yee eT & faa 3 wee) () 57 Wen 23 Fearn wer & sik sam ferme 4 ate B1 (vi) WRT FEN 24 G 26 TH aa-sala yer & sik Wee WRT fee 5 sie BI (vii) Ale sreereA GB, a cat Sarcit ar water BE) Heecied % Sra at arate ae B1 General Instructions : (i) All questions are compulsory. (ii) Questions number I to 5 are very short answer questions and carry 1 mark each. (iii) Questions number 6 to 10 are short answer questions and carry 2 marks each. (iv) Questions number 11 to 22 are also short answer questions and carry 3 marks each. (v) Question number 23 is a value based question and carry 4 marks. (vi) Questions number 24 to 26 are long answer questions and carry 5 marks each. (vii) Use log tables, if necessary. Use of calculators is not allowed. YEARS 56//C 2 QUESTION PAPER.COMLaie C,.HoBr & ur a aaeaet st Gert fafay a Sy afife & vie 1 waits faite 31 Write the structure of an isomer of compound C,HgBr which is most reactive towards Sy1 reaction. 2. Pb(NO,), FH BAW eH HR eT at a Fema @ farsa Sar HA eT a wat) fe at year sifaal Pb(NO,), on heating gives a brown gas which undergoes dimerization on cooling ? Identify the gas. 3. Uh oof da ak we orate dle & seem cif 1 Give an example each of a molecular solid and an ionic solid. 4. feu 7a Ate ar ag qtest. am dif : 1 CH )~CH)-OH Write the IUPAC name of the given compound : CH) -CH)-OH 5. Bleet wir wt fea a en HRT Te? 1 What is the reason for the stability of colloidal sols ? 56/1/C 3 YEARS P.T.O. QUESTION PAPER.COM6 @ WR ae fe (A) step KB) H Ga A afew gereia 21 SAT et A a fre Ky, (ere feria) ser @ sik ei? Gi) Ue sree fac F fre yar on frac, afiean saeriat thisie & frat at cata $2 @ Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two gases will have the higher value of Kj (Henry’s constant) and why ? Gi) In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes ? 7. fr at der fafar : @ BrFs Gi) XeF, eI aa ta : @ = Fe3+ wan & welts fae FG so, Ht wanfes fren ara F? @) XeF, fea awn t SbF, & a? Write the structures of the following : @ BrP, (i) XeF, OR What happens when : @ SO, gas is passed through an aqueous solution Fe** salt ? (i) XeF, reacts with SbF, ? 10 YEARS 56/LIC 4 QUESTION PAPER.COM8 Fa UH sree Pate alfe CoCl,.6NH, #1 AgNO, % wea fern aT ett 2 afte & we Ata ae Agel & aH thea aaa da Fi feed : @ wreaae a ata a @) Fea a aed. a When a coordination compound CoCl3.6NH; is mixed with AgNOs, 3 moles of AgCl are precipitated per mole of the compound. Write @ Structural formula of the complex Gi) TUPAC name of the complex 9 Ge afiiet: Hy + cl, YY onc1 & fea 2 Bek @ Fe afttea wt aife ate arofeaa fafaq G@) kw afte fafa For a reaction : Hy + Cl, —PY > 2HCI Rate=k @) Write the order and molecularity of this reaction. (i) Write the unit of k. YEARS 56/U/C 5 QUESTION PAPER.COM P.T.O.10. 11. 