comp Ai Bi Ci T=conte Pi

benceno 13.7819 2726.81 217.572 90 136.49678358

etieno 13.9726 3259.93 212.3 24.260321206

160

140

120

100

80

60

40

20

0
0 0.2 0.4 0.6 0.8 1 1.2

46.70761368 Yi
 Xi P Yi
0 24.2603212 0
0.1 35.4839674 0.38467171
0.2 46.7076137 0.58447338
0.3 57.9312599 0.70685559
0.4 69.1549062 0.78951323
0.5 80.3785524 0.8490871
0.6 91.6021986 0.89406228
0.7 102.825845 0.92921919
0.8 114.049491 0.9574565
0.9 125.273137 0.98063406
1 136.496784 1

1.2
comp Ai Bi Ci T=conte Pi
benceno 13.7819 2726.81 217.572 90 136.496784
etieno 13.9726 3259.93 212.3 24.2603212

T Pi de sat P2 de sat X1 Y1
76.1991 89.9999652 14.4830745 1.00000046 1.00000007
80 101.328714 16.7754147 0.86601689 0.97502642
85 117.895318 20.236352 0.71435989 0.93577429
90 136.496784 24.2603212 0.58572479 0.88832834
95 157.294203 28.9133064 0.47582386 0.83160372
100 180.452793 34.2656498 0.38125343 0.76442497
105 206.141423 40.3920162 0.29929509 0.68552351
110 234.532148 47.3713357 0.2277649 0.59353547
115 265.799729 55.2867227 0.16489849 0.48699972
120 300.121145 64.2253746 0.10926277 0.36435631
125 337.675121 74.2784502 0.05968773 0.22394513
130 378.641653 85.54093 0.01521344 0.06400491
131.8362 394.578734 90.0000176 -5.791E-008 -2.539E-007
 Chart Title
1.2

0.8

0.6

0.4

0.2

0
70 80 90 100 110 120 130 140
-0.2

X1 Y1
130 140
comp Ai Bi ci P sat
90
acetonitrilo 14.2724 2945.47 224 83.2068575
nitrometano 14.2043 2972.64 209 41.9827049 80

70
temperatura 75
60

xi Pi yi 50
0 41.9827049 0
40
0.1 46.1051202 0.18047205
0.2 50.2275354 0.33131969 30
0.3 54.3499507 0.4592839 20
0.4 58.472366 0.56920466
10
0.5 62.5947812 0.66464692
0.6 66.7171965 0.74829455 0
0 0.1 0.2 0
0.7 70.8396117 0.82220666
0.8 74.962027 0.88798941
0.9 79.0844422 0.94691408
1 83.2068575 1

comp Ai Bi ci P sat T sat 1

acetonitrilo 14.2724 2945.47 224 70 69.8445717
nitrometano 14.2043 2972.64 209
1.97390258

88

83

78

73

68
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
73

68
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9
 90

80

70

60

50

40

30

20

10

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

T sat 2 tempe P sat 1 P sat 2 xi yi

89.5835974 69.8445717 70 34.5959784 1 1
71.8184742 74.8421755 37.2880037 0.87106158 0.93131634
73.7923768 79.9483812 40.1474845 0.7500463 0.85664268
75.7662794 85.3287655 43.1819929 0.63630037 0.77563893
77.740182 90.9936684 46.3992915 0.52923059 0.6879519
79.7140845 96.9536191 49.8073318 0.42829816 0.5932151
81.6879871 103.219332 53.4142529 0.33301316 0.49104852
83.6618897 109.801705 57.22838 0.24292966 0.38105844
85.6357923 116.711812 61.2582224 0.15764133 0.26283722
87.6096949 123.960906 65.5124718 0.07677756 0.13596308
89.5835974 131.560406 70 0 0

4 0.5 0.6 0.7 0.8 0.9 1

4 0.5 0.6 0.7 0.8 0.9 1
comp A B C temp
metano 16.59158 3643.31 33.424 318.15
acetato de metilo 14.25326 2665.54 53.424

comp A B C temp
metano 16.59158 3643.31 33.424 318.15
acetato de metilo 14.25326 2665.54 53.424

comp A B C xi
metano 16.59158 3643.31 33.424 0.85
acetato de metilo 14.25326 2665.54 53.424 0.15

