(@) The Gom-—Haber cycle below links the lattice enthalpy of sodium oxide with ite enthalpy change of formation. (On the Bor-Haber cyclo, write the correct letter from Table 2.1 in each box. 2Na“(g) + (9) 2Na"(g) + Of@) +26" 2Na‘(g) + 01) +¢ 2NaG@) + O1@) | 2nais) +%0.(6) 2Nals) +4040) Na0(e) ro) (i) Calculate the lattice enthalpy of socium oxide, G. (i) The student thought that he could determine the lattice enthalpy of Na,CO, using a Born—Haber cycle that links lattice enthalpy with enthalpy change of solution. The enthalpy change of solution of Na,CO, is exothermic. * Sketch this Born-Haber cycle, * Explain how the lattice enthalpy of Na,CO, could be calculated from the enthalpy changes in the cycle. (@) An ore of iron contains iron({I1) oxide, Fe,0,. Iron is extracted from this ore by heating with carbon. The equation below shows one of the reactions which takes place. Fe,0,(s) + 3C(s) —> 2Fe(s) + 3C0(a) AS = +543 K-'mor" and AH = +493kJmor Calculate the minimum temperature at which this reaction becomes feasible. ‘Show all your working.2 (4) (ili) A buffer solution with a pH of 4.00 is made using benzenecarboxyic acid and sodium benzanacarboxylate, Calculate the mass of sodium benzenecarboxylate (IM, = 144.0) that should be dissolved in 1.00 dm? of a 0.0120 mol dm-S solution of benzenecarboxylic acid to produce a buffer solution with a pH of 4.00 ‘The value of the acid dissociation constant Ka for benzenecarboxylic acid (CeHCOOH) is 6.31 x 10 mo! da [5 marks] QI1 Hess's Law can be used to obtain enthalpy changes for reactions that cannot be measured directly. Use the following enthalpy changes KCIO,, + 3Mg, + KCIO,, + 3MgO,, AH = -1852 kj mol Ky + Cle > KC, AH = -437 Kj mol" Mg, + 40, > MgO, AH = -602 Kj mol" to calculate the enthalpy change in kJ mol", for the reaction: K, + ACL, + 140,, > KCIO,, 240999 LEEW 4 rUUEES QI 2-Methylpropan-1-ol can also be converted to produce diese! and jet fuel. “The first step in the process is the production of 2-methylpropene. CHH,.0, > Ci * HO, 2-metylpropan-1-ol 2-methylpropene Using the data below, calculate the enthalpy change, in kJ mol", for the production of 2-methylpropene from 2-methylpropan-1-ol. ACy + SHyy + 40x 2 CHO, AH =-335K) mol" 4Cy + 4Hyy > CHyy AH =-17J mol" Hy + 40 > HOy AH =-242Kk{ mol! 2