12. fre afitwasit @ data warater ati ai fear : @ wetter ae afaiear i) sett afta Write the chemical equations involved in the following reactions : @) Hoffmann-bromamide degradation reaction (i) Carbylamine reaction 500pm @R (AE H WF Uh AS bce. Wes FT feted Ga 81 Aa IAS 75g cm~3 81 wat % 300 g A feat Vey ada aa F? An element crystallizes in’a b.c.c. lattice with cell edge of 500pm. The density of the element is 7.5g cm~*. How many atoms are present in 300 g of the element ? ae aife at sata fewer afte & fra fra ales wa 7a : CjH,Cl(@) + C,H,(g) + HCl(e) Time/sec eee CyH,(@) + HCl@) Time / sec Total pressure / atm 0 0.30 300 0.50 Calculate the rate constant (Given : log 2=0.301, log 3=0.4771, log 4 = 0.6021) YEARS 56/UIC 6 QUESTION PAPER.COM13, fret vel at afenfira sift : 14, @ artis stengs Gi) Ser fase Gai) Hara arenes Define the following terms : (@ — Lyophilic colloid Gi) Zeta potential ii) Associated colloids @ Free & aftercr at fat ar are ifs @) Uplift & freed A writen st an ype det 7 (i) STR sTaTgS Bosra & Fremty F AS ve St eT afer eet F? (@ Name the method of refining of nickel (i) What is the role of cryolite in the extraction of aluminium ? (ii) What is the role of limestone in the extraction of iron from its oxides ? . TF MgSO, (M=120 g mol“) H 4g Ht 100g 9a A ya TI eda WB faeer & erin ar oftaer aif, ae aa aie fe MgSO, #1 Yia: Aer esa 1 (K, Wa % fed =0.52 K kg mol} Calculate the boiling point of solution when 4 g of MgSO, (M= 120 g mol~) was dissolved in 100 g of water, assuming MgSO, undergoes complete ionization. , for water=0.52 K kg mol~}) 10 YEARS 56/UIC 7 QUESTION PAPER.COM P.T.O.16. Fre cifsre : @ SO, WH arare @ safe Ted, UH Bras eI @ ARGH eas ve sae Gi) 1, Ft en IC afte feaite 21 Give reasons : @ SOx is reducing while TeO, is an oxidizing agent. Gi) Nitrogen does not form pentahalide. (ii) IC1 is more reactive than I. 17. fre afateansi H yee at afr sone fafian : ® CH CH3-C-O-CH3+ HI ———> CH () CH;—CH,-cH-cH, _Cv®78K OH Gi) CHCl; + aq.NaOH i CHCl, + aq-NaOH © CgHs- On Bowen + : YEARS 56/U/C 8 QUESTION PAPER.COM18. Write the final product (s) in each of the following reactions : CH, | (a) CH3-C-O-CH3+ HI ——— CH3 (b) CHg-CH,-CH-cH, _C¥/573K_ OH _ () CHOly + ag.NaOH © OgHs~ OF Ga fra snot et dae : 3 @ then wesa-tre afte aa ta ZI Gi) Velie fact 4 (CH,), N #1 Stat (CH,), NH afew ata Z1 Gi) CR WH St ater vent TH & seein sen Be Give reasons for the following : (@ Aniline does not undergo Friedal-Crafts reaction. ' Gi) (CHs)2 NH is more basic than (CH); N in an aqueous solution. ii) Primary amines have higher boiling point than tertiary amines. 56/L/C 9 YEARS. P.T.O. QUESTION PAPER.COM19, AN He Sadia HH : @ easin a ahha F @ Wir = 1 arent 7 Gi) 2A a ae-2-84 F fra Ff yer sere at ferfiaw : CH,-CH; Bra, UVlight @ a ON ‘i Na Gi) me Es “Gy cther” cd Gi) CH,—-CH,-Br _A8CN , 4 How do you convert : @) — Chlorobenzene to biphenyl Gi) Propene to 1-iodopropane (ii) 2-bromobutane to but-2-ene OR Write the major product(s) in the following : CH,—CH, Bra, UV light 2 @ KI ere OLN . Na Gi) 20H CH CHa aerate a (ii) CH3-CHy-Br _A8CN YEARS 56/UC 10 QUESTION PAPER.COM20. @ Gi) Gi) @ Gi) ii) 2. @ Gi) (ii) @ @) Gi) 56/U/IC TS seater F gee St eT afin eet 3? 