101.33
comp A B C yi
metano 16.59158 3643.31 33.424 0.4
acetato de metilo 14.25326 2665.54 53.424 0.6
P sat s x1 yy P sist yi
44.5109029 1.1070755 0.25 1.86400979 20.742189722 0.2822054894
65.6414575 0.75 1.07164218 52.758115904 0.7177945106
73.500305626

P sat a yi g sup g2 sup y1/g1*Psat

44.5109029 1.1070755 0.6 1 1 0.0134798434
65.6414575 0.4 1.11326866 1.6905575251 0.0121083471
1.0599902 1.9297812001 0.0127169509
1.0447777 2.0349074734 0.0129021162
1.04006785 2.0735544867 0.0129605423
1.03854712 2.0868217358 0.0129795203
1.03804793 2.0912685735 0.012985762
1.03788311 2.0927470524 0.0129878242
1.03782858 2.0932372945 0.0129885066
1.03781053 2.0933997066 0.0129887325
1.03780456 2.0934534961 0.0129888073
1.03780258 2.093471309 0.012988832
1.03780192 2.0934772077 0.0129888402
1.03780171 2.0934791611 0.012988843
1.03780163 2.0934798079 0.0129888439
1.03780161 2.0934800221 0.0129888441
1.0378016 2.093480093 0.0129888442
1.0378016 2.0934801165 0.0129888443
1.0378016 2.0934801243 0.0129888443
1.0378016 2.0934801269 0.0129888443
1.0378016 2.0934801277 0.0129888443
1.0378016 2.093480128 0.0129888443
1.0378016 2.0934801281 0.0129888443
1.0378016 2.0934801281 0.0129888443
1.0378016 2.0934801281 0.0129888443
1.0378016 2.0934801281 0.0129888443
1.0378016 2.0934801281 0.0129888443
1.0378016 2.0934801281 0.0129888443
1.0378016 2.0934801281 0.0129888443

T sup a yy1 P sat y1

331.201142 1.03881803 1.0236487 77.9882055 0.6696698578
2.11815627 105.350621 0.3303302245
1.0000000823
P
101.33

T sup P sat 1 P sat 2 a b1 SPU b2 SUP

330 74.217902 101.050431 1.0451 1 1
329 71.196518 97.5775065 1.05033 1.459831017 1.459831017
330 74.217902 101.050431 1.0451 1.2097147712 1.172266761
331 77.3458969 104.620596 1.03987 1.3169265086 1.2373791879
332 80.583438 108.2899 1.03464 1.2592465146 1.1799642028
333 83.9335154 112.060258 1.02941 1.2669398487 1.1814475113
334 87.3991742 115.933603 1.02418 1.2465706689 1.1639678416
333 83.9335154 112.060258 1.02941 1.2363289524 1.1556300279
332 80.583438 108.2899 1.03464 1.2590455003 1.1728615208
331 77.3458969 104.620596 1.03987 1.2705867316 1.1815104209
330 74.217902 101.050431 1.0451 1.2876631055 1.1945565337
329 71.196518 97.5775065 1.05033 1.3035907255 1.2068200448
328 68.2788639 94.1999403 1.05556 1.3212540287 1.2205741697
327 65.4621128 90.915869 1.06079 1.339394852 1.2348681043
326.662771 64.5344849 89.8291407 1.06255371 1.3586474878 1.250239231
325.662771 61.8483392 86.6672113 1.06778371 1.3583597784 1.2502392379

