#17

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.. .
:

CH 2OH (CHOH) 4 CHO + I2 + 3KOH CH 2OH (CHOH) 4 COOK + 2KI + 2H2O

:

1. 2KOH + I 2 KOI + KI + H 2O

2.
KOI + CH 2OH(CHOH)4CHO + KOH CH2OH(CHOH)4COOH
K + KI + H 2O

,
:

1. KOI + KI + 2HCl I 2 + 2KCl + H 2O

2. I2 + 2Na 2S2O 3 2NaI + Na 2S4O 6

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 #17

1.
2.
3. 150 -
4. 0.1 N (12.7 25
1 -)
5. 0.1 N-
6. 0.1 N-
7. 0.1 N- 0.2 N-
8. 1%-

10 , 1
10 , 150 - , 25
0.1 N- , 2-3 -
38 0.1 N ; ,
.
20-30 - ( 18
. 0.1 N ,

1-2 1%- 0.1 N

.

:
, ,
.

,
.
, 1 0.1 N 9.005 ,
18.01 .
 #17

C=( B A ) f 9.005

100 C=(BA) f 9.005 10

B - 0.1 N
Na 2 S2 O3 -

-;

A- 0.1 N
Na 2 S2 O3 -

-;

f *- 0.1 N
Na2 S2 O3 - .

Na2 S2 O3
f *- - : 10-15

0.1N
Na2 S2 O3 - , 10-15 20%-

( ) 10.00
(. 0,05181 N), ,
5 - (). 100
,
. 3 1%-
;
, ,
. 2-3-
.

10.00 0.05181N
KMnO 4 -

10.66 0.1N
Na 2 S2 O3 - ,

10.00 0.015181
f= =0.04841
10.66