3 fre aga Ff waa at wear afar : g q bo-en-c1%-0-8 <» bf n we seatnias oa h stew FA seal HI aferd sifiE eicis, ueiteia, asia What is the role of Sulphur in the vulcanization of rubber ? Identify the monomers in the following polymer : g g --0-cH,-oH,-0-€ < »S! +, a Arrange the following polymers in the increasing order of their intermolecular forces : Terylene, Polythene, Neoprene er sik taeie & ate & dercrs aie Ht fafer 3 fers are F fee yar a fete adam der 8? Wer wets sik ciara wer & fed ued He UH UH sere Sif Write the structural difference between starch and cellulose. What type of linkage is present in Nucleic acids ? Give one example each for fibrous protein and globular protein. Ba YEARS P.T.O. QUESTION PAPER.COM22, 23. (a) Waa [Fe(H,0),)3+ & fae daw, Dass ween sik for fafec! (WA. Fe=26) >) FiPAaH [Pt(en),Cl,]?* I UH Shits creat fafae st were fata a (@) For the complex [Fe(H0)¢]°+, write the hybridization, magnetic character and spin of the complex. (At. number : Fe= 26) (b) Draw one of the geometrical isomers of the complex [Pt(en)Cl,]2+ which is optically inactive. aaa area & ero ta fie ce A wat BaT UT UM a aie aR aie oirafia 6a 8 ta Gf GM Hi sed Tee! UH fer Se on FG aT ee BT SR fr ws) fits & ue ast fa A. Ga ot Se Slat & Wa A 7A SRR A Stal Vita at sik orn fe fh. fee Test 4 cifed E faa A se at at dit ar at sik aa a dimes a otk wife ora ae at were di at fia st were & organ fi. fds om eel aa sik ahs a fer 7 Gen egg ee a srt Fl tert fre ae dif : @ fran 4 fer yea (wa S wa a) a eater? @) teefes ere? ww sae faz Gi) eH terefes afre fer oH cn afer? a aaCET! Due to hectic and busy schedule, Mr. Singh started taking junk food in the lunch break and slowly became habitual of eating food irregularly to excel in his field. One day during meeting he felt severe chest pain and fell down. Mr. Khanna, a close friend of Mr. Singh. took him to doctor immediately. The doctor diagnosed that Mr. Singh was suffering from acidity and prescribed some medicines. Mr. Khanna advised him to eat home made food and change his lifestyle by doing yoga, meditation and some physical exercise. Mr. Singh followed his friend’s advice and after few days he started feeling better. * After reading the above passage, answer the following : @) What are the values (at least two) displayed by Mr. Khanna ? (i) What’are antacids ? Give one example Gi) Would it be advisable to take antacids for a long period of time ?. Give reason. 10 56/UC 12 YEARS QUESTION PAPER.COM24. (a) (b) (@) ) ) (a) ) 56/U/C fre afafea & fea 208K WR Ee, aT Ue afore : 5 2Al(s)+ 3Cu2+(0.01M) + 2A1?* (0.01M) + 3Cu(s) fea 7a : E,. = 1.98 V AS BS Earl a svat aes st ae we sin we a aa & fers feaar ar wet arm sik wi? [E°(Fe2+/Fe) = -0.44V] fea Ta : E°(A2+/A) = —2.37V : E° (B2+/B)= -0.14V araTt CH,COOH & 0.001 mol L~1 fae #t UTA 3.905 x 10-8 S em-2 81 waa Fret area ok faeer Set @) a URC aE fear TAT d (H+) = 349.6 S cm? mol~} HR X° (CH,;COO-)=40.9 S cm? mol~+ fers aa at vines aif: sar diate wa fag Tarte Aa F Eg SOT TT ae fara aafereee Mt aM S? Calculate E°,, for the following reaction at 298K : 2Al(s)+ 3Cu2+(0.01M) + 2A12+ (0.01M) + 3Cu(s) Given : E,.y = 1.98 V Using the E” values of A and B, predict which is better for coating the surface of iron [E°(Fe?