Em RAK MAK G £ RAB WHR MAR BWR RAR MOR Beh Rw - itu & He REF Ii SHR PEAUFER RRO PRAE LER AMA Te RPPLFIRPPRHAM PERLE REM RAR SAME SORA, AMREHPRRELSA SSL AH EH REAR BEY HEALS AP ABE 6 2B He do GR 2 i fo RBA, ATT a AR HERR RAPED RERRAME. Ae HERA RE AS AGL RL at EAT AEE RE AR BAG 11 PDE, PP RY AT a a BART RA TR TE ME, HARKER CATPSFRPRSE BER ERHHR AMR RLS APRA T ERR AEGABERATS METAR RE ERBRKRE(SMAAI— HF ARATRE, BRRRH SERRE MEPRSEHERMRAS MARE RA KERR TEL ORR, PRAREBNS LSS HFA AHH, MLARL ARMADA GH PAAACLAKEM PRALRS IME, HLRLPS LEBER SRB 2003 #5 A USES AB BN eeBD Ot MERA PERAARSLGRARR FARMER BH fo SRRELARLHANHAR, —F-ROARKERKELER PSOE PE KPEROE A A-MEPRE RESO PPLART RRR LRAT &. DHMH ESE MELA SEA RERLERRTKPERAE MPON RAT AP PAAR, BRR EAM EMERS BE BMA STRAY PRR RRA TAME AER R BARR BAR, AGHEL MACELELHOTRAATAABM CH PMEREBREE( HE HE) BRT iho ARRAS RRP EMPRERA PRRLARR HAS HAP REE © $2002 4 ALHBTH SOAS PLCSER( BARE RARE ONSRS 4 HET HASELAPHRKE RRA GRAM, KR SHH SRF E SERRE LPR DEALER MMA EEBEP RA ESR RT ERS THAR, SHAS RELEMAARRAGR AP ERA SHARA PEER BLT ES BLP RT R CEKERRMLERR DAB AMF fo ER PF oR PROASALMHAPEMPALH AKERS, SHH MRAHAA AFG NKERE AMBALF SR RRAE, ARTRHPERASHRA PEA PRET STM IM, TASER TA ELE, ARGAKPLSERPAB LARP (HARE) ME AH THA PERRET ORE, BE LM AP LSE ARM PRES ROMA, OAT ERIE — AR) M5 (BLE) RAE SHE) ab BEBO AE) MBAR AE) MARE EE) RK RAB) BERT —¥) RH LAR HPA TSE) EHR RT OE), ERAKKERTRA. ARERR ESHER RAH AM EHS PEA he RS HE KEALRRARELESBAAD MMT AEMRH LH ALMOENERMK, DTH MRA Ke LSKEMA, BRAK, ERAS MRE ee 2003 #7 A USES AR aeae Ame Bow Ae ~ rn a Roe BAAR a FRAT HORA ERAS RFSH STREAMS ROP BS Pais HRA Riv RTA Bad MTOR CRAM MICH Re HOT PRET AE Soe Bra ROT Pea Bu PFU ~ Rik aan ~ BT AaeMSNSeL BI BPR ~ BAR LFRMRFSLFER ~ Sot CARMEN LARRR A RO ER BER . Ba WOE Re ROR ROG het e moe Ste CRRERHRRTH - Be se OT RO ARERR RIE RE ROY BPTAAQ ERGY ALT RAR RSS RALS EERE R-T HAMAR S BS SE Ce EeTSS wee oat aoe W 5 BAK PLERRRERLSE Hi BoE wat Ste ERR & i Ree ma HANES BREA ERES ee Gee PES AUF BERARLER ake AKAR RRR RAR ~ BET WRTREE aie PORTE ERR LERHNAR KA RANGED PES SOD TLAMMBSF LEO RAT ReG5 RAR BREAT RADBAe TE #-H AeMREK EG REMEBER TSA RRS AE BUS SARS. CHROMATE BIVATSEE. PRASPUTKMERR AME AAKZ MARA. OROLFH AS RHERAEMN, MERAKHELRLOA SL MKERLSZAAME, KES SHE, AT RRS AREA, ARR TS RS, MRT RSH FAD ee Tk WELFARE OLE OF A BAM AS De +h. PUR AE EE. EE JI, ARB TER UBT EF AUER ET BES oP RU — i TREMBLE LEAAORALD CMT ELA DME SR TS Pa AD EAR HER HH RH — FRADE ALF FE MGS ARS, GIR Pa TG SI TE DTD WEA HASHRCRR, KS ARE EAP ME (Pa) FP OOSE-B (kPa) a» ~ SBR BUA AK CODER AMER GARR B-TAR RRA FF ASFZARAMERAA SFORDF SRST RE ATER BRR MURR RABE TE. BREA HONEY, CE CRRA EM. BRET HERA TERRES WOKE ER RRR HE HRARL te MRE STAB TR, BEL RRR E SFR ER RA, FEHR ADT OSS RR MASS Se ESB otPASSA ESB ot Boe RIOR HT ee A ORAM ASABE. REBECA R- BAD RS ME AB 1 AERA = BRIER 1 BERRA TEL FRE SE OS BA TE p) RACV) HET) AE) AGCRMRM BM FABE ST SORE LP WMS ZARA Yn hl EM AWK AR V AE p RR RRRELR EH ADR VEL pe “on Mp St AMAR V RET RE SRA RARE, AMR RM VOT. 4 pT HENCE V Me RIE, RRA RES SH, FRR Von. UL STEERER TY ARP VouT/p SNS LNA RBS RPG V=ART/p AB SR pV =nRT RALLYE. CEPR pW Pa Veh TAK WBA R 3 8.314Jemol 1+K7', WR p VA kPa, VLA dm? Wt, R ABS [811-1] ARAAERR GRR MERA SERRA TRE SRE FG — BB UA UA FE SP HA HMARSRREH BRO AUTOM PE. PRM TOS, SR HORT DIOR BRIA DF AYER BR CEEADMTEL) EL RUS SE A FR HAS FE RB SEU 288. 5K KM 373K ST AER UY 23. 7208 IE A N 23,489; HAF BIKE 201. Ses KA HE 1.012 X10" Pa [ie] TARE 204.5 107° 9.449% 10 4 =0.1781(dm"} FAS AU 27B_ 1.012% 10% _ 0.1781 1.293 5gg°5 * LEST =0.2177(g) HARTEROw ORT 23.720 ~ (23.4490 0.2177) =0.489(g) FSEUA BRAY FA BR 2 a BR A AB WB x My SEA ai oF Herat PAR UR DHA FEE 84.1. (ih 1-2] MM =(0/p) x RT, BARA EHO TN o/p (aK EL AULA TA. A 279K NG CHAP ADD TIN p HR p/p MTR: pePs oAgem 3) ef( p70?) 1.013 x 20° 15454107 1.5255 6,753 x 10° 1.0241 x 10° 1.5212 3,375 x 10° 0.5091 * 10° 1.5084 DARREL UAE) p/p RE p AF ote 10) BET TEL 0 7p Xt p TRAC 1-1). SAD] p— 0, MIP Be CT He /p fic A pO AY CHF SPRUE PSB BETES EBRD (p/p), of RA MALTERSTES TRG AMS TR B. RPA AMAR ERE SAB p= 0 BY. p/p =1.50% 107 pu LOPay 0.3366 0.6733 1.010 FRUL M =(p/p),-0°RT FAL CHF oo = 1.5010 7X8. 314% 273 = 34.05 RAM RS RRS M=12.011+3% 1.0079 + 18.9984= 34.033 WERE. 2. Saar BE ae BF HE ACS RAB SA Re EA EEF 1801 Fh TARROTAP ENED SERS FRR ARO HEA RIA EH C pg) SS Flo HRCPRERA: pas pit bet pst + = EM pists p, RRA CAND E Opi FI PE we IE EA HS AG SS ON GOSAOS SE OR aE ce a BOR ORE EAE, BAe eA pV =nRT barbrt potent py =m RT/V tng RT CV bo ARTSY = (nyt ng t ta RT/V BU ng RHESTKN RMD RAE DW np emtme~ tn = Sm by = ngRT/V = ar mt BENE ABT SE A UR AAI DD A HE A A PAD TAM FLX aR. WA ALB IR EMDR BOA ny Bi op ABA RRM X, AX, Sl 4 Xq= ap/Cagt ty) = ng/g Xue nal(nat ny) = ny/ng mem X= ming bV=nRT a. pa Vana kT (4.2) HCL BRUR(L.2), pN pg ¥=aRT fg RT if ba ni/ng = X; a ba XPy YAH Y at 2 AS DAB A SP SRB RAE BR -RAMRT HR ERRRSERETRARHORARAR. AAR AMES PI AM RAE SN EMS F 1, Xt Nyt t Xa a SB AS ASD ae OY AL BRS SP A RA BE, SEHR ELAS RAHAT REA. HEED BRIA AIT) PATE AE TAB AOHCH BERR AUA A AYRE A, ICP CHE HL OF Bk PEA LRT AH A WARTS ASA PR A RE A POA RELA, GRAAL PHS, kA MR RRR BRR AAA A HLM.Be TR [611-3] 6 298K Bt, BRA LAM RAE 370ml, TEMA DH 100. 51kPa, HEP ERE EME NF RAMA SDI UA) BR 100.51kPa, 27 298K Bt KALA EW 3. 1672kPa, BEL DEN p= 100, 51kPa~3. 17kPa=97. 34kPa BUR VV, =370mL, po, — 97-34kPa, T; = 298K RHR V)=2 mL, po, = 101. 3kPa, T,= 273K We BVT; _ 97.37% 370% 273 yer 3 x 293 326CmL) = RRAERSA BH PCR MADE BEANS ME SE A FSB DAS BA A Si TERS RAE SURE. TERR AT ERS BRAGG HOPE aR SE LB a AS A RT AMES TH LER SRRBR ENE E, WPPRIS AUK, pV = uRT BD pV/nRT= 1, A pV/aRT AL, MR mR ES THA. BUDE mol HAE STR R HEL z= Pee V,, _ Va( 38) RT RT VC) Pp ZHHTAMERAF, EROERR 20 SE AE A REP UR A A BE RAS co FU AN RE RA SOT HS Od TE RIN 1-2 BE PE 1-2 2 A, CH, CO, PRT IF BS Zp. HAMA, Z=1 ORE BAUGH Zp KK RMA RAP Z EST 1, MR LAA Re Be SEK BRIE AEN, Zp ase, 0 Le BRM. BREE HP plea BABA EEDA MA-HARER TaN Aa 7S BEF AH, FHT. Fy T BERS HR WS PRG ARETE OE ARE E188 SERRA TLS PSP AR AS 1-2 ILA AN Zp 0 SOF MES -8iS SE BOR FORT HE BARBER. KHAMBEUANAT REET BE. FU SC HR LE BE NL TE GBB SS FAS AK 20 Me PF A HA KAAE ABE Che ey RRAADF 8 eV) PRR, MERA AAATSS CARED SEIN THERESE ED FRAG AA REED Bt a eT A A AOR BSR EU Met RY GL dios A ETE. RA PR HAA SHOA VA) MEARE TRE GANA. BS b AKAWBE RO BS URARAXH EER. MARES, TKR. EMAAR T BEN AD AE TE a RAS 4 18) Va f= ¥.- AURA BAS MORES HBA PCV gq O)= RT Hop V,, ARAB ACE IR AA BL Dele dy FRAT PE a CE RH SL FER TRS FH BE (1 BE SE we A OR ARE BRE FE A SD HR SLAY FMWD YY HF Da IB BE WRF eT AB FL MERE SR ho A CB, PAE NRE DSU THEA, SPF MD SC RM eH Hy OF a HI ALE UBL PEA REGRESS F Und FD SAS WS a TR SF eH BD 5 FH Es TD TT RB 2 EP 9 ER FRESE EER. RA SLT Zea LAR SEB RTT I Bo BEART ARB AGES TRIB RD RRSP A AN FE ( yy) BH, SRT niet FETED (pe) AEC Da). bam Pet bu Diy BURA AAR EAA DY BPS TT EL tg Pa AE RS AAFRA EDA. CSVSET SLOT DME PR IV, Be Pac /V a) I pee al/V,)? RAERE ba= pet all /V,) SH EOLA i Bea BY AP GE HEH. BUM AAC ol BR wk PF PE a FAD Keely PAINT ES ARDEA 70 BY PEE BT SI AS ety ETNTUAB TE ACA FEAR A BE BOT EE (ptaQl/¥y 2 CV a> 8) = RT RAEN A TARA RIE TOT AY BY O/ V7 BEAR,Boe ARTE ORAAREM, CRED AERA RRER EN OTA A EMRE EAST AD BCR EAA AT, A OY 8 PE I See. RU —ES He eR Ra /(Parm®-mol*) |6X10°Am! mol |) WHE | a/(Parmé-mol"?} [6% 10*Gmi smal |) a 0.0247 0.0266, Nr 0.141 0.0391 He} 0.00346 0.0237 O 0.138 0.0318 CH 0.228 . 0.0928 Ar 0.136 0.0322 Né 0.422 0.0371 co; 0.364 0.0427 HC 8.554 0.0305 \CH,OH| 0.965, 0.0670 co 0.150 i 9.0399 CAs 1,823 i 0.1154 FRAT PACER A EF RHE UE RRS FET SR OH A. TP AR aT) ASR ME Fa AR ED ARES SA A AR A TIER TDR Av 5 FY ETS A ALES A SPU A A AU PB ES Be SES RRR T 9 SCR RAB), SC FR HB WB A FENG De AVR AE EM, DOTA eA ES — ED ET RADWELL. SRE ALT ve EL US a ER ANE UE EE ARAL MA AE A I, RST Bea SE MARAT RAR TED BRL NG AE ID AES PTE TT CE A A Lol C540 EE ABA, UR RV RAR TV EE WFR RE He. —AE IR OI FR 8 AL TBR 1-2. Rid ESOP EMR BR ie | TK pea | Ve/m' mol! m.p./K bp. K He 5. 2.28% 10° 5.77107 1 a He 33.4 4.30X 10" 6.50 107 16 20 Nj} 126 | 3.39% 10° 9.60% 107° 63 104 oO, | 154.6 | 5.08% 108 7.48% 107° Sd 0 CHy | 190.9 4.64 10" 9.88 107> 0 456 CO, | 306.1 7.39% 10° 9.56% 107£ 104 169 NH, | 408.4 1.13% 107 7.a3x ws 193 240, Ch. aly 7.71% 10° 12g 10"# taa 239 HO | 647.2 | 221x107 asoxtes | 273 373, PAS SS AES otia SS SE CaP a EB Ot BAR ORE FU LRG HY , He Hy No sOp SPAEAE GE CAR ARB CAS CU SBE AB HLA, Ae GK Bt FTE AR HE SF Za Sd 9 ABA ee AY OD BAR HE SF, QO, NH 5 SOE FLAG BEF Bb A I He HB SSURGEEAEE IAKARGRART RURCATARS. RR PAGEL PRRA. EREPRET RAMA Z MEE REGS EZ ASF IR Roe Me ik ABR EAE LSE ASE AE AE Ae Re ML, HOB. -EMRGKA BEHRMAN. ROAR TIO HOEY ALA A me TK eA RI TK — BAHRATR ARAMA AAR APEMA CHT R. Lee RAPT ATA TAU PARP EHS P PRATT RR RE, FA i Pe EZ) SF a ah AEA RD I ABA A BE Db ETT J RAT GE HH A A AYE A ST A FA HH AMHLAHSALHECT. BAAD F SOE SAS TROD ADL MAS EB BE BE ERM NPFRALA LHR ARP EROATRGSAA EM. PRAACRWAFLECMA TRAN WA Ae RMS ADR DL UB ER FYFE I HUASS FAL WE BREE A ORE EA HR SL I Av S(O RCA ACE ORE OO KAS AS, RUE I ER ERR CARRIE, RAAT EE FERAL EE ADT, A Fede HARA TM RR RE HSM SEO CELE MPA. RAAF SRM 2 AWA £THERER, PROCARRMEL OAT BUT Me AARMERKA, SRRREORLREASH FARR -HASP L PHL AAINE ED) BRAEMAR AS REM TA, HABAe RAPE A aR Ot AR PE 2 ALR UE EGA ff Fe I PE AS BB A SINS 3H DAME EDEMA RK. RANBIR ZR RARROR RAE CMA TEA KAO, AOL LAS FD He TIT RF a WH AEB MAF EDS UR. WR, A SUK PRE AMD FRE S OR EM A RR AR UAE AU BEA ARICA TRL AR CEE SEAL Bg be C/T HE EY A AER (ME 1-3). ARTA heal oe 2526 TINT A031 32IIIAISIO IIIB fark) lgto/Pab Hi-3 AMGARAR SRE RA DP A RHR, BREE. _ . AH. 2.303R BARAK MABE, AH lee= ~y 3037! ® SOP AH BURIAL Jemol AAALAC AL. EA ARB E A yeast Tn) SODAS EL ER. 3. RRA *EMRIA AT AL MOR ERR UCL A OF RE A A RR A TE FERRO T The F AP A a GL A A IP a PAZ WE ARSE, CE UR ROI AE STK DFP Ma A, UIA ShARACEAA. GORE EEG AE AE PRE DTD AREAS GE SER AHIIRALIE FR RTA APA He MER AA He. BTL AOE BE eG SS OeaS SOR ES Bat Bw ORTH 51 A A A A 1 sd — A ME AS SA tA TA TE — HE AY ABE AES FR Amol RAR AA ITA HR AP 2 PO HS RUSH, RR, CERRRALET HEA BR, = ER MOOR DA, FR POCA OO RH PP a A PE, PEEP AER EP ETT RZ A US A A RTE Re PET AE. EER ALP ASA TE. RE (88 AEE ACR EAD SEAS} PEE TTR RAR BO AS TT SP FP ADE 2 (AIM SARE FR. HOSE AUR Ie 1.013 * 10°Pe Rt RE ARE AB A FRB BAU h RP 89 SE ET A A I, aT DL DR FA SS LS PRA EN). APRS FP A A BE eA PIBESAAKHDR. RAE RIEM ROR RSE, 38 1. SUES ACME 330K BLAIR ATAU, fE 100KPs TF BCA 1 OL STAR CELA AEE AVA PURH 17 ASkPa). ffs) AHS EER) SOP ARE AE) RT RH SERL (2) BATA A 100k, Fri 973K RARER 2, SHEAR A ede 295K AVE Is 97. 2kPa FM BA 850m. PMR IG OR ED? ERED FRE RAMEE? (ER 295K BK MDA EY 2.6434KPe) 3. AY 0.2L REA O; HN, RGM. HARB 08K, MH 95, 9bPa BY, AMAER TH 0.0020mL i N,, Flr (UN, AEST BBA? (2) Ne HO; SE BB? (3) Op ROAM RAB Bo? 4. GHB 0.13 1eH, HT. S2gN, AF IL VERA SRS TAME. HE ORK WN RAB CR. RA SIR GHEY 4O1kPa, AUTH WBA I TE EP 5. RYE 313K, 9001s HY A, 152_ EA RERE. 2E— BRS AL EG ORE TE FE MRT OK MAE ARR — EBT A (1) REREAD, (2) AE BET IET A HEE AS BEC) 6. RMF RE AAI RH 597 02KPs, WE A 160d? (HE 101, 325kPa Pah A PR POM RUE VE AEN 131. 