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  • NH) (Oh) KB (Oh) NH OH) (Oh

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    Wiliyardi Pramana
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    This document describes several acid-base titration calculations involving NH4OH and HCl. It shows the reactions, defines the acid dissociation constant Kb, and calculates the pH at different points in the titration by using the Kb, concentrations of reactants and products, and the titration volume added. Graphs of pH vs volume of HCl added are shown. The key calculations use the Kb expression and mass action equations to relate pH to concentrations based on the titration progress.

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    bab 7

    Original Title

    bab 7

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    This document describes several acid-base titration calculations involving NH4OH and HCl. It shows the reactions, defines the acid dissociation constant Kb, and calculates the pH at different points in the titration by using the Kb, concentrations of reactants and products, and the titration volume added. Graphs of pH vs volume of HCl added are shown. The key calculations use the Kb expression and mass action equations to relate pH to concentrations based on the titration progress.

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    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
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    6 views3 pages

    NH) (Oh) KB (Oh) NH OH) (Oh

    Uploaded by

    Wiliyardi Pramana
    This document describes several acid-base titration calculations involving NH4OH and HCl. It shows the reactions, defines the acid dissociation constant Kb, and calculates the pH at different points in the titration by using the Kb, concentrations of reactants and products, and the titration volume added. Graphs of pH vs volume of HCl added are shown. The key calculations use the Kb expression and mass action equations to relate pH to concentrations based on the titration progress.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
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    of 3

    Bab 7

    NH4OH + HCl --> NH4Cl + H2O


    Penambahan 0 ml 0,1 M HCl
    Kb

    [NH4+ ] [OH-]
    [ NH4OH]

    Log Kb = log [ NH4+ ] + log [ OH- ] log [ NH4OH ]


    -Log Kb = -log [ NH4+ ] - log [ OH- ] + log [ NH4OH ]
    = pOH + log [NH4+ ] [OH-]

    pKb

    [ NH4OH]
    = pKb log [NH4+ ] [OH-]

    pOH

    [ NH4OH]

    NH4OH NH4+ + OHKb

    [NH4+ ] [OH-]
    [ NH4OH]

    [NH4+]

    [OH-]

    = [ OH- ]

    Kb

    [NH4 OH]
    [ OH- ]2 = Kb x [ NH4OH ]

    = 1x10-5 x 0,1
    OH

    106

    = 10-3
    POH = -log 10-3
    POH = 3
    PH

    = 14 - 3 = 11

    10 ml 0,1 M HCl
    NH4OH + HCl --> NH4Cl + H2O
    5
    1
    1
    1
    1
    1
    4
    1
    1
    pOH = pKb + log [ garam ]
    [ basa ]
    pOH = 5 + log 1/4
    pOH = 4,4
    pH = 14 - 4,4 = 9,6

    20 ml 0,1 M HCl
    pOH = pKb + log [ garam ]
    [ basa ]
    pOH = 5 + log 2/3
    pOH = 4,82
    pH = 14 - 4,82 = 9,18
    30 ml 0,1 M HCl
    pH = pKb + log [ garam ]
    [ basa ]
    = 5 + log 3/2 = 5,18
    pH = 14 5,18 = 8,82
    40 ml 0,1 M HCl
    pH = pKb + log [ garam ]
    [ basa ]
    = 5 + log 4/1 = 5,6
    pH = 14 5,6 = 8,4
    50 ml 0,1 M HCl ( titik ekivalen )
    pH = - - . 5 - 1/2 log [ 5/100 ]
    = 7 . 2,5 ( - 0,65 )
    = 5,15

    K + 100ml 0,1 M HCl


    NaOH + HCl --> NaCl + H2O
    Awal
    50x0,1
    100x0,1
    Reaksi
    50x0,1
    50x0,1
    Sisa
    50x0,1
    [ H+ ] = 45 / 100
    pH = 1,477
    pH

    8
    6
    4
    2
    0 10 20 30 40 50 60 70 80 90 100

    ml HCl

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