*/Fe) = —0.44V] to prevent corrosion and why ? Given : E°(A2+/A) = —2.37V : E° (B2+/B)= —0.14V OR The conductivity of 0.001 mol L~} solution of CH,COOH is 3.905x 10-5 S em~!. Calculate its molar conductivity and degree of dissociation (a). Given d° (H+) =349.6 S cm? mol~! and 9 (CH,COO-)=40.9 S cm? mol~! Define electrochemical cell. What happens if external potential applied becomes greater than E°,,1, of electrochemical cell ? 13 YEARS P.T.O. QUESTION PAPER.COM25. (a) fret et aro afed Ga : @ ae & We Mn Seas SA rae + 7 Teles wae FEV & MY Seay Ta ae + 4 at cee 21 @ C+ WH yaa ara 1 Gi) Curt aan Gia dd @ af Zn2+ Tam abe ee EI (>) FT atte at yeh afar : @ 2MnO, + 4KOH +0, —45 Gi) CrOF + 4H +60 3 aaa 3d THAT Jot H aa ars fea ara ze: Sc Ti V Ct Mn Fe Go Ni Cu Zn fra ae cif : @ sae al fafee W afc sree soem eater 21 erm cif Gi) FH 8 ae Beis seas 2? Gi) SF ae Hae +3 SR sae eetar B? Gv) SA Tae +3 seen FT yaa sears 2 sik wi? (a) Account for the following : @ Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4. Gi) Cr+ is a strong reducing agent. (ii) Cu?* salts are coloured while Zn* salts are white. (b) Complete the following equations : @ 2Mn0, + 4KOH + 0, —45 (i) Cr07" + 14H* + 6” > YEARS 56/1/C 14 QUESTION PAPER.COMOR The elements of 3d transition series are given as : Sc Ti V °Cr Mn Fe Co Ni Cu Zn Answer the following : @ Gi) Gil) (iv) 26. (a) () © (@) (b) © @ ©) 56/1/C Write the element which shows maximum number of oxidation states. Give reason. Which element has the highest m.p ? Which element shows only +3 oxidation state ? Which element is a strong oxidizing agent in +3 oxidation state and why ? fra after 4 a sik Bat drone fafad : 5 @ —CH,Coc) —HP4-BaS0_, 4 _HAN-OH_, p Gi) CHsMgBr }£%,, q Ps, p 2. H,0" fre at ean Fifer @ CH; —COCH, sit C,H;-CHO# i) CH,COOH ait HCOOH # Fr ai Sree aed EU eas wa A fear : CH,CHO, CH,COOH, CH,CH,OH Ta aen-feen aren 4 ffed carte aftr a feafari fre a Renin Toners afttina & of se aed ge eH HY rater wife : CgH;COCH,, CH,- CHO, CH,COCH, artes ara ait, yo ot afta ait ae tar? fr afte & sere a fefar : i-Bu),AlH_ CH,CH,CH =CH-CH,ON $459 > CHO ® @ frarre wrest ~ ASB | NaOH SR 1% we 7 Re — B araétert a ther sada are sate A ae rad ae aT 21 Aan BS a fafaus YEARS 16 QUESTION PAPER.COM Pro.(a) ) © (a) ) © @ © 56/UC Write the structures of A and B in the following reactions : @ cH,Cocl Hy,Pd-BaSO, , 4 __HpN-OH , p . Cl PCI, i) CHyMgBr rar A ds, B Distinguish between : @ CgH,—COCH, and CgH,—CHO (i) CH COOH and HCOOH Arrange the following in the increasing order of their boiling points : CH,CHO, CH,COOH, CH,CH,OH oR Write the chemical reaction involved in Wolff-Kishner reduction. Arrange the following in the increasing order of their reactivity towards nucleophilic addition reaction : CgH,COCH,, CH, ~ CHO, CH,COCH, Why carboxylic acid does not give reactions of carbonyl group ? Write the product in the following reaction 1, G—Bu),AlH_ CH,CH,CH=CH-CH,CN 3-750" Aand B are two functional isomers of compound CjH,O. On heating with NaOH and Ip, isomer B forms yellow precipitate of iodoform whereas isomer A does not form any precipitate. Write the formulae of A and B. YEARS 16 QUESTION PAPER.COM