72hPa, REE AE RTA BA 7, MBA EET OU RDA HOE. TALE PAGINA OH ER A REG AR ASML 175, FREE AT ED CIES ET) 8. Ch— PREM 0.50m! MULE ARA, BEAT 16kg HIE SOK 1 CH, HBL PRE 2 AL REEARD RETR ATE AGSBOR AMIR FE SB aE a a 8 A SO PAD HEA OU 101. 325kP EAL, SAE RP—PRIRE 1000 .B--T RGR OT RERAM TEA, EME HAT Sm TIP, 10, ERVACE 77 UIA 41 BAT OR: RRB p ART ARH BPH A MB, In pAaPe) = ~ A/T +B (Cb) ADP AR PILAR OH Co) EB AA FH ASE WOT 5 LL, GIZA 25900) - mol |, AE 293K OF AY AAR I IY 7. 58 108P a, BOR AE SOK Bt AY ATE ATE 5 12. RAVAULIAS 40k) mol | oR 298K Bt AN ARR 13, 0.520g MLAGSH FE Ret 5e A SFR A A A TRAE AA RKIR AT AE 27 93. 3ePa WEKATRARY Bool, RBA BT KOO, MAB. MM APRS AERA R SRA SAMA RDA (6 36.8U 9 1OTKPa St AEM A, PRADALARIE Np 75.1% ,O; 15.25) CO) 3.8% 0 5.9% 5 IR CO RSE A 2) CO, BIKA, AS. RUE 40°C BE CHC (=F AE) IG MLR HY 49. Bia, HA AOL FEAT HE OT. 101kPa FSR 8 ot CHC) FEZ. BOR:C) CHC MHRA BRR TRE RS OY Q) 4.0L FB THE CHC Be? aa-R 1G) 2.0L (2) 113. 2. 1) 82%mL (2) 735mL 3. (1) 0.267 (2) 25.6 kPa, 70.3kPa (3) 0.733 4. py, =202KPay Pu, =105.8hPas Pay, = 96-2kPe 5. (1) A3.7L (2)78 dg 6. ¥ = 40dm? 7.341.44K 8, p38) 8. 29MPa, p(WE) = 8. 1OMPa 9. p=17kPa 10. (a)A = $023.61K, B= 18.08 (b)Aq Hy =41. 77K) -mot”! (e)105,037KPa 11, 1.27% 10°, 12, 3.94KP2 13, 99.2% 14. (1) 28.6g-mol’' (2) 3.83 kPa 45. (1) 7.8L (2317.76 Re Soa eeBae SR SES HeR Se BR. SEOTSH Sh FR SRR BLA ABA RED ES OT TD RES 0 BRST RD PRAY JSP A HS a OD EN a fe BARAK ARI z RU ACRROMEMFSOADGR FRADE a) ® | BMA erm | MR BEER Gece [ome _| om a og | SUNN RE B) seamen) <1 | SATB) ma aeemie | ak Ey & a _ MY | aba a aK Be TR e[PAF! 1-10 | xor | amram | Ram | s i 5 em) i-iwo [228% ce enc FelOiDs | [FeCOHs]4 |g | ee Oe wR | BB ~ SARE wana | >i 2EB* | acaemtes | wee | mL * Rettae EAR POE AMR SAS AS ESP ROR LARP BUCS RSA SPRAY BU Ea | sh BARRY SPCR. BRETT Ah yO A RHE) Clin) SBT FRA REIN FES PR kA ABAe RR SESE = BRAD SEHR TAR FARE BR AA LAR EF A EK OR EK 1 THEE AEE A fd > EP OY BE Hw (ER HE OP ST OTE WE A ADR AG ROR ER AR ES oc, Has ALE molsL* ma any SA AWK mE My Al (2.1) aPAL MA CA MAY 2 ERE JE Lg SRESL PF eSB Me she ED RR ARB $02 mol+ke Bl tym bn TE Some (2.2) 3, ERR RE SE SA 9 DB eg) PP BB (oe) DB Bb ALTERS IEW a0 a=" (2.3) TERM A AB UAH SP EE A ARS) BA A BA AI ny ta nm ays OT nat ne ta= AT nat ne ER rat xp=] 4 RS BRAKE ARRAS NARA ARETE w,, BE w= A (2.4) = RTE REE A HT Sp AS = — SS PS 0 Se RSE SER Bald ee-B atPORES Bat BAe 28 SEs AR te ARIES HEAR RM TRA SSR ERA Pe BARAK ROB BES RHR SEAR TRA SAK SRE FR RAV BREA A EAT PA AISI: A SSF Ee TE BE SCHARF RISER A ORI OD FR PD AL Da FA AB AT EAA ti Aaa AAD SPU, PES LRAT FR PT oe MES Be ER HB HE 1 PPR AS REALE Fe EERE F BRAEMAR ER RR Sat, ELFLORS KMRL DRS TOS A AAT E AIR). See BUBB BE A ES 2 CIE A Ca 2k a a 2s AAI AH GP ST A 28 os EA] WEAR. SUE ZEEE FEE AE ROARS AE DUA AUER LSE OS AR AR SP INR ER EB ER. BM B= PE X te (2.5) Sb p WMH, pf WABANRAR, xy WMO, Bre WR BOB K, ME y= bry ASR p= ph X(L~ aa) (2.6) HORUS TRG Ap Ap= pl p= paz (2.7) BEAL PsN RR sw EH RA BS “PEO RR RURIE Loo “TL, nat ny Wag sre zqy= phn “tat Mp ty Pa pe tA, ng VRE ARRAY py A My AE A AE Ap= Krby (2.8) Ap= pn Xca= pat 2H 4A FA AY SRT PA FR He Fe A RR TE CB (Ty ye AD 100 HE, AD ARC EE FF Bb AUR C101. kPa) Ai DUK BOD ak BE AS 100°C . ANS AES A TA A 2 MERE EAE RL FR EAL EP Be 2373.15 KCLOO'C DBE PE A AEB Es I A, BESBae CR RE (101. 3kPa)Et RTS RHR ERT ANR. AS R Ee BY REA « REDIF Az I OH, OE 2 AS BB kL FE CAT) SS RS SR PR (>) HAPRERY AT,=Kytba (2.9) ACHE IC RAUBER BE A00 hk F EB BA Dla SH HE ALK. 3 FRE BL FE 46 — me NOSE TF (— BE BD 101. kPa), MR ST RM 1 AP AE A REAR CT). ARP 273, 15K COU DF FR RE Fk FEAR, STK ABEL 273. ISKCOT ) 0 ek Him A> BME BA SI LEP FE 273. SK BY HART RF oY PH OK RS TD AD RAT UR ATT BUA ESET. MN A RRA ST A VRE ey SB, SBR PR ATURE BL SARA lO BE A FUSER APE US Re SE RR TAT) SR REAR PRAE (RUE RCE RAR AT= Ky by (2.10) SRP, PUTS AAR AL LF PR. BA PA oe FA SRO RLE. SRO RUE FERS LAA PRA AES. Ain A A pg eS TN COO RR) A RRP EB FRE Ae AG A AHL — FE HH EERE. SS2FFC2.9) 40 (2. 10) 0 EAT VR SPEAR AD BE BE AS 2 TDA Se HE ER BE TBA 2-1) 46 200g AAP HEF 10q HAIR (CoH1204) RIE EAE 101. 3kPo KALE BAS Yk REL [98] 6(CgHi0,) = 0. 28(mol-kg |) AT,= Kuthy=0,512%0.28=0. 14(K} 7, = 373.1540. 14= 373, 29(K) AT: = Ky ha= 1.86% 0.28=0.52(K} T,= 273.15 - 0.52272. 63(K) [OH 2-2) HE 100g ACH ME 1. Sng SAR, MN FS SE BE AY 272. 96K, OR CRRNERER. RO SE ESBae BR SRT TAR TRS Se a aoe 8 (8) AT\= Ty - T,=273.15-272.96=0.19(K) 1, 1000 Ma * tty AT)= Ky bx= Ky — Kimy* 1000 _ 1.86% 1.50% 1000 5 Mas ge AT, «100X019 MA7Ce*mel 0 4 FRSA CER ANE EH SE 2-1 Bay FA ape aR SE ea Be ABS ETE LCA A) Fe AK CB) BF a A RFR PE HE “VER FS, ARSE Fa BEE, wf CARR Bk BP PO A ZT FS, APUA TE EAN Ta OS tA RR PO oP BK ES FE A MATE HF 2-1a). KARMA F AAT RHE HER. BEAR DARA DL AB SR ps — RTE Se a a 2 RI DEA A B BD u +a H AEE AL Ak a) W21 SERN REE RAE APA bE 9 EK EAH ORAL SE, RNS BN TAR FA mH PEE BEAR CHS 2-1b Biz)» C2QRPT HER 1886 EA SIE RE BAAS th EE CAE SR A TS SH A eT HV = ny kT Qn) W=cgRT (2.12) Kot WBA, AY Po My kPa R WA RL HW 8. 314)-K'emol bye SR A RRR AC mols L's TT MOR I A Ky VBP AR L. STRRMS BARROS RAT RRR a, cy OBA SPREE, A212) heal Ra WH b6,RT (2.13)Bae A REST RE 142-3] 298K Bt,1.00L A 5.00g 19E A HFM, HIG IRE Ee 305. 8P a, 2k TR Oe (#) ny=nyer-7aet Mga MaRT _ 5.00% 8.31% 298 AV 305.8% 1073% 1.00 OSes ES (48) FRE BIC KE, BREE SR OCP A ea a ABLALAR ATPL BG BAHL (OA ARDPES” 3 1 — HCE HF IE DI Me Td AS BS RE. RSL” RA YEE POSE 2 a AL kU Ed BST ORL AUPE EE ELS RR ED TAB TBR EI A CHO) TA PERRIER ESD F 5a 78 FS aa AE CAE AR ES OY BL AL IRS) FR UAIE IA SZ. CH3OH TEAK A 98 BE UZ. BE CH; -O—CH, KAS GA ACME REDS, FF PA A—OW BH, SKA, A C,H,OH 4 CH,OH. C)H;OH 4 HO #0 1,0 5 1,0 3-F RBA Be, HEADS BAS TD ZB RE AR PE BF. EAARAY KERB KA DEAD OME RK RESTS LM PEE Ak MLB AEF BER AE RA ARE 0A SAB SS PB A AT ECE PR ARSE Bh 1 PR BE He A Ae ARR A DLAC HW A BT SP Map PATI, EYL VA HE PO A i TF — RS ee JR SUAS PEI BE | AT SREB Ry EL FL Jy Ba FA HOA CP AB ATR BE Toa TEL HI BERT EK EPRER = 4.05 10"(g-mol”") LER TE SE LIB — Ps ED 7 a PH GK MERAH MEE, RRP AR A, Ka cxl/d (2.14) A K ASP ch TEA ERG o PACE ch BPR A TER Al @ PRE. 2. BRE i SER ECS BotFad Sas SE DR EEE oe Sle Bh Ae ee RD ESAS OS OS — IR A A BLA Fa SPAS SSF RE ACHAT AA TETAS BS YE) PAR Bw FESTUS ATE RE Fy Ta a BL 3 A RS. SRAAMERRRAR RA. AOR EMP: AED OK REBD BF 60 ~ 125mL 19 SUG Sb HER AL A SLE SB, AREA BE SRT, PEGE REM AMST EXRLE? SARRAGH ERRTARNCSA. CRIP SA ORK RELA LAT IE. TERIA AE RR RAD BI TK BAT VC) A RI Hea Ce) Wo (an) SARI DUS HBP ARRER YM m,(g) J mom eee) aww ADK panena c= Sieg SUSE A TEARS HOP BYTE EE, ch, WUE AE A EAI A oR HF AAR BE [02-4] & 1, HA 100mL, HbA 1,10. 00mg, FA OmLCCL, PIR BE AR (1) WOmL — KA (2) HAIG 0m, HEKER. RRR RR (K = cei = 89) 5 [at] CF mL — kay, 100) m,=10.00% (5 zayr709) 7° 134mg) _10,00-0.13 = p= 1000-913 1099 = 98.7% (2) AHL 30mL, P= BL, _ 100 ms= 10.00% [Eze 0.00054(mg) _ 10.00 - 0.00054 B= 10.00 % 100% = 99.99% ifs IR PR RY AR A 2} SA AT A He — CET ARae eh sae Bo Aes — ae SRT RE TT ME OTT, — RA RY RE EE EYEE RE CAE a EH), FD — SA Pe a HC A) SL AR EP HH HB PL Be a A 9 OVAL AY EB AA EHR HR APT 5 Pea HA BAUR RSE. GONE TRIAS A REL AS. NET RRND RAM AERA — RATT EL AEA. BETTE TEE SP it MTEL A tt a RE SS OE A AH A a RELA, PRARELEN GLE R-RAHRER A . WER Fi RAR-EAR-R BARE EW BH KR -BMPWRE REM MA R Bo LEAR EDR BBE DE AP DR A EB AU FE STR AH Wy Psi A (1) RBIS BE A ABR Mo RE aN RE SP TT RBI PK © (2) AB a Ws «A REA SE A NA ET HL EDTA (ZIBM ROA ESE NWES RAF FOR AT aN mM"! +y'—My""* (3) LIER ER: EATER AL Ws BH OO EO HSU EH DE RMT RRA Ag’ +X —=AgX 4X :Cl7 Bro 7 CNT SCN”) ‘BeoR FAA TR PL RV TPL ARUBA BR AB HCL ARNO, AR EIN, KO, PEAEACAL) RISA RE (LA NH,SCN REA Fe?™ PEAT PT EGE Ag” tH Ay LS a: WE CBr I SAA A ARR TALE AA (4) SLAG ARCH EB = BAR AG RF aD Dk Re MME ROA SLRS PASH He, EAE RE ZEBRHEA EF MnO,” +H" + Se->Mn?* + 4H,0) BRO BER BL EE TER CrO2> + 14H? + 60+ 2Cr* + 720) Ba CFC 29 06) eB a, HO — BE oe AEF RR ELST KI EAE RAY 1 PRI ee ae RE, ai SOMES oo @Wie SER ce Bae RR SET FA Na:S,O, WHEE AUT Lily + 28,0)? +21 +8,02°) 4. 2 RAE DT AT A FRI SER APA SE PTH EB A Sy A I LE RR BD AB TL SE QV HSE SPAT LP a aE BT BY A I A PO A CL) FE De OS 5 RE EAA EET IE MMSE EIAZ 990.9% LAL. (2) FR NC EER. FR A ey BZ RAG TR AR Ite 5 (3) BAS HE TARR A AE ES 0 3. ERR (1) AUBERT: LSE FIR EAL AB RAL SEK BE EA HERERO A. WANAACA ES RAR ERR. BRE SEITE DATE FAI EA BE HK Q) BALE ARGROROR EMEA MMAR a Eee SORE AG ALARA AE TBS, TEMA OE Pe) Pe A ARAM GLAS AHSAN REMAN . RAT JAE RT. RT CaCO; AOE MA eR TY HCL ARNE FP RSE ee, AY HCL oT NaOH BR AER AEE (3) SEH SE Be PF Be UE IR NT Rt, A RFD ae | SCM AT A DS 9 B,C Ss BEE ws Sb A FE A EI TRAD BRE. AM A K:CrO, #2 NavSO. AOREMEMY ARERR wh a ERRAE SP BE KyCr.O, SUH Na,S.O; SEH NayS,O, 24 BF Ne.S,05 BEACH Na,S0,.NaS,03 5 KyCnO, HRA EATER A. RAR R FOE AS BLE KoCr.O; ARPES PMA HAY KI, CO, 4 KI eR 1;, SF Na,S,0; KI EAIR A bo (4) FABER Ss A A A A A SH PR AR I BEACH OT NE A ee BLS KMnO, $208 HRN EE BEA a Ceo* EH Ca?” BLIE HH CaCO, HFA H,SO, BF ITT KMnO, REPEL EF Co" HAM COP JA HE care 4 REP RE RSE 4B MM FF LA SE a SEB FROME. SRM REY RCA TR «Bi EE, A AMER 2 MT BBDBae Oh wee Ka GAR, CEMA TTS AERA Ek A A GOP AER RAT FE EAL Sp 9 AL PEARSE PT 8 TE A A HE FUE An EAR EP YR EN BY CT Zp se eH SK HERD RARAOAARR EAR ARR, SP RT RRR STERN. EAREDA OMAR PRT: (MAM AR SHARAN BARK ARRON S EA TE (H,G,0,-2H,0), KABA SS SREAMAE (bE RB, AR He Bae 99. 9% Bb (OEMBE LRARARLRPHA RDS MARA CO, (DRARHAARAMERAE SH MPSA RS MA TDG ERE. AHO Ney B,O;* 10HjO Al Nay COs 4 2 fi KEE MP BF MIR BE ASE EAR ba WS RER AW SRK FSB, Nah NayB.O;-10H,0 Wk & AYE a eR FRET IT FE 89 HEL SAT RO a EP RRA A HS HEE ARE TT SP TRE TB) A. ERR RTE EA RE RA ET TH EP RE A AB PR RE GEIR CD DLS EIRP iE EAR Se TE OR BA 5 — A RE HI 4K HRM SRR ESAS {AMARC 100mL 0.01667 mol-L- HY KyCrO; BRAERR SE. ET AEU AL Th 8 Bo a AR FRAME A KC. O, 1) RR: m = c+ V+ M = 0.01667 <0. 1000 x 294.2 = 0. 4904 (gq) HAA — BUSH RE, BAI KyCr0, 0. 4910g F 100m. fb HEAR He RK EEE DEES] OPE SZ LOOrmL, 0 2 ITE EP BB A AE TL ok BE 3~4 TK, PUES BB TEI DK EHH ET KC, HE HR. FORME eK C205) = 2 = = spc SRO = 0.016690“! PF ARATE BLMIES K,Cr0, REBESUR AN 0.01667mol-L”' BE RTL BEA EPRI BOE 0.01669mol- LEW TE BOR 5 RE FGA Ee RS EERE EH A EI inf FEAR EA A A AE A EE ER ee ‘pp BRET PR SHED MR AE GL LDR Ae) A HOSES BRA ES -B OBae BR SES A BACAR a TT PR HE BF A TRE GH RRR BRS HARES Ra M-HhERERKE BRE ALE). {Bl MAAR! ILO. Imol- L718) NaOH fre RRR AT Se TEAK Ra CARR de WY N2OH (an = 0° Ve M= 0.1% 1 40= 40g) FREE FRG IS RS FEA: PRUE FAV RE ME 0B 9 a — Fe SL EYL Ye SH RH He. ACS FF a 0 20 30m FEY. HR EE SFE F-R EY AE BF, PR A Se wa SE RUE Re RUE AR, RO Rh a AUARES PREM BE ARTEH: RA BR ERM 0.4—0. 