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func to bind sand, fine & coarse agg, to fill voids between sand & coarse agg to
form compact mass 4 main chemical compounds - dicalcium silicate C 2S
slow strength gain for long term strength tricalcium silicate C3S rapid strength
gain responsible for early strength tricalcium aluminate C3A quick
setting(controlled by gypsum), susceptible to sulphate attack tetracalcium
aluminoferrite C4AF little contribution to setting/ strength, gives grey colour of
OPC types a) Hydraulic Cement i. Natural Cement ii. Portland Cement made
from calcium carbonate (chalk/limestone) mix w silica, alumina & iron oxide 6
types Ordinary Portland Cement OPC medium hardening rate, obtains
strength in 28 days, suitable for most works, can be attacked by acid/sulphates
Rapid Hardening Portland Cement RHPC finely grounded to increase rate of
hardening, RHPC obtains strength in 7 days due to C 3S and C3A adv can removed
formwork earlier, save cost, produce heat suitable for cold weather white
coloured cement for decorative works, pre cast, paving, made by china clay
without impurities, extra care as easily soiled - low heat Portland Cement
hardens and evolves heat slower than OPC, slow strength development, for dams &
mass concrete constructions, reduce heat evaporation, develop little heat due to
C3S & C2S blast furnace cement mix of OPC w granulated blast furnace slag,
resistance against sulphates, hydrates & harden slower than OPC iii. Aluminous
Cement b) High Alumina slow setting, rapid hardening & produce high early
strength due to high alumina content darker than OPC, clean to remove traces of
ordinary cement, no admixtures, not for structural purposes, for high T applications,
roof cement grout - cement water mortar cement sand water concrete
cement sand agg water
Polymers long continuous chain molecules special below MP, chain flexible but
not stretched easily, below glass transition point, chain locked & rigid
thermoplastic (polyethylene, polystyrene, PVC) soft when heat, hard when cool
thermosetting (epoxy, phenolics, polyester resins) permanent hard epoxy
strength & moduli vary w T & formulation, brittle, high tensile & compressive
strength, high resistant to chemical & wear, excellent adhesion, thermal coefficient
> concrete disadv. Sensitive to mixing, cannot use in moist cond, strong odor,
strong allergenic app adhesive old to new concrete, patch voids, durable overlays
& coatings polyester adv. good chemical resist, easy, > strength, > ductility,
inexpensive disadv. Have marginal bond quality, > expansion & shrinkage than
concrete app floor coating, protective coating, sealer for epoxy injection, binder
for polymer mortar methyl methacrylate MMA low viscosity, high strength adv.
Rapid strength, easy to mix, impermeable to H20, resist acid, abrasion resist disadv
expensive, fire hazard, odor, > shrinkage app pavement of bridge decks,
impregnation, precast element Polystrene adv water resist, dimensional stable,
cheap disadv low tensile, low modulus, poor heat resist brittle, poor weather resist
PVC adv excellent insulator, diverse app, chemical resist, long term stability, flame
resist, weather resist, glass adhesive, oil resist disadv low modulus, moisture
sensitive in production app pipe, raincoat, window frame & molding, electric cable,
floor tile, siding fiber reinforced plastic for structural shape, repair materials or
reinforcement for concrete, composite material w artificial fiber in a resin matrix
( consist fiber & resin types), high tensile, low moduli, linear stress-strain
relationship (plasticity, elastic limit, will return original point) app reinforcement
bars, prestressing tendons, frp sheet to increase flexural strength in under-designed
member adv will not corrode, lightweight, strong in tension, method of construction
same as steel reinfor disadv low moduli of elasticity, cannot be shape at field, more
exp, diff coefficient of thermal expansion from steel