Series SSR/1 See Ne. 56/1/3 Roll No. Candidates must write the Code No. ae a. on the title page of the answer-book. fendi see-aferr i te 4. ata faa @ Please check that this question paper contains 15 printed pages. Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. @ Please check that this question paper contains 30 questions. @ Please write down the Serial Number of the question before attempting it. @ Fu sie az cf fh sa yeaa Hyland ye Is 8) eo sei-va Hares gar chl afk feu mm are wear a aor Seep oh He-gw Ferel @ Fun sie ax oi fh ga yer-ua F 30 waa B) © Fun wer at Sw fora oS ae A eet, eT aT eR saya fer Time allowed : 3 hours ) { Maximum marl reite weer : 3 Uz] [irae 3 CHEMISTRY (Theory) warm faa (fafa) 270 £70 General Instructions : () All questions are compulsory. (ii) — Question nos. 1 to 8 are very short answer questions and carry 1 mark each, (iii) Question nos. 9.to 18 are short answer questions and carry 2 marks each. (ix) Question nos, 19 10 27 are also short answer questions and carry 3 marks each (v) Question nos, 28 to 30 are long answer questions and carry 5 marks each. (vi) Use log tables ifnecessary, use of calculators is not allowed. [P.-T.0,2s S6/1/3 ware fide : () aii wer aeré é1 Gi) BH en 1 a 8 & ue oft ay a B) ae Uwe sie HB (iti) 9 Fen oF 18 % yea a-x) cist & ay sata ae By (iv) BY eM 19 8 27 a wer sit cai ated % ory amt wer By () aH der 28 8 30% ueq Gfa-uts afet & ah sata we #) (vi) ortereersear et ct orien Serer sete Pea ar eee B 1 Secrest & vat a1 orate wet BI What type of substances exhibits antiferromagnetism 2 fra san & vend ufecheqerrca waltia ant 27 Express the relation between conductivity and molar conduetivity of'a solution. we fromm fl areveet oit Hee areal & Ata 3h vein ay afters afifsre| Which has a higher enthalpy of adsorption, physisorption or chemisorption ? fort ati wet ate et, vita-saete, a weet oreetrer ? Write the IUPAC name of the following compound : Hot, Ce cert CH, 1H CH,5. 56/1/3 farafetiad aif ar IUPAC arm fafa: H,C-CH-CH,-CH-CH-CH,OH, CH, IH CH, Inwhich one of the two structures, NO} and NO}, the bond angle has a higher value ? at deat NO} eft NO} 4 8 Peal crac ator aftr ata ca? Name a substance that can be used as an antiseptic as well as a disinfectant, om ta vard an ary fhe fare sear feet aan dergarefl al wei ada e Avrange the following compounds in an increasing order of their acid strengths: (CH,),CHCOOH, CH,CH,CH(B1)COOH, CH,CH(Br)CH,COOH Prati a arm at ge orefta armed 3 on A xara AAfau: (CH,),CHCOOH, CH,CH,CH(Br)COOH, CH,CH(B:CH,COOH Write a chemical reaction in which the iodide ion replaces the diazonium group in a diazonium salt. ve daha afi fatten fed oe easier aan 4a ersten Wg sreiisgs sre gra fentia ater 3 (PTO.9. Formulate the galvanic cell in which the following reaction takes: place : Zn(s) +2 Ag*(aq) > Zn** (aq) +2 Agts) State : (i) Which one of its electrodes is negatively charged (ii) The reaction taking place at cach of its electrode. (iii) The carriers of current within this cell, wa vate Ge a yaaa aif fared Prater after ach 2: Zn(s) + 2 Ag*(aq) ——> Zn (aq) +2 Agis) ferfaa : (i) a Ser A ae orate salary | (i) waves ergs K aA ae af (iii) ea oie ora ares | 10. The resistance ofa conductivity ceil containing 0.001 M KCI solution at 298 K is 1500 Q. What is the cell constant if the conductivity of 0.001 M KCI solution at 298 K is 0.146 « 107 Sem! 6.001 M KCI faces =I we arereer Set F 298K ye uf 1500 @1 af 208 K 0.001 M KCl Seat one da At arc 0.146 * 107 S em! tdi aa ar fErts ea em? 11. State Raoult’s law for:solutions of volatile liquids. Taking suitable examples explain the meaning of positive and negative deviations from Raoult’s law. 56/1/3 4 2=] aca - | Or Define the term osmotic pressure, Describe how the molecular mass of 4 substance can be determined by a method based on measurement of osmotic pressure. sree sal & Piers & feat care fram