6g Oe BB AM KHCH,0,)3 AHF 3 A 250m. IGMP HA 40 ~S0mL FIR ZI IMA 1 ~ 2 ROCHE SS 20 Fl, Ue BL GY NaOH Seve se SOL A RPL A RBS ADEE. BUR AT KHC,H,O, + NeOH —=KNaCyH,O, + 1.0 a| & n (KHCgHyQ4) = 2 (NaQH) fe] BE NeOH rR EM se EY _ ma (RHC HjO4} 1000 = c(NaOH) = FENSOH) x M(KHGHO) a RE SA 2 a ad Pd 6 A Pa He} 2-2. z K22 MES PRNARRERURGE KERR RAEN S ROK eer HCI [Nae EDTA | KMnty [ NaS.) | | AgNO: fom | SB T.KB. =) KMn0, ! foam | acme | eee ne | RB | RB | Kec — BRREOEA RE WHOA RA ROK RE TT DAE ER ER BRET BEM ea GRE ew He He PROSE AA) TT AL ABB SE eID A, RE DU HUE AE AT AS PE RE K) MAR-RERMNA ARPA TAMARA. Hitt RI ARS YE MRD OR EES ea ET OH, FT SPE BeBae OR Sarat 1 Rem A POE A UE HY LR OLR PR pH BROS Ha A FERS AF Hi RA BOM TG ARE EH. 2 ORE Fe AB DOERR ESE e RMR SRA TK. WeA- BA LABOR K IR HCD RRR URH LIN NaOH). ERELE Bg A 1 A BH SE HAS HB OW) HL AR TAS A PA eB AEA V) AU DH CATE RAT A — A BTS pH HARES Ah ABR RHA oe RP TAG SP LP MH Ew, LT A SS AR RRR CE TM HS (D BR DEER) RM BREA PILE CS mL HS BRE UO PAGE RAAEMBAR AD H! +0H =H,0 BX 0.1000mol*L” "NaOH JB HSE 20.00mL 0.1000 aol» L~' FIC! $5988 fl BEE AE HARTER pHME. aE FRO wT AOR pH RT HC) A PRIS. (7 )=¢CHCl) =0. 1000 mol LL“! ,pH= 1.00 bE SRA PSA HCL Re ee HAY NaCl 2H RA pH SRR FH CLAVE, UL co. Vo WARMER HCI ARMA AURA, cv BE DEEP AHEM NaOH Ye ASB WC ARIE PRT cH") = cbse Hol ) = eV Vit¥ HAT TR— RAR Me “hp A NeOH 3 10.00mL, 0.00mL Af RE PA 50% (HCL BEE ME that +) 0.1000 20, 1000 10.00 _ 4a). pe e(H7 = 30.00 10.00 9.03333 (mol-L~*), pH=1.48 HLA NuOH % 19.98mL, V=19.98mL Af ASAP AT 99.9% AY HC) BOR BE +0, 1000 x 20.00-0. 1000 % 19.98 _ SCmol*L-! = eC b= 20.007 19.98 5.000% 10" *(mol*L7'), pH= 4,30 cAI RAE MMA 20. 00mLNsOH HEL, MOR TE JF 5c FF REL BY NaCl, Stat pH= 7.00. d4CHTTEAUR SHH NaCl AISLE NaOH AAR, HERRON pH RR Pat #EEY NaOH AY OH MPR BEATE PATH: eV -ca¥y (OH) ~ ¢GtSt NaOH ) =~ vt eS de - OMS Sa Bat BAe Re at RIP ARIStR ith AAA. to: 4A NeOH ¥ 20.02mL, V =20.02mL af ,NeOH HE 0.02mL, BH 0.1% —) 0.1000 « 20.02 - 0. 1000 x 20.00 _ - ot ye (OH) = 30-07 26 02 =5.000% 10" mols“! pH=9.70 FLSA Bit Ae PRY pH RAT 23, WR SAE NaOH FEAR Sy BR AER pL (ELA Be 4 yA ba el, BEE BA 2.2, HLF 0,1000mal-1. ‘NaOH BABE 20.00ml. 0.1000 moi-L- HC) ABN pH AE A NaOH | BR HA | SH NOH viet) | RRM | Cvemty (Vfl) ra t 0.00 6.000 20.00 11.00 18.00 oo | 2.00 | 2.28 19.80 990 | 0.20 2.30 19.96 | 0.998 0.08 4.00 19.98 | 0.999 0.02 4.36 | 2.00 1.000 9.00 7-O0 AR) ) RBH 20.02 1.001 ao | 9.70 20.08 1.002 | 0.04 10.00 20.20 1.010 0.20 10.70 22.00 1.108 2.00 11.70 40.00 2.000 20.00 | 12.52 iy 32 2-3: AUPE 2-2 wf LIAR SE AP A AE APES 99.9% EA NeOH (BUR 19.98enL, BARAT pH (ASUS 3.3 TB, TRE am A BUTE APR 99. 9% 2B LOO. 190 HEL Fh 7 0. Oden (5 1) PERE AS pH (Eth 4.30 262% 9.7038 Bi TJ 5.40 P pH AAD RRR RHE ET AY AL pH FEE BE AR Ae A pET SEB (RVR RUA SE SER CEA ST SRE TF Mi 99.9% 3 100, 1 We TBF ACU AIM, PARR RAIN pH SoM SERS Re AL, CRS RE ER). AOR IE GR pH BAe PRAISE Sie AUR , 175 O. 1O00mol- LHC! RHEL 20.00mE, 0. 1000 mol “Lo NsOH HE 3838 ERIE pH 9.704. 30, CMELEY PMOBERE VARA RATAR REST ASRART RAH. BEE NTO BUR HARE i SUBREED REHA HE Se LY Ah , PE EL B OO LA PAN RR AL LEE HEB COE AL aL AR cP AS AT ee GR FA PES FH a MT FT, A HH AlBae 2h So ee 4 1 mol-L* 0.1 mol-L? a 0.01 mol L” 10 — ore 8 —_ “6 van 4 eae 2 0 o 0 20300 ow 2 30 40 (NAOH Yel. (NaOH. [212-2 @,1000mol+L.~!NaOH Hiatt B23 PME NOWRA 0.1000 rol LT HCD 5585 ah 8 AR TBD PACE ICU a A EE EERERNRED WERRGCMNA) SRAARNREAR, RAKES AK RRGARK RZ RCE RD 2-3 Ba). SRB EK 1015 SE FSUGAB SP MY pH EAL HE LSB It 2 4 pH Meth, ALAM, FA Lmol+ Lo! NaOH 3 Ba L mol+L” "HCL S005 , SR SE HD pH3. 3 ~~ 10.7549 0. Ol triol* L NaOH FF HR HE. 0.01 mol L” "HCL HER, ABA ih A PHS.3~8.7. (2) RAR SOE — TER) -AEREKRRPRAABT SG. BRB E-TARNB* RN OH” +HA—H,0+A Pt , 598 WES BRAY EAT Ml, EO. 1000mol - L! NaOH #5 HR HAUSE 20. 00mt. 0.1000 mol-L”'HAc HH Hl, MARS AREF a EFRERAAA PERERA TE. BH WEA AT RRR Hepa eS APR EY — TORR AH pH EA ROE AAA HD PG NaOH ERR AWAD A MEE Ac oe RI HAc SA RSE MPN RK EAL aD A RE NH PE LS EN pH EL SRIF ae 4 SE eR 2 Be . HOS SCH MSE Ceo OtFa So A -B O BS AR BETH At #24 10, 1000mol-L” NaOH HAE 20.00mL. 0.1000 mol-L”HAc SRA pH EW ANA WR RC! HH NeOn | cvs | ERR | vemiy | vs) oH 6.00 0.000 20.00, 2.87 10.00 0.300 10.90 44 18.00 0.990 2.00 370 19.80 0.998 0.20 6.74 19.98 0.999 0.02 7.74 20.00 1.000 0.00 8 rasta) RH 20.02 1.001 1 0.02 | 9.70 20.20 1.010 0.20 10.70 22.00 1.160 2.00 1.70 20.00 2.000 i 20,00, 12.52 HK 24 AB 2-4 TLL 0. 1000mol+L7! NaOH 3 HH 0. 1000 mol-1.~ 'HAc #3 HLT, WE RBH pH7.74~9.70, SRR ARB A EER EK TANS A 3 TP pH AGL b. Ha, APSE ASN TD EERE FU RRERARAR EA FE EWO 2 a HA, SUA OK a FA A a ARMA c. WERUK ATEN ARON. FB 2-4 o 10 FBO, molt L7'NeOH FE AUB HE 0.1 mole Le PORE UO RAE REPRISE 24 FPO Lined LOH RR A TE We a PO ee O. Lmol- Le AE MOS HR BE. BM ERK WE EAR FORK HAc Rite EIR PK AK, EK, Ky ERS LR), RRB K. 25S BM Ye LAL I HH RK PEALE 300 20 F (NaOH) cK 210" ie SR EIR OLA pH ECA AP ATE MAE 0. 1000mol« L” HCL BE RBH 0.1000 mol- L”'NH5* HO PE PR, WERE UR EEL pH6. 25+4. 30, BRADY SEE EGTA),

Vac Sa APT HE IRA Hh NaHCO; 5 Na,CO; a EY NaHOO, NagCOy NaCl, | atv.) NaCl H;CO, Nalco, [##*| (co,+H,0) ik CEERES KASnee St) NaHCO, # NayCO; EAA HA (HCl) + (V2 ~ Vy) M(NaHCO,) we(NaHCO, ) = m ¥ 1000 w(NagC,) = HOD Vie Me oe MiNez60s) SR RLOS HERR ATLA. VV < Vo, SIR — Rk SEA RAD NoOH 4 NaHCO; FIER, AAA RR AVL NR DA TARR AE APE. BEL BS RUE RA LTBae ER BESTE FAT ABE WADE HEA) HF FT A RE 9 Pe ED AE] BA NaOH, NayCO; NaHCO; REA) S ARSE A Bt Ss HCL EER Vim, RE SH RBS AN CAS HC) ER Vol WR AROS VV, ORR R25. B25 Viiv, BAD SAM RAMS VoV, MER) Vi>v>o | o0,¥,=0] ¥,=0, 4,0 NaOH #1 [ Nali6o, # Na al BPE ROAD NaCO, | Nm, 42005 NaOH NaHCO; EARP, V,=21.64mL, V2 =2.68mL, ¥,> Vo, itt NaOH Hl Na,CO; AR AREA w( NaH) = HCD = V2}+M(NaOH) _ 0.1017 x (21, 64 - 2.68) x 40.00 7a 1000 0.2000 1000 =0.3856 _ eCHICD)+ Vp" M(NagCOs) _ 0.101722, 68 * 108.0 w(Na005) = m * 1000 ="9.2000%x 1900 7-445 (612-7] FO. 01010 mol L“'EDTA 828 EK AR HD 100.OmLK HF EA T deal HE pH= 10 MZ, WH EDTA 28.30mL, BR— #8100. OmL KA, Jn) NaOH (3 HAS BE HE, Me”? 8981699 Me(OH)2 ULE, APE ARIS TAPE EDTA 20.20 mL. HSE: (1) AUS BEBE CEL CaCO, mg LAB) 5 (2) 2 a 85 AER A AP RCP BILL CaCO mgs LA MgO; mg*L EAR) © (8) AERP RAREST EDTA SMEAR (Sh HZ ROL, LBA MOREE ROWR BWIA Nat, Y-2H,0). EDTA RANA HERE Se AEBS BPA 11 ARE RAL. FAL EDTA fh Ai ae a we AT RAH Mt + =Myr-* a a(CaCOs) = 2 (C2* )= n (EDTA) n(MgCO,) = n(Mg** ) = n(EDTA) HUE oh — (RAE Tok A BEL CaCO, HAA chC900,) = OAD 28 HO 1O0.T 956mg Lt) CELE aT Me?* 2 ABHEAL A Mg(OH), GLBE ALIN 6 A AE 7k Hh BG m0 oP HEL CaCO, FH RESO ECS BotFESSOR HS Ow Bae Bh SESE ch CaCO, Spe) = 001010: 01010 x 20. 20 x 100.1 D090 7 204. 2¢mg-L-') FCS AE AY EL, MgCO, eam e(MigCo, $e =" 01010 28-3020. 20) 84.38 a 68 o7(mngel 8) (Bl 2-8) RR AEA RET A. A RP EE BOB MEH: Sr PE Br, BESKRE De SAA Eh ER a AY Br, ARGH Add Bi) KI, FH CCl, BE ALAS 1, GREER F= 100%), BA AAG AB BUR Fe) ASRS L, ERR PK AB CULNNIL | 21 —=41 +N, + 4H"), BAS Br HL. RERR Br AM ANS KI RR, BEATER a A, FA NaoS,O; RHEE HORE WAR. C1) ab BB ea (2) AAR FE IEEE TD Rb RL RAR AE JUEBAK NaS,0;) SF BKB? (3) INE OY EH EME KI ATER 25. OOmL, RAT FEE 0. 1000mol-L™' Na;$,O; 20.06mL, it Bit? KI AE (e- Lo!) MKD = 166, (4) SHARE PARA EBA EE, BIH 0. 1000mol-L~ AgNO, (EH AEH BRET HEHE HPL ALR OT a a PL) (5) FEC3) BUCA) RE ET RT a, PR oe SS HE Ek BH MRAM ED? EUG INEE ERA ee BT PSX (1998 2 FA 5e FERED UE) A KR AY KI A A TS RE AT PAR. (D3Br, +1 +6OH S10, + 6Br” + 34,0 Oy +51 +6H"—31; + 3HZ0 HNNH, +21, 41° +N, + 4H* L+25,077--21 +$,0,77 (217 ~ 103 3h er see ~ 18h, —36NaySOs Sa | Me Imol 1 HK 3omolNa SOs, 44 FRA 36 fie “e(NiyS,05)° V(Neg8203)* MCRD (exp = EDBae AK SETHE 3% 0.1000 » 20.06% 166.0 =a 0.370084) (4)36-¢(ABNOs)* V(AgNOs) = 6(NayS,0s)- V(NayS.05) _ c(NaS:05)+ VUNa:5:05) _ 0.1000. 20.06 VCAgNOs) = 36cCAgNOs) = "36x. 1000, ~ 0: 56(mL) (S) AA PH F HEHE Bl + 0. OlmL, BCA IK $8 Mie EY tO. O2mL, EAD (3) C4 YP BY A FE RB A Ae pH RE, =E 100% = ee 40:82 5 100% = £3.6% URE ACA SU OL LA FE BE RD MRE A HE. (812-9) ak PAE PE DM AE. TRY A 2 PERL ( CODD) AR FE OK BT Se BB — SH in EE 100% = 40.1% RE,=E x 100% = ‘14 7F JEP BEA CU) Kvn, JK CxO, ) EI AG A OF | BORLA (SSN Mh SD EA FH x0, FAR ALIA mee"). KMnO, Be aE ¢ COD G77 #58 RK 100.OmL ACRE, 2 HySO, BRACE, MLA 10. 00m, 0.002000 mol L* ¥ fy KMnO, RIESE AR UPR BL OL ESS HA 10.00 mL 0.005000 mol-L~! NasC,0, 3/3 | WW FSP 3. som. FIRS OEEY KVin0, ARM MERE RET CRE) hse | HE ACHE co, GE: ELC A ARTE EHEADE C ERLICH CO) x (8) ERED HAM -AARGSHBE RMT bel n(C)= n(O}) | (1) CO rk HR IBHEBI BE) + O, CO; (2) 4MnQ,> + 5CUK PS IREY RL) + 12H" =4Mn?* + 5CO; + 6H,0 a(C) =3m(Mn05} (3) 2MnO,~ +5C,0,2> + 16H*—2Mn?* + 10CO; + SHO | na(Mn0,)=$n(COF) BRL n(O,)= n6C) =F ay(MnO) = SEG MaO)~ mg(MoO )] | = Sn (ak Moy) Su(C2027 91FS SO EB Bae eR ab ae = Pl e(R Mod, 1-21 08 GOP”) — Sn GE MnO," 1; 10.2000 10,00~ £40. oosooa x 10.06~ $0, 2000 3,509) 10°> = 8.75% 10 (mol) _ 79, noMo, _g.15x10-*x 32.00x 1000 4 PVE Vy 0.1000 =2,800(mg* 1°") [852-10] RARER SAME KT PRA. HRI 0. 3162g, ATE JUS GFA SoC, Heat Pe?! C2 BIRR Fe" FELL 0.02028 mol-L-'K,Cr,0, AE PRNREDPD E.R ATE a Be EMC OY FE KC, ARE A21 dom, HRRE PAGE. DHL Fe Ml FeO; RR. [4] WeteAXRMATEKAMT: (1) WR Pet 2H = Pe +, Fe; + 6H*=2Fe?* + 3H,0 Qype pa YB CyOP7 +6 Feet + 14H —2CP* + 6FeS* + THO n(Fe) = (Fe?) =6n{ CO?) n(Fej0,)= Fn (FP*)=3n(Cr,0; ) Seco; Vero) Mee _ 6x 0.02028 21.46% 55.85 we lFe) = 1000 0.3162 1000 2 4612 Bec, OF Vo, a My, 0, tenes Vox! Mio, 330.0208 «21.46%159.7 w(Fe0s) = 000 0.3162 x 1000 =0, 6594 FLT ASAT PH REA BRT — REF EHR AND DESPRE HF Ab BPA Re ty A Se BN A I HARS, PHRANERWEE HRA REINS HREREMMMREOK, 1, RRR ZRRERESTLET RFRA RCN ARERA RA. RARE Fg A BE BOE Fh BT RH se PU ER A EH MM SHRM EP CSRR AM,Bae eR Ea et REREWKAER AL TILA: OARS PERERG TAKARA. BY RT TA HRA SLATE ARR, QLBRE RSRELHTRAASAOAAMARWES, AERO BARRO RRAS. (3) ih SAYRE a FT EF AD AR ASH TR HB, MRAARRAP ARNO TATE, (A)PAEE TARE RBS MRE Bh TOA EIR RE © Ata, A RB, RE A PS Ek I AA SA IR SRRZT BANARAS SARE VERE GRRE STEM. SUGAR ep GA” HFS a a SP TR CREMITARSH RAHM ANT RG TERRA APTA“ A AR CBA EA BI SE op AL AR Ee FER Ws AP a A ERE SP BTR RS A MEER. 2 ABLE (BLE SPRAIN RHEE AE SE A A) AP) RH = FRSA EU RE 22 UP aes A EA MOTE ERT AAT AAS AU — RAR ES FOR th FA SE RG A A A) EA ASE HE SHALLY MAEM TE RRA, BERLE RC ae FER URC A RD RELI FE 0 = RRR RE LRES REE PRARMCRLAEO TERS AT AORE RE, SBR SARAS Hats) WAP RAE EL. NE IR RE EAS ALMZWMEA, REM HAREM RE Hem KN OT RE (E) = WE 2) RCo) (2-21) anatine (ee) - © x 100% (2-22) AUREARAMRRERTAE ENA. Aan PET FE AL DOR SPB 2. 1750g A 0. 2175, (RE BS (HA 2.1751g A 0.21 76g, RS ES ATR BHP Bl 0 Re CRE SORUSS OR ES ot ee oe £ = 2.1750 - 2.1751 = ~ 0.0001g £,=9.2175 — 0.2176 = — 0.01, PTR BL RE, = 52-001 & 100% = - 0.005% = 9.0001 =- RE,= 0.2176 * 100% = — 0.05% HAL aT OL XTRA MRE ANSE. RE PR SVERE AATRER. AL AAA RERRTRM EAR Ow ae, RHR MAL RIEAA E.R DR RL om AR Mi 2. i 2 AS IE ELM LEP, AMARA Ft RATS FTW BAS (pid se RAE SCRE, LUE HP RS MSR FR BE LIL UF AB 2 RR ALAA I A A A ET BERTH. MERE SAKWERR SSRN EERO R POZA. JL Ae PFGE PRB RES A UR SE A AA LE (1) 8 A A 2 A BE Cc) HL A A HE A 2 (Rd) BRE bP ARUN ARPES DORI MEN oy 2, IRATE GL eodoyt teens tds (2-23) MO CANA A da BR dj=2,—2(F=1,20) (2.24) HAN Rd, Ra, = $< 100% (2-25) (2) 57 SSA EARL EA «ESB PEP BAS SE Ba (Red de Te SP RFE ED AT SBE EES YA 2 i FR 1 VEY Ze Ee ERE. SR SidgiebD inna (2-26) a a Rd = 100% (2-27) [eh 2-11) shor A AE Aa HE He OY BD HAAR (% ) 35.18. 