resta 6.9197E-009
y2/g2*Psat P sistem x1 x2 g1 g2
0.00609371 51.0893442 0.68867636 0.31132364 1.11326866 1.69055753
0.00360456 63.6419615 0.77059896 0.22940104 1.0599902 1.9297812
0.00315772 62.9934294 0.80108435 0.19891565 1.0447777 2.03490747
0.00299459 62.9061202 0.81162207 0.18837793 1.04006785 2.07355449
0.00293877 62.8957826 0.81516345 0.18483655 1.03854712 2.08682174
0.00292009 62.8946185 0.81634197 0.18365803 1.03804793 2.09126857
0.00291388 62.8944897 0.81673288 0.18326712 1.03788311 2.09274705
0.00291182 62.8944755 0.81686239 0.18313761 1.03782858 2.09323729
0.00291114 62.894474 0.81690529 0.18309471 1.03781053 2.09339971
0.00291092 62.8944738 0.81691949 0.18308051 1.03780456 2.0934535
0.00291084 62.8944738 0.8169242 0.1830758 1.03780258 2.09347131
0.00291082 62.8944738 0.81692576 0.18307424 1.03780192 2.09347721
0.00291081 62.8944738 0.81692627 0.18307373 1.03780171 2.09347916
0.00291081 62.8944738 0.81692644 0.18307356 1.03780163 2.09347981
0.0029108 62.8944738 0.8169265 0.1830735 1.03780161 2.09348002
0.0029108 62.8944738 0.81692652 0.18307348 1.0378016 2.09348009
0.0029108 62.8944738 0.81692652 0.18307348 1.0378016 2.09348012
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348012
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
0.0029108 62.8944738 0.81692653 0.18307347 1.0378016 2.09348013
x1 X2 SUMA b1 real b2 real
0.54612161 0.60165997 1.14778158 1.45983102 1.45983102
0.38997493 0.42681236 0.8167873 1.20971477 1.17226676
0.45144659 0.51324493 0.96469152 1.31692651 1.23737919
0.39792316 0.46964456 0.86756772 1.25924651 1.1799642
0.39943074 0.47580884 0.87523958 1.26693985 1.18144751
0.38115939 0.45922259 0.84038198 1.24657067 1.16396784
0.37202644 0.45054583 0.82257227 1.23632895 1.15563003
0.39059671 0.4694819 0.86007861 1.2590455 1.17286152
0.39949451 0.47869027 0.87818478 1.27058673 1.18151042
0.41243588 0.49185212 0.904288 1.28766311 1.19455653
0.42411839 0.50366806 0.92778646 1.30359073 1.20682004
0.43671491 0.51629398 0.95300889 1.32125403 1.22057417
0.44928862 0.52877935 0.97806798 1.33939485 1.2348681
0.46227392 0.54153811 1.00381203 1.35864749 1.25023923
0.46227392 0.54135098 1.0036249 1.35835978 1.25023924
0.48245319 0.56110139 1.04355458 1.38962485 1.2753984
comp A B C temp a
metano 16.59158 3643.31 33.424 318.15 1.1070755
acetato de me 14.25326 2665.54 53.424
P sat xi xi alfa 1-2, x1=0 alfa 1-2, x1=1 b1az/b1az
44.5109029 0 1 2.0515635281 0.2241255706 1.47472761
65.6414575 1 0
ln(b1az/b1az) x1 x2 b1az P az
0.3884733009 0.32454977 0.67545023 1.65712536 73.7601461
comp P sat T P zi xi
acetona 195.75 80 110 0.45 0.45
acetonitrilo 97.84 0.35 0.35
nitrometano 50.32 0.2 0.2
burb P yi=zi yi/Pi sat dew p ki yi
88.0875 0.45 0.00229885 101.51581 1.77954545 0.5087154266
34.244 0.35 0.00357727 0.88945455 0.3389022104
10.064 0.2 0.00397456 0.45745455 0.1523823629
132.3955 0.9999999999

7.9830E-011
V xi
0.73652164 0.28586818
0.38102252
0.3331093
1
comp A B c xi T
benceno 13.7819 2726.81 217.572 0.33 100
tolueno 13.932 3056.96 217.625 0.67

comp A B c yi T
benceno 13.7819 2726.81 217.572 0.33 100
tolueno 13.932 3056.96 217.625 0.67

comp A B c xi T
benceno 13.7819 2726.81 217.572 0.33 103.306836
tolueno 13.932 3056.96 217.625 0.67

A B c yi T
13.7819 2726.81 217.572 0.33 109.130891
13.932 3056.96 217.625 0.67

A B c xi T
13.7819 2726.81 217.572 0.28177497 105
13.932 3056.96 217.625 0.71822503
1
Psat P yi
180.452793 59.5494215 0.5448083332
74.2597197 49.7540122 0.4551916668
109.303434 1

P sat P x1
180.452793 0.00182873 0.1685294188
74.2597197 0.00902239 0.8314705812
92.1563765

Psat P yi
197.148486 65.0590003 0.5421583358
82.0014921 54.9409997 0.4578416642
120 1