fred ofea aerate ae anergy fF wsce fay a Sere site arene fara a aay caf ate 31 waar Toe, ara At afeerer Fee aoe if, Pe were arate 3s omer We aerator orig zerera 4a ae fae sen 21 12. Assign a reason for each of the following statements + % @ Ammonia is a stronger base than phosphine. (i) Sulphur in vapour state exhibits a paramagnetic behaviour, Rafeafer want a @ act % fed aren Ferd » @) web A ster setter ates ac ae 8) (ii) 1 sae A aeax Sager sae yahtia am 21 13. Draw the structures of the following molecules : (i) SE, Gi) Xer, a fer orysii A dean ates Are : @\ SE, (ii) Xer, 56/1/3 a [2T0.4. 15, 56/1/3 Explain as to why haloarenes are much less reactive than haloalkanes towards nucleophilic substitution reactions. 2 OR Which compound in each of the following pairs will react faster in SN2 reaction with -OH ? Why ? @ CH,BrorCH,I (i) (CH,),CCI or CHC! Brarea Ph Resi afters arfitaeanait & oft Reha Retest Al over aril aafe ann Baretter ah 2? aaa Preteen ucts sitet & 8 ata a cits On 3 ute suo arfhfeen F afte: tof & sien stm sie at? (i) CH,Br sre CH,I (i) (CH,),CCl sear CH,CI (@) State the TUPAC name of the following compound : v HC, H SNE H H (6) Complete the following chemical equation : CH,CH,CH=CH, + HBr _peroxide16. (a) Fefcigg afte a1 TUPAC am fifa; (3) Pafeted cai ate a gr Fife CH,CH,CH=CH, + HBr TTS What are biodegradable and non-biodegradable detergents ? Give one example of each class Saftsterota stone sie sida factaaoie srensts en ata 82 wks SAR A U-wH saree dif) Define the following terms in relation to proteins (i) Peptide lin! (ii) Denaturation waa a deal a rafeiiad A afer fated ; @) Teme ear Gi) SRR (Fel) List the reactions of glucose which cannot be explained by its open chain structure. Tea Al SA aftiaarail a fated fee set gett tac tea 3 sree WR AAS Fai ST RAT S6/1/3 7 [PT.0.19, 20. How would you account for the following ? () Frenkel defects are not found in alkali metal halides. Gi) Schottky defects lower the density of related solids. (iii) Impurity doped silicon is a semiconductor. Or Explain the following properties giving suitable examples : (i) Ferromagnetism (ii) Paramagnetism (ii) Ferrimagnetism frafataa aa oma aa aad send - () eweh mg terest Fae eae orm aa 81 (ii) aie du @ diet % waa ge oa #1 (ii) SEgaaT A Sifts falerria sefarers et stat 21 wera Sar ae ea ge Aratertad ht sare sf: () che-gaere Gi) aA (iii) Wi-gerra (oy che-gaara) Calculate the temperature at which a solution containing 54 g of glucose, (C,H ,0,), in 250 g of water will freeze. (K, for water = 1,86 K mol kg) aa ad oil often -Aifsy fra w 250 g wet S4 g taste, (CH 304) Wie aR aa FACT IA SEPT! (K, (Set) = 1.86 K mo kg) 56/13. 821. 22, 23. 56/1/3 Explain the basie principles of following metallurgical operations : 3 () Zone refining (ii) Vapour phase refining (iii) Electrolytic refining frafetiaa org-aai wanil & ones fer a} oe < >-cHo CH;CHY) ano) 3 o A i) KOH, heat (b) Describe the following reactions : (i) Cannizaro reaction (ii) Cross aldol condensation OR (a) How would you account for the following : 3,2 (i) Aldchydes are more reactive than ketones towards nucleophiles. (ii) The boiling points of aldehydes and ketones are lower than of the corresponding acids. (ii) The aldehydes and ketones undergo a number of addition reactions. (b) Give chemical tests to distinguish between : () Acetaldehyde and benzaldehyde (ii) Propanone and propanol S6/1/3 14(3) onfere gerd, aneres saat scare, ot a a am ai, sat Fras ge Frfaiag cafttan Pecil a yl Bm Oo, Or... —— 20) Zn-H,0 (CH,CH. Gi) CO 7S a (a) Prafefern afters a ala Aten - () FARO cafeBear Gi) Fa testa Ge aaa (a) Fesffadt 3 arom fata; () Reston & sft Aerie ater Uses afte aie eid 2) (ii) Yeserest sik ast a aaaais ackieh areit A atten ar a @1 Gi) Mees sie HAA agT at sere sift BA A) (a) Fiefofadt # fe fear & fea carts vteit at then ; ( Uhetreers ak aaiteers § Gi) Sth sit sata a 56/1/3 15