34.92, 35.36,eae Se sho TER 35.14,35.19. HAR AE PAE RE a 35.18 + 34.92 + 35.364 35. UR) x= 19. 36+ 35: 11+ 35.19 35 15¢q ) 5 SU a AS AT OR ESP 4, =0.03,d,= -0.23,d3=0.21,d,= —0.04,d5=0.04 » 1 . \. . 5 _ LY jg, j= POS =O.29 20.214 0.08 20.08 _ 9 1445) 5a _ OL _ RA = © 100% = 575% 100% = 0.31% BEAL AE ETA RE EAM SS oe SE AGAT. BHLAADER ROCA. BEES HARA MS, LRH L EER. LL RRR IA ERAS 2 ARR LABRET (ORS ARS AR Pe BS 8 ES LT A — HERE SUA (UREA FEN TLR AL HE BD A AR BIG AR BILGE RCS AL BN ae DH A TRU SE A AT OF AE £0,000, SREB RW 0.2100g, ERT 0.210 RBM RIG 10 BA SH THEA EA-BMMRE MRSA B 0.2100+0.0001g RA AMR—H. AWA 0.210g ak 0. 21000g, FM MS HAT RP ME BA SEO RA AAMMS BSCE. MRR CAE RACE HBAs ECL RT oO PSE AP HK 22. 00m LB PO" ERS WAR ARAS, MRA RAG al 0.022001 KA AMO h OM RE ABA BRE TOG TOD Be BORE OY OR BAN HLA (ARE BRE SE RBA ERA Ae. BLN 25. Omgitt SAVE pose WAAL WE 2.50% 104g, DAES MM 250002. 2 ROE 132 FA SAE HMO SHE LT A BB -F Y ABBA TB AS , P r BEAI — EMM DE TISH LYRE 2 ee a FAT BS KR, WAS ORAMM AMASR IC MEA AL Re Ad aE: FEM IAEA EK = StS AE “0” 5 A A OH SRE RA LH 5 AE EAH Bk Me UAC Sa AY aR a BE Ace SAVRO SCAG GX — AI ETF Bam (6 289 WA BOR RS PUES OR RECS BoPOS oR kee Bat Ea AR BETTE 0, 52664 0.5266 0.36266, 0.3627 10.2350 10.24 250,650 250.6 18.0852 18.09 (2) RE 3 LIN NR BBL HR SY FBR LA A SAE Pe 2 2K CH BIR IO) BO TR fi GH 50.144.4540.5812=7 HEUER) RE RIE — RAAT +1 RE TEP 50.1 TR K(40.) DRESS MAREE ART RARARE WARE TU SBR PHARMA REA SU.14 1.45 +0.9812= 50.14 1,.440.6=52.1 (3) RRR EAE HE ALIN AR A Be a a et ARCH 9 GN FRA PRM TR ERA — PROG BU TE RA RR a OR TB SR ATR SS SH. IAM 22.1879 x 0.154 x 60.06 =2, 19 x0. 154 x 60.1=20.3 ARAM RED HN “a 100% = +0.005% +t at +x 100% 0.6% + ag * 100% = +0,02% EARRFORE MARAE Y BURKE ROP LA: D EERIE, SHS a BM tO K.CrO, 3D Fe"! Bh 156 IG ETA n (KoCrOr) =n (Be”! ) 65 XB 1000 45 ae BIA EH XA AS FOR) BR RS EBS D FRR R SE MEAT RSF 8, UG CE 0 EB OL BH A 8. 68 ER RAL AM BEB RRS o © WRAL pH pK, PHAR AAT AEA AR ae FASE I, Fe SD PRRRBMEMNA/). GIN pH 11.208 AMS BR A RAAT] Zen H cCH )=6.3% 10° Pmol-L. @ EHAMEP MRE TH AL at eR — BOR PAAR UR ERNE, RO eT RAST BSE eRe HA Ra RB ASBae A Rea 3. ERATE AREAS BME MAA ATRMEAWA AR PLE RAE TE CREO MTR, BA RULEHCADRER LER TRAK) MM OLR T WEE, Fa, Say AE RLS iC 25. 00mL Fi 25. OmL, BARRA KN AR AS 0G MAK RA READ RES TR MRA RA ee HBL AY PALM, EGA He FR Pa iH TH a a aE 7 RE ROO A TR ee RES — A a A B80 BB OE RAR EEO 2-6 BT. R26 PALER E i om EB BMBF CRA wee +0.01mL 25.01mL, BAT +0.01mL, 25.00mL, Fa £0.01mL, 50.00mL, 10,50 100mL a Bt £0..mL 25.UmL, PZ WIRE =0.0001g 28.1093g HERR ERRNO. le) 20.le 28d aa —. BRR 1, PED HY TATA cCmolL8) APES plac 2) USERRA CO) 1000 _ 10002 yee! A Toupp= oe" he 3 Tpp9— 98.91" Ke = 1000p ke 10006 rately”! © gag = 9a-" Ee D-Taotip+ Re ke 2. Lk OR AO, Lind oF FU AR RE Co) ALN! B-AL(SO.)5 ©. Na,COs D. NHC 3B. BEEZ, TNR AA EA BE YB 9 230K A «3 AL28:3.73 B.A. 15!2.63 C.1.2451.00 D.5.18:3.78 4. FU K.CQ) BME SURALAL 0.01667 mol L” FH LL. F AUS HE RR ASE co) ATESHE SE LAR 4,903 32 K.CrOs MEW RT HAT BT 100m. AREAS AA TL 68 SRC LATE ER 90cm. XK EST. BASHIR EAGER 4.903 3 K,Ce,Oy EMEA E SEAT fib 100i. 2 AEE , HR HES HERE A LL RO SABA, PET SB ok Mee AS 2 ~ 3 SE A SR dk REA AD We See MESA Otats Se Ee Bae BR SoHE C. BGR LEG 4.9 6 K.CrO, SMB EF Be ARE im L00mL 7k PME IE FY Se BE 8B ae ALL BOSAL, PEA Kd ea ABO AE 2 ~ 3 OA SAE 65). DES RE EARS. 9 HE KOO, BAD MAP RAE AT W0mL ok AE AA LL A WP AB ER Omi HEA. S. tiie NaOH A998 FE EES C3 AFTRA = BABROP RA C. D.€aC0; 6. FAS MGR — TGS RR FSA PP A A Coy AEE. BR Cm Dae 7. FAREMEGTE Ne,CO, Pra HCL ARI 2 NayCO, ABS BOK AS co} AL ii BARE CARH D.A-# 8. PRATT TRS « ) ARP MAES BAL Se A CTA SN FR — PE DTA YB NaoCOs FE He ARE Aa AE IC ER PR BU ERD AAR RR AR EB {3 ALTE ST RU BTR ARS CRT TERE DBAs 10, ELS Ree BOR CD (>) A.Ca0% = 25.30 BCH" ] =0.0235mal/L, Cpls 4.462 D.0.0001 =. 1. (0OmLNaC] 10 AAT 1205 EH PAB SL 7eNAC] BCE: CUNACY 5258 BE 5 (YEE AT Ip NeCL ORR AP 53) FAP Ne CL 80 Aw EE (4 NaC] AYLI AR ARTE (5) RCH Fe NoC! BONER DRE. 2, MT BF LAKE — 3.007 RH EBIK, 2E 100n APARNA BBC CyHs0, 9 PH? 3, SERINE A UE BAR) APRN AT, = 0. 56K CK) = 186K keg mol |) SRT A HE a WIE 310K BB RTE 4, Be Gaia LALA ACTH 0, 4000 0.0660 0, 5333, FM AM], 18. 00g RL AD PSF 1.000kg AP BRATEA EIET 0. 0S10K BRR ABD CR RR QDMA AF ROT Tx. 5. AREA KZ LR K 09.6. ATR TEMCIE 29 0. 150mol- LAS CER 50. Om, FER FOF (1950. OmL ARB (2G 25. Oro. RAK «(3H AK 10. Oral. RAK RU BGA A EB HEA HH 6. ME NaOH AGRE SER IBF.) mols”! NAOH FREER 20~30mL. fl;Bae BR SET RL CRE PRI BF EY BE RICH, ) 2 57 (200 FR SFE EH) C,0, 2,0) fe SE, ARGS (DEA HAF ORME W 20.00022, HAUL AM RA RS (A ARC ft ly 7. AFP (A (Riedabl encthod NEA AS Rt. AOE AE 1. 6582 AR EH A SE RA NH; 3 UL 25.00mL,0.2018mol - LFS HCL Rae ERB, AB) IC] LL 0, 1600mol-L~ NaOH SPHERES ds NoOH ERO. mL. HEAR RARE ORR. 8. AAR 100g TALE AR TIS A EAE SCARAB. Matth NoOH Mhe HHA) NH, MAK -F 50-00mL 0. 2000met+ L” "HCI ER MET AE *P Sab HCL An HEFCE HE 20.80mL 0. 2000mol- L”' No OH REFS HIE 6 BRR AH HE ARMORED UER N AE BH 6.25 BRAK REM). 9, ETB SE a RR, BOR Ch AOE PE AREA. ALAA Re AR Ue i FS ER RAE 1152, AE Sie sk RE) EL A RE AC ASE KL, PSR ARAL PRL 8. 1000mol “1,” 1NayS:03 BRHE SOW RAT a A LPR FES MERE R 20 02mL. COS aS RAE eRe. CORN ARP ARES RAK, £ 10, ER ARS MAE 0.30002 DUARTE MA 8 ESM RGD: CO STE on PS FERPA S ULIE WR DEPRES TPE LTE TAR | MA 25. 00a. 0. 02000rme1- LOUK BrO,-K Be SMES IE AT RAE AR SRO MBE LE Ay RE ry KT EAP LABEL 2 ALY AE 0, 1000mol~ Lo! NeyS.Oy EAR ERIE 10.8001. $FSE RA SE RY Be Bt aaa Bt, LRRD 9.001. RUKABSEA) £001. JIC 29 00mL. HER IM ASEM REAE pH= 10.8 FV 0.01000mol*L“'EDTA 3022 HAE 23.25mL.. FAK 25.00mo]. HR AT ACNE), CoO, fh Ca” FRE CaCO, OLE FAN, RLU, TERR. FEM Ca, TLE RL, AL EGR EDTA WRG PF 8.98mi. HALA S001 RAE Mg?* SHER A 1S~300mg.Cel! ARENT 50~ 400mg. (5K HF RPE RES TES EM? 12.0, BBE GB BME RUE AS eS eH OL TS V €RRN: 0; +21" +H,O-——O, 1 + 20H7 4 25a. mols L- KLM AEA .00L Os BYR CHL FEST abe STH 30min HAZ Fide RSI PEE BE EAI BI Om Amol LHS, #8 1E0-05044mol- Lt NeyS:Oy ARES RIDE ALHY 1p, RATE 29. 33mL 6 CLIK RBIE SS Oy RTA A IMT 4 te? SME Se MSOS Sa ee Bae 28 BER (2) FETE L.OOL 24" Oy AY BURE. DEA ASM ETRE MAD tA? 13. KIO, fRSEMEAY CAE RE No,SO, BAR. ARAL O. 2001eKIO, SALA KT (Eth AR NapS20s TR HERB E , VA E49 738 5d AER BL TDA: NenSyO, RAE 27.B8OmL., Litt NapSiO, HE HEE Ar GL? BE Ne:S,0, PRAT SS 3M? . 1, ARORA RADA FE (PD.O,) 0. 1000g, ARSE REAR ZERAAT BD 0. 02male L*K:CegOy ERE Seal AH PLOW, aE: 2Pb?! + Cr0,2> + HxO—2PbCr0, + + 2H" OAD LAR A PLCO, DUBE ARARIEEA Do A KL TBE, ULDE AD 48 ALJ 0.1000 eacl+L“! NepS0, FECHA 120ml, RALAEP Pb;O, 19 4 SC PLO, HED FEE 685.6) 5 15, FUSS FEM A AE 2A IR APY mol +L ")0. 2041 0. 2049,0, 20390. 2083, AR EE OEE FIER NEE JaISR —. eR LA2BRCABSBECTA BEC OD MA —. ipa 1, (1) $B 100g HO 4 35-9gNaCl; (2) 0.2645 (9) 5.42 mals (4) 6.14 molt kg” 445) 1.099 2. 14.8g 3. T76KPa 4. (1) CH;Os (2) 180; (3) GMOs 5. (130.0141 mol +L7!,90.6% 3 (2) 0.00446 mol 1", 97. L% 33) 7.07 10°# mol -L~',99,5% 6. (1) 0.4 ~0.61(2) 0.1 ~0. 25 (3) £(0.03~0.03)% 0.2~ 0.19% 5 (4) UR AREER ORS ER DP RA HRERAAMPOMNRE EAMES AERAGR EDM, 7. 0.03026 8.0.5114 9, (UICoCCIO), MI CoC s230-06161 10.1.430% 1 PERM 12. KA SLB 2) 35 Stengs (3 JEM AO HMA BSE A Sy 13. (1) 0.2018 moi+L7's(2) 0.02561g 14. 91.45% 15. 0. 204350.0003;0. 15%Ble Rte REAM $=R RFRHSTZARE PRE ARAMA. RELESEABAMES— ERRFRH REAMAMRAAPRAAD DL. BSP AT ANA RS BOT OD AREMMEST I ROSE WORRY RAMEE MS oh Tis aR MOT ASR TIA OE FO PRS FE ER BOF FM OE TESS RAMA KA TANKS RAER ORS 96S ROE A OA A a EE Bi POPP Rs — RFRA SEM ERD 1908 EW SEA ch EF AEB OE a GE BO hy ET AR HEP A KA DTRE MEM LARDE. RRR MR RAR E = me? IR me == ar ee Segeny Mey FOR AMR BH 6 = 6.626% 10 M]+s,d WHER KTR THF AE THe SRR ABKT « 1924 PEM PMERE AD BLK HERR BM KIRA a SRC VAT Lk ER OO BR PES HA RESRURARSH DE MRA DIRT FRRRA: hah eae AP nm BHENAS, 1 SAF OEE, LOAN ALES WORRY AEF RB. pe me Se Se Oe aS ce OOSS SO AE eB Ot Bae APR ERE A FAHEY RA REF SORA BIE. 2S a aR AT MRA LREHRFRIVSASH RAR LES X RRA GRAS, Wh HARA fic Bt FT Oe A ah RT A LAB RARE T a HUE AFA EI OTE T a PERAK AE ME. Ho FEF 1939 EA AE YL PORE 1927 FES NE HRS AR BSE a BL ASE Ry eB FER, EA Ol ea Re Ar Apeh Fb Ar WNBA AMR, Ap HAE NAHE, Ap = me dv dv WEEN AER A We eK. ARERR A AMARA RABE HBEAAR, CHAT EM RMA BAT AT te ATF RF PML HT AT TR ER RHE OUT AAT RE Pe VOR SAE EOF PUA SELPRUE LE RSET AY BE AR [13-1] (TET A FAT EE Or Ad; (2M 1 «10 3g Bee at Ee 1 x 10s BS RE AE Aa bom, RAGE BE Av. (SR) CLR FAA eh 107 A a, a BB SB) Ar =10° in, MW FRE m = 9% 107 kg, HE Ar-Ap=h 4 a soe ge ppg 71m) AGE PRIME SAAT TWA Tk AE 10 — 10? ms FE RE SKRTRARE UK. (2) FRR FER HER Ae = 103m, BRAT HME BEE don ph = SSI 2g 6x 10° 3(mes71) HRA PRE I A DS EFRARF AE LEER EAL TRS LA TESTER EAU fs RR. 1926 EA SEMEGNE BLT RT SL GARATHORN RA Be TR TR ANRERAA DES VANE NAAR RARE BEBe RSME REM ay 2 8282 Solace Vigo At y RRBK© RARE, V ASG BROT ORE: RERRE Ke. WRERAST ARES TENS POMS mE RV LRT RR PR HENWEE y ANERATAT HR RE. 2.0 Fe RF PEBVHROW oy BRA TSARAHMEE HEREWER 88S GBM nin MSA Sy 2 BB yn faye), TER BP eR E . . HIRACRRATSHRE HAMM RERSK nlm HRM AUE ERTAEPREEACRN LT EDREVERH HATH. () ESPEN DST SR MERE. n IE BH 1.2.3, AREY RFS n RE. e=- Bev KH FFB RAK BERRI, ER TRE SER-UTERAER. » GSR REE RSMAS: 1” 123 45 67 BAAS K L MN OP Q QQ) APM ARP EF OER HES PRTESERTRK BREINER, (01,2007 - Do M4 a= 1 BEL RAY OFM n= 2 UE WD OB AE RADE PSR UFO t o123 4 THES s pdt g A-SRTRORT AE AAR LOS A ROR TO ARE ROKR HEN ABLE = OCs BLE) s OS IE MARE, 2 = 1p HURL) PERSIE = 2d PISS. Mn =3 0. 