P sat P x1
229.395594 0.00143856 0.1726275532
97.1750999 0.00689477 0.8273724468
120

Psat P yi zi V Ki
206.141423 58.085494 0.4840457836 0.33 0.2374371 1.71784519
86.2048853 61.914506 0.5159542164 0.67 L 0.71837404
120 1 0.7625629
y1
0.48433702
0.51580145
1.00013847
comp A B c T Psat
benceno 13.7819 2726.81 217.572 90 136.496784
etilbenceno 13.9726 3259.93 212.3 24.2603212

160
xi P yi
0 24.2603212 0 140
0.1 35.4839674 0.38467171
120
0.2 46.7076137 0.58447338
0.3 57.9312599 0.70685559 100
0.4 69.1549062 0.78951323
0.5 80.3785524 0.8490871 80

0.6 91.6021986 0.89406228 60

0.7 102.825845 0.92921919
0.8 114.049491 0.9574565 40
0.9 125.273137 0.98063406
20
1 136.496784 1
0
0 0.1 0.2 0

comp A B c P Ti sat
benceno 13.7819 2726.81 217.572 90 76.1991122
etilbenceno 13.9726 3259.93 212.3 131.836193
160

140

120

100

80

60

40

20

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

T Psat 1 Psat 2 x1 y1
76.1991122 90 14.4830815 1 1
78 95.2366102 15.5347401 0.93429752 0.98865921
83 111.033365 18.7879616 0.77198468 0.95240063
88 128.801801 22.5790446 0.63471291 0.90835741
93 148.701234 26.9722259 0.5177712 0.85548018
98 170.895285 32.0361072 0.41742932 0.79263004
103 195.55142 37.84363 0.33071524 0.71857595
108 222.840477 44.4720268 0.25524678 0.63199239
113 252.936191 52.0027493 0.18910367 0.53145735
118 286.014713 60.521375 0.13072947 0.41545058
123 322.254127 70.1174942 0.07885608 0.28235218
128 361.833975 80.8845764 0.03244507 0.13044144
131.836193 394.578671 90 0 0
 140

130

120

110

100

90

80

70
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
 140

130

120

110

100

90

80

70
0.8 0.9 1
comp A B c T Psat
pentano 13.7667 2451.88 234.014 55 196.979001
heptano 13.8622 2910.26 216.432 23.1113747

comp A B c T Psat
benceno 13.7819 2726.81 217.572 134.100354 414.910703
etilbenceno 13.9726 3259.93 212.3 95.7486241
P sis
207.455352

comp A B c T Psat
benceno 13.7819 2726.81 217.572 111.87675 245.92171
etilbenceno 13.9726 3259.93 212.3 50.2280416
P sis
118.720826

comp A B c T Psat
benceno 13.7819 2726.81 217.572 91.4394888 142.252018
etilbenceno 13.9726 3259.93 212.3 25.5324136
P sis
66.3842753

comp A B c T Psat
benceno 13.7819 2726.81 217.572 72.4274423 79.7653192
etilbenceno 13.9726 3259.93 212.3 12.4696746
P sis
36.0231502
P x1 yi ki V
110.045188 0.5 0.89499143 1.78998287 0.2
0.5 0.10500857 0.21001713

x1 real y1 y1 X1
0.35 0.7 0.7 0.35 3.0909E-010
0.65 0.3 0.3 0.65

x1 real y1 y1 X1
0.35 0.725 0.725 0.35 5.0117E-011
0.65 0.275 0.275 0.65

x1 real y1 y1 X1
0.35 0.75 0.75 0.35 1.0850E-011
0.65 0.25 0.25 0.65

x1 real y1 y1 X1
0.35 0.775 0.77499779 0.350001 9.9920E-007
0.65 0.225 0.22500221 0.64999361
comp A B c zi T
benceno 13.7819 2726.81 217.572 0.33333333 110
tolueno 13.932 3056.96 217.625 0.33333333 P sis
etilbenceno 13.9726 3259.93 212.3 0.33333333 90
1 V sup
0.83552799

comp A B c zi T
benceno 13.7819 2726.81 217.572 0.33333333 110
tolueno 13.932 3056.96 217.625 0.33333333 P sis
etilbenceno 13.9726 3259.93 212.3 0.33333333 100
1 V sup
0.57504122
Psat Ki yi xi
234.532148 2.60591276 0.37092968 0.14234156
99.6169485 1.10685498 0.3387114 0.30601244
47.3713357 0.52634817 0.29035863 0.55164746
0.99999971 1.00000146

Psat Ki yi xi
234.532148 2.34532148 0.44077982 0.18794004
99.6169485 0.99616949 0.33278953 0.33406919
47.3713357 0.47371336 0.22643063 0.4779908
0.99999998 1.00000003
comp A B c T Psat
benceno 13.7819 2726.81 217.572 100 180.452793
etilbenceno 13.9726 3259.93 212.3 P sis 34.2656498
75.99375
V sup
0.54683341

R 0.74129351

comp Psat T xi b1 P bubl

etanoato de etilo 79.8 70 0.05 2.35696553 9.40429247
n-heptano 40.5 0.95 1.00237782 38.5664867
47.9707792

comp Psat T yi b1 P dew

etanoato de etilo 79.8 70 0.05 2.35696553 0.00026584
n-heptano 40.5 0.95 1.00237782 0.02340115
42.2529574

dos casos
comp Psat T xi xi alfa x1=0
etanoato de etilo 79.8 70 0 1 5.0948057
n-heptano 40.5 1 0

comp Pi sat xi b1 P sis yi

especie 1 124 0.59211071 1.3491471 99.0567111 0.59212197
especie 2 89 0.40788929 1.87962289 68.2343462 0.40787803
167.291057 1

comp Pi sat T xi b1/b2 ln(b1/b2)

ciclohexano 75.2 144 0.6 2.37523689 0.86509718
fenol 31.66 0.4
zi Ki yi Xi P
0.5 2.37457413 0.6778056216 0.28544302 51.508991
0.5 0.45090089 0.3221943784 0.71455698 24.484759
1 1 75.99375

yi
0.1960421037
0.8039578963
1

xi
0.0112323595
0.9887676405
1

alfa x1=1 b1az/b2az ln(b1az/b2az) xi az b1 az

0.7620230536 0.5075188 -0.6782215303 0.8569587 1.01962792
0.1430413

-1.12649E-005

A b1 P yi
2.0997504284 1.39928315 63.1356556505 0.70069555
2.12954886 26.9686067564
90.104262407
2.0997504284
3.055334E-011

Paz yi
81.366307719 0.8569587
comp Pi sat xi bi P sis
etilo 79.8 0.05 2.35696553 9.40429247
heptano 40.5 0.95 1.00237782 38.5664867
47.9707792

comp Pi sat T yi xi bi
etilo 79.8 343.15 0.05 0.01042712 2.53524873
heptano 40.5 0.95 0.98957288 1.00010329

comp Pi sat T
etilo 79.8 343.15
heptano 40.5
yi
0.1960421
0.8039579

P xi
0.00024714 0.01042727 -1.435E-007
0.02345437 0.98957273 1.4347E-007
42.1914057 1
comp fi moles Ai Bi T P sat
etano 10 817.08 7.277361 373.15 122371.016
propano 20 1051.38 7.392262 37556.2255
butano 80 1267.56 7.492753 12469.0932
2 metil propano 90 1183.44 7.349085 15052.1661
200
Zi=yi yi
0.05 0.05
0.1 0.1
0.4 0.4
0.45 0.45
comp A B c T xi
n-butano 13.6608 2154.7 238.789 95 0.25
n-hexano 13.8193 2696.04 224.317 0.75

P bar 4.92331231 71.4065799

Psat P yi ki zi V
1346.85074 336.712685 0.67497157 2.69988628 0.5 0.58827465
216.189245 162.141934 0.32502843 0.43337124 0.5 0.58827465
498.854619
L
0.41172535
0.41172535
comp masa(g) PM n moles fraccion molar xi
nitrogeno 2000 28 71.4285714 0.511627907
dioxido de carbono 3000 44 68.1818182 0.488372093
139.61039

presion total atm 3

Temperatura k 303.15
R atm-l/mol-k 0.082
PM promedio P parcial V parcial Volumen total densidad
14.325581395 1.53488372 591.864286 1156.82564935 4.32217249
21.488372093 1.46511628 564.961364
35.813953488
densidad parcila
1.7288689969
2.5933034954