0=061,2, ERS TALE RR Le 2a A 3s,3p.3d, RAAB = BFA AAT BLL 3s, 3p, 3d. 3) MRE mn BATH m REMFREASE RG. m= 0,21, 42, oy EE BRE on RUS LAM PAE ADF m le BY, m = O.FSLE s PRBS C= 1m = 1,0, 41, 82, ERE p WE HEP p Bikl-p, .py.p. SRAM XYZ St. BAAD 6 (IAS TRY ERE A EAE HP ae 8 AP DEAT IH eS BLT. 2 PAS Se Ee oTHSS So BoB Oe Bae RESO SR EMME =—2,-1,0, 41, +2, RMA RF RIE d NER ART 4 Hild. 42 Ald? RATA TA . FUPEBORAT d Hitl tLe For Litt. FT ERB S PARE I, BIB Hy BY OBA BET RO A BR Voz MSP BB nl on RE: = Cry zy mlm) HOR CBT LR A BE XYZ SMSF 93S I, ARV AE PE ERS FREED BOF th BUA Bnd Bom — SRE BE TAT EIN BEAR TAF LE PSHE TEAR AIR HF Al. (4) ABER FBC m,: eM FH om, Dee WF Be He 1), HA A 4> MD me, = + 2 BEI a eT HARA ARAL HAY de 3. FE ERAT BT, p Re bE ff MM TLL |? EE EE ORE) EMT IPED | gl RARE BOS Ta EE A PC EF LA REE, ILA A AE AT OL PURE as NLA A A AL AE BES AY JL EE A oh I LE HT Hm Ze pl? AER RAR BF AOI Ah Pa PMU Bea 3-1 SB a TUR SS OF 2B ATER. 1=0 BE AF ZAR MT Hy SWFA = 1 OE PE TL MIRIMEPHE BON p MF = 2B FARE ERE BOW d EZ. 3-1 MeaBEE RSME BI BoA — SRF RF ER 1, MAH RE AMPLE L RRR BT SOT RT PRT Oe eA 32. SER BER AIOE LAO TA FIG & He Ae A A A 32 PHU ME OLR AL SBF RFE URSA WF ILM: (C1) AE ADL 2 He DFE AO A AS RT fh, CHER A ERR — A ERAT SR AER HB ERK. RRR AEA A no + 0.70 Te A I, FERAL HR OY REAR ds 3d A 4p AY oe + 0.72 HAL 94.0, 4481 4.7, EAR HERE (2) ERE MC HAA) ARP 0 ARE PST REALMS, PUM By < Es, < Byg< Ego YARRA BR. PM By, < Bsg< Buys Ea < Eur< Esa< Boye 2. SRILA BT AEWTRE +. POF HLF Oa Dy LS Ee FSR aa SEO AE eSUSSF OR ea oe at ESR RFMOHRERME Fis HREM ETL RA TR A SO A BE DL 22-0. RP 2 SAME. ZR HREM, CRRA Ya] Fe 41 if 8 BRK i ER SR Sh, PRAT ek HA FR — A SB Sr A AL TBG | M/S RA TR RS A OEE EE SAL A 3 ARR SRRINS ABTA ATA, ATR Ree LT, fn 4s HF AE HA UE WN Fs ALD AE DS aE i WRF ARERR AR Ey, < Ego BEAT ARID AB i SF SU PE EN IS 2 Ts DAT A FRE EP NE HO Le Be EA RL wD LE DF AAT MC I = BOF ES TR (EB SUG IE IETF AN FF ST RE A RE IE (2) LA AD 1928 FRR PARDEE PROSE RACHA T RAKKA NT PRABMRERSM EMT. FER FRB RHEE 2 PF EAT A REI AZ (3) Bee LM (SE a Aa GB HE), 1925 AERPR ROR 0 ACE 0 AG HEH AA oa Is FY AA He SAH TAO Eh HST ABER TH BASU. TE AMAT SOMES Oe RAS EVRA ARERR AHL REN. AFI: pec “ i i PR: / ra i 4 & Bi piat CAR IPHL T EAT AY Be AH RE bP FH A BS = BE AS PROTA. BART BBE AOL RE AH A 6 UF APA 3-3 TAR 6 PYM CSP ABSA BE Ro aN F332 PRAMBS RF RE ME AT AF HEA) PH RRK Is 2s 2p & 1282p" fi] fe} (Tt Is 28 2p as hb AH oe a oT) AT OM, NPY FLA UTR EAR ER wD WANA EHR ES Ob Mme HE Sea. A Wu PH eh HR eR LL Ne] 3893p! RRR TRA TOM TE EA. SL wr [Ar]atsd! 28 ariast3el (ad Bee) » ERT arjas!3dl(a REE) oP Le 2829 3s%3p? wCu [Arlas3d ssl [Kr]5s°4d'°5p8 [83-2] Hee FU A HE a? RU RN? ()1s2s'3p! — (2)Isp? (3) 1s°28? (4) 18°28*2p "35'S! (S)1s'2s'2p? (6) 19°28? 2p 3p! (8) (BIR 2s HI AA 2 TT. 2B n= 1 BERRA p Hie (2a. (4)(5) (ODER RA. Soy RFWRF Sa AR AMR RRMCEER SRT SMES SHORTS MR, TRABREARE HOOP ION HUBER, ROR T IF FA A EA TO ME EE HA. — FFOBF REGS AMNAE FEMUR AF SME TRAV Swe TV he ER ERE AT BOA TARE TE. RRMA 1 PUR. M2 tet. RT 2A RBA BS BERRA 4 TE TL AE 8 Ta F MASH SARK HLA PY A RRE S A 9 HAE, AR FS PT RS 18 HSC R A A NR AE 16 TL FART SPH 32 OA TP RAE 32 BR SAN BG, A ARM A 26 IDR, REA. MIR A BO A Rn BD $86, 5¢.60,7d AE Sp WE SEA 25 THLE TCL 50 hE TELS A HE ce 50 ROSE See MRS BOSt SE ae Mahe oO Bt BSP MENTE ME PRA. RTR-RRAAA ls MiB HAR BE ns A, BI snp AR BONE FS 1 ANTS) 8 RM EL, ERLE TBD SOSH eS LBA ABR A ESS 0 RS 7G EH SUSE eR ATR . AAT + A = RF MBF RRASRMER FRA 18 A RMA TAPS RRA, HP ERIK AIR RSE BOP TK MRT ES A TBI De BRE); HAG MO AY I) AB RAO FHF 8910. Ta] — 7 A ae BA PRAM RRYBSE GU ENE R SRF HBF RRS TRNAS ATERELE RUM. RERARAAAE LORFS SY OER ARRANGE ETA RT. RUTH IAF AR a FA SE RENATAMOTE AHMAR CRA RETE. SRAR a rawnor: skier ns? PRLR ns np! (He BA9h) KBR (n= 1db Ps? Pd BSH) ds KG (n- Vd ast7? FARR (- 2) Bn - Dd? Pas? [013-3] AMALIE RNP PRO 25, FROCK AT A TAK RH BH HM KET RHA KR AU REDER AS. (WE) Feta stb[ Ar] ad%as* FHM Sd%4e? I I LB kd TR OUR Rbk Mano AUG TOR AE I A TE — RFFE TRO SATA ADB OAK. AMRF PATO HR EER KMART DAR. ARR RT EER TF mE ARIE wT Cs BBN Zp OA BUOY EE TS RE EEE HEE AMAR OTT ER, CR. ET RE MAGES 1) MIR TR = PR OTE EA 77 .67 #0 60pm.BSE RFSGHGREAME Rte TEBE PHSOATH ARTO RENE, SRS HEU XX FORA (SIE OE AI AI, SE A A WAR 2HSRER. PRELE MT RRS 2H ee FH A BT ROBERN. HALALERFEBRABESS. VF PELE EB Ee (1) I-A ERERALAGLE SM. ARK, BoE SRR. THAR TSS AR RMN, ERLE EH ES Zi, (2) I-A MARS AR OEMS a) RE ST CHC BAF AERP 10pm LRA HLA 4pm), REARS MK, BN FEE (ne — 1d BL AD dF ARS BE LE MAB, AMY ds KF EMM AK LET dO FG SN RE PRE FLSA, TOPE Bw A AR Te BE AES EE. (RRR SRF EI Fe PIE e — 2) BE. EE RE FAK A AL RE OER AE LE FMC Et FER BN MEK 2 FRE PR BAR (1) A-ERREMRTREALATEREMBA, PRA RBONS, OR HERTRBARER AMR (2) RUBRIC ANE EL FLARE A BL OR AALIE. BC Zr(145pm) A) HE(144pm) ,Nb(134pm) fl Te(134pm)Mo( 130pm) #0 W(130pm) FEA TE ESCA EARS EL RR IT MR EG MEA CR PE EAD AR =e mE REM RED) ATER ATR T REG FRB EE. SMEAMERR THERA RNS ESF Hi BA TE — tat . SEH F ERATE FN OTE OE BEAR AROSOMAME 1. RUA REA I Ly PRO AT VATA RACRE MA. SBOE I, Re) RRO ORTRBRABT, SRERR, ARGOADERRAT RT RAG RFEEU RAT ORF RRD. TE REY HS AE Ty EN A, 3-4 DE C1) FEF ATE Ke ATR fH SEITE A ELT OP) SoS — a ETT HS POSS ES oatROSE SE OR ASB Bt Bae RFS ME o fo 20 30 40 50 eo 70 go So ib0 emcee M34 RRB OEM BOSS — AL BORE EL Ae, FORAY Sh es FA 2p! BAK 1 A oF Mg 2s BER ae Ay TM BEER HE LY Os? SHI 2 1 Pos PERE Ue, DRE, LAD RTH 2p HAE > pW Fs 2p HARE, RE 282p REA DRAE IS pat. HATTER NE MERA PRA, EE KAR ENOA RAF HEY os np? RTE MEY AE Re 2) RAMA Re eR UA RS PATEK (3) RIE Ks — RR EP A TB). AMRPATAMMERRRS BRR) ALANA He HR HARB. BARRE MS RATES OT CRS MACS. PALMS FUSS — Ss = BEEK WW 496 4562 fH 6912K]~ mol” | HS — ABE HE UL BK RE. EAB RRA ALR 1 OS. BROS — BYR Pa AL HK He 7381451, 7733 AL 10540 kJ ero | SAL A fle HE Pc Be ER Fa BT” ARE ES + 2 PL Kes. ALEBTAKOH NEM BERR RHEOE REAR, 1962 FHS KBEMER ER ARG Xe ES — BAB CLIT. 5 kj -mol™') 43 0, 58 — 1 RE C1E75.7 kf emol VJLP AE AT PeCh, FT EA AAL O26 EO,” CP iCls] > AMER PCs BE WHEL Xe MALAVE A HD. MEG ARAY PiCle RUM Xe RA. ZERM F IM IR — FE Xe! (PeCh 7 6 RT AB — MA MAEHAKSW) BTRREA REHM RR, SBF RM FEI — TRAY ET BE) PF AS BE A ABCRAMWF RAB Y. LKB WF RAW EARRAN— FATE A FHRHMER, CAKE AKAD THRRAEE, ORS MLS ey Y, BELA ROCMMRT Rak tt STR, CRM BIMT RAE AAABa RSE QTRARAARES RENEE, FEARRARERARBA, R TR HAE AL FA WERE AS EAT A, OR A PEA EE FRARUTORIAX, LARAFLVAMET MAR ENA R. RU BF RARER T FRU IEA. BARR SOS ATT HF OY | I A Fe AEA ARR PMA EBABY MRR EM EAT SRNR, 55 AMATO WHF RAE AY eV ADA KES RRB. Be FIN Ah Sh >, BRS EMMA A Ra FH YX Be 2 2922p" NB 282p' HE p WI PSMA REA DAREMA T Ne UE 211A ce AY FSS TY, a SENT. JEP ALB A A BF A Le FL A (2.077) AG. ON)ABES SAW TM MEE PREG AA TERE RRR. Li Be B Cc N oO F Ne 0.618 = -0.5 0.277) 1.263) ~0.07 1.461 3.399) -1.2 FO EAD HB Ha tt ( X) 1 Bark fe PED FURS | OER TI BE A A SE. MUR 1932 A AUCH ERS. (HAL AB UT RETESET ARE A BE Ey Bt Ey AP SB: E, +E, rr ae ca) FA AWAD AB RRP RA FO RI TE X KR ER T BRE Re |Xa7 Xz] =0.102 YA SCHABAE(k| “mol ALAS se AULA SF Ne AE 4. OC RR 3.98) SET AACR AE. SOER—TEARARNE LES. MRT PE PRE RE RMB EAM FON MER FMA PROF RR Heb, wR AREY, MRS RNA LMT to (a) — AS EE OY Et eA BE SE EATER MAL Db EE TOR AE PE, TR A SAA LMSCME MAB BOR CAM RR RBI K ATE TK SLATE AAWLAEAM, EAMRP ALA HRS KANT MAE FH MEY PERI . HS, RAMESH AA FG Se SF OESFRO SE Oe MRE SB Ot Bae MTS R ERM BA HE, PAN Fel TE) AM Fo I) AY HY PEASY HWE 1.8 1.9, 2. EA CL) RTH NS ATES EE, ER BRM RE RAF 2.0, i BEA TT EAE 2, 0, PETAL e Se RE Sb PR A 7 BR HH REE LOE. (2) HH POREAD. ABNER FRASER K AB RNRE REA. SHUN PE REA ITHE 1.7 RENT THEA 50% SELL, WLR PAF MW AX PLL EMA ORES ES TEM, AFR. WR AX <7, RF SAB RN FN. SANSA HS RK AMS REE RS Raw. 1813-4] EKA MBAR X, ft Xp. A Na+ Xa= Nat Xue AMB PSHE (DRE QAP RCAXST. SHEA ME? CFB 23 HCHO HRA) [ie] (at THROMB X\=Xp= XM 2N= NPN 2. BAS Po FURY 5 EAE 2, CLT As ABA AL.Go EA ELL As MERLE BME RE OLA. (2) RYE F HBL XD Ny Bl Xy- Xpet.8 MXq+Xp= Xt Xe Xe=XAXy- Xa= Kel Xa—V) wr MS Nand 8 cS X}-3.8X,4 1-820 (X4-3.25 X4— 0.58) 20 mi X,50.55 FAH X23.25 BAH (4.0938 013.5) HUY F.Xp=1.33,B 0% Mp,Ses RT O,Xy=1.4,B YH Zr. Aik ARYA TR. (3) (i RHE oe AE Fic SORA oe HEE SL ASK 1) VAR TR Af E (13-5) CATR ANH PE 3.44,0—-0 AREER Eo. 9 = 142K)-mol! HATH 48 Xe—O SBME Ex. o= Shel -mol”! MITE Xe AU THEM (iF) SEARLE HE ook [X,- Xgl =0.102 JO BY UAE Xe Xe BARAE Ex. = 0, a B= Bunxe™ 143 2 Ego+ Ex xe -84- 2-13.(EER RPE ia X= Xq~ 0.102 13 =3.44-0.36=3.1 RAY LIER RE PE ORES RETAS ARABS ANAT KEAL, RMA A OLAS A, Ce AE ae i Ah CREAR AN. = 1 RE SR BP BB EBV, EAT GLA EL IRA se FcR AS AN OEY 2. <7 LOW ABARAT RISE KAS 990-Onon OB: SE BC 3. EPR FRA RK: (a) Rie Coe MALT (babies O.seV AEF. Ce) FHT 10°C ARE ATIEF, (AAD FRA n = 100 BEES Ce) Lis HR BE 18 2 0 VER CU BY 0. Ske) 0 4. UES FE Lx L0°'V ALE Fe REBE 0 = 5.9% 10 es URE FRA me = 9.1 10 kes 5. BEF PRW ER m = 10g, 2850 v= 1000 ms! LAE AP I AN MEKA 3h SIRF RA te AR ae EE = 104s) 6. FACE 0.01kg, BIE 100m) ABIRCE 10 Sg, BE Orns") A A BRE a AED (BEE 10° Pkg, BEAR Imes 2) PEGA 1000m- 57) 9F EE AY AA HABE HY 10% WME RE RAW ER MAR ARE AG SEY 7 RMA ERPS GF EMA EY 100V, BTSART OAL Oo HERE 10% ABR PDA SR AG aI A? 8. HA FARR FHA, He OO FM TN EHR 218s Agse2Pb 9. HEL RAF ROP TEAS NM PA FE AER sagFel™ gyGa? si Sb" 10, GRIM An =3,1= 2 GPE EA 6 DRT THE : (1) M RF A oe PPAR (2) MR ATR EE BD I AP EM TE (3) MP MEF BS EE HR 11. A WERE PM ong BISA + J, — hg RAT MF UE A Rte (sp Bd ERA HH BRS SF? Qa THERA FRESE FY a SEO NE CeMS ES oot BSR MEAN R MM (FER 8 AL 17 ATER FER A? (YB ATA DAE HAIR? 12. FEA RAR EH 112 S aki: (2) 112 S20R ABIL BIRR? 0} CRRREBE SR? (3) RUN CHR AE SP el LABS PT 13. BAR AG OF BA. CL) BARB G8 SO AR? 2) RF RAMBR—T Se Re FHLRAATERABD? G) B14 SRT RULA? BIL (Foe WE SM RAT 14, ERATE EE A ADB 123 OL, L RRR RAYE Be vB = 1, 2d Dim = TOLER SALE bits = th SAME oe RRS AT SMU 0 An RRA CS RM spd RA). KTR SR RR A TR I fH. FRILP MBSE TPR RK. C1) Mes RR eh wT eee SL PR A (QAERRNE THSTLR AMET. QO) BRE 2-2 HL FRA RS BOE HO. (3) Fe EI I ea ee AE EL 2 tims sym =O, 21. E20 t (nm (B20 1ChO RMF) 15. 46 XeFy(g) PRR Byxe-p) 7 133kI mol”! Fe) PARSE Eye p) = 155k -mol”) RAR I Hx HERA. 16, RABE GE RA BAT O FIER OF RT OST AOE Y: HY a) mol! AIG) *AlC@) 326 Alfg)-r AP! (g) 4 3c 5139 O:4g)+20l8) 498 2Alls) + 3.0,lu)-r ALON) 1676 2AP* (g) + 30F” Cg) ALOA(s) ~ 1311 GSES Lert = 3,204 107 eg, p= 9.612 X10 Blagemes”' 2.2.96 1 3.122.Spm.90. Spm, 12.4pm,3.32% 19" pm, 22.087 x 107m 4 AS12010 m5. 2= 6.6010 Sm, fe RAR Ar = 6.5% 107% 6.6.63 X 10°'m,6, 63 X 107m, 6.63% 10°9m,7.27% 10m 73.88% 10" mmSe RPA 3d 4s 4a 8 8. seat’ OTT I [R} eas cass’ (ATP) & 3 Pb éstep? [HCPL 9. Fe” jana’ [FT tT Pit Tt FA 4d 5s oe carpe” FOTATATTG] se isnaa’ss’ (HT THT TH LY 3d 1. 0) 304s @) ROM eK Fe a OTT) TL, (93.9 1S (212 G)As*2sh2p? MH LS 2e29"3F (4)3,12 27 12. OCH My Bh QSRRK 3)+2 13. QA GBA NR RG 4, Fae FLIRT AD pad f BANAL AB HARA 2 PH SAF TERI BE TM EFI WY As? 2st, 2pt, 3s Spe’ Sap! voor SE EF Ae CH OS PB) 7 is! 3 4 _ 6] 7 at | ae 23229} [2s |26°ap'|2s 9 10 i 12 13 3st 3st _ as?3o! |3s°3p 3¢3p" 1s ] Jo) 27 ] iS] ty 0 [21] 2] 23 as | ag |dee3e! 423u?las?3e? jatsa' [astap’ [eat |acay’ aa 2a Pm a ROS EE RS 4 ay & fe (3) FESS Kee) SE cl ra 19. 3.2. 16, 586i}+mot™! SS BREESE SOR cB Ot | 3) BOR Sey SS AFR SAE a AE A AFR PRE AE A HB A ERAGE AEM TD STE LT TS EN PF $NA A As GPR CRA 2 BIL POR) PE SAPS AE EB EU PR OE ABHENCHMNAHTABLU RATAN SH BPR AIR — BRS 1916 AE, PER A IR LF UO SUS AG UAE A FED RAS TRF MBAAME. (aK Q hae tk ME 2 RR - - ATES RAT SA I ES OE ATHENS RTAANT. REET Bs A oe TPR LS a GIG FGF A HPT AA ARTE LAE SR Ma a I, AI CRM TALE TRE UAL, MAR RFT a SA FUMESTREATRENES TAN THM PREM FT HULTGREN POR ALR Pe RF desi, TR} AAO FA NOS BS A A AA HEALD Pe He PISO A TOR RF AOA FIER 8 LT Hh FE Aa: H: + *HH:H(H—-H) 10+ + Ol!Boe are 4H qo] SSeS en ENS(WEN) dH GH | HECHH | . . : | | H H FEBMA SAY RP IES — HAF IG SEE SOR AR Hs FIG MSE Hh RHEE SRF SEL. AF EF ES Fe AE TR FP RADA ARIE FD A Hh BT Fo PA a GT PSR GEEK ARERR GEA BE OT SPE hh RF Dd AF 2 IS I SRE EAB TE 101. 325kPa 298K Ot, Incl di AB FRR BASE ART ATS BPEL ROE, RA EK Be ERK. TESLA FOE OD NRT AP A Bn; HO, tH : hoon 4 q Oo: i 4 iCl-Ch. S 7 RAB ANIG: H—-C=C—H | Ht (CSN), H SEAS HCE IRAE AS DT TRE AS ER EL a, HB RABE : C) TSTMS ORE, EDT SRT RRA TB FEMLAFH AMR AF ERTRRES TA. Mn: NH,* thi FH -54+4-1=8,NO, Ha FH=5+6x34+1-24, 2) GLPTRS TOBWEN, ARLE RES CE TRS MRT ES HCA BCR REG FH ATER EM). UR Fa ARAL le a EEO AT Be OE A O AFTERERAE KE TORE 4 TR. © M-ATALAREF, SERA ERR @ KRASTARTATHERETOLSORET ES ARSE BREE PORTA @ SAR ARTES SARTRA WRT SELRAT RA MK IRD H-O-X. (3) RT BK EE SS ST A he FR HEPAT WRI TA-TRE ARERE C-CHBEMSR-ARZIA, He Clo” Hh FB 746+ 1= 14, BARAL C—O: ] HCN BFR = 1 +4+5= 10,7 BR H—CAN,C gH Bae oN JIS ET RUSE SE aR eeFae SS a a ke BO Ste Pi] RA AA H-CEN, :O: 1-80: |? SO? ft FH =6x34+6+2=26, ARH i 50, PH FIH = 646% 2= 18, AHMAR :O-S—O:, WEA 20 FOB FAA BR MU AP RE AT BR 2 HE PSK BO -S= 0 a6=—8—6:., FB Sa SRP WE ESC SF TR LE ON ET SR So LY SP PP Re NO: #1 10-N—O:F NPA 7 OF, - ét SO PAF AF —Be—F: P Be FABRA 4 PHF. =e Pre, MARA AP RCRA HE VB ik. Ee Ef WEEE) (Heisler) AER (London) At FH Fab HA AGORA RHE. AMO EH, OPP at Hf rR "YH, BFA E RE R SARA 41 Bg BR, BRASH RFE PF SRAAMR SEH eH Of ROA Ro MP 1s IRF SLi ee SE 4 HM) RR — TBF ILS RRRAWKR, WK : Ks, REE. SRG EGHAR, CO tym (74pm jit, RGAE RR ARR Ey PEE ig H aFeR OE) HERRERA aera AUP ER SO RF HE PP ee U AH BEG AAU SEEM ART ER ES BR A, PECL F ILE BER A KT RUE ATE 7, SERENE BR So RM H, MRRHMRRAREA MER EMA TIL HRT RE ROVE ME AE RAE HH, Fe AUB IL IC JE RR SE Ue RN RA IRE HT BA BD AR TTae are AUS RCH RFAERT RAKE EE. Al: () RF ARRF BAAR F, UT RRA SE or A, 9 HCL RE MAF AMF BEAM PRE TAM EF MBE PARC Ht RAE Gt LR AB ak, HR ASB ARTAATARAHET BRFRA—t+ A+ AMT BAT RAB, DFM HLO 3 F. (2) 4TH FSD—TA RARE FAS HAAS RS be FE SERENA. MER, OFA T HRS REARS SHR TRA HF. (3) ATPR FRM CMWRFLERAES BARS KART OS K BR ALAS SC Oh RE LL PP. ETE ASR TEI ST BOR TA ROE Aste ea amt. SRM RPM RSA A RE ERS a KES DH o Boo RUT RNRM EW MH OH 4202) MH MAD s ~sH& WAC s~p, RH .CM CM p,—p, HR. AUN DOSE RA IE 4.2(b) 4 p,—p,p. p, BERRA eB. HIN, PT BT NR AAP RE EDR ppp, BUR, SB NRE AD ET Al42 o Bint BA SMI BRT o HABA TN TRF EG 2p, - 2p, 2p. ~ 2p, FREI FE ALABAMA, ARF o MY x BAAR, I 3 TF Kk. MERFME MAG ERA AAT o Re eh oe. SAE oe SF] 9 Bw PRL a AN Fb AY Dt — BGR UF SET DEAN) te TF a PE SE Se SE Oe Ee otase Sone Bt Be Fe As3 NPP A446 CC, PFD MOAR. BLARLSRR NT Sk >” BRAS MAE CO AF oD A A ART AD 2p FA 5 AIRF A FA BCMA Op HLT IE LIN TSE AT HT SUR A tT 2p BFET SRT TF 2p SRE R— TA, it ARTS He CHO:. AULH A H RM AE RITE yg. Ae AF AMNGE LERMMFUNATH SAE MMR EH Vv APTS-OM MERE. JSG ABER. a. PACD TRAM AR SHED WERRS RE NOD ‘ SEOMABK FEE o MOKA FAB IRF TAM. BOR, wR T AUT, RHEBRE-SSRF SFO TASS SSURBIC A TER FN PRR A a AE PE AAR. ARF OER SAT AS AN RS ST, REA RI FE RRA ST RANE RLABRRAENCES, CA RAF ODER AAR BRE (Usp? AG Eh CCL, FAN A — TE a 4 CLE Hei 4 EGU CIR Fe A A fee , Z CICC = 109°28' (4-4), C FA HME 2220", 2 TRAM pF WET ARIE 4 4 C- CLS ENE? EAD MCU IER CCl AFM C IRF BS 1 PLFA 2s HRA 2p HL PE Suitl LCE RA 4 TRAE TLRS 4 > CURE 3p TI A SECM. NF CPS CLF meet, ESN 1 Ps BA 3 Hp PRE AR RRL A op OM, RATED AE A 5 Mp HR Tp? FLL spt Ae He AA Pl Ay 3e Hh Wy 109°28" 6» OOO » ©OO @.. oP ® © q DOO OOOO 4s geese (2) sp! Be RWG BE, 4 MATER PEL A CPBE = f 120°. BIRF AINE FH) OL 2s°Op' REBEL 1 TOs FS LS (4 2p Sith IBY. A hs M2 Tp HHS ERM 3 TRE ADAMS OTP RRS aatccouttats mp BO RRAD i op? RAGA IE S « OHO**,, OHO™*DOOO é fo B OF Sh sp ata ABBA 2 op RHRBER—E ME AE 7 Tale AH Ys 120°. LAL sp? A He HE ASH UA AZ H! BPFOS HOD, ELHIFH IF CHT HAT HAF TAFT CREAT 3 opt BH HOWE IP HRERA—-TCRERE MET C B45 CHAT RNRER TSA PREG 2p MONEE MR x BHU CH OFM C—C MEP 4vaE op? ~ sp’o HEME p— px (4-5) (3) spb: RWWA BeCh DFR HAM Be RF AE 2 7 CRF PI ABA ZLCBeC1= 180", BE: Cl—Be—Cle Be Jat F AS fat th Fy 2s? MARAT 2 AP 2s FE BLL ASH 2p HME Ts AIHW Tp ME Re BRR 2 TREE TAS Dp 2p spaett, 2s apo" xOOO™> @O®OO © asp Bishi 2 CM FREE. BARES Ss AS MAST op ATER. MAEM, HE D-H A WY 180s SEA sp RACHA HT MI ZA FAS WL. CELI HI CPR 2 fH FEB A OREO nope Xu So REET NERA CF RE, RAMS 2 gal” Sp spot 4p 2p BSA —/h CAPA EI 2 4h 2p SR RARE LLB CAD = BRCM Pi SSO MEO ®@Ue SR Ee ot wae ose BPH CHC BBR o BT oe ARO. CAV B PEA LA SEF Ae ELIE) BER AAS SC EEE ‘HG EAL Pa aR A ie 2 A PB AD A CCL, PT CTA RET 4 op? Pe HABE STL) 5 4 HEE SA ed PAD AY BP BeCh, Ftv ABE SHE Bbc ALARA MID F Ae AG RSBE HF He A (BAG J A FR EAE YD oF Ut eA HT OP A AS ASE 2 AI ER, JBM NH, BFW H,0 AF. NPIS FH 2s2p°, HER MR” a sp? FALSE, JOR 3 + sp SURREAL CARAT 1 1 op SE Rah Hite ASP op’ SUEDH SITAR TH 1s RR ERS NH LT sp SURE BORN AEF BOUTS TO FIA SIP A RABEL NAF SHRSY «RD HREM S, AHNH M 109°28 RF 107°18' (HB 4-6(0}) 076 HO FF O UF EE g g “HBAS ARA 4 1 op) ALATA AT 2 MDOT oN He 9 RRB 2 RMT FN op! FA LGA HL i Nt f IRF AY 1s TARE AN MD fa TS EG 109°28" JE 443) 104°30'( A 4-6(b)).. FACE MDT o RIE ASH Hetcty paul AS NEA OMT “te ee SRE Tw BR SA AE AI 3 PTR A SE BRAT IN ETA RL LE AE TE Ne A StS OME, Le (Ck SHE HAR A DL I ALOLIME MCR A TBF 5| AL RIT ES. MBBE HERR (VSEPR) ia) (b) AACR IG HT 1 BE BB EBL DF mS IL Sekt, FRE BFR UE RS AR TE ih oP FA IL TH 1, BAER SEE AP AB, GEG MUAD SE RE A LM PACH A LAIR, ER ORT GIT A Era FR hI FRR (bp + Ip) FEE bp RED FMR Ip Mohs Fxg Re. RA BE LT AS a ET RN 2. AU SEO AF fy EAL C) HET OFS FLY PT POR TORE F BRK Fy P a FA OLE SR A A RE TA, OT RR 2, BI CEFR EF HH MUBeF, PPR FMM = (2+ 1% 2) 2=2, BF; HR FMM = (3 41%35)/2=ee eee 3,NHs thei FR = (5 + 1% 3)/2=4,COs SPEER FM = (4 +0 %2)/2= 2,805 Phar FPR = (6+0%3)/2=3, EEE MRT EPR Tt Sb 6 TPR AC RAT WS, NO; HF ME = (540% 2)/ 252,53 AsO” HEB PMR = (5+0%4+3)/2=4 NH,” Phe FRB = (541 %4-1)/2=4 FA Sb RSF wR EF aS A FS Fa (2) ARE TTR AT IE 4 a SL. KA RESMATFHERRCO RSA MAD 2 Pet HRM, 180° =f RAR .90" Be 120° CHE AR = ie 4 | TIRReEE® MESA EE see F HEA IW SHEA | ae aT ee ah FB = BE ff WATE a) aBea PUB, 109.3" em FH | A |T @ SHO GRRE ORT AP og HRA PARLE Gp ees FY RR LH ade a ERLE. SNH OHERE RIB = (543)/ 254,50 bps 3,bp=4—3 = 1, PBFA APH, ARs = AL) 4) Sede A ALA ESE A Tt I A Ap MEHR DRAM. DR FER PE MBE RS ATI, ESPN RL A A LAHORE 6 TL FE HD kW Hk. HERR FRI KANMUE 4 lp lp >lp~bp > bp bp» SN SE, FALSE AE SF, SPF FS BYE ES PREM = (6 1X4)2=5,BF SASL SAE bp 4 [p= 1 SATA 4 TAP RRR LR Wie Se ESB ot 9 F Ps 1 ch . N N ora S—F Ss re | real 2 wn bo F F fa) (by cr B47 SR PLA Fah B48 COUL, FEM ABBR AP AAR DART TH A PT A 4-7) E470) POR Gee Fat ALM ORY 3 AL C90", Ip — bp = 3), HAR 180° HA — #b 180" Ip — bp = 1)_ 40H 4-70b)P ,90°HS Ip ~ bp=2,120°H8 Ip - bp= 2. BARA, ABs. ATESE SE ae aka oo a Soe rr FEA 90°F 90° Ha RRR A, Fe oy SO UE, ALR SE, FLD (b) HE HS MTA F ARASH STO EE tk. EST PHBSEAN 2B R AMA TH MM EH ARK Fy ARE ABs. ANTE COCI, 1p, FCO IR RUSE ME 2 4+ C—C BRN FRU HE ZCICCI= 141°18", ZOCCI = 124°21'( 4-8). WH x (AMEX @ ) BY BLA eB REPRE TULF AD RY on EE oS SP a dem FORK 1 BP p UNECE b RAE x BP RFRA. CHES CRAY SRA so? Bett TE 3 sp" RACAL 2 ST HISB AY C UFIER sp? - sp? C—Co HE ALC MATE 1 #5 HR AD s RAM sp’ — 3 C—Ho #.C HRT MEAS Lh, St CRF LAREN pUBSA TE HERMES BR—TA «RCE who TECOS EH ob CRF sp RLS 3+ ORFAS MTS FOL. CHR—T pHESAFT HER AREF ORFSA-TSST PRED 8 pM RMT HAT TM pH LAAT pay ik COS WEP te FSA 6 TAF AE RUETK 1 BIEN xf, ILE 4-9 (a), CO, SFC AF AH op AAC, ESMTARTES MT Hp, Mp. HTS RAT p, Mp, MEERA PERF MG TAK «HH x, | An, $2 4-90), C x +0——C—-0o# [Al : ee @ o) Heo COs #00, WRF UMA = AHREE- ORFOEA-FHLIOR SAREE p RiEOp SUH EASE RDF p BBN 2 SAT RR 1919, AMR MRE Fat, RLF AS OE $0 CO FN, BPA 14 PE C10 Pr) PE PE A oe He 4-2. Al CON, MARE - F waarmee] SA) RS | ee) ie | ae |e co. 28 199 [-191.5] -140 34.8 93 1.250 Ne. 28 = 209.0] - 195.8) = 46.8 33.8 on. 1.251we ay RHAHHE PEERED TRE, RAM T, EMBO, TARGA) TE A RH ALL AE JOB) AUG EIKO TA EM 0,18 TA DE od (FLO © SRSB AU O Uh o HEEES, ATA RATHI PRON SO, NOP HME AT AE HORE xh AIK mE ATAILBEIN COS C24 AT) A RS MT AH ah $3 ALF-ARIN NOS BO} BP, 80, te MERSF = AEA, LIRA EA nf A xd. (Bh 4-1] FARR RFA (a)H,S; (b)H;SO, 5 (c) = SAL (NA, * BES) 0 UB) (RA 6 THT BID PPR AM UREA TOT, RN PPR RAAT ER FH CBIR 5 2 PRE RR OT, WR AOTC AIE HHS COR BSAC: HOS (b) 5 H,SO, FORRES 4 PUREE . SPW GUE COREA BRT NG PARTS SMES SLA) (e) = RACAL MLD 5 MOP TAY 3 PS SEARS Ap 2 BURSA AURA TL) [904-2] Wis! HCO, HB Ss ME HSE CAR] (1) yA a PRAT SRITER: HHO-P OH 00 (2) OA TA" SLU 2 PF HOH . | 20550: (3148 tt FROM 38, THE HCO, POF RA 1X24 4x 24 6X4 = 34 PSC A AEP A 4 4S (38 ~ 34 = 4) ae ee A A, AE 9071, FL H,C,O, 1 Be ea LA 0-6-0 ° 20:70: [814-3] Ai VSEPR MGs FH He op: (1) NH; .H2Q,NHi (2)SFy\CIF3.XeF, (3) 1Fs Ly [8] GONH: HON 2 °4b4 bp + Ip= 4 Eh 2 aA OP = ASE FP MM FRE AT aE OE FU AL RA] JN, EAVES F LO Rs SME BOeS Sra ESB OF ee ee VEST .NAS SEPM T 4 K (2)SF, CIF; .XeF) bp + lo= 5, Fat a5 1 BY ES “aii "Aa Pn Se Bb BMA RD. SF RA MAMET, RSI FS FS PaLGY FR SP, PF B9 LAAT BY A 4-10 BEA A Ip SEARED Fe ap EF BH (2) ,Ip—bp Wat We He HE'S A BY EEL: (b) sIp—bp S 3d. BPR SP, (a) AL FT FR REST REA FEE A 90H 120° SF, BPEEHO- i | F co ¢ — OS — i Sq (3 Qo x F é © @ oT Halo Sk, FOLD CIF, Ip=2, APF A Ca) (b) Co) AEH OLE 4-11) 0 GBR CIPS HR (a)T FE a FLAT FO HER RAB 90", RIB Ad) F . " F lo | ve |e ws 4 r— S mc q F ~F x. : ag, F F ” ars" J F w oo «) @ PSL CFs Fa LATA XeF), bp*2,Ip= 3, 4E(a) (b) (o)= ASHE MAM 4-12) , (2) HR MO Eo F + ls ‘ ron, F i | o>) (eh Wail Nek, FAL ABae ae (S)IE slp + bp=6, BEM HARI p= tS AP fk. 1; TWA Uy bp+ Ip=5,bp=2,1p= 35 4-F MWA (a) Cb) Co) =P HR 4-13). JEP (HAD BIE. a ) ly ~~ co) © BSA3 Ly FRILL (Aas) ARETE RS RRA. U8] TSAR AE RIE SEE BIER gp? ARAL, ED oo? SHA —+ ped MRE A op? ALSO 0 ERK, BLT BURT FY + op ATA PE PAA H SRAFME 2 sp REMAN SARE SH yy 4 HIGH o BR, AHCH BLZCCC 499 120°, EP RT IB . 4 BT EARL p, MEH EF rR wth PM OS BR Bee FEU AO HE EP DS dP OGRE HG A HARES. 1. BR EADY MAURER RRR. WMH PTAA To BAH 1546 Op FAA A o MT EM EN, ENA ORB, ARR 3 SFL HG POM RO TS BF Be BP RR AB A ag- MEET 5 AT Be MROKAABUATHORT RRO BE, Sok, ARAM AA RA Gil s ER p KH RM RARIRT DF BRA AE ATE 2. SRE ik DFE RAT BR I FD LT as OA RE © TURF DFP 100kP2 A 298K F MASA AB IT RA AT AIRF BRE Siar ARE RM i AB DTA Re WLS SE a ENA Ce Otwae He PUSS aR eee Bot ® 180KPa, A—B(g) Ag} +Blg) D(A—B) ‘GAS TE 298K BY, DCH—CI) = 432k] - mol”! D(CI-CL) = 243 KI + mol! 48 BF FFL mol HC) BGS 432k) HER. WIFE Lmol C!—Cl BA 243K) FER. MEARE BRE EES FA HE 0 NH, PF ART SOT AD NH, ARPENS PRER-RM, NH;(g)—NH»(g)+H(g) Dy = 427/+mol™? NH; (g)—NH(g) + Hg) Dz = 375kJ+mol”! NH(g)—=N(g) + H(g) D3=356kJ+ mol”! NHs(q)=N(g) + 3H¢g) Dg = Dy + Dy + Ds= 158k} +mol”! NH Jt F 4! N—H SBP PERERA 3 PS OTF AE D+ Dy*Ds_ 1158 E(N-H)= 3 3 = 386(kJmol !) PAL SBR GR As ESR LA OA Be BS TES Me AER. 3. RE SPE PME ee EK DE). AML, PT =F A) BEN BE I Tapm, BLL HH BEA 74pm, BE BG A BAB EO RH, BY SRM 43 hf OG AE ASE Rid HANSA Peebat [484 17pm] BGR Edema") | FeOHRE | BEK L/pm | BA B/(KJ-mol*) wl 4 436 cc] is 346 HF | 92 3m c=c 134 02 Ha | 127 432 ce 120 835 Hep} ll 366 NON 145 159 Hel} 61 298 NEN 110 956 FOF | li 159 (-H 109 a4 CHO | 199 243 NOH 101 389 br-Br | 228 193 OH 96 464 1-1 | 267 151 SoH 34 | 368 HN BS AH SL LA JAF CL Br ST AS AR I ER, CHC MCHC RE, CHC SEE RAT RRA KB SATE HEAR SESE BD SURMISE 2A WRK.BUR ae 4. Bf PITS AINA RADE K ARR FSW MRR SR. Ry HO ff 24 OH 862 61% As B 104.5" eatBee THO AFR V BSA. ZE NH, SFP NH EDAD HE 107°18" RL NH, Se = ES 5. BEES RB He . PENMCROF LE SAF PLANTAR NRE BR BRE. AE HC) PSG Fee FE A dE Cl — FR HE SE EP AE RAT Tcl deme. MBIA ANT Fk OC pagth. & Hg BHCC), L WLR (mm), BENE Cm, BRAS, AEA fa HAT RM a AM HCL AY p= 3.57% 10 Com CL IDB = 127 pm, th OT EE g= fio SWE 99,1107 Th Fe BEC FEM AF) = 1.6022 x 10° BC 28.1 CL ieoazxig c7 "18 JA-CLBRA 4TH. 8 RRR, CRT A RAR 8 = RF th FM — OE A FR ER BM HCL HES Hy 2.18 A316 2.18 au-io~2x (a aateg)=0-18 wy geo y{. 316) LE Ba=7-6 2x (3 sg23.16) 0.18 5 LaSRM aR EBSA SRL RE FD AR SE OE AF HAG $5 VOL) TT RSW A PR ASE OEE ETA TS EAS Be ASS OaROS Sree aR Bet ae Sw Bo AF EALA — BEA FERED PAT EE ER NE EE A ERE FA WF ROOST HCL, oF EAT aL KE I A eb FA ARF -W SARS —-RRE ML, ARS MBAR EST PRE AR BT THIRMEBF ORF SF A BEA Ab a) ERE CEREAL DORA REF B91 RS SP PERE PP th RE A RAF HER AHN AFORE T ES tM, MM CO,,C—O ARE BMAF CO, FMS A BA A AY AP C—O BEAU AR EA RT IE AR MRE EDF. UA TE CCL PARE CHCl RARE A} Ft AMAMAS MOD FRR, BAT RR TRE FORERAT ORR EMARAR. TFINRRERERAF REA DME Rl THE SD FAERA BED) BF AE Ore AS BADE IF a tS a TL A ARE “4 100 ~ 800k mol), RAGE Sb SPF MAB fF Ce — Fe HT HET ER A 4 LBL kJ mol", HEALER As 1-2 PIER, A FB EB HE PR OA OR, 2 A YE DPS OER— MEM EE, RARE. ATE AK DAR WRT Se LE ES A RAS By ETB Ye FH Be PAF AE Sp ARS A ER. 1. RAR HT Hy Be A PHA RE SZ av AR EO 0 A BA MO ARK M414). 2. RSH BPNREERED F SREAFZMURRED FT SRST SH. SEARLE F rh FE BUA SF A BO ET eA Te TE OE AH FERPA. PAR SRA TNA BRE BSP EA BRERA o TAPE REEDS FS UE SF AE Ee AEC PER Te AUOBEEN ES ATHFUSRE RE PERRO 415). FFI TRH PUT MRBEREL GRIT PERRREP ERA CRBS PRDAe Sew ON <> a ae) QO aE) A414 RET PA 15 BEST SEA FE EAL BH. 3 oma >> Wt NE SP a FANT AER BMIETA ADE SHRP AL AOGWRBLATI ED, eI OR <> a SPORE LALAL FPA AT BOGS AN Hes GREER Bi RECA. MENON T BMA LATER ED CATA, B41 ROAM. =.a8 4-4 FT MAMA RR A ig AMAMARARMELBRA CHATEE REEL BAT © a? N ‘ati aac | ake ware HE +20 4,0 100.00 HCL - 84 Hs ~ 60.75 HBr 67 FySe i ~ 415 HI -35 | HT: “13 Hea 4-4 YD RA US 417, YE A RA OF) 38, BEAT -F BR SIGS RITA, ELE HF IO A TR” HAA RARE EE ADEA EKER PLAST DFAS MBE ADF EMT A, URE HIRT Cn FL ROMA AST Sa Fs See eR FE TE LS HURST RG PLE PR NP ALA SE ATE APE AE, RE 7K PE PR LMR FES (A 418) ASP O-H-0 BS SACRUREAKBARFAAMETH HARE ARERRE OS. Fa ae SO a 2Bae ate Pa Se Se OR a Roc H. ‘\ “S A H gg —_ aa i, 17 34 Fame W417 GR RAR RCA WB ASE TARA ARM XH YR RH ,XY HARERW OH RES Y HEM RA. BR SXY AR AEA KS, EK RR YE RA), AME ESE HX, ELAR, ARR 040K) mol | KERR ELSPA eH ASRS TAA CAA RATA A I. SiH AAS RAAT RS, MH TF By XH EAL TOF RF Y BAT MIA 48,00 4,0 5 H,0,HF 9 HF; RA FR RMS TRE ARORG. H-TAEH XH ESEA BAT VY GST RAE, MAA TAS ME 8 4 _L 8 —-CHO,—COOH,—-OH,—NO» Fmt F TERE EHR SF. SF AEA EIR, RHEE I RP A PGR FREI A HF 1 Bo CE 7k PB H A THES T ARR A A ae HEM 1. PRUNE Pid UE EE AYE (a) RRP Oe F fe BIE HRA Cb) SDT PIR a Fe Se a BR AS Cc) ARR Fi EA 2 TAP (OHFH ATES SAM RE OH 2. BL URED AREER) PL FER TR? RMwae ew Lalssd? bMdgedy (desde (side, 3. FRADE TER A he x Ba GIN; (HIG, GIB @)Oz 4 FRIST FPR {aLip (WC, ()G* (AYR, 5. Bw OF 0,07 5 OF MERI (a}OF O7 >OF (JG >O, >0, 507 (d)O, > 0,7 >OB” >OF 6, FAMED F BCs O: WRI (DB SCC NK Oy (B)0, >Nz >> By (<5 N70 (DBS OS Ny tI E 1, Bas Fy A BT (1) Hr H,S,PHs {2)0F; CO.SO- YCIO; BO, .H,SO, (4) HPO H:PO; {5)CHy Cally (6) HSO, 10; 2. SAL O, Bi NO AEDES SAS OPERAS A) BLAS 2F BAB O; 40 NO MAK ARTE RE a TE 3. Git NO, ASR BA ERM E Ate BS RE 4. Qu RB Po, (JOH, (ICH, (QO=C—H, Ht HANA — TAMA» 5. (a) 5 Ht NU PH NiO #1 HS AYE METS (BSR ACAI) (b) BAG I FRE TAGES 107°, 105° 93°41 93° 6. NOR AA BSH. E SAAR (O, LE MI AA AAT AY CO: RI — A AU BSW AD BA 7. RUF AFA LHW SCL (WIG) ,PCIgS = AME) COC, OF tH = AI) SOC = A #8), HC, RRA) SCICV AD SECA TIE) TRAE BL FA PR FRE ARR 8. GAADOE RL Fat AR Bie, ALP St Fw FS ASO” NEL) SP) SI, \XeF, NO; NOP SaBry KeF) PCL .AaFs AIF” SbF)? HT RUS a TA SL or HP Pe ASB SAH IPS IC, SECIS ds = 10, Fu FAS SORA J Se AY I A a BWIA, GACH, GIF, (O)HNO, (4)CR, CeiHe CNH; (g)S0; (nINO1 (Ny (ICs, 1h Pe SCASHTS BUGS ALE Bel, AIRE CBeCl FEAR HR ITE WR HR UE (BoC) i a SRPEEAOA MMM TREN R ERD, 12. WHA FARA FE ae I? BAT (1) OF:(p= 1.00% 10° "C+m) BeF(e=0) WS SEC EES 8 otewe are (2) PR=3.43X10 Crm) BFy(p= 0) (3) Ska(u-2.00% 10°" Crm) Sak (0) (4) NHy(y=4.96 10 Com) NF = 0.67% 10 Com) 13. dA PA Pt TE a Ra ()Xe IP, GIO GINO (S)BF; (GH, (HS 14, HE PRB PA ()B(OH}, Q)HG GICH,OH (4)F2NCH)CH,NH, 15, EF FU AT HY OB RE (1) HFQ2OU) 5 HCK - 88); (2) CH,OCH,( - 250 ) § CH,CH,OB(18T ). 16. FARRAR MERE 2 ARSE EAD AY dl BREE RE CR 17, (1) AT = FB Mey N A= FP AEA A HSS), BSR SU 2 EN SPSA LOS A120" EEE AE S78 FY (2) ALMA EE BILD TE BFs PERE A 640K) mol *. HE NFS PACH 280K] +mol™? 3 AeA AY 2 Ho (3)NE, ADSBA HW - 129U TH NEL, mB AO — 330 NH, HEEB RNR, AEE AE? JaRER Leb 2a) (bs CAR CFRR 3.0 4d S.a bc ZL 2, RDMEEABN OO: NO: SPARE OLLKK( 92.) 05.) Corp) (na) Cag) NOLKK( 03,7 (3, €72,) Cap) Crp)! Op A NO SSAT RUD 7 UNTER ‘“) 3 ‘ ERT BRS SK A ge ee een PUSS Oe EE ce ot a0 + Gn OCH 5. HONAE He PH NUL sp FRAC HO 2h oB2t he A [s=8-2-8:] B [: - 4 ‘| 7. SiCQCsp") PCy {sp"d) , COC {ay}. SOCK, CR SF HE 597), HeCh (op), SCL CA SF HE sp) SF (spd?) 8. SOR” GEDUTIDE) NH CE EUAK) SE,(V 2), SF. QUE mE), XeE, CF METH), NOA(V FB) .NO; CV $B), SnBey FTA BD) Me (ARAL) .PCL” GEISER) , Asis A RUE), AIR?Bae oF EAN) SbF” (USE) 9. TCT FE) TF, UAE) IC (HRY) ICL” CP MEA) 1” (VIE) 1 (HAR) awent [icone] cl. / LL. RH Ch—Be CL (Be sp $e HE) SR Om Be “bea SEK a cl a a Nao BL Yee” a 12. OF (WE), Her CHEER. PF, PRPR PR PRI vee cae cl a a 48), BR CP = 662), SE, CRI PUTER), SoF, TE DYE), NH (= fi BE), NES(= RAE) AB NT, BERL PAE 5 NOH PE ALT NF) PTR 13 ROM. 15. HFLCH;CH.OH & BERGE BAG 16, OS Kee Bo DpyP® DA@ —* DADs cit 0 00 K KR > osk —> 90" KCIO; ,Na:B.O; at RF YF CuSQ,-5H20. SES ESBAR Bese (a) HERA ()) LF (ch LHe fa) APL) Re) MRAM (0) AEE Ooo ORE (RDI eR) OTE in (a) RR (by DAE to) mB WG SER Ee BE S-4 RABAT Lo PAIK | $UEE AP NaCl (RIA, CRAG Ch” A TEESE PRED 8 POL An 6 Ay BIRBPEY CL HE= 8 1/8612 =4( 1) RARE Nat SPS EAB AE ar 1H OD 12 ABE AUP ARATE AD NaS B= 12x 1/441 = 404+) Blk Ne Cl 2M AP Na ALA TCL HBR, CL Na’ = 121, BPEL LBS Eek SE NaCl, | SR Be A RE AL — 28 BEBE RS OH A Ek a AAS. WPSRARAR ERA BMS Bb, Aline BHA PASO, EF ARH HE, UE AR CE TL LLL EL ah ABE = DHESRERD ‘SRSA Ee A A AE AS 7 | 8BAe mk AL 5-5) O2Ooe CoO 0999 DpO@e >OQCc 0/0,0 aeQD 2S ee e909 os @ 55 SHRP EAS FRAN ED @) SPER AB LOSHEE RET 0) BTR ALAR RRR () EPR RE OF SE Ed) SR ESR TRE COS FR PE SE BR AT REF —— 9 FF HEE HEERA. (2)0F AR PAT CE RM SE RR RR FAALEAARNRSRA—AT BE-C MET ENS AA F PRA SZ Tal OTE A A EE AR DEMhh: MPO RIVE RRRLER SRT CARES AT ERFHERETHEF ZAM RRMA AA. (4) EF SP RI A TR AE AE BP PP Ae SR BLESTE iF Bl LAL AEF C$. Nat CL”), ChAT DA 2 AF CN SOL )o FRA RI WR ER PLT CHEF IRRRAD hPL BD TL ILE PE PE ET FI AA KATE 0 RS SAS ot So wT ak — RFR PE BEE YA ANA) YRS LA Da ST oF TT, BTA AAP EE DEA BROT RES RRR TE A ref AR, BIER FA IEA LR 5-2 A 5-6.AS SE Oe aE Fe a BAP Bee R52 “ARF SRMAMRAR iat ace EAE Re R Amit RB PHBA CN, CN_ BRK BRAK NaCl ae LAER 6:6 A 1 csc we RAUB Be aa 1 EH Za et CHEER ad mm 12 AT 2a a AAW RR ag mai 12 CaF, 12 SEAR Ba aa 12 SORRTO) 12 CEH RRR 63 Aa wa 2@ TO ALN Cor Senne (HS-6 SIL Fh AL eat FOF aR OPE BLE TE SK, Pe AF a AS OS EP He CM AHIUAT ARE RAP RA HP TURNER FRE RR, i EMF MRAM AS, ALA ATE AA SA RAR oe HEA (iit 7 PRB AVA BEC 57) HP AE a eA TR SH-TRAF RABE, ELAR RA AAT A Ae AE SB IN WM A NF BTA «A PR EB 5 — A BABA PF BR Pe AIS We, LTR AEE BLATT , Ge BTS ACT A BR DT as BRE = 1 1:25 FETE De RARE PL AB ASA ED a PE SEH REF BC: eH PRS RB = 1SBAS ae A Bae awe ee AS? LHR RRA TER EBT MA SCCN.)— Me ERR PRA ME. re fr = 0.225 ~ 0.4148 CN, = 4.74 /r- =0.414~0. 732 BY,CN, = 657, /r- = 0.732~1.000 It, CN, =8CWE 5-30 5-3 AB MARR FTYSSRAMMAR rife bed Aue 1.225~0.414 4 ZnS 0.414~0.732 6 NaCl 0.732~1.00 8 ol BF RCRCCN TF Ae: CN . ACN. = ER FR/R RFI BT B/E FBG Pts SALA TiO, ABR, (Tit )/r (OP ”) = 68pm /140pm = 0. 486, ATLL CN. = 6, EBS Tit GRAMS CN. =3. SLARAP MBF MR: AE RM = LL, Ti? BR OF a — 9, Bl TH BFR ae ES AY 172, UEXRAAA FOS OORT TA, aH SA LAE RU BEB FANS ROOM AST EAR ELE TF EERIE. = aE FER T AED FA RT EAR, EERE ATAKEPASEAT ALAS TM TE OER AE US M,X,{s) *aM?* (g) + 6X" (g) HOM AAG LTH ABM BEE. 1, Bérn-Haher (46 M. Born MF. Haber Bb TS MF AGA FOSS OES otURS SOR MOE eat @ BAR Ree Sis) W2Br)) ——*“#_» xprie) “| s sem fag, W2Bre au [ate vam ae, aa, as Brig) Ea Br(gy Ki) “¥en tig ALRSAE 2 FG ES TA AR KBr RAY Bl: Ks kia) 8,12 =89.2k] mmol”! Kg) -e “BK AHO,=418.8k)-mol! fe Jeet) Lone) A,H25=15.5kI-mol”? dente) Sane) HE 4=96.5k)+mol”! Bir IRF RAG ty FB ike GE A Fe AE BTR ME Br(g) +¢ ‘Br (g) A.A 5 = - 324. TkJ mol”! K (a) +B, Kel) AyHQ = ~393.8k)-mol! AUG Hess E@: LE RNA ERE RRP ILE AB RA BH Ao =295.3k)-mol’ + SAUL AHS = AHR + OHS + HG, +B Hie + OHHins + AHN SHRo= —U MoU = - OHO + HE, + HE 2 + HE tHE tHE) = ~ (393.8) + (89.2 + 418.84 15.5 + 96,5 ~ 324.7) = 689. 1hJ “mol”! KBs) ERA, RRS FET A DAF SEAL) Born-Haber RH S69 — HAR ABA EE ALL KJ -mol NaF 923 NaCt 786. NaBe 7a? Nal 704 KE 821 Kel MS KI 64 BeO 4443 MgO 3791 Ca 3401 SQ 3223 Ba 3054 2. Born-Landé 30 ALI SAA ee EF La a PP 9 Bérn-Landé 3%:Baw Kee ‘0 n KK ABR Ro RE WEP 21.2, BIL FTA A H Madelung #H,SMAWH A Kin H Born PR, SATM ET RRAAMAK. BHRE: He Ne Ar(Cu! ) KrfAg!) Xe Au’ ) afar 5 7 9 10 2 4 Ry UA pm, U BA kJ -mol '3y ALT, K = 1.3894 * 10° k]-mol”'+pm. . -s[Ame2f) LN] U = 1, 38940 x10 »[Aae (1 LVN mol"! EF NaCl, Ro= (95 + 181)pm=276pm, 21 = 22=1o A=1.748,2=8, RAL U=770 k]-mol|, SRB GRAAA Sara BERT A AE MOTOS - AES EST ee AR EH AE - REMTORG. STRIFAGH EARP < SEN FEM FS A EM Cc» 8). HFRS RPO ER BAF ORLA” BESTEST HRPM AA TM” gee RE oo Bile ARR RT EMA AUER ESS RAPER RM ZWEWEARK, £54 RRM LH LAT HR R84 RFWMLE a/(10- VC -V |) Ry BREE ae HOE ae RR Li’ 0.034 Br 9.0033 F 1.16 Na! 0.299 ar’ 0.058 co 4.07 Kt 0,923, sit 0.0184 Br 5.3L Rb! 1.56 Ti 6.206 v 7.90 cst 2.69 Agt 1.91 oe 4.32 Be! 9.009 Zn! 0.32 se na Me" 0.105 ce 1.27 sé 17 cat 0.52 Hg’ 1.39 on 1.95 a 0.96 Cet! 8.8L NO,” 4.47 MS SSa NES BatFa SO a eB Bae Re EREBP RAS TA RIE MEENA Te RET ERE, HE PPERK HUERSR EAA, RAFREEK. REN: EBT: (1) BFE AMRK AAR MRC. (2) AAAS BFR ERA. REA AMRK 8 FSO ~ITMFBr DC >E. (3) SAA LAT ON ClOs SOL ARAMA TEE, ERTS OY HUARD AE PIE OTE A RB ED RUT ORT ARE ER, OES FOE AS On LL UF ClO, SO? A RELREORTRAAAY ARTA 18 BERANE FU Ag* Pb’! He) BASE REM RT RSE) Wa AA CBE Fi Bet AB! Si BS EAB FAS Ce OM RAE fel se sanmtonmcnzonceneana C)® (2 C FR ANE ZAWRKRRRE RARE Rete atte cols OKHRFR. UEAI RA RFMERF cy aepmenenenem SEBARE RMR BES St RGA FAG ERATOADR I MHFARERMED REE ABTA oe BE HEAERE WF SEEN ER AA PHRERH REE AS TR AEA 5-9). UFR PFE AS EE HR: BFEEZA/om SEU “pm an Agr 29 26 wera Agcl 307 aa sive) AgBr 322 288 RD Ast 346 299 26h (NF Ag’ S18 RES ABER AT OCT HATE BL A Py A SGA, DEULMA AgP BY Agl aR (CE Fl Oot (8 be DA TA) EOLBAe BR 4 Agh BURP Ag’ 3 1” BER 299pm, HEIN FEB 2 A 346 pen SHE 5 FERAL SRT ek a PA Ag BEF OK, ARE 0. Lamol- LTE AgCl AgBr Ag fj PSR BE ARK 92.0% 1074,2.9x 10%, 2.71077 mol-L71, Agh AgCl AGHA & Aghr WRB Ag] WIRE E.. SEAL ADT FR tah A i FCO AE AGS CCaS 09 BYP BIE r. /r- =97pm/184pm = 0. 53, BER FAR iF 6 AY NaCl Baia ERE Cds ASU PAROS 4 AY ZnS BB CE MS SOS RE CPO BARA So ALF AP MD TR PORTE or Zr DATE (S81) RWB RABR SRE TEEA om k SRY A RK. (8) DAMM FYE r= 127 pm. HA 5-10 AM AC = 4, SABC BSR EA = AE BI ACi=AB?+BC? AB=BC SfULACT=2 AB? AB=,/ TAG = [Lex iam) = 399.29¢0m) SRA RR APR A AA HEL 39 359. 29pm, [Bl 5-2) RUE PREC. 77 ESE 0.732 BF AB RSF A PB ARR CCL BD. 1) CsCl M1 aa PRS 5-13 Bp: HT RAE BER AT RA F-MEPOERL, REPROD 2 DAES BAB a. ACR SARE AEE DY MRS RRA A, HBF CRE Rh. BORE Hed=r. +r, aro HEAL o = 2a?,ch = 6 ta? = 2a? + a? = 3a? MU c= VBa. Ri e=2d,a%22r ALA ERIE Dd VE X27 Mer, tr Sr rity. =f9— 1 (=0.732), Bl rr BEF 0.7325 (8153) BU CONFKAMREL MARROW A ENBAS— CO HE 3. 25grem * MrGER MLK 481pm, BME CAO HIE AML Ai BD CaO AF A Fe? RF ATA a? LW} BH Imol(56g) CaO, HERESY 562 53.25 geem™2 = 17.23em? ARIE, jh Ky LTT AS= 2.58 (cm). BABE 4Blpm= 4.81 x 1078em, 2. 58em KE sel) CCl aa POSE BTSE Se a Ee Ot BAe Rhee AUHEF CoO MWA 2. 58em+ 4.81% 10 Fem=5.37 104). FD Lmol(6.023 x 10" 4+ )CaO FI #8 (5.37 x 10")? 4S RR. 20 RBM Coo SORT ag A CaO HALE AD ae HE UAS-4) TR PRS TA RE aR AODROMANS RA DMS LATOR GE OF AYSEB EY NaCl Aas (4) CaP, (La RE Ca? 8 TAD ae A HED! | (5) ME 5-12 SnINeAl A chi. I I i 1 i i Ue) Iyye (DB x gH 1=2 O mnt Dax prexdn4 WS.12 SANTOR (yl xp H6xL=4 Nasl2x4+1=4 1 2 (SSM A MRMADA 4b CHF AXE 6x5 +4 =8 (815-5) (1) AVAL Born Lands Sati} KE dae ROABAAAE. EAL KE A RENGCI UAE (2) 231th Born-Haber BHR EH KE ab RAE 2 802. SkJ* mol, 45 Bern Lands MIRARHH HARES, (82) (1) 68 Born-Lande As _ KAziz: 1 vee (| ett K = 1.389 10°, A = 1.748, 2422 =1, Ry = r(K*) + CB = (133+ 136)pm n= h(+9)=8 BOBILA: ANC Bx +6% =4 F :4X2=8 1.389 X 1 XE SXTKT, 1 4 i = SR AST idm * = 790. 0kJ+ mol! (2) Born-Heber nit pres ta ase = 802.55 70-0 109% = 1.655. [41 5-6] (1) 91H Nak \NaClNaBr Nal 190 GS 8 oo A BUR OOK FF 9 (2) SUSE — ERR TE SAG BS, I A BAK 2ST) MgQ(2800T) CaO(2590T) SrO(2460T ) BaO(400T 418F)BSR awe [9] CL) NaF NaCl .NaBr Nal 29 FAK, FRR EEE AA, El Bom: Landé 23081 50 ABBE SB FH PRCA X IME SF Bs RT KAHIT A NoC] YEP AB TERE Now A PBI PR ERK SROKA EAC) TUS BK PAIR SEA ARK I NaF’ > NaCl > NaBir> Nal. QEAB RRP LAY NaCl DAF RAR RASH OF EAT Hh Mg?” Bl) Ba * BEF ARERR USHA, AR GE He RS PU ARE UC EE sh ATE AREE AL WT RA HL EH HSE Ht DT a RT) A ABER 1 BoO 45 MgO Hib Be’? VEEP FGF Mg’? AEF EAE (BO 14) fh fed T MgO FY Ate He, AF AE) Be” BATE ARSE , Tf BeO AES IM PEAT BRD BF UA A AE BO) A BT PIG BAK BO BOA ASE LE MgO fe AOE 1. RFI FL ARE RE ME AAAS RS RETRY, (1) CsC1.An,CO,HCL (2) NeCl.Nz.NH, SiRF aE) 2. AARP BL AG OT 2 A AP HR +O; HS, Pt, KCI. 3. BR FAM a. CDSG CCL ALE, CH, .CP, UE. Cl, AAR. (HCE AEF HF. (0S0; £0 iF S0,> C4) NoF HIE AT NeClo (5) TARR ADA A 7 RGF A A HAPML GA ALWP). 4 BELATANLE LAR RETA DEAT RS E. 5. A NaC] BEA AYR—aR HE AEE I 1 S8dgecm SARE FE 74.56 AGMA Ko 6. IRTBY KCI REC R BE 1,.9893g-cm™ Ti RH AMAT KW 629, Spm, BELIEF SH OTA RF RS RSM KNEE SK. 7. MgO ARTE 420pm HL HEE A RR RRS RR MgO EH BE. 8. EMSC MAAR AMT 5-13 FR PORE SO RF EOE HEA AK DL OLR ENKFAL PANE BR LRRD be AY AE. TL) SAAC EF AM WHY? (2) AIBA Vou Leno! SrCly A887 View? TM ATR THE BREN MBPT 9. Eo Ti A OFM — HLA AT 9-14 Bea CLS RCA RE, (2) HE TEP IPAMAG Eu RPA WU OlPT HEMA LE? EMTS DLE OR Ho OB SILT En Ti BHR? 10. RH ABA BTERRL. GTAMTAM TD AARP BAF SARTO ERS 00.015. 4.0) FB REORREG fp) NAT SET WORE ESS 7 ORES Be aS Eo BtPES Aa RECS oat BAe ater 5-13 fas-14 1h. # AB BRA REPRESS TABI SS) 4518600.) E40 F9F9, 04,5) MiG mA 12. A VADER AB DAF B.A RFF EN 1670m.B BFF EM 2pm, RPERE RH WA ASM (aD APB (Odd SH BHAT AE? CDA AREAS BT CA ROSSA (RE AE 13 READE AS LA AL Si PSE PAE 17pm OR RE SAL RL A. 4 RAAT ZnS WA 1) SC Ha TK AM BBOY o = 308pm, = 5905p, CAF RRR 0.0.02 ,4 45.5 REG HOH L). ERP (a) ACTA JF AAR LEP IL SCT (oT RRO ARES (G)Si HERD CRM SBE A? (cli SiMC HR K o 1S. RAMEE BA No(s) 99 Cle(g) 52 EB AER NaCl) , MASE RE NaCl (5) sCa(s)-5 Che) BERL GALA RL CaCla() MAREE RE CaCl(s) » 16. aH F FURS EA oA BPE KBs 2E SREY Na, MgO, KILKP,BoOo 17, WF NH. Ro! KAA ah OO A AE. BE NAH BO a 641 ROH BAG AE (O73 “mol” 1) 44S NHAC] A A HE'S RDCL ARAB AE L6ROKJ- mol"). LAT 33 :(1) BAH SEA L2O8K)F NAH OR EAA. (2) HORE NELLA NEL ada eee DO AEA AURA, BaF Rises eH Fila NEM@) __NEHG) NHC) NELCKa) ‘Atmel! K7! 129.6 192.6 66.9 94.6 184.0 NH a) EVP AGA Hp = ~ 894.5 k]-mol! ERE Dy, = 435. 5k) mol", Dea = 4284] “mol, BRE 4-217. ORF TRAM Yy= 78.2kJemol”?, Y= — 354. Skfrmel 18, 2RR AA OUT BEN 8.0 gem. TA: CD Nu RATE SBE RF fH EES (2) EAA BL NBR SER PAYS TB RB eo? 19, i) SEH Ob eh A FB BTR PA a 2 LB PD 0 (1) CARD Ey BRD (2) BORDA BD: (3) SULA CRMY TAE EH S PHBA LT CRT EEAwae Be ASPCRT WAT CRPMLERRAM EL TRDR STOOD RS CRF TR BL a 2 CRF ae bb SHCRFRTEE ED HRD tee 4 CM TT A Fb (GB S15 He). 20. REGAN FaIR F NaCl Stk Serb dbs F Na! SEB — op iS MAS CS 5-16 Bax), RP Ne ST ERBN- THI TC APFARM ROM SRB BOC ATA RA), Bea 282pm,r(C1) = 167pm,r{ Nat) = 116pm it R= Ae Oa MR BB HES al. OR AWE Le Near Ke fl Xe 9B fh Gb BE — 68.9 ds, $C, = 185.70, = 152.90 AL 07. 1C , PRB RE A RITE A OR SPB 22. RHEL BB ETE ULAR EE AEP UE CORA EAE Hikes (age 40 a RE OK A Aa tale 23, EP 1H: - w o SoH0 apes wO-< CHO fs (2) NECA F ICL TLE TF MgO, (3) Hg 5 SHA Me Em Pi Hk, DAR UGK EP H., SEESR 1. CLYCSCL BAB Au 8 BAAR HB AUG 5 COs TICE 4 TAB PRA 5 (2 NACL A FAIR Si FARE ABU Ns NH, 9 TIE ABA 2. OTS FAME Pe SABIE KCL FREE Ge FR oma 3. CPM RARE SF RS AC TY ns 2) HF SF Zl AE: C3)SIO, AAD, SO, BAPE AMA CEE” EGIL CL os, NoB WESC (5) LA RI AL eR De ALA Bd ST Fee 4. AGH MR SEER 5. 629. Spm 6. 6.0214 10" 7. 3.60gem™? $. (084 Q24V/y 9 (IRUTIO, (Q)HG ()Ea HT ROOK AT rue nis OP Shy Per = 16722020.76 GPE P DH PREBE (eM CAAB Ce) OH P13. =S409m, V= 1.58% 108pm?, D=2.3%grera™* 14. (ae# 2=1.04 QZ (OAH P WS AHHORELC MNES A (0)189pm 15. NaC (5) AEH #RX2300K) “mol”! NoCTCs) 686 BLA I ALT defemel’ ' CaCl) 2888 ~ 798 kJ -mol”! CaCI (394 we A — 150 KJemol”' H CaCl sdb CaP AICeCh OAL 16. MgO> BaO> NaF > KE> KT ROS Sa a dece BotRO SEAR aE 8 aot BA BED 17. NHgH(s)-*NHy(g) + 1/2Hy(g) £2 = 1.1 10" NHH(<) ABS AE ; NICH) + NHG(g) FHC) £'= 2.9% 10° NHC AERA AFAE 18. (1)250pm (2}52pm_ 19. $A: 74.05% + 68.02% SMA :34% 20. 6pm 2. GRARKAR: ABR RAND 22. 2 23. OH () SCH BA FS MNT RTA | QIN MyO AT ARTE, IC SATE mu AISA NCL GVH RSA S AERSKE RCHERLARSLS TH SAR CERMESSSTH BW MOE RRR MR TE APIO TERE EIA ET BA AE KD RE RRA MEK HR , AVI — BG WEA PAT 2 BE APS] AR 2H SK AGMA SAS TT ARAB ZS De DF 5 AEADAB AB, BA EBA MEAG HT UIP ARR SAR A ET ik ER 4G EES ML MEAT A BERT WE TE EA A EMRE HEH, ERA AR IR, AB A A SA BS A YL SUG SAB RATA PG IL RT RK. — Hee SPE ASE PLAT) PSE By BE AB a 2 AB A BC 3 HR B. PIMA A LEA ELE @ A+ 6B —~gG + RH EERE LY fe Bohs oC af MV ARBAB my ny PHAR —WRERANA 0.0. RBC. .0, AB SAS REPU A Be aS AL” a ey Me IT — "a ‘Ny He BLS HA TI > BRS eG A = .aaee AU RHC AT SAT PTL AT RE de ue

a ip EB VS RE — Aen ade dee dew Wa ge PR de BO v8 at E.SRAGEZ AMER LR OH RURERAAZA PES CRM KALA WHS IRMA PRACR EL AK. VABM CO (g) + 2H, (g)==CH,OH (2) WO, BORO SM AR: devo 8 decayorn Yoo ~ OH err de FEU CHOW “EMR He ais Be aS | AL: BR Lm CHOH, BT FE ‘2molH) A Hp RIE CHOH 4: AAS 2 FAD dey, devo a Ti CO AY FEY CHLOH 4 ne eH He deco 1 Aen, _ Aeeeaoney ae Dae de ANB GA+ bB—gGthH, FREEMAN KRY — 1 deal 1 dey _ 1 doe ade 6 de g dt DRM RAE LRRD A SP 2p B A PR IE BA A Td SE AE ‘SO 6-1 Bijan 7 ve BE BU Gd 3 PER AR AR TE A A GSS >, TG Rk AD DER BH ei HL ate Dw EH yO a ZADANAE, H RRRSMHRCRAK MFL-AMEMR MER, LOEROT ECC SARA BY AGA I, RACES A BPR AE AIR Ra rdN, 4 Len. * 1dN, es tea sae ?? ~ *war? "Var 6-1 REM LRABR KERMIT RR aT AU SW V SER ANZ A REN, RARER i OR AREER ME SON Te EF AS Tk FB 4 AD MB I HT Ba 1. ek FLAG AR Sh A DA HB AL 2 ER PO ON ME LIE A Oe SO OR” EE — RT BS AAA BREE REMI. HUE OLA IEE A ASA THR 7 I at 2d RE Wf BLA SE AV UR EA DEI RRA. 2. BRE AMMEN ARS OE TRA RE SE A AR SO RAT (Yt BER RG BR DN AR J I SE AL KRGM CERERRA, APA AMORA: EH AR IKE TER Obi AF HOS BE BE AE SASS, [Bh 6-1] S56 RY NH, 45M RTM LSPA NH; AACE HH 1LOOmmHg, 100s FG NH, BUS} HEME 86. SrmmHgg, GA FATA Ya AH BE BATE TAT) 8 A, Pe 8 BO # SHARREZMORK FR GY LARS (a) 2NH3(g)>No(g) + 3EA(2) denn, den, _ dhe, own de ON ge de HA iy RH DE HES Be oR AAD BE) _ dena, des, 1 ba, get 2 de dt 3 de Ai SSR Ree oo Ap oak SPS A (86.57 100) m 4 Beg OT be O}s | 8 067SGumHg's) FAG oy BP MEAD ET NE EEE MPRA 20 Bo MARRS WPA ES ZAIRE ET A, ME HPRRERELA CEM EWEERES—. ERR BERRRLAT A PERT MAS RRM AGT ROM MAT ROM SAASROE POR be ee BOR CPRSAKS LP APG PF RET AI PE SP — A MTC AAMAS RM REM Z— CMT LES BAe AAP WMAF ALAR TF AT 1, BAER (1) BRE RDS FE EBB SR (2) ARLE SE A i SAE I A ea 9B A) RBG ABE ED 2, PE PEA BAR SR EAR A ES Sa OR HR et — 22 RCS ER WRF TES FS BO Se RE ES SMAAK. ~Ha zx, (6-13 Reb AEST FO, = FEAR ALLE SUE RA OE CE HA D),¢ RRALATHO RAE RAH, SEU SEE 2 ET LAE AO SF RY Zygr antag) BRE 8: = 2 Zaym tannda re Aid WHERE R BUAWH, TSR SRE, MARMOT RR. ZK Maxwell 3325) 4 @ 0 BE Ba SP 78 EB Hs geo* 6-2) Shp E WEA. ABATE IN BRERA BLT ST FS On A ae UR Sen EARS So FI FS EK CY 2, BT Z=2ZL aq (6-3) #5(6-3) (6-2VRRACG- DE Bn aZage &F (6-4) Wah mF MLR RH ode yy? : ak" (6-5)BAe LIRR HeBECG-4) (6-5) EAE EG Wh T AGE YSN BURL DD FR RA ET A BY RAR. = RSH - LEAS BID AT HA I a HE HB ch Eyring Polanyi FA ¥ 1935 Fa ARH ASMEFAPE ROEM LRH MIC ROLES Bl AT 1, BREA CD) CE RGAR RO PRE RE RES ARHAA-TELMNTBS: 2) MRSS RMD T ARUN LET RSDP RE HEASR, ATR CARERRAT RSD ae, 2. BGR A+B (AB/*+P 8 «a fast cata ROD TATRA TO MIE” RR r= (6-6) AP E rE FE AE coat RRB FP ARNE 0. HE FRU SRA, RAG-OR rake (6-7) SH A HERE RN, SL EE A. APF Ae rekeatn (6-8) 1REC6-7) (6-8), TA RT bey a SERS CLR EA EE RE EA A PUES SR Ee EaRi SE ES A Ot BAR IRA RCI EAE AR EAN. [16-2] RAG SEU AAR SEL 2HI =H, + 1) 4E 556K HY, B= 44000Cal* mol", A= 35X10 Fem, M= 127.9. RBRBM bo (8) RIS 4Naa? -& ae aRT 46.02 x 10 x (3.5% 1078)? | 56 18 127.9 =5.4%10 “(Lemol'+s°1) SHA 3.5*10 MA. MRR ERS OSRAS, k 44000 987556 Fa BME RRNA PRE 0S Be A 8 BE 1, RRM AREA SEACH LBD ee SL BR OT ERPRARNH RT HEBARARERR MG MARR . Hy + Ch —2HCI BULTMEE RM CRT ER LE: Chi M 204M Cl +h —*HCL+H He+Ch—*HCl+Cly Cl) +M—*CL. + M (6.9) StH M Ream SON AS He AR BI A hPa ER PE 2. RASH ERKERP RERVAROREATRAARM AFH. i. AARNE CH,COCH; —>CHy +CO+ Hy WAFRM — CH,COOH + GHsOH —*CH;COOC;H; + HO SAPP Hy +212 (6-10) LRU BCA A EM, BA A, MOE EP OF PBL LPAR AR HT RAPER. UML TR LUGE OE 3. RR ERT RM TEPER OBS Rb, C-ERET RRR RER ere LYM, KBAR AAA ERD, ME HEBRE LPR ART POT = 4 - He) HELL M, RSPR PRA ARE EES MAP RE Se ie OE ee aS FRKEZ ARE. AMBIT (6-9) (6-10) HEHE v= kehew (6-11) v= Ren ch (6.12) RAREST RAR OWE. 4, ERER SERB E611) (6-12) PAI & RRR. PAL eR WE eM SPRACHE LSE MABE Bk AEA TH SE OA 5 ee UH WA, RA FAA Ee OT SE EMM A ORAS RRR ATER RAK. MTR aA+ 6B—=P MAR DBESKERIARSBER RRA E A =e, - boas iden Ae w a Beary a de bdr ky 6 AR, nuasere, ky Al ky FL, A EF EZ th [9163] ZHRENER SHEE NRE SREZA BRA, 4 Dena opeere (8) RRM RMR AO REE ERT A i= kachels MSSM MHES Bat fh neq thie Ma tyeam tent ae, Sm tnee hace GEO keen SAAT ARIE A AG AGHA ALAR A RAH ABBERDR THAR BLA DARGERAART A, SR BERT A YY —— Arrhenius 2% 1. van’ t Hoff Hf 2488 van’t Hoff EM — ROME AE SAB LOK, RRA HM 2 4 BD Hee aaa 2. RABE EA ME aL A HS A, A TS 6-2 BN 3 1 BAS LT OR TM, A HR WBS UL Pe A AN